CN108893816A - A kind of scribbled with anti-static function - Google Patents

A kind of scribbled with anti-static function Download PDF

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Publication number
CN108893816A
CN108893816A CN201810780816.9A CN201810780816A CN108893816A CN 108893816 A CN108893816 A CN 108893816A CN 201810780816 A CN201810780816 A CN 201810780816A CN 108893816 A CN108893816 A CN 108893816A
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CN
China
Prior art keywords
nanoparticle
silk
fiber
scribbled
antistatic
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Pending
Application number
CN201810780816.9A
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Chinese (zh)
Inventor
罗鼎明
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Foshan Nanhai Beauty Underwear Co Ltd
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Foshan Nanhai Beauty Underwear Co Ltd
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Priority to CN201810780816.9A priority Critical patent/CN108893816A/en
Publication of CN108893816A publication Critical patent/CN108893816A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
    • D02G3/328—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/16—Physical properties antistatic; conductive
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

This application involves a kind of scribbleds with anti-static function, including yarn body, reinforced wire, antistatic fibre silk, heat insulation fiber silk, core, radiation resistant fiber silk, crease-resistant fiber filament, spandex fibre, copper fiber, ventilative gap, flame-retardant layer, viscose rayon layer, India rubber silk, wearing layer and silk fiber；The antistatic fibre silk is a kind of antistatic far-infrared polyester fiber, then which adds compound additive using polyester as substrate, by melting blended be prepared；The compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle.

Description

A kind of scribbled with anti-static function
Technical field
This application involves yarn technical field more particularly to a kind of scribbleds with anti-static function.
Background technique
Scribbled refers to the yarn that spinning is mixed in a certain ratio by two or more different fiber, as polyester-cotton blend is mixed Spinning, polyester-viscose blended yarn etc., also useful multiple fiber are distributed adjusting by different proportion and become mixed yarn, high-quality mixed yarn, Exquisite in workmanship, without wiring, braiding is fine and closely woven smooth, and spinning original just belongs to a very ancient activity, from prehistoric age with, The mankind, which just understand, is spun into long yarn for some shorter fibers, is then made into cloth again, and so-called spinning is taking animal or plant Physical property fiber makes its obvolvent become the yarn that a continuity infinitely extends by way of twisting, to be suitable for woven one kind Behavior, the present invention are exactly a kind of high-strength blended yarn made of one kind is spinned according to a certain percentage as multiple fiber.
But not only structure is complicated for yarn currently on the market, but also has a single function, be not provided with antistatic fibre silk and Radiation resistant fiber silk cannot make yarn body have the effect of antibacterial, anti-radiation, resistance to electrostatic, be not provided with crease-resistant fiber filament, no The ability that yarn body can be made to have conformality and easily restore, influences the aesthetics of yarn body, is not provided with spandex fibre, copper Fiber and viscose rayon layer not can increase the elasticity, toughness and slickness of yarn body, be not provided with flame-retardant layer, cannot make yarn Line ontology has anti-flammability, influences the service life of yarn body.
Summary of the invention
The present invention is intended to provide a kind of scribbled with anti-static function, set forth above to solve the problems, such as.
A kind of scribbled with anti-static function, including yarn body, reinforcement are provided in the embodiment of the present invention Silk, is breathed freely at antistatic fibre silk, heat insulation fiber silk, core, radiation resistant fiber silk, crease-resistant fiber filament, spandex fibre, copper fiber Gap, flame-retardant layer, viscose rayon layer, India rubber silk, wearing layer and silk fiber；It is wound with and adds on the outside of the yarn body Strong silk, and yarn body is internally provided with core, the core has been externally wrapped with heat insulation fiber silk, and the outside of core is leaned on It is wound with radiation resistant fiber silk at one side position of nearly heat insulation fiber silk, the heat insulation fiber silk has been externally wrapped with antistatic fibre Silk is tieed up, yarn body is internally provided with flame-retardant layer, viscose rayon layer, the viscose rayon are provided on the inside of the flame-retardant layer The inside of layer is provided with wearing layer, crease-resistant fiber filament is provided on the inside of the wearing layer, the crease-resistant filametntary side is set It is equipped with silk fiber, the side of the silk fiber is provided with India rubber silk, and the side of the India rubber silk is provided with copper Fiber, the side of the copper fiber are provided with spandex fibre, and the outside of yarn body offers ventilative gap；The antistatic fibre Tieing up silk is a kind of antistatic far-infrared polyester fiber, then which adds compound additive using polyester as substrate, pass through Melt blended be prepared；The compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle.
