CN108910961A - A kind of preparation method of ferroso-ferric oxide - Google Patents
A kind of preparation method of ferroso-ferric oxide Download PDFInfo
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- CN108910961A CN108910961A CN201811021160.9A CN201811021160A CN108910961A CN 108910961 A CN108910961 A CN 108910961A CN 201811021160 A CN201811021160 A CN 201811021160A CN 108910961 A CN108910961 A CN 108910961A
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- iron salt
- ferroso
- ferric
- ferric oxide
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- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 229940056319 ferrosoferric oxide Drugs 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 150000002505 iron Chemical class 0.000 claims abstract description 28
- 230000005291 magnetic effect Effects 0.000 claims abstract description 17
- 239000002608 ionic liquid Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 238000000975 co-precipitation Methods 0.000 claims abstract description 6
- 239000011541 reaction mixture Substances 0.000 claims abstract description 5
- 239000012266 salt solution Substances 0.000 claims description 16
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 10
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 8
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 claims description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 6
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical group [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 5
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 claims description 4
- 239000008236 heating water Substances 0.000 claims description 4
- KZDMWVBUOTWRDX-UHFFFAOYSA-J sodium cerium(3+) tetrahydroxide Chemical compound [OH-].[Na+].[Ce+3].[OH-].[OH-].[OH-] KZDMWVBUOTWRDX-UHFFFAOYSA-J 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 5
- 239000003125 aqueous solvent Substances 0.000 abstract description 2
- 238000009413 insulation Methods 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- -1 catalysis Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 239000000696 magnetic material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- 229960002089 ferrous chloride Drugs 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910001412 inorganic anion Inorganic materials 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011553 magnetic fluid Substances 0.000 description 1
- 238000000593 microemulsion method Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/08—Ferroso-ferric oxide [Fe3O4]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Hard Magnetic Materials (AREA)
Abstract
The invention discloses a kind of preparation methods of ferroso-ferric oxide, this method is using ionic liquid as reaction dissolvent, pass through coprecipitation, nano-scale magnetic ferroso-ferric oxide is prepared, soluble divalent iron salt and soluble trivalent iron salt are added in ionic liquid and obtain solution, then it is slow added into sodium hydroxide and insulation reaction, reaction mixture is centrifugated, washs, is dried to obtain nano-scale magnetic ferroso-ferric oxide.The present invention utilizes the special nature of ionic liquid, replace the aqueous solvent in traditional co-precipitation method, conveniently prepare nanoscale magnetic ferroferric oxide particle, particle diameter distribution is uniform, and spherical shape is good, and magnetic property is excellent, and preparation method is simple, equipment requirement is low, is suitable for producing in enormous quantities, is a kind of preparation method with bright prospects.
Description
Technical field
The present invention relates to the preparation methods of magnetic material, more particularly, to a kind of preparation method of ferroso-ferric oxide.
Background technique
Nano magnetic material is as a kind of emerging functional material, due to its unique physicochemical properties, make its physics,
Chemistry etc. shows the specific use different from conventional magnetic material.Nano ferriferrous oxide is exactly one of multi-functional
Magnetic material, magnetic recording material, magnetic fluid, catalysis, medicine, in terms of have a wide range of applications.
Ferroso-ferric oxide（ferroferric oxide）, chemical formula Fe3O4, it is commonly called as iron oxide black, magnet, magnet, black
Iron oxide, belongs to cubic system, and inverse spinel structure has excellent Magnetics characteristL, therefore also referred to as magnetic iron oxide.
The principal element for influencing nanoscale ferroso-ferric oxide performance includes superparamagnetism, coercivity, magnetic saturation amount, crystallinity
And partial size and pattern etc..The preparation method of ferroferric oxide nano granules has huge shadow to its performance and suitable application area
It rings.Method currently used for preparing nano ferriferrous oxide particle mainly has physical method and chemical method.Wherein, physical method
The nano ferriferrous oxide purity of preparation is low, particle diameter distribution is uneven, so its application range of products is relatively narrow.Chemical method obtains
Product run-of-the-mill it is preferable, operating method is also relatively easy to, thus obtain extensively research and concern；But its also have it is unfavorable
On one side, it as reaction principle is typically more complicated, is not easy accurately to control its pattern and performance.
At present be used to prepare nano ferriferrous oxide chemical method mainly have coprecipitation, hydro-thermal method or solvent-thermal method,
Microemulsion method, sol-gel method etc..Different methods, reaction principle, consersion unit and reaction condition have very big difference,
The pattern and property of product are also not quite similar.
Ionic liquid, that is, the liquid being composed entirely of ions, since it is low with fusing point, electric conductivity is strong, dissolubility is high etc.
Characteristic not available for many usual vehicles, thus be a hot fields of Recent study, it is sent out in compound synthesis field
Wave important function.
Ionic liquid is generally made of organic cation and big inorganic anion, common cation have quaternary ammonium salt from
Son, quaternary phosphine salt ion, imidazolium ion and pyrroles's salt ion etc., anion has halide ion, tetrafluoroborate ion, hexafluoro phosphorus
Acid ion etc..
