CN108938436A - Washable skin care fabric product - Google Patents
Washable skin care fabric product Download PDFInfo
- Publication number
- CN108938436A CN108938436A CN201810241570.8A CN201810241570A CN108938436A CN 108938436 A CN108938436 A CN 108938436A CN 201810241570 A CN201810241570 A CN 201810241570A CN 108938436 A CN108938436 A CN 108938436A
- Authority
- CN
- China
- Prior art keywords
- skin
- microcapsules
- care layer
- washable
- user
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000004744 fabric Substances 0.000 title claims abstract description 128
- 239000003094 microcapsule Substances 0.000 claims abstract description 120
- 239000000758 substrate Substances 0.000 claims abstract description 62
- 239000004909 Moisturizer Substances 0.000 claims abstract description 17
- 230000001333 moisturizer Effects 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 14
- 238000005406 washing Methods 0.000 claims description 47
- 239000000470 constituent Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 22
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- 125000003118 aryl group Chemical group 0.000 claims description 16
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- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/007—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows comprising deodorising, fragrance releasing, therapeutic or disinfecting substances
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G9/02—Bed linen; Blankets; Counterpanes
- A47G9/0238—Bed linen
- A47G9/0253—Pillow slips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
Abstract
The invention discloses a washable skin care fabric product, which comprises the following components in parts by weight: a fabric base material; and a skin care layer removably disposed on the fabric substrate, wherein the skin care layer comprises microcapsules and the microcapsules comprise at least two active ingredients to improve the skin condition of a user, wherein the active ingredients are selected from the group consisting of: skin moisturizers, skin whiteners, skin anti-aging agents, fragrances, and combinations thereof; wherein the skin care layer is to be placed in direct contact with the skin of a user.
Description
Technical field
The present invention relates to a kind of skin-protection products, particularly but in non-exclusive manner, are related to a kind of skin-protection product comprising activity
Ingredient is to improve the skin of user.The application further relates to a kind of sleep tool packet comprising the skin care used when sleep
Product.
Background technique
External skin-protection product is usually liquid, gel or the emulsion components that can be used together with paper film or paper washer, will
Ingredient is kept on a skin surface.Facial mask is the combined typical example of liquid component and paper film.Generally, due to liquid component
It will evaporate and/or be absorbed by the skin and facial mask is caused to become drying, so facial mask cannot be left on skin surface the long time
On.Facial mask may make to have dry skin in turn, and cause skin irritatin.That is, a facial mask cannot use more than 1 hour
Or overnight.Moreover, some people may think that the quality of liquid and facial mask mixture is not good.Liquid component on facial mask is usually
It is excessive, it is thus possible to be leaked out from facial mask, cause confusion or bother.The leakage of liquid component also leads to the wave of active constituent
Take.
In some cases, it can be protected using the skin care item of gel-like at night in the case where not using solid substrate
Hold skin wet.However, may be stained with everywhere, and be difficult to tidy up if user turns over and rotates in sleep
And arrangement.In this case, most of to be lost at branch due to the movement on head.
Therefore, there is still a need for a kind of improved skin care item, the product can use for a long time, and user is allowed to stop
It is easily used when breath.
Summary of the invention
According to aforementioned, the object of the present invention is to provide a kind of skin-protection products, wherein eliminates aforementioned disadvantage or at least
It provides a kind of for transaction and the useful substitution of the public.
The present invention relates to a kind of washable skin-protecting fabric products.Washable skin-protecting fabric product includes fabric substrate；And it is removable
Except ground is arranged in the skin-care layer on the fabric substrate, wherein the skin-care layer includes microcapsules, and the microcapsules include
At least two active constituents are to improve the skin of user, wherein the active constituent is selected from consisting of the following group: skin
Skin moisturizer, skin whitener, skin anti-aging agent, aromatic and combinations thereof.Skin-care layer will be placed with skin with user
Skin directly contacts.
Specifically, washable skin-protecting fabric product touches that get up be dry during use.Preferably, it is washed at least five
After washing the period, relative to the amount of microcapsules existing before washing, at least 50% microcapsules are present in the shield
In skin layers.
The present invention also provides a kind of sleep tool packets comprising washable skin-protecting fabric product.
Moreover, the present invention relates to a kind of washable masks comprising the detachable skin-care layer with microcapsules；One kind has
The washable pillowcase or clothes of detachable skin-care layer comprising there are the microcapsules of at least two active constituents, wherein institute
Active constituent is stated selected from consisting of the following group: skin moisturizer, skin whitener, skin anti-aging agent, aromatic and its group
It closes.
Without being limited by theory, it is believed that skin-protecting fabric product can be transmitted active constituent with controllable delivery mode,
To improve the skin of user.The shelf-life of the active constituent for including in microcapsules is wrapped in microcapsules with them
It seals and extends, so that the influence of external environment minimizes.Active constituent will be reduced significantly in this way to be lost to the external world.Make
Used time, when the skin surface of microcapsules and user contacts, the mechanical pressure of application or micro- glue when biodegrade occurs
Capsule will rupture.
Without being limited by theory, it is believed that other advantages of skin-protecting fabric product of the invention can be, not to skin
Extend under the premise of damaging and uses skin-protecting fabric product.For example, user can wear or straight with skin-protecting fabric product
The time up to an elongated segment is contacted, especially in rest or travelling.Moreover, the present invention can make in the dry state
With, while improving the health of skin.In other words, very convenient use.
