CN108896606A - A kind of unstable state cylinder heat resource method temperature becomes effective thermal conductivity measurement device and method - Google Patents

A kind of unstable state cylinder heat resource method temperature becomes effective thermal conductivity measurement device and method Download PDF

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Publication number
CN108896606A
CN108896606A CN201811116254.4A CN201811116254A CN108896606A CN 108896606 A CN108896606 A CN 108896606A CN 201811116254 A CN201811116254 A CN 201811116254A CN 108896606 A CN108896606 A CN 108896606A
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temperature
temperature measuring
measuring point
cylinder
charging cylinder
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CN108896606B (en
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柴晓琴
邢德山
薛建明
樊腾飞
张乾
程文煜
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Guodian Environmental Protection Research Institute Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/20Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity

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  • Life Sciences & Earth Sciences (AREA)
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Abstract

The invention discloses a kind of unstable state cylinder heat resource method temperature to become effective thermal conductivity measurement device, which includes charging cylinder, electric heating cover, insulating layer, insulation cover, thermoprobe, intelligent temperature controller;The cylinder that charges is cylindrical;Electric heating cover is covered in the periphery of charging cylinder, and insulating layer is located at the periphery of electric heating cover;Intelligent temperature controller is set to outside cartridge body;Cover is insulated to be set at the both ends open of charging cylinder;It is equipped with 5 or 9 temperature measuring points in cartridge body, each temperature measuring point is laid at cartridge body length half on circumference and circle center line connecting or is laid at cartridge body length half circular cross-section diametrically;Thermoprobe is respectively equipped at each temperature measuring point;Thermoprobe is connected with intelligent temperature controller respectively;The axial length of charging cylinder and the size of internal diameter are 10:1~20:1.The present invention carries out the measurement of solid particulate matter effective thermal conductivity, and heat transfer can be reduced to radial heat transfer, thereby simplifies the calculation method that unstable state cylinder heat resource method temperature becomes effective thermal conductivity.