The technical solution that the embodiment of the present invention provides can include the following benefits：
Of the invention is scientific and reasonable for structure, safe and convenient to use, is provided with antistatic fibre silk and radiation resistant fiber silk, can So that yarn body has the effect of anti-radiation, resistance to electrostatic, it is provided with crease-resistant fiber filament, can make yarn body that there is conformality The ability easily restored improves the aesthetics of yarn body, is provided with spandex fibre, copper fiber and viscose rayon layer, can be with Elasticity, toughness and the slickness for increasing yarn body, make the fluffy softness of yarn body feel, are provided with flame-retardant layer, can make yarn Line ontology has anti-flammability, improves the use quality of yarn body, the design is not only simple in structure, practical function, Er Qieti The high use quality and service life of yarn.
The additional aspect of the application and advantage will be set forth in part in the description, and will partially become from the following description It obtains obviously, or recognized by the practice of the application.It should be understood that above general description and following detailed description are only Be it is exemplary and explanatory, the application can not be limited.
Detailed description of the invention
The present invention will be further described with reference to the accompanying drawings, but the embodiment in attached drawing is not constituted to any limit of the invention System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings Other attached drawings.
Fig. 1 is structural schematic diagram of the invention；
Fig. 2 is cut-away view of the invention；
Figure label：1, yarn body；2, reinforced wire；3, antistatic fibre silk；4, heat insulation fiber silk；5, core；6, prevent Bergmann's fiber silk；7, crease-resistant fiber filament；8, spandex fibre；9, copper fiber；10, ventilative gap；11, flame-retardant layer；12, viscose rayon Layer；13, India rubber silk；14, wearing layer；15, silk fiber.
Specific embodiment
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment Described in embodiment do not represent all embodiments consistented with the present invention.On the contrary, they be only with it is such as appended The example of device and method being described in detail in claims, some aspects of the invention are consistent.
Embodiments herein is related to a kind of scribbled with anti-static function, as shown in Figs. 1-2, including yarn sheet Body 1, reinforced wire 2, antistatic fibre silk 3, heat insulation fiber silk 4, core 5, radiation resistant fiber silk 6, crease-resistant fiber filament 7, spandex are fine Dimension 8, copper fiber 9, ventilative gap 10, flame-retardant layer 11, viscose rayon layer 12, India rubber silk 13, wearing layer 14 and silk fiber 15, the outside of yarn body 1 is wound with reinforced wire 2, and yarn body 1 is internally provided with core 5, and core 5 is externally wrapped with There is heat insulation fiber silk 4, and the outside of core 5 is wound with radiation resistant fiber silk 6 at a side position of heat insulation fiber silk 4, every Thermal fiber silk 4 has been externally wrapped with antistatic fibre silk 3, and yarn body 1 is internally provided with flame-retardant layer 11, flame-retardant layer 11 it is interior Side is provided with viscose rayon layer 12, and the inside of viscose rayon layer 12 is provided with wearing layer 14, and the inside of wearing layer 14 is provided with anti- Wrinkle fiber filament 7, and the side of crease-resistant fiber filament 7 is provided with silk fiber 15, and the side of silk fiber 15 is provided with India rubber silk 13, the side of India rubber silk 13 is provided with copper fiber 9, and the side of copper fiber 9 is provided with spandex fibre 8, yarn body 1 Outside offers ventilative gap 10.
In order to facilitate weaving and use, in the present embodiment, it is preferred that antistatic fibre silk 3, heat insulation fiber silk 4 and anti-spoke Penetrate the outside that fiber filament 6 is wrapped in core 5.
In order to make yarn body 1 that there is wearability, the service life of yarn body 1 is improved, in the present embodiment, it is preferred that Wearing layer 14 is a kind of component of nylon fibre material.
In order to make yarn body 1 that there is gas permeability, in the present embodiment, it is preferred that the diameter in ventilative gap 10 is 0.05mm, And ventilative gap 10 is at least provided with ten.
In order to make yarn body 1 that there is easy restorative and toughness, in the present embodiment, it is preferred that crease-resistant fiber filament 7 is a kind of The component of polyester fiber material.