Summary of the invention
It is reaction dissolvent, the excellent nano-magnetic of processability that the purpose of the present invention is to provide a kind of using ionic liquid
The method of ferroso-ferric oxide.
Technical scheme is as follows：
Using ionic liquid as reaction dissolvent, by coprecipitation, nanoscale is prepared in a kind of preparation method of ferroso-ferric oxide
Magnetic ferroferric oxide；Described method includes following steps：
（1）Analytically pure soluble divalent iron salt and soluble trivalent iron salt are taken, according to molar ratio Fe2+:Fe3+=1:2~2:3 claim
Measure divalent iron salt and trivalent iron salt；
（2）Divalent iron salt and trivalent iron salt are added separately in ionic liquid to and are stirred 10 ~ 20min, it is molten to obtain divalent iron salt
The concentration of liquid and ferric salt solution, the divalent iron salt solution and ferric salt solution is 0.3 ~ 0.6mol/L；
（3）Divalent iron salt solution and ferric salt solution are uniformly mixed under agitation, while with heating water bath and being kept the temperature
At 30 ~ 40 DEG C, then proceed to be slowly added to powdered analysis pure cerium hydroxide sodium under agitation, after adding keep the temperature 30min ~
2h；
（4）It is centrifugated reaction mixture, by isolated product with heptane wash 2 ~ 3 times, then is washed with deionized 2 ~ 3
It is secondary, it is dried at 40 ~ 60 DEG C to get nano-scale magnetic ferroso-ferric oxide is arrived.
Wherein, the divalent iron salt is one of frerrous chloride, ferrous nitrate, ferrous sulfate or a variety of, the trivalent
Molysite is one of iron chloride, ferric nitrate, ferric sulfate or a variety of.
Further, the ionic liquid is [Bmim] BF4。
Further, step（3）In, the additional amount of the sodium hydroxide is 0.5-1 relative to the mole of divalent iron salt
Times, it is described to be slowly added to be to be added to complete in 10-30min.
Ionic liquid is a kind of solvent of green high-efficient, plays important role in synthesis chemistry, synthesis is each extensively
Kind organic substance, but the research for synthesizing inorganic compound with it so far is still less.The present invention is special using ionic liquid
Property replaces the aqueous solvent in traditional co-precipitation method, conveniently prepares nanoscale magnetic ferroferric oxide particle, grain
Diameter is evenly distributed, and spherical shape is good, by Magnetic Test, has preferable coercivity and magnetic saturation amount, and preparation method is simple,
Equipment requirement is low, is suitable for producing in enormous quantities, is a kind of preparation method with bright prospects.
Specific embodiment
The following are a specific embodiment of the invention, the present invention to be explained and illustrated.
Embodiment 1
A kind of preparation method of ferroso-ferric oxide, preparation method include the following steps：
（1）Analytically pure frerrous chloride and iron chloride are taken, frerrous chloride 0.5mol, iron chloride 1mol are weighed；
（2）Frerrous chloride and iron chloride are added separately to [Bmim] BF4In and stir 10min, obtain solution of ferrous chloride and
Ferric chloride solution, concentration are 0.6mol/L；
（3）Solution of ferrous chloride and ferric chloride solution are uniformly mixed under agitation, while with heating water bath and being kept the temperature
It 30 DEG C, then proceedes to be slowly added to powdered analysis pure cerium hydroxide sodium 0.5mol in 20min under agitation, be kept the temperature after adding
2h；
（4）It is centrifugated reaction mixture, by isolated product with heptane wash 3 times, then is washed with deionized 3 times,
It is dried at 40 DEG C to get nano-scale magnetic ferroso-ferric oxide is arrived.
It is detected through SEM, obtained ferroso-ferric oxide partial size is between 60-150nm.
Embodiment 2
A kind of preparation method of ferroso-ferric oxide, described method includes following steps：
（1）Analytically pure frerrous chloride, ferrous sulfate and ferric nitrate are taken, according to molar ratio Fe2+:Fe3+=2:3 weigh protochloride
Iron, ferrous sulfate and ferric nitrate；
（2）Frerrous chloride, ferrous sulfate and ferric nitrate are added separately to ionic liquid [Bmim] BF4In and stir 10 ~
20min, obtains divalent iron salt solution and ferric salt solution, and the concentration of the divalent iron salt solution and ferric salt solution is
0.3mol/L；
（3）Divalent iron salt solution and ferric salt solution are uniformly mixed under agitation, while with heating water bath and being kept the temperature
At 40 DEG C, then proceed to be slowly added in 30min under agitation powdered analysis pure cerium hydroxide sodium to pH be about 8.5（Hydrogen
The additional amount of sodium oxide molybdena is frerrous chloride, 0.7 times of ferrous sulfate integral molar quantity）, and keep the temperature 1h；
（4）It is centrifugated reaction mixture, by isolated product with heptane wash 2 times, then is washed with deionized 2 times,
It is dried at 60 DEG C to get nano-scale magnetic ferroso-ferric oxide is arrived.