Description

A kind of unstable state cylinder heat resource method temperature becomes effective thermal conductivity measurement device and method
Technical field
The present invention relates to a kind of devices for measuring to solid particulate matter effective thermal conductivity, and in particular to a kind of non-steady State cylinder heat resource method temperature becomes effective thermal conductivity measuring method and measurement device, belongs to thermal energy, environment-friendly engineering technical field.
Background technique
There are three kinds of basic modes for heat transfer in particle system:Heat transfer, thermal convection and heat radiation, Different Exercise Mode, The particle system of different-grain diameter size, whole heat transfer ratio difference shared by three kinds of heat transfer types is very big, which dictates that particle system The difference for the heat-transfer character and heat-transfer mechanism of uniting.In carbon base catalyst(Activated coke)During desulphurization denitration technology and equipment, To graininess carbon base catalyst(Activated coke)Heat-transfer mechanism, heat transfer property measurement and application research it is particularly significant, regenerating Design and the bed temperature control of adsorption tower of tower etc. will use these research achievements.
In regeneration moving bed, particle slowly moves in round tube, and particle and particle, particle and wall surface are in one for a long time A " quasi-static " to contact with each other, need to consider and guarantee is the efficient heat transfer of bed wall surface and particle system, particulate interspaces Fluid(It is normally gaseous)Flowing can weaken the heat transfer of wall surface and particle, so the flow velocity of interstitial fluid can control very low, Thermal convection will be weakened in this way, therefore the heat transfer in moving bed is main heat transfer type.To the biggish feelings of the system temperature difference Condition, the minor change of temperature can all cause very big influence between the radiant heat transfer object, at this time should consider radiant heat transfer Inside.
Continuum Model:It is the continuous media integrally regarded particle system as fluid, inside particle system The thermal coefficient in some region is determined that the diabatic process in this region is by assuming letter by the shape and position in this region completely After change, the heat transfer equation that can be indicated with math equation is proposed, because regarding particle swarm as fluid, primary condition and boundary condition It can obtain, then the Temperature Distribution of entire particle system is obtained by calculation.It can be obtained according to continuum Model hypothesis The heat-transfer character of particle system on the whole.Particle system is anisotropic in practice, in research particle system heat transfer When problem, effective medium picture is particle system to be regarded as a kind of continuous media, the heat transfer property and particle swarm of this continuous media It is close and have isotropic property, finally solve the temperature field of particle system.The present invention is equivalent by material in cylinder For continuum Model.
Steady state method be on two surfaces of sample to be tested Temperature Distribution reach stablize after, the Temperature Distribution inside sample is no longer Time to time change enters Heat Conduction state, carry out experiment measurement, the starting point of analysis is steady heat conduction differential side Journey.It the characteristics of based on Heat Conduction test philosophy, has the following disadvantages:1)The thermo-physical index measured is single, is only capable of surveying The thermal coefficient for measuring sample, is unable to measure other indexs, such as thermal diffusion coefficient;2)The temperature difference of tested sample two sides is lower, test Diabatic process be often heat transfer, thermal convection and heat radiation three's collective effect, therefore cannot accurately obtain leading for heat transfer Hot coefficient.
Unstable state measuring method has quick, multi parameter simultaneous measuring and the spy that can carry out dynamic process online observation Point.Temperature Distribution by measuring sample changes over time, thus to calculate thermal coefficient.This method is low to environmental requirement, Measurement has advantage under hot conditions.The thermal coefficient of existing cold store enclosure measurement material, mainly using normal power planes heat Source method, i.e., according to the lower analytic solution of the big object of semo-infinite normal heat flux effect and its application in engineering in practice, measurement material Material is limited to heat-insulating material.But it is complex using this method calculating process.
Summary of the invention
The purpose of the present invention is to solve the deficiencies in the prior art, it is simple to provide a kind of structure, and can simplify The solid particulate matter effective thermal conductivity measurement device of measurement and calculating process.
In order to achieve the above object, the present invention provides a kind of unstable state cylinder heat resource method temperature to become effective thermal conductivity measurement Device, the measurement device include charging cylinder, electric heating cover, insulating layer, insulation cover, thermoprobe, intelligent temperature controller;Charging Cylinder is cylindrical;Electric heating cover is covered in the periphery of charging cylinder, and insulating layer is located at the periphery of electric heating cover;Intelligent temperature controller is set Outside cartridge body;Cover is insulated to be set at the both ends open of charging cylinder;5 or 9 temperature measuring points are equipped in cartridge body, respectively A temperature measuring point is laid at cartridge body length half on circumference and circle center line connecting or charging barrel lenght half Locate circular cross-section it is same diametrically;Thermoprobe is respectively equipped at each temperature measuring point;Thermoprobe respectively with intelligent temperature controller phase Even;The axial length of charging cylinder and the size of internal diameter are 10:1~20:1.