The working principle of the invention and process for using：The outside of yarn body 1 is wound with reinforced wire 2, facilitates reinforcing yarn The fastness of ontology 1, yarn body 1 are internally provided with core 5, and core 5 has been externally wrapped with heat insulation fiber silk 4, has made yarn Ontology 1 has thermal insulation, and the outside of core 5 is wound with radiation resistant fiber silk 6 at a side position of heat insulation fiber silk 4, every Thermal fiber silk 4 has been externally wrapped with antistatic fibre silk 3, and yarn body 1 can be made to have antibacterial, anti-radiation, the function of resistance to electrostatic Effect, the object that yarn can be made to make possess good antibacterial and anti-radiation effect, use convenient for user, yarn body 1 Be internally provided with flame-retardant layer 11, can make yarn body 1 have anti-flammability, improve the use quality of yarn body 1, it is fire-retardant The inside of layer 11 is provided with viscose rayon layer 12, and the inside of viscose rayon layer 12 is provided with wearing layer 14, increases yarn body 1 Wearability, improve the service life of yarn body 1, the inside of wearing layer 14 is provided with crease-resistant fiber filament 7, crease-resistant fiber filament 7 side is provided with silk fiber 15, and yarn body 1 can be made to have conformality, easily restorative and soft smooth, improved The aesthetics and comfort of yarn body 1, the side of silk fiber 15 are provided with India rubber silk 13, and the one of India rubber silk 13 Side is provided with copper fiber 9, and the side of copper fiber 9 is provided with spandex fibre 8, improves the toughness and elasticity of yarn body 1, makes yarn Line ontology 1 is i.e. secured and elastic, and the outside of yarn body 1 offers ventilative gap 10, facilitates yarn body 1 ventilative, originally sets Meter is not only simple in structure, practical function, and improves the use quality and service life of yarn.
In order to make yarn body 1 that there is antistatic effect, in the present embodiment, it is preferable that antistatic fibre silk 3 is a kind of Antistatic far-infrared polyester fiber, specifically, then the polyester fiber adds compound additive using polyester as substrate, by molten Melt blended be prepared.In terms of content, in the polyester fiber that the application obtains, the compound additive including 7-19%, surplus For polyester；For compound additive under above-mentioned mass ratio, polyester fiber obtains preferable technical effect.
Above-mentioned compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle.SiO2Nanoparticle, Fe2O3Nanoparticle is tradition The material with far infrared transmission, in prior art, usually it is added in polyester fiber separately as additive, However, individually addition far infrared additive has the shortcomings that infrared frequency range is narrow in the prior art, and in technical scheme, a side Face, by above-mentioned SiO2Nanoparticle, Fe2O3Nanoparticle mixing addition, can expand the frequency range of far infrared radiation to a certain degree, Unexpected technical results have been achieved.In compound additive described herein, also packet Fe3O4Nanoparticle, Fe3O4It is point The representative of spar type ferrite is dual media, under electromagnetic field effect, the loss to electromagnetic wave include ohmic loss, from Son and electron resonance loss, polarization loss etc., are the excellent absorbing materials of one kind, in technical scheme, by Fe3O4With it Remaining additive is compound, can achieve unexpected beneficial effect by calcining as the wave absorbing agent of polyester fiber.
It further include SrFe in compound additive described herein12O19Nanotube, in calcination process, the SrFe12O19 Nanotube can be used as dispersing agent, promote the uniform mixing of each substance in compound additive, and then disperse in polyester fiber It is even, so that the far infrared transmission of polyester fiber and antistatic effect performance are uniform.
In compound additive, the SiO2Nano particle diameter is 50nm, Fe2O3Nano particle diameter is 100 nm, CuO Nano particle diameter is 30nm, TiO2Nano particle diameter is 60nm, SnO2Nano particle diameter is 50nm；The Fe3O4Nanometer Particle diameter is 10nm；SrFe12O19Tube diameters are 500nm；
In compound additive, SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2The mass fraction of nanoparticle is respectively 4 parts, 3 parts, 2 parts, 5 parts, 9 parts, 16 Part, 16 parts.
Further explanation is made to the present invention below with reference to embodiment.