It will be understood to those skilled in the art that the present invention described herein can be into addition to those of being expressly recited
Row various modifications and variations.The present invention includes all these modifications and variations.The invention also includes in the description refer to or
Any or all group of all steps and feature or these steps or feature of the individual perhaps combination of person's instruction
It closes.
By considering that description and accompanying drawings, other features of the invention and aspect will be apparent in greater detail below.
Detailed description of the invention
Fig. 1 is the embodiment of eyeshade of the invention；
Fig. 2 shows the sectional view of the eyeshade of Fig. 1 along line A-A observation；
Fig. 3 shows the embodiment of the pillow of the pillowcase with the application；
Fig. 4 shows the sectional view of the pillow of Fig. 3 along line B-B；
Fig. 5 A is the complete microcapsules that display is attached on the skin-care layer of the fabric product in the application embodiment
Microgram；
Fig. 5 B is the microcapsules for the rupture that display is attached on the skin-care layer of the fabric product in the application embodiment
Microgram；
Fig. 6 is the schematic diagram of the embodiment of the dipping process for being attached to microcapsules on fabric substrate；
Fig. 7 is an embodiment of eyeshade of the invention；
Fig. 8 is an embodiment of eyeshade and its ornament of the invention.
Specific embodiment
Unless otherwise defined, otherwise all technical terms used herein have and those skilled in the art in the invention
Normally understood identical meaning.
Include following element but be not excluded for other elements as it is used herein, "comprising" means." substantially by ... group
At " refer to material by corresponding element and usually and inevitable impurity, such as usually by the various preparations of acquisition material
Or the by-product and group of method (such as tracing into other components or solvent) generation are grouped as." consist of " means material
It is only made of, i.e., is made of corresponding element corresponding element.As it is used herein, unless the context clearly indicates otherwise,
Form " one ", "one" and " described " are intended to include odd number and plural form.
The present invention provides a kind of washable skin-protecting fabric products, with fabric substrate；And it is arranged on fabric substrate
Skin-care layer.Skin-care layer includes the microcapsules of active ingredient, preferably at least two kinds of active components, to use for improving
The skin of person.Particularly, when in use, skin care is placed on the direct skin contact with user, at the time of contact will
Active constituent is effectively discharged into user.
Statement " washable " used herein means that: skin-protecting fabric product can be subjected to washing at least once.At this
In invention, skin-protecting fabric product is dry when in use, that is, it is dry for waiting touch when in use to get up, and can be washed, with
Removal bonds any dust thereon or is not intended to existing pollutant.If the skin-care layer of skin-protecting fabric product is also subjected to washing
When washing, at least part of microcapsules keeps complete after wash in skin-care layer.In one embodiment, relative to
Existing microcapsules before first washing cycle are washed at least five washing cycle, at least ten washing cycle, at least 15
After washing period, at least 20 washing cycles, at least 25 washing cycles or at least 30 washing cycles, microcapsules are at least
About 50%, about 60%, about 70%, about 80%, about 90%, to about 100% keep complete on skin-care layer.
Particularly, relative to microcapsules existing before first washing cycle, after at least five washing cycle,
The microcapsules of about 75% to about 100% can be kept completely on skin-care layer, after at least ten washing cycle, about 50% to
About 85% microcapsules can be kept completely on skin-care layer, after at least 15 washing cycles, about 35% to about 70%
Microcapsules can be kept completely on skin-care layer, and after at least 20 washing cycles, the microcapsules of about 15% to about 50% can
To keep complete on skin-care layer, or after at least 30 washing cycles, the microcapsules of about 3% to about 30% can protected
It is kept in skin layers complete.
It will be appreciated by those of skill in the art that the amount for determining the microcapsules on skin-protecting fabric product can be executed
Method and condition, for example, the quantization under electron microscope.It is, for example, possible to use the amplifications of 40x, 10x, 400x or 1000x
Rate determines the amounts of microcapsules, and average-size is from about 1 μm to about 50 μm, or from about 1 μm to about 25 μm.
Determine 50cm2Skin-care layer sample on wherein microcapsules average diameter be 5 μm the amounts of microcapsules include
Following steps:
Three points on skin-care layer are randomly choosed, under an electron microscope with the power view of 400x,
The point is marked, so that they can be found again later；
Before washing, the number of complete microcapsules is counted in three points showing in field of microscope；
After wash, the number of complete microcapsules is counted in three points；And
The complete microcapsules retained on skin-care layer are calculated relative to existing complete before first washing cycle
Microcapsules ratio；
It is understood that in order to preferably observe microcapsules and count for convenience, adjustable magnifying power.
Alternatively, smell tracker can also be applied to microcapsules, so that user can simply smell, and
Determine whether microcapsules are still present on skin-protecting fabric product after wash.It is provided using smell tracker for true
Determine the existing simple and direct method of microcapsules.
" skin care " means to adjust and/or improve skin as used in this article.Skin-protecting fabric provided by the invention
Product can adjust and/or improve the skin of user, especially reach when skin-care layer is contacted with the skin of face of user
When certain time.Skin-protection product is dry when in use, and user is allowed to be in contact with it up to the extended period, such as but
It reaches at least 30 minutes in non-exclusive manner, or at least 1 hour, without being damaged to skin.In one embodiment, make
User wears skin-protecting fabric product as eyeshade in rest or during sleep.It is very advantageous that without excessive slush pulp
It is leaked from skin-protecting fabric product, and user will not be allowed to feel moist and be difficult to deal with.The work contained in microcapsules
Property ingredient can be easy to be absorbed by the skin in microcapsules rupture.