Claims (4)
1. a kind of preparation method of ferroso-ferric oxide, which is characterized in that using ionic liquid as reaction dissolvent, by coprecipitation,
Nano-scale magnetic ferroso-ferric oxide is prepared；Described method includes following steps：
（1）Analytically pure soluble divalent iron salt and soluble trivalent iron salt are taken, according to molar ratio Fe2+:Fe3+=1:2~2:3 weigh
Divalent iron salt and trivalent iron salt；
（2）Divalent iron salt and trivalent iron salt are added separately in ionic liquid to and are stirred 10 ~ 20min, it is molten to obtain divalent iron salt
The concentration of liquid and ferric salt solution, the divalent iron salt solution and ferric salt solution is 0.3 ~ 0.6mol/L；
（3）Divalent iron salt solution and ferric salt solution are uniformly mixed under agitation, while with heating water bath and being kept the temperature
At 30 ~ 40 DEG C, then proceed to be slowly added to powdered analysis pure cerium hydroxide sodium under agitation, after adding keep the temperature 30min ~
2h；
（4）It is centrifugated reaction mixture, by isolated product with heptane wash 2 ~ 3 times, then is washed with deionized 2 ~ 3
It is secondary, it is dried at 40 ~ 60 DEG C to get nano-scale magnetic ferroso-ferric oxide is arrived.
2. a kind of preparation method of ferroso-ferric oxide according to claim 1, which is characterized in that the divalent iron salt is chlorine
Change one of ferrous iron, ferrous nitrate, ferrous sulfate or a variety of, the trivalent iron salt is iron chloride, in ferric nitrate, ferric sulfate
It is one or more.
3. a kind of preparation method of ferroso-ferric oxide according to claim 1, which is characterized in that the ionic liquid is
[Bmim]BF4。
4. a kind of preparation method of ferroso-ferric oxide according to claim 1, which is characterized in that step（3）In, the hydrogen
The additional amount of sodium oxide molybdena is 0.5-1 times relative to the mole of divalent iron salt, described be slowly added to be added in 10-30min
It completes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811021160.9A CN108910961A (en) | 2018-09-03 | 2018-09-03 | A kind of preparation method of ferroso-ferric oxide |
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| CN201811021160.9A CN108910961A (en) | 2018-09-03 | 2018-09-03 | A kind of preparation method of ferroso-ferric oxide |
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ID=64407474
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| CN201811021160.9A Pending CN108910961A (en) | 2018-09-03 | 2018-09-03 | A kind of preparation method of ferroso-ferric oxide |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109806844A (en) * | 2019-03-21 | 2019-05-28 | 西南大学 | A kind of magnetic metal organic framework materials of dephosphorization and preparation method thereof |
| CN110508284A (en) * | 2019-08-30 | 2019-11-29 | 中南大学 | A kind of preparation method of two dimension ferroso-ferric oxide class fenton catalyst and its application in wastewater degradation containing aminobenzenesulfonic acid |
| CN113041996A (en) * | 2021-03-05 | 2021-06-29 | 福州海关技术中心 | Preparation method and application of magnetic graphitized carbon black |
| CN115818724A (en) * | 2022-12-16 | 2023-03-21 | 上海允复纳米科技有限公司 | Nanoscale gamma-phase magnetic ferric oxide and preparation process and application thereof |
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| CN103449534A (en) * | 2013-08-06 | 2013-12-18 | 陕西科技大学 | Method for preparing magnetic nanoparticle by using ionic liquid as template agent |
| CN104030363A (en) * | 2014-02-17 | 2014-09-10 | 瑞安市浙工大技术转移中心 | Preparing method of ferroferric oxide nanometer particles |
| CN104386760A (en) * | 2014-10-31 | 2015-03-04 | 山东师范大学 | Method for rapidly preparing magnetic carrier material in large quantity |
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2018
- 2018-09-03 CN CN201811021160.9A patent/CN108910961A/en active Pending
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| CN101162634A (en) * | 2007-09-20 | 2008-04-16 | 华东师范大学 | Ion liquid based magnetofluid preparation method |
| CN103449534A (en) * | 2013-08-06 | 2013-12-18 | 陕西科技大学 | Method for preparing magnetic nanoparticle by using ionic liquid as template agent |
| CN104030363A (en) * | 2014-02-17 | 2014-09-10 | 瑞安市浙工大技术转移中心 | Preparing method of ferroferric oxide nanometer particles |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109806844A (en) * | 2019-03-21 | 2019-05-28 | 西南大学 | A kind of magnetic metal organic framework materials of dephosphorization and preparation method thereof |
| CN110508284A (en) * | 2019-08-30 | 2019-11-29 | 中南大学 | A kind of preparation method of two dimension ferroso-ferric oxide class fenton catalyst and its application in wastewater degradation containing aminobenzenesulfonic acid |
| CN113041996A (en) * | 2021-03-05 | 2021-06-29 | 福州海关技术中心 | Preparation method and application of magnetic graphitized carbon black |
| CN115818724A (en) * | 2022-12-16 | 2023-03-21 | 上海允复纳米科技有限公司 | Nanoscale gamma-phase magnetic ferric oxide and preparation process and application thereof |
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