Embodiment 1
A kind of antistatic far-infrared polyester fiber, specifically, the polyester fiber using polyester as substrate, then adds compound add Add agent, by melting blended be prepared；In terms of content, in the polyester fiber that the application obtains, including 7% compound addition Agent, surplus are polyester.
Above-mentioned compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle；The mass fraction of each substance is respectively 4 parts, 3 parts, 2 Part, 5 parts, 9 parts, 16 parts, 16 parts.The SiO2Nano particle diameter is 50nm, Fe2O3Nano particle diameter is 100nm, and CuO receives Rice corpuscles partial size is 30nm, TiO2Nano particle diameter is 60nm, SnO2Nano particle diameter is 50nm；The Fe3O4Nanoparticle Seed diameter is 10nm；SrFe12O19Tube diameters are 500nm；
It the following is the preparation process of the antistatic far-infrared polyester fiber：
Step 1 weighs FeCl3·6H2Then O weighs FeCl2·4H2O, so that n (Fe3+)：n(Fe2+)=1:3.5 Above two substance is dissolved in the distilled water of 100ml, is made 0.05 mol/L of concentration that the iron ion in solution is total, then should Solution is placed on magnetic stirring apparatus, is stirred to being completely dissolved, and NaOH solution is slowly added dropwise thereto after mixing to pH value of solution Value is 12, and then heat temperature raising makes 50 DEG C of solution temperature, and lauryl sodium sulfate is added thereto after isothermal reaction 1.5h, after It is taken out after continuous reaction 0.5h, cooled to room temperature, then, it is 7 that product, which is washed to pH value, obtains Fe after dry3O4；
Step 2 weighs Sr (NO3)2, then weigh Fe (NO3)3·9H2O, so that n (Fe)：N (Sr)=11.5:1, it will be upper It states two kinds of substances to be dissolved in 30ml distilled water, makes the concentration 0.25mol/L of the iron ion in solution, add on magnetic stirring apparatus Thermal agitation is to being completely dissolved, by metal ion and citric acid molar ratio 1:1 is added citric acid, adjusts pH with ammonium hydroxide after mixing Value is 6, and after continuing heating stirring 2h, surplus solution is blotted with absorbent cotton, then by absorbent cotton in 90 DEG C of dry 12h, finally will It calcines 2h in its Muffle furnace for being put into 1090 DEG C, after Temperature fall, obtains SrFe12O19；
Step 3, according to mass ratio, by SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle is uniformly mixed, and dehydrated alcohol is then added, sufficiently stirs It mixes uniformly, obtains compound additive slurry, be then baked to, under nitrogen protection in 440 DEG C of calcining 3h, 870 DEG C of calcining 5h, It pulverizes to get compound additive；
Step 4 mixes antibacterial agent, anion emission agent and ethylene glycol, and ultrasound 5h at room temperature after stirring is mixed Liquid；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains polyester master particle；Wherein, esterification temperature Degree is 270 DEG C, pressure 280kPa, and polycondensation reaction is carried out when esterification yield reaches greater than 96.5%, and condensation temperature is 290 DEG C, is taken out true Sky is to 20MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；Polyester master particle is melted, was then fed into Filter is filtered, after metering, into spinning pack, then by the tow of ejection carry out it is cooling, oil, be wound into after deflector roll Preoriented yarn, wherein spinning temperature is 273 DEG C, spinning speed 3500m/min；Polyester preoriented yarn is through a roller, hot tank, two It can be prepared into polyester fiber after roller, scroll tube, winding, wherein draft speed 500m/min, draw ratio 3.1, a roll temperature It is 90 DEG C, two roll temperatures are 140 DEG C.
Far infrared test is according to professional standard FZ/T 64010-2000《Far-infrared textiles》, polyester fiber is carried out The test of method phase emissivity, the fiber that the present embodiment is obtained are cut into the powder of 0.5mm long, are modulated into starchiness with waterglass, apply One layer of dry crushing end is spread on the copper sheet that diameter is 2cm, then on its surface.
Test result shows that inspection result shows that its normal emittance is 0.96, according to this field about far infrared performance The assessment of bids is quasi-, and normal emittance, which is more than or equal to 0.8, can be assessed as far-infrared textiles, and the polyester fiber in the present embodiment meets mark Alignment request；
The microwave absorbing property for testing above-mentioned polyester fiber, obtaining maximum wave absorbed crest value is -23.5dB, is better than -10dB bandwidth 1.2GHz has good microwave absorbing property.