Therefore, in embodiment herein, skin-protecting fabric product of the invention is referred to comprising fiber or by fiber
Manufactured product, and skin that is adjustable and/or improving user.For example, still in non-exclusive manner, fabric product
It can be facial mask, clothes, pillow, pillowcase, ornament, gloves, socks, scarf, towel etc..
The fabric substrate used in this application includes the combination of natural fiber, synthetic fibers or both.Herein
In embodiment, fabric substrate is made of natural fiber (for example, silk), to provide suitable comfort to user.Another
In one embodiment, fabric substrate can be made of the combination of synthetic fibers or natural fiber and synthetic fibers.Specific real
It applies in mode, fabric substrate includes fiber, which is selected from: silk, cotton, polyester, nylon, tencel, artificial silk, wool, sheep
Suede and combinations thereof；Or silk, cotton, wool, cashmere and combinations thereof.It in this application can be available in the market using other
Natural fiber or synthetic fibers, with give skin-care layer provide support.
It includes the layer being arranged on fabric substrate with microcapsules that skin-care layer used herein, which refers to,.Reality herein
Apply in mode, which can for example form in the following manner: on fabric substrate spread, coat or rolling or
Person is included in microcapsules in fabric substrate.In another embodiment, skin-care layer can be for certain thickness separation
Precoat, to be physically directly or indirectly attached on fabric substrate.In a specific embodiment, microcapsules by using
Adhesive and be attached on fabric substrate, directly to form skin-care layer on fabric substrate.Adhesive is that can protect microcapsules
Hold the substrate on fabric substrate.Adhesive used herein for example can be but in non-exclusive manner be acrylic acid, poly- ammonia
Ester, silicone resin or combinations thereof.
In another embodiment, skin-care layer is prepared in the following manner: by that will have certain thickness fabric substrate
It being impregnated into the bathtub including microcapsules and adhesive, the isolated skin-care layer for being impregnated with microcapsules will be formed later, and
It can be removably attached to fabric substrate ready for use.
The microcapsules of the application will at least two kinds of active components be encapsulated wherein, for improving skin.It is managed not
By under limitation, it is believed that using microcapsules can be effectively protected active constituent from or utmostly reduce by not expecting
External factor caused by effect, for example, too high moisture, evaporation, heat, oxidation, ultraviolet light, sunlight etc..Therefore, compared to
Liquid or existing skin-protection product paste, the shelf-life of the skin-protection product can extend.
In the present invention, the average diameter that microcapsules can have is from about 1 μm to about 25 μm, or the μ from about 2 μm to about 15
M, perhaps from about 3 μm to about 10 μm or from about 5 μm to about 8 μm or about 5 μm.Those skilled in the art is, it is realized that for example
The average diameter of microcapsules and the method and condition of particle size distribution are determined by laser diffraction method.In general, microcapsules packet
It includes polymeric shells and keeps at least two active constituents and selectively keep the chamber of auxiliary material.Microcapsules are easy by machinery
Active constituent to be discharged into the skin of user by least one of pressure and biodegrade.That is, be pressed when microcapsules or
When person they and user contacting with enzyme, protein or other matter interactions, they can rupture with discharge activity at
Point.In a specific embodiment, microcapsules are easy by enzymatic degradation.
" active constituent " used herein refer to compound perhaps substance its when with the skin contact of user or set
The skin that is adjustable and/or improving user when close to the skin of user.In one embodiment, activity at
It is selected from consisting of the following group: skin moisturizer, skin whitener, skin anti-aging agent, aromatic and combinations thereof.Herein
In embodiment in, microcapsules include at least two active constituents, or kind of the active constituent from 2 to 20；Or 2 to 10 kinds of activity
Ingredient；Or kind of the active constituent from 2 to 4.
Skin moisturizer (also referred to as moisturizer) is the substance for capableing of water lock, and usually, to be hydrophilic,
And hydrogen bond can be formed with water.Skin moisturizer attracts moisture by the air near such as absorbing, and can pass through
It forms hydrogen bond and absorbs hydrone.Hydrone can also be retained in use by forming barrier layer on a user's skin by it
On the skin of person, to prevent water point from evaporating from skin.Skin moisturizer of the invention can be selected from consisting of the following group: the third three
Alcohol, glycerol, urea, glycerol triacetate, caprylic/capric triglyceride, cetearyl ethylhexanoate, palm acid ethyl oneself
Ester, hyaluronic acid and its salt, butanediol, pentanediol, coconut oil sucrose, sher butter, dimetylsilyl silica,
Sorbitan isostearate, shea butter (missible oil wood (Butrospermum parkii)), d- panthenol (vitamin
B5), Phenoxyethanol, methyl p-hydroxybenzoate, methylchloroisothiazandnone, dimethicone, cyclohexyl methyl and combinations thereof；Or
Person can be selected from glyceryl triacetate, octanoic acid/Trivent OCG, ethylhexyl palmitate, butanediol and combinations thereof；Or it can
To be selected from octanoic acid/triglyceride, ethylhexyl palmitate, butanediol and combinations thereof.