Further, when using 5 temperature measuring points, one of temperature measuring point is located at the center position of charging cylinder, separately One is located at the inner wall of charging cylinder, remaining is distributed on both of the aforesaid measuring point line;When using 9 temperature measuring points, wherein One temperature measuring point is located at the center position of charging cylinder, and another two is located at the inner wall of charging cylinder, three measuring points at Straight line, remaining is distributed on aforementioned three measuring point lines.
Further, electric heating cover uses mica electric heating cover;Insulating layer uses silica wool insulating layer.
Further, thermoprobe is fixed in the cartridge body by thermoprobe positioning device;Thermoprobe Positioning device includes upper clamp plate, lower clamp plate and locating ring;Locating ring is 9, and clamping is set between upper clamp plate and lower clamp plate;It is each to survey Warm probe is set in corresponding locating ring.
Further, insulation cover is equipped with casing;The connecting wire of thermoprobe passes through casing and intelligent temperature controller phase Even;It is further using flexible insulation resin seal between connecting wire and casing, it is insulated on cover and air inlet-outlet pipe is set, and lead to External hose is crossed to be connected with gas cylinder.
The present invention also provides said determination devices to carry out effective thermal conductivity method for measuring, the effective thermal conductivity Measurement is realized by following steps:
(1)Charging cylinder is heated using firm power, after reaching assigned temperature, stops heating natural cooling, when record Between and each measuring point temperature measuring data, obtain the corresponding heating experiment curv of each temperature measuring point and temperature measurement curve;
(2)Using the temperature measuring data of the temperature measuring point of center position, according to the cylindrical coordinates one-dimensional unsteady heat conduction differential equation, Constantly adjustment thermal diffusion coefficient, calculates the temperature value of other each temperature measuring points, obtains the corresponding heating calculated curve of temperature measuring point and drop Warm calculated curve carries out assessment with actual heating experiment curv and temperature measurement curve and compares, until the curve being calculated The curve obtained with actual measurement reaches highest degree of agreement, and the thermal diffusion coefficient finally chosen exists as candidate particles material Effective thermal diffusion coefficient in test temperature section, so that temperature, which is calculated, becomes effective thermal conductivity.
Wherein, step(1)In before being heated, be first passed through industrial nitrogen discharge the intracorporal air of cartridge;Specified temperature Degree is 500 DEG C, and heating method is:It is heated to the temperature measuring point temperature at center and reaches 500 DEG C, heating terminates.
Step(2)The middle cylindrical coordinates one-dimensional unsteady heat conduction differential equation is:
Wherein
t--- temperature, DEG C;
τ--- time, s;
a--- thermal diffusivity, m2/s;
r--- radius, m.
The present invention has the following advantages that compared with prior art:
The present invention carries out solid particulate matter effective thermal conductivity compared to the sufficiently long charging cylinder of radical length using axial length Measurement, and insulation cover is set at both ends, axial heat conduction is negligible in cylinder, and heat transfer can be reduced to radial heat transfer, thus simple The calculation method that unstable state cylinder heat resource method temperature becomes effective thermal conductivity is changed.
And the cylindrical surface heating unit of power invariability is formed in conjunction with cylindric charging cylinder using mica electric heating cover, and set There is silica wool insulating layer, prevents heat to function of environment heat emission, it can be achieved that being evenly heated to surveyed solid particulate matter material.
Effective thermal conductivity assay device structures of the present invention are simple, easy to operate, and are simplifying the same of measure and calculation process When, maintain the accuracy of measurement.
Detailed description of the invention
Fig. 1 is the cross-sectional view that unstable state cylinder heat resource method temperature of the present invention becomes effective thermal conductivity coefficient measurement device;
Fig. 2 is the structural schematic diagram that unstable state cylinder heat resource method temperature of the present invention becomes effective thermal conductivity coefficient measurement device;
Fig. 3 is the fixed structure schematic diagram of thermoprobe at temperature measuring point in Fig. 1;
Fig. 4 is the sealed structural schematic diagram in Fig. 1 between conducting wire and charging cylinder;
Fig. 5 is the temperature changing curve diagram of each measuring point when carrying out effective thermal conductivity measurement using the present invention.
Specific embodiment
The present invention is described in detail with reference to the accompanying drawing.