Embodiment 2
A kind of antistatic far-infrared polyester fiber, specifically, the polyester fiber using polyester as substrate, then adds compound add Add agent, by melting blended be prepared；In terms of content, in the polyester fiber that the application obtains, add including 19% compound Add agent, surplus is polyester.
Above-mentioned compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle；The mass fraction of each substance is respectively 4 parts, 3 parts, 2 Part, 5 parts, 9 parts, 16 parts, 16 parts.The SiO2Nano particle diameter is 50nm, Fe2O3Nano particle diameter is 100nm, and CuO receives Rice corpuscles partial size is 30nm, TiO2Nano particle diameter is 60nm, SnO2Nano particle diameter is 50nm；The Fe3O4Nanoparticle Seed diameter is 10nm；SrFe12O19Tube diameters are 500nm；
It the following is the preparation process of the antistatic far-infrared polyester fiber：
Step 1 weighs FeCl3·6H2Then O weighs FeCl2·4H2O, so that n (Fe3+)：n(Fe2+)=1:3.5 Above two substance is dissolved in the distilled water of 100ml, is made 0.05 mol/L of concentration that the iron ion in solution is total, then should Solution is placed on magnetic stirring apparatus, is stirred to being completely dissolved, and NaOH solution is slowly added dropwise thereto after mixing to pH value of solution Value is 12, and then heat temperature raising makes 50 DEG C of solution temperature, and lauryl sodium sulfate is added thereto after isothermal reaction 1.5h, after It is taken out after continuous reaction 0.5h, cooled to room temperature, then, it is 7 that product, which is washed to pH value, obtains Fe after dry3O4；
Step 2 weighs Sr (NO3)2, then weigh Fe (NO3)3·9H2O, so that n (Fe)：N (Sr)=11.5:1, it will be upper It states two kinds of substances to be dissolved in 30ml distilled water, makes the concentration 0.25mol/L of the iron ion in solution, add on magnetic stirring apparatus Thermal agitation is to being completely dissolved, by metal ion and citric acid molar ratio 1:1 is added citric acid, adjusts pH with ammonium hydroxide after mixing Value is 6, and after continuing heating stirring 2h, surplus solution is blotted with absorbent cotton, then by absorbent cotton in 90 DEG C of dry 12h, finally will It calcines 2h in its Muffle furnace for being put into 1090 DEG C, after Temperature fall, obtains SrFe12O19；
Step 3, according to mass ratio, by SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle is uniformly mixed, and dehydrated alcohol is then added, sufficiently stirs It mixes uniformly, obtains compound additive slurry, be then baked to, under nitrogen protection in 440 DEG C of calcining 3h, 870 DEG C of calcining 5h, It pulverizes to get compound additive；
Step 4 mixes antibacterial agent, anion emission agent and ethylene glycol, and ultrasound 5h at room temperature after stirring is mixed Liquid；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains polyester master particle；Wherein, esterification temperature Degree is 270 DEG C, pressure 280kPa, and polycondensation reaction is carried out when esterification yield reaches greater than 96.5%, and condensation temperature is 290 DEG C, is taken out true Sky is to 20MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；Polyester master particle is melted, was then fed into Filter is filtered, after metering, into spinning pack, then by the tow of ejection carry out it is cooling, oil, be wound into after deflector roll Preoriented yarn, wherein spinning temperature is 273 DEG C, spinning speed 3500m/min；Polyester preoriented yarn is through a roller, hot tank, two It can be prepared into polyester fiber after roller, scroll tube, winding, wherein draft speed 500m/min, draw ratio 3.1, a roll temperature It is 90 DEG C, two roll temperatures are 140 DEG C.
Far infrared test is according to professional standard FZ/T 64010-2000《Far-infrared textiles》, polyester fiber is carried out The test of method phase emissivity, the fiber that the present embodiment is obtained are cut into the powder of 0.5mm long, are modulated into starchiness with waterglass, apply One layer of dry crushing end is spread on the copper sheet that diameter is 2cm, then on its surface.
Test result shows that inspection result shows that its normal emittance is 0.88, according to this field about far infrared performance The assessment of bids is quasi-, and normal emittance, which is more than or equal to 0.8, can be assessed as far-infrared textiles, and the polyester fiber in the present embodiment meets mark Alignment request；
The microwave absorbing property for testing above-mentioned polyester fiber, obtaining maximum wave absorbed crest value is -18.9dB, is better than -10dB bandwidth 0.7GHz has good microwave absorbing property.