Skin whitener be compound perhaps substance its can prevent or reduce to form melanin, and/or will be on skin
Excessive pigmentation removal.Skin whitener can be selected from consisting of the following group: hydroquinone or derivatives thereof, vitamin
C, ascorbic acid, ascorbyl palmitate, Sodium Ascorbyl Phosphate, magnesium ascorbyl phosphate, green-tea extract, take off it is black swash
Element, azelaic acid, kojic acid (tripeptides), arbutin, biostearin or retinoic acid, mequinol, Nicotinic Acid Amide, glycyrrhiza glabra, A Suo
Pungent, glutathione, glycolic, hydroxyacetic acid or 2- hydroxyacetic acid, Aloesin, hydroquinone single-benzyl ether, extract of soybean,
Corticosteroid, acetylglucosamine, gentianic acid, Tretinoin, 'alpha '-hydroxy acids, salicylic acid, linoleic acid, 18 carbon diacid, palm
Acid, stearic acid, arbutin/deoxyarbutin, pearl powder, retinyl palmitate and combinations thereof；Or it can be extracted selected from green tea
Object, melatonin, glycolic, hydroxyl stibene, glutathione and combinations thereof.
Skin anti-aging agent refer to compound perhaps substance its can reduce or eliminate aging effect.Usually, skin
Skin antidotal agent has anti-oxidation characteristics, and postpones skin by reducing free radical or removing free radical from subject
Aging.Skin anti-aging agent can be selected from consisting of the following group: ubiquinone, caprylic/capric triglyceride, D-α-tocopherol acetate, life
Educate phenol, vitamin E, palmityl tripeptides -38, palmityl peptide complexes, geranylgeranyl group isopropanol, benzyl salicylate, transparent
Matter acid sodium, knotweed flavones, high mallow extract, lactose-ceramide, biological peptide, hyaluronic acid, carboxylic acid, glycoprotein, coenzyme
Q10 (there is vitamin E and C), Ceramide Complex, beta glucan, Argireline NP, carrot cell extract, 'alpha '-hydroxy acids
(AHA), beta-hydroxy acid (BHA), glycine, niacinamide, resveratrol, grape seed extract, curcuminoids, acetyl group hexapeptide-
3, palmityl-pentapeptide 3, palmityl-tripeptides, palmityl-oligopeptides, kojic acid and combinations thereof；Or caprylic/capric can be selected from
Triglycerides, acetic acid lycopene, tocopherol, palmityl tripeptides, geranylgeranyl group isopropanol and combinations thereof；Or it can select
From acetic acid tomato grass ester, tocopherol, palmityl tripeptides, geranylgeranyl group isopropanol and combinations thereof.
Aromatic refer to compound perhaps substance its be rich in or be substantially made of aromatic molecule and in subject
It is upper that there is therapeutic effect.Aromatic can ease off the pressure and subject is promoted to sleep.It can also alleviate skin, mitigate
Respiratory disorder, the growth for inhibiting bacterium and/or promotion wound healing.Essential oil has become the main source of aromatic.Aromatic
Some examples are lavender oil, citronellol, grape seed oil, jojoba oil, lemongrass oil, attar of rose, bergamot oil, terpinene-
4- alcohol, sage oil, pot marigold seed oil, sunflower oil, camellia oil, Ma Lula oil, Flos Rosae Multiflorae seed oil, avocado oil, Sweet Almond Oil, nut
Oily, wild orange oil, oil of grapefruit, oil of chamomile, cinnamon oil, ginger oil, sage oil, thousand layers of oil, eucalyptus oil, rosemary oil, cypress
Tree oil and tea oil；Or lavender oil, attar of rose, terpinene-4-alcohol, pot marigold oil and combinations thereof can be selected from；Or it can
To be selected from lavender oil, terpinene-4-alcohol, pot marigold oil and combinations thereof.
It is understood that can also use in the present invention, other are available in the market, help to improve one
Or the reagent of multiple skins.
In improved embodiment, microcapsules can also include the extract obtained from plant, fungi or algae, can
To improve skin in a manner of cooperateing with or add with mentioned reagent.Such as but be not limited to, plant or fungi are extracted
Object can be obtained from following: ansu apricot, rosemary, lavender, shaggy portulaca, sunflower, extra large cabbage mustard, Crithmum maritimum, aspergillus oryzae, light
Fruit Radix Glycyrrhizae, black bearberry, emblic, acrophyta, Bai Sang, garden sorrel essence, pomegranate, aloe, raspberry, grape pip, witch hazel, golden small cup
Flower, olive, grape fruit, fructus rosae, dessert almond, Avocado Oil, vinifera, Jojoba, soybean, missible oil wood, carrot or high mallow.
Algae extract can be obtained from brown alga, such as, but not limited to wing algae (Alaria esculenta), Laminaria digitata
(Laminaria digitate) and membranaceous entoilage algae (Dictyopteris membranace).
In an embodiment of the invention, microcapsules include at least two active constituent as described above.At one
In specific embodiment, microcapsules include at least three kinds of active constituents as described above, and such as, but not limited to: microcapsules include skin
Skin moisturizer, skin anti-aging agent and aromatic；Or including skin moisturizer, skin anti-aging agent and skin whitener；Or skin
Skin moisturizer, skin whitener and aromatic.In another embodiment, microcapsules include that skin moisturizer, skin are anti-ageing
Old agent, skin whitener, aromatic.In another embodiment, microcapsules may include more than one antidotal agent, a kind of
Above skin moisturizer, more than one aromatic, plant extracts and algae extract.Based on the present invention, it will be understood that
The various combinations of above-mentioned active constituent are equally applicable to the present invention.