As shown in Fig. 1 ~ Fig. 4, it includes charging that unstable state cylinder heat resource method temperature of the present invention, which becomes effective thermal conductivity measurement device, Cylinder 1(Or 5), mica electric heating cover 2, silica wool insulating layer 3, thermoprobe positioning device 4, insulation cover 6, thermoprobe, Intelligent temperature controller etc..Charge cylinder 1(Or the cylinder 5 that charges shown in Fig. 2)Cylindrical, both ends open, opening is equipped with insulation cylinder Lid, the two are connected with each other by nested mode.2 sets of the mica electric heating cover peripheral sides in charging cylinder 1, silica wool insulating layer 3 Positioned at the peripheral side of mica electric heating cover 2.Intelligent temperature controller is set to outside.The cylinder 1 that charges is interior to be equipped with 5 temperature measuring points, passes through survey Warm probe positioning device 4 is fixed(The device can position 9 temperature measuring points if necessary), 5 temperature measuring points are set on cartridge At the half length of body 1, and it is located at charging one of cylinder 1 diametrically, place is at inner wall position from the central position Equidistant placement.
As shown in figure 3, be respectively equipped with thermoprobe at each temperature measuring point, thermoprobe by locating ring 9 and positioning splint 10, 11 are fixed.Thermoprobe is connected by conducting wire with external intelligent temperature controller.As shown in figure 4, thermoprobe conducting wire 12 is logical Cross the conducting wire extraction tube 13 on insulation cover 6(Or conducting wire extraction tube shown in Fig. 27)Intelligent temperature controller is led to, thermometric is visited With flexible insulation 14 fill plug seal of resin between needle conducting wire 12 and conducting wire extraction tube 13.Cylinder 1 charge in use, opening insulation Cover after installing solid particulate matter, passes through the air inlet-outlet pipe 15 on insulation cover with industrial nitrogen(Or intake and exhaust shown in Fig. 2 Pipe 8)10min is purged, the air in reactor is discharged, opens the switch of mica electric heating cover, voltage is adjusted, begins to warm up.If Determine to maintain heating power constant, until the solid particulate matter that center position detects after mica electric heating cover is heated to 500 DEG C When temperature also reaches 500 DEG C, mica electric heating cover is closed, heating is terminated, makes the intracorporal solid particulate matter natural cooling of cartridge To room temperature, retention is sampled.The temperature changed over time that each temperature measuring point detects is recorded respectively, is calculated acquisition material and is existed The heating measured curve and cooling measured curve of each temperature measuring point.
When present invention charging cylinder setting, since when axial length long enough, axial heat conduction is negligible in cylinder, heat transfer It can be reduced to radial heat transfer, thereby, it is ensured that the size of axial length and internal diameter ratio is not less than 10:1, it is controlled to control cost System is 10:1~20:Between 1, optimal choice charging cylinder specification is:Length 3m, internal diameter 0.2m.
According to the heating measured curve and cooling measured curve of each temperature measuring point that experiment obtains, effective thermal conductivity is carried out Computing Principle is as follows:According to the cylinder heat conduction differential equation:
Wherein,
t--- temperature, DEG C;
τ--- time, s;
a--- thermal diffusivity, m2/s;
r--- radius, m.
Corresponding discrete scheme is as follows:
It is assumed that a hot diffusion coefficientaThen value utilizes the primary data of a certain boundary temperature measuring point(Center leans near wall Place), same time interval when according to data record(Step-length), calculate the temperature value at 5 temperature measuring points of each moment.All It calculates after completing, the degree of agreement of calculated value and measured value is assessed, by constantly adjustingaValue improves degree of agreement, final to select It is suitable to takeaValue, as effective thermal diffusion coefficient of the tested granular materials in test temperature section(Maximum value, minimum value or Average value), then the effective thermal conductivity varied with temperature calculated by effective thermal diffusion coefficient --- i.e. temperature becomes effective system The several and effective thermal conductivity in test temperature section(Maximum value, minimum value or average value).
Embodiment 2
The temperature variation curve such as Fig. 5 of apparatus of the present invention to the continuous mode of effective thermal conductivity with embodiment 1, in measurement process It is shown.Effective thermal conductivity by tested granular materials is calculated is 0.14(It is minimum),1.67(It is average)With 4.62(Most Greatly).
It is characteristic of the invention that measurement is convenient(Compared with steady method), it is practical(Particularly suitable for material in pipe Diabatic process), it is practical that related experiment result has been applied to engineering.
It illustrating, effective thermal conductivity is a physical quantity in order to simplify the calculating of particulate species material heat transfer and definition, Its numerical value and material properties, particle diameter distribution and measurement means etc. have relationship, compare between different measurement methods and have no practical meaning Justice.Any measurement method measurement institute's value is both needed to the inspection by practical application, is subject to appropriate repair when necessary Just, it can apply.