Embodiment 3
A kind of antistatic far-infrared polyester fiber, specifically, the polyester fiber using polyester as substrate, then adds compound add Add agent, by melting blended be prepared；In terms of content, in the polyester fiber that the application obtains, add including 15% compound Add agent, surplus is polyester.
Above-mentioned compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle；The mass fraction of each substance is respectively 4 parts, 3 parts, 2 Part, 5 parts, 9 parts, 16 parts, 16 parts.The SiO2Nano particle diameter is 50nm, Fe2O3Nano particle diameter is 100nm, and CuO receives Rice corpuscles partial size is 30nm, TiO2Nano particle diameter is 60nm, SnO2Nano particle diameter is 50nm；The Fe3O4Nanoparticle Seed diameter is 10nm；SrFe12O19Tube diameters are 500nm；
It the following is the preparation process of the antistatic far-infrared polyester fiber：
Step 1 weighs FeCl3·6H2Then O weighs FeCl2·4H2O, so that n (Fe3+)：n(Fe2+)=1:3.5 Above two substance is dissolved in the distilled water of 100ml, is made 0.05 mol/L of concentration that the iron ion in solution is total, then should Solution is placed on magnetic stirring apparatus, is stirred to being completely dissolved, and NaOH solution is slowly added dropwise thereto after mixing to pH value of solution Value is 12, and then heat temperature raising makes 50 DEG C of solution temperature, and lauryl sodium sulfate is added thereto after isothermal reaction 1.5h, after It is taken out after continuous reaction 0.5h, cooled to room temperature, then, it is 7 that product, which is washed to pH value, obtains Fe after dry3O4；
Step 2 weighs Sr (NO3)2, then weigh Fe (NO3)3·9H2O, so that n (Fe)：N (Sr)=11.5:1, it will be upper It states two kinds of substances to be dissolved in 30ml distilled water, makes the concentration 0.25mol/L of the iron ion in solution, add on magnetic stirring apparatus Thermal agitation is to being completely dissolved, by metal ion and citric acid molar ratio 1:1 is added citric acid, adjusts pH with ammonium hydroxide after mixing Value is 6, and after continuing heating stirring 2h, surplus solution is blotted with absorbent cotton, then by absorbent cotton in 90 DEG C of dry 12h, finally will It calcines 2h in its Muffle furnace for being put into 1090 DEG C, after Temperature fall, obtains SrFe12O19；
Step 3, according to mass ratio, by SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19 Nanotube, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle is uniformly mixed, and dehydrated alcohol is then added, sufficiently stirs It mixes uniformly, obtains compound additive slurry, be then baked to, under nitrogen protection in 440 DEG C of calcining 3h, 870 DEG C of calcining 5h, It pulverizes to get compound additive；
Step 4 mixes antibacterial agent, anion emission agent and ethylene glycol, and ultrasound 5h at room temperature after stirring is mixed Liquid；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains polyester master particle；Wherein, esterification temperature Degree is 270 DEG C, pressure 280kPa, and polycondensation reaction is carried out when esterification yield reaches greater than 96.5%, and condensation temperature is 290 DEG C, is taken out true Sky is to 20MPa, when polycondensation to inherent viscosity is 0.74 deciliter/gram, discharging, and blank；Polyester master particle is melted, was then fed into Filter is filtered, after metering, into spinning pack, then by the tow of ejection carry out it is cooling, oil, be wound into after deflector roll Preoriented yarn, wherein spinning temperature is 273 DEG C, spinning speed 3500m/min；Polyester preoriented yarn is through a roller, hot tank, two It can be prepared into polyester fiber after roller, scroll tube, winding, wherein draft speed 500m/min, draw ratio 3.1, a roll temperature It is 90 DEG C, two roll temperatures are 140 DEG C.
Far infrared test is according to professional standard FZ/T 64010-2000《Far-infrared textiles》, polyester fiber is carried out The test of method phase emissivity, the fiber that the present embodiment is obtained are cut into the powder of 0.5mm long, are modulated into starchiness with waterglass, apply One layer of dry crushing end is spread on the copper sheet that diameter is 2cm, then on its surface.