Multiple embodiments are gone to, Fig. 1 to Fig. 2 shows washable skin-protecting fabric product according to the present invention, specifically
Eyeshade 100.Eyeshade 100 includes fabric substrate 102, with elastic ribbon 104.Fabric substrate 102 includes natural fiber, and
In this specific embodiment, fabric substrate 102 is substantially made of silk, is provided to user enough flexible and easypro
Adaptive.Elastic ribbon 104 can be wrapped up by silk or other fabrics.Eyeshade 100 further includes the rear side in fabric substrate 102
On the separation skin-care layer 106 that is removably attached, so that skin-care layer 106 is when in use towards user.
Skin-care layer 106 is impregnated with microcapsules (see 400 in Fig. 5 A) comprising at least active constituent.Microcapsules are activating
When can discharge active material to user, for example, through mechanical pressure or biodegrade.Micro- glue in the present embodiment
Capsule discharge active component can reach the extension period in a controlled manner, and be easy to be subjected to the mechanical pressure applied by user.
In other words, when user, which wears eyeshade 100, to sleep, microcapsules can rupture the discharge active component in a manner of slow release,
Active constituent to be delivered continuously to the skin of user.Meanwhile user will not experience feeling of wetness or experience
It is dirty for coating skin care activity ingredient.
Fig. 5 A shows the complete microcapsules 400 that fiber 402 is adhered to before rupture, and Fig. 5 B show by
Rupture is after mechanical pressure or biodegrade with the microcapsules 500 of discharge active component.As shown in Figure 5 B, the microcapsules of rupture
It is found to be present on fiber 502, although being released from active constituent.
In this embodiment, microcapsules have such average diameter: from about 1 μm to about 25 μm；Or from about 2 μm to
About 15 μm；Or from about 3 μm to about 10 μm；Or from about 5 μm to about 8 μm；Or about 5 μm.Preferably, microcapsules are for example
It is distributed before being attached to fabric substrate, skin-care layer etc. with narrow size.
Skin-care layer 106 can be woven into fabric substrate 102 by adhesion mechanism or be attached to fabric substrate.In Fig. 1
In Fig. 2, skin-care layer 106 can be removably attached to fabric substrate 102 by the adhesion mechanism, by being arranged in skin care
Two bandages 108 on layer indicate.Then bandage 108 can be attached to fabric substrate 102.Adhesion mechanism is provided to user
The method of user close friend, to remove detachable skin-care layer from skin-protecting fabric product when needed.Such as following situations: work as shield
Microcapsules in skin layers are used up, and need more to be renewed with unbroken microcapsules skin-care layer when；When skin-protecting fabric product by
To still user is not desired to washing and skin care layer when washing；Or under other scenes, adhesion mechanism is useful.
In this specific embodiment, skin-care layer 106 can be removed from fabric substrate 102, and new a piece of skin-care layer can
To be attached thereon.Selectively, detachable skin-care layer 106 can remove before washing from fabric substrate 102.
The adhesion mechanism of substitution may include be still button in non-exclusive manner, it is zipper, loop fasteners system, magnetic tight
Fixer system etc..In one embodiment, skin-care layer is removably attached to fabric substrate by magnetic fastener system, should
Magnetic fastener system includes one or more magnetic parts on fabric substrate and/or skin-care layer.Those skilled in the art
It is appreciated that how to arrange adhesion mechanism so that skin-care layer to be directly or indirectly physically held on fabric substrate.Other can
Capable adhesion mechanism can be applied in the present invention to realize effect disclosed herein.
In alternative embodiment, skin-care layer can weave or otherwise be permanently attached to fabric substrate, from
And form single piece type fabric product.
Selectively, elastic ribbon 104 can enable its adjustable and band regulating mechanism is integrated into eyeshade 100
Section.For example, elastic ribbon 104 can have an end for being woven into fabric substrate 102, and via band regulating mechanism 110,
112 are removably attached to the other end of fabric substrate 102.Band regulating mechanism includes in the detachable of elastic ribbon 104
Multiple holes 112 on end and the button 110 being arranged on fabric substrate 102, are fitted to according to the required length of user
In hole on elastic ribbon.Therefore to user provide the eyeshade of user close friend, under different conditions (for example,
Family or in travelling) be adjusted according to needed for.
Fig. 3 and Fig. 4 shows another embodiment of washable skin-protecting fabric product, especially pillow 300.Pillow 300 has
There is pillowcase 302, covers soft packing 304.Soft packing 304 can be rubber, fiber, air cushion etc..Pillowcase 302 is outside at it
Surface on be coated with skin-care layer fabric substrate.Skin-care layer includes microcapsules as described above.In sleep, on pillow 300
Microcapsules ruptured, and discharge active component because user presses.Therefore, allow skin that excessive liquid is being not present
In the case of be easy from pillow to obtain active constituent.And microcapsules slowly discharge active component can reach the extended period.