Claims (9)

1. a kind of unstable state cylinder heat resource method temperature becomes effective thermal conductivity measurement device, it is characterised in that:The measurement device packet Include charging cylinder, electric heating cover, insulating layer, insulation cover, thermoprobe, intelligent temperature controller;The charging cylinder is cylindrical; The electric heating cover is covered in the periphery of the charging cylinder, and insulating layer is located at the periphery of the electric heating cover;The intelligent temperature control Instrument is set to outside the cartridge body;The insulation cover is set at the both ends open of the charging cylinder;The charging cylinder Inside it is equipped with 5 or 9 temperature measuring points, each temperature measuring point is laid at cartridge body length half on circumference and circle center line connecting or fills Circular cross-section is diametrically at barrel body length half;The thermoprobe is respectively equipped at each temperature measuring point;The thermometric Probe is connected with intelligent temperature controller respectively;The axial length of the charging cylinder and the size of internal diameter are 10:1~20:1.
2. measurement device according to claim 1, it is characterised in that:When using 5 temperature measuring points, one of temperature measuring point Positioned at the center position of charging cylinder, another is located at the inner wall of charging cylinder, remaining is distributed in both of the aforesaid measuring point company On line;When using 9 temperature measuring points, one of temperature measuring point is located at the center position of charging cylinder, and another two is located at It charges at the inner wall of cylinder, three measuring points are in alignment, remaining is distributed on aforementioned three measuring point lines.
3. measurement device according to claim 1, it is characterised in that:The electric heating cover uses mica electric heating cover;Institute Insulating layer is stated using silica wool insulating layer.
4. measurement device according to claim 2, it is characterised in that:The thermoprobe passes through thermoprobe positioning device It is fixed in the cartridge body;The thermoprobe positioning device includes upper clamp plate, lower clamp plate and locating ring;The positioning Circle is 9, and clamping is set between upper clamp plate and lower clamp plate;Each thermoprobe is set in corresponding locating ring.
5. measurement device according to claim 2, it is characterised in that:The insulation cover is equipped with casing;The thermometric The connecting wire of probe passes through described sleeve pipe and is connected with intelligent temperature controller;Using flexible insulation between the connecting wire and casing Resin seal.
6. measurement device according to claim 1, it is characterised in that:Air inlet-outlet pipe is set on the insulation cover, and is led to External hose is crossed to be connected with gas cylinder.
7. any measurement device of claim 1 to 6 carries out effective thermal conductivity method for measuring, it is characterised in that:This has The measurement for imitating thermal coefficient is realized by following steps:
(1)Charging cylinder is heated using firm power, after reaching assigned temperature, stops heating natural cooling, according to one Fixed time interval records the temperature measuring data of each measuring point, obtains the corresponding heating experiment curv of each temperature measuring point and cooling is surveyed Measure curve;
(2)Using the temperature measuring data of the temperature measuring point of center position, according to the cylindrical coordinates one-dimensional unsteady heat conduction differential equation, Constantly adjustment thermal diffusion coefficient, calculates the temperature value of other each temperature measuring points, obtains the corresponding heating calculated curve of temperature measuring point and drop Warm calculated curve carries out assessment with actual heating experiment curv and temperature measurement curve and compares, until the curve being calculated The curve obtained with actual measurement reaches highest degree of agreement, and the thermal diffusion coefficient finally chosen exists as candidate particles material Effective thermal diffusion coefficient in test temperature section, so that temperature, which is calculated, becomes effective thermal conductivity.
8. measuring method according to claim 7, it is characterised in that:The step(1)In before being heated, be first passed through The intracorporal air of cartridge is discharged in industrial nitrogen;Assigned temperature is 500 DEG C, and heating method is:It is heated at charging cylinder inboard wall Temperature measuring point temperature be 500 DEG C when, maintain the temperature, until center at temperature measuring point temperature also reach 500 DEG C, heating terminates.
9. measuring method according to claim 7, it is characterised in that:The step(2)Middle cylindrical coordinates one-dimensional and unsteady state is led The hot differential equation is:
Wherein
t--- temperature, DEG C;
τ--- time, s;
a--- thermal diffusivity, m2/s;
r--- radius, m.
CN201811116254.4A 2018-09-25 2018-09-25 Device and method for measuring effective heat conductivity coefficient of temperature change by using unsteady cylindrical heat source method Active CN108896606B (en)

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CN112083029A (en) * 2020-08-13 2020-12-15 四川士达特种炭材有限公司 Device and method for evaluating comprehensive performance of filler
CN113933342A (en) * 2021-09-03 2022-01-14 华中科技大学 Rapid inspection device and method for heat insulation performance of heat insulation bottle for logging instrument

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CN113933342B (en) * 2021-09-03 2022-07-12 华中科技大学 Rapid inspection device and method for heat insulation performance of heat insulation bottle for logging instrument

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