Test result shows that inspection result shows that its normal emittance is 0.96, according to this field about far infrared performance The assessment of bids is quasi-, and normal emittance, which is more than or equal to 0.8, can be assessed as far-infrared textiles, and the polyester fiber in the present embodiment meets mark Alignment request；
The microwave absorbing property for testing above-mentioned polyester fiber, obtaining maximum wave absorbed crest value is -21.5dB, is better than -10dB bandwidth 1.1GHz has good microwave absorbing property.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of scribbled with anti-static function, including yarn body, reinforced wire, antistatic fibre silk, heat insulation fiber Silk, core, radiation resistant fiber silk, crease-resistant fiber filament, spandex fibre, copper fiber, ventilative gap, flame-retardant layer, viscose rayon layer, bullet Property rubber silk, wearing layer and silk fiber；It is characterized in that, being wound with reinforced wire on the outside of the yarn body, and yarn sheet Body is internally provided with core, and the core has been externally wrapped with heat insulation fiber silk, and the outside of core is close to heat insulation fiber silk A side position at be wound with radiation resistant fiber silk, the heat insulation fiber silk has been externally wrapped with antistatic fibre silk, yarn sheet Body is internally provided with flame-retardant layer, and viscose rayon layer is provided on the inside of the flame-retardant layer, is set on the inside of the viscose rayon layer It is equipped with wearing layer, crease-resistant fiber filament is provided on the inside of the wearing layer, the crease-resistant filametntary side is provided with silk fibroin Dimension, the side of the silk fiber are provided with India rubber silk, and the side of the India rubber silk is provided with copper fiber, the copper The side of fiber is provided with spandex fibre, and the outside of yarn body offers ventilative gap；The antistatic fibre silk is a kind of Then antistatic far-infrared polyester fiber, the polyester fiber add compound additive using polyester as substrate, by melting blended system It is standby to obtain；The compound additive includes：SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19It receives Mitron, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle.
2. a kind of scribbled with anti-static function according to claim 1, which is characterized in that described antistatic remote In infrared polyester fiber, in terms of content, including 7% compound additive, surplus is polyester.
3. a kind of scribbled with anti-static function according to claim 1, which is characterized in that the antistatic fibre Dimension silk, heat insulation fiber silk and radiation resistant fiber silk are wrapped in the outside of core.
4. a kind of scribbled with anti-static function according to claim 1, which is characterized in that the wearing layer is A kind of component of nylon fibre material.
5. a kind of scribbled with anti-static function according to claim 1, which is characterized in that the ventilative gap Diameter be 0.05mm, and ventilative gap is at least provided with ten.
6. a kind of scribbled with anti-static function according to claim 1, which is characterized in that the crease-resistant fiber Silk is a kind of component of polyester fiber material.
7. a kind of scribbled with anti-static function according to claim 2, which is characterized in that compound additive In, the SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19Nanotube, CuO nanoparticle, TiO2 Nanoparticle and SnO2The mass fraction of nanoparticle is respectively 4 parts, 3 parts, 2 parts, 5 parts, 9 parts, 16 parts, 16 parts.
8. a kind of scribbled with anti-static function according to claim 7, which is characterized in that compound additive In, the SiO2Nano particle diameter is 50nm, Fe2O3Nano particle diameter is 100nm, and CuO nano particle diameter is 30nm, TiO2Nano particle diameter is 60nm, SnO2Nano particle diameter is 50nm；The Fe3O4Nano particle diameter is 10nm； SrFe12O19Tube diameters are 500nm.
9. a kind of scribbled with anti-static function according to claim 7, which is characterized in that described antistatic remote The preparation process of infrared polyester fiber：
Step 1 weighs FeCl3·6H2Then O weighs FeCl2·4H2O, so that n (Fe3+)：n(Fe2+)=1:3.5 in 100ml Distilled water in dissolve above two substance, make the concentration 0.05mol/L that the iron ion in solution is total, then set the solution In on magnetic stirring apparatus, stirring to being completely dissolved, it is 12 that NaOH solution to solution ph is slowly added dropwise thereto after mixing, Then heat temperature raising makes 50 DEG C of solution temperature, lauryl sodium sulfate is added thereto after isothermal reaction 1.5h, the reaction was continued It is taken out after 0.5h, cooled to room temperature, then, it