The invention also includes a kind of methods for preparing skin-protecting fabric product.Particularly, this method includes that preparation includes activity
The microcapsules of ingredient；By microcapsules setting fabric substrate/layer or on fabric substrate to form skin-care layer, and may be selected
Skin-care layer is attached to fabric substrate by ground.
In embodiment herein, useful microcapsules are prepared by the in-situ polymerization effect having follow steps:
I) it is prepared by the way that the first monomer and second comonomer to be dissolved in the aqueous solution that pH value is about 7 to 10 comprising polymerization
The mixture of object precursor, and selectively by mixture higher than 50 DEG C at a temperature of heat；
Ii) mixture of polymer precursor is added in the mixture comprising active constituent；
Iii surfactant) is added to step ii) in mixture in, and be sufficiently stirred；
Iv) activation in iii) in mixture in polymer precursor to be subjected to polymerization；
V) scavenger is added selectively to remove excessive reactant from the mixture of generation；
Vi microcapsules) are filtered, and wash microcapsules selectively with removal of impurity.
" polymer precursor " (also referred to as prepolymer) refers to monomer as used in this article, has been activated into
Between molecular mass state, and another polymerization can be subjected to, have being fully cured for high molecule mass state poly- to be formed
Close object.In an embodiment of the invention, amino polymer precursor is by being dissolved in water for the first monomer and second comonomer
It is prepared in solution.The pH value of aqueous solution increases to promote to be formed middle element quality state.
In step (iv), after the active ingredients are mixed, the pH value of compound, which is adjusted, to be arrived less than 7, to promote centre
The polymerization of molecular mass state, to form the polymer with high molecule mass state.Low pH, which further improves to be formed, to be had
The microcapsules of smaller particle size.In the case where not being bound by theory, it is believed that the surface tension that low ph value can reduce continuous phase makes
Emulsification between monomer is improved, thus the microcapsules formed can have narrow size distribution and lesser flat
Equal diameter.
Scavenger can be added to remove excessive reactant (for example, monomer) to mix in the middle product that formed of step (v)
Close object.In one embodiment, formaldehyde is used as the first monomer and melamine is used as second comonomer to form melamine
Polyimide resin.Formaldehyde scavenger can be used in step (v) to remove excessive unreacted formaldehyde.Formaldehyde scavenger can be primary
Amine, secondary amine or tertiary amine, ammonia, glycine, urea, ethylidene-urea, ethyl acetoacetate or sodium hydrogensulfite acetyl acetamide.Alcohol
(such as methanol and ethyl alcohol) can also be used to remove other excessive unreacted reactants.
Then, can using such as coating, filling and spray processing with by microcapsules be attached to fabric substance/layer or
Person is on fabric substrate, to form skin-care layer.In one embodiment, with reference to Fig. 6, microcapsules are arranged in including adhesive
In liquid bathtub 600.Adhesive can be acrylic acid, and polyurethane, silicone resin etc. is to bond or be fixed to fabric by microcapsules
Layer or fabric substrate 602.Adhesive can be in washing cycle, will be at least about 50% to about 100% or about 60% to about
100% or about 75% to about 100% or about 90% to about 100% microcapsules are maintained on skin-protecting fabric product.Precoat
Or then fabric substrate 602 is placed in liquid bathtub 600 by impregnating unit 604, to occupy microcapsules.After this, face
The bed of material or fabric substrate 602 are subjected to fill process and/or curing process by calender 606 and/or stenter 608 with will be micro-
Capsule solidifies and is attached to precoat or fabric substrate 602.It will be appreciated by those skilled in the art that being generally used for textile industry
In machine be suitable for the present invention to obtain the skin-care layer with microcapsules.For example, stenter used herein is usually to use
In making fiber extend and make the common machines of fiber thermal finalization.Selectively, washing step and drying steps can be executed
To remove excessive reactant.
The invention further relates to a kind of methods for smearing washable skin-protecting fabric product.This method comprises:
Skin-protecting fabric product is placed on user, wherein skin-care layer will be positioned to directly connect with the skin of user
Touching at least about 15 minutes；Or about 15 minutes to about 22 hours；Or about 30 minutes to about 20 hours；Or about 1 hour to about 16 hours；
Or about 2 hours to about 12 hours；Or about 3 hours to about 11 hours；Or about 4 hours to about 10 hours；Or it is about 15 minutes to about 3 small
When；Or about 25 minutes to about 2 hours；Or about 30 minutes to about 1.5 hours；
When skin-protecting fabric product has dust or pollutant on it, at least one washing of washing and skin care fabric product
Period, wherein at least about 50%；Or 50% to 100%；Or 60% to 100%；Or 75% to 100%；Or 90% to 100%
Amount of the microcapsules after washing cycle relative to microcapsules existing before washing cycle, be retained on skin-care layer.
As described above, skin-protecting fabric product can be subjected at least five washing cycle, at least ten washing cycle, at least 15
Washing cycle, at least 20 washing cycles, at least 25 washing cycles or at least 30 washing cycles, and washing cycle it
Afterwards, at least about 50%, about 60%, about 70%, about 80% or about 90% to about 100% microcapsules relative to first wash
The amount of existing microcapsules keeps complete on skin-care layer before period.Specifically, after 5 wash cycles, about 75%
Microcapsules to about 100% can be kept on skin-care layer completely, relative to micro- glue existing before first washing cycle
Capsule, about 50% to about 85% can keep complete on skin-care layer after 10 washing cycles, after 15 washing cycles about
35% to about 70% can keep complete on skin-care layer, about 15% to about 50% can be in skin care after 20 washing cycles
Keep complete on layer, or about 3% to about 30% can keep complete on skin-care layer after 30 washing cycles.
In one embodiment of the invention, skin-protecting fabric product is placed on user with drying regime, without the use of
The adhesive of any liquid or cream forms.In other words, extra liquid or emulsifiable paste is not had to seep from skin-protecting fabric product
Out.
It will be understood by those skilled in the art that in the case where not departing from spirit or scope present invention as described above,
The present invention described in above-mentioned specific embodiment can be variously changed and/or be modified.Therefore, present embodiment is in institute
There is aspect to be considered as illustrative rather than restrictive.
Example 1A
Active constituent formula
Table 1 lists three kinds of formulas that the skin of user is adjusted and/or improved by distinct methods, and especially the
A kind of formula focuses on anti-aging, and the second preparation, which focuses on, makes skin moisture-keeping, and last one kind, which focuses on, makes skin restore green
Spring.
Table 1
Example 1B
The preparation of formula 1
Formula 1 as listed above is prepared based on following components:
| Ingredient | Weight percent based on composition total weight |
| Sweet Almond Oil | 30%-90% |
| Ethylhexyl palmitate | 1%-5% |
| Dimetylsilyl silica | 0.05%-0.30% |
| Butanediol | 0.01%-0.2% |
| Sodium Hyaluronate | 0.005%-0.04% |
| Pentanediol | 0.01%-0.2% |
| Caprylic/capric triglyceride | 5%-20% |
| Geranylgeranyl group isopropanol | 0.05%-0.4% |
| Cetostearyl alcohol ethylhexoate | 1%-50% |
| Sorbitan isostearate | 0.1%-5% |
| Shaggy portulaca extract Pilosa Extract | 0.03%-2% |
| Sucrose cocounut oil acid esters | 0.005%-0.3% |
| Palmityl tripeptides -38 | 0.001%-0.04% |
| Laminaria digitata extract | 0.01%-0.05% |
| D-α-tocopherol acetate | 0.1%-0.5% |
Example 2
The preparation of microcapsules
Microcapsules are prepared using interfacial polymerization.Hydrogen formaldehyde, melamine and water are thoroughly mixed to form aqueous solution (A).For
Ensure to be completely dissolved, the pH value of solution A is adjusted to 8.5-9.0, and the temperature was then adjusted to 70-80 DEG C.
The active constituent as described in the formula of example 1 and emulsifier have been mixed to form in organic solvent dichloromethane
Machine solution (B).Solution B is mixed with the speed of 3000-4000rpm with solution (A) in homogenizer.In mixed process, by water
It is added gradually in mixture, to trigger the microencapsulation of two phase interfaces (that is, between organic phase and water phase).By methanol and
Formaldehyde scavenger is added in resulting mixture to remove any excessive unreacted formaldehyde.
Example 3
Fill process
The microcapsules obtained in example 1 are introduced into bath foam.Concentration of the microcapsules in bath foam is about 70-90g/l.Bath foam
It further include 50g/l adhesive, 20g/l softening agent and 2g/l wetting agent.Fabric is immersed into bath foam, and enters filler/squeeze cylinder.Bath
The minimum absorption rate (pick-up ratio) of liquid is 80-90%.Then uniform microcapsule is distributed on fabric to form skin care
Layer.The absorption rate (%) of bath foam is the percentage of the bath foam quality that knitted fabric absorbs and dry fabric quality, is calculated as follows:
Absorption rate=(quality that bath is expected below)-(quality of dried noodle material)/(quality of dried noodle material)
Quality is with g/m2Metering.Therefore, the quality for the microcapsules drawn by fabric can be calculated based on following equation:
Quality kg × absorption rate (%) × microcapsules of the mass percent w/w=dried noodle material of microcapsules are in bath foam on fabric
In concentration.
In this example, when microcapsules are when it is 85% that the concentration of bath foam, which is 70g/l and absorption rate, every 1 square of rice and flour
The mass percent for expecting the microcapsules of (w/w) is calculated by 1kg dried noodle material × 85% × 70/1000=5.95%w/w.
Finally, in this example, fabric passes through stenter.By the heat fixation technique at about 160 DEG C and will do
The speed of dry machine was set as 10m/min, and microcapsules are fixed on fabric, with about 3 minutes of offer at about 160 DEG C
Drying time.As a result the skin-care layer containing microcapsules is formed.
Example 4
Manufacture facial mask
By in example 3, the skin-care layer for being impregnated with microcapsules is made into and is cut into facial mask.The hook part of loop fasteners is arranged
On the side of skin-care layer.It is made of silk, wherein the fabric substrate of insertion cotton (is similar to skin-care layer) in the form of facial mask
Preparation, and the fabric substrate has linear fastening strip on the surface thereof, and which couples with the hook assembly on skin-care layer.So
Afterwards, skin-care layer is attached to fabric substrate via loop fasteners to form facial mask of the invention.
In addition, being also connected with elastic ribbon on facial mask.User can easily put on facial mask by elastic ribbon, simultaneously
Facial mask is securely fixed in user on the face by elastic ribbon.Patch when user's sleep, with the skin contact of user
Microcapsules on skin-care layer may rupture and discharge active component.Fig. 7 and Fig. 8, which respectively illustrates eyeshade of the invention, to be had
Or without ornament in the case where example.
Claims (18)
1. a kind of washable skin-protecting fabric product, it includes:
Fabric substrate；And
The skin-care layer being removably arranged on the fabric substrate, wherein the skin-care layer includes microcapsules, and described micro-
Capsule includes at least two active constituents to improve the skin of user, is made of wherein the active constituent is selected from following
Group: skin moisturizer, skin whitener, skin anti-aging agent, aromatic and combinations thereof；
Wherein the skin-care layer will be placed with direct skin contact with user.
2. washable skin-protecting fabric product according to claim 1, it is dry for touching during use.
3. washable skin-protecting fabric product according to claim 1, wherein the microcapsules are easy by mechanical pressure or life
At least one of object degradation is discharging the active constituent to the skin of user.
4. washable skin-protecting fabric product according to claim 1, wherein the fabric substrate includes natural fiber, synthesis fibre
Dimension or combinations thereof.
5. washable skin-protecting fabric product according to claim 4, wherein the fabric substrate is by natural fiber or synthesizes fibre
Dimension is made.
6. washable skin-protecting fabric product according to claim 1, wherein the microcapsules are easy by enzymatic degradation.
7. washable skin-protecting fabric product according to claim 1, wherein the average diameter of the microcapsules is about 1 μm to about
25μm。
8. washable skin-protecting fabric product according to claim 1, wherein the skin-care layer passes through magnetic fastener system
It is removably attached to fabric substrate.
9. washable skin-protecting fabric product according to any one of claim 1 to 8, wherein at least five washing cycle it
Afterwards, the amount relative to microcapsules existing before washing, at least 50% microcapsules are present on the skin-care layer.
10. washable skin-protecting fabric product according to any one of claim 1 to 8, wherein the fabric product be mask,
Pillowcase or clothes.
11. a kind of sleep kit, it includes washable skin-protecting fabric products according to any one of claim 1 to 9.
12. a kind of washable mask, comprising:
Fabric substrate；And
The skin-care layer being removably arranged on the fabric substrate, wherein the skin-care layer includes microcapsules, and described micro-
Capsule includes at least two active constituents for improving user's skin, wherein the active constituent is selected from by following group
At group: skin moisturizer, skin whitener, skin anti-aging agent, aromatic and combinations thereof.
13. a kind of washable pillowcase, comprising:
It include the fabric substrate of silk；And
The skin-care layer being removably arranged on fabric substrate, wherein skin-care layer includes microcapsules, and the microcapsules include to be used for
Improve at least two active constituents of the skin of user, wherein the active constituent is selected from consisting of the following group: skin
Skin moisturizer, skin whitener, skin anti-aging agent, aromatic and combinations thereof.
14. a kind of washable clothes, comprising:
The fabric substrate made of natural fiber or synthetic fibers；
And it is removably arranged in the skin-care layer on fabric substrate, wherein the skin-care layer includes microcapsules, and described micro-
Capsule includes at least two active constituents for improving skin, wherein the active constituent is selected from consisting of the following
Group: skin moisturizer, skin whitener, skin anti-aging agent, aromatic and combinations thereof
Wherein the skin-care layer will be placed with direct skin contact with user.
15. a kind of method using washable skin-protecting fabric product according to any one of claim 1 to 10, the method
Include:
The skin-protecting fabric product is placed on user, wherein the skin-care layer will be positioned to it is straight with the skin of user
Contact at least 15 minutes；
When the skin-protecting fabric product has dust or pollutant on it, wash the skin-protecting fabric product at least one
Washing cycle, wherein relative to the amount of microcapsules existing before first washing cycle, after the washing cycle,
At least 50% microcapsules are retained on the skin-care layer.
16. according to the method for claim 15, wherein the skin-protecting fabric product is subjected at least five washing cycle.
17. according to the method for claim 15, wherein the skin-care layer will be positioned to direct skin contact with user
30 minutes to 20 hours.
18. according to the method for claim 15, wherein the skin-protecting fabric product is not using any liquid or emulsifiable paste shape
In the case where the adhesive of formula, with drying regime is placed in user.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2018/087278 WO2018210304A1 (en) | 2017-05-17 | 2018-05-17 | Wash-durable skin care fabric product |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HK17104948 | 2017-05-17 | ||
| HK17104948.6 | 2017-05-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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| CN110735195A (en) * | 2019-09-03 | 2020-01-31 | 冯杰宝 | regenerated cellulose fibers containing shea butter and preparation method thereof |
| CN111041841A (en) * | 2019-12-24 | 2020-04-21 | 淄博大染坊丝绸集团有限公司 | Finishing process of argan silk fabric |
| CN111395004A (en) * | 2020-05-09 | 2020-07-10 | 徐建平 | Preparation method and application of nicotinamide mononucleotide bioenzyme textile fabric |
| CN111990713A (en) * | 2020-05-19 | 2020-11-27 | 龚梅清 | Natural antibacterial and anti-virus mask cushion and preparation method thereof |
| CN112144290A (en) * | 2020-08-25 | 2020-12-29 | 深圳全棉时代科技有限公司 | Production method of skin-care fabric |
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| CN112450668A (en) * | 2020-12-16 | 2021-03-09 | 青岛嘉司复合材料有限公司 | Hyaluronic acid quilt with skin care function and manufacturing method thereof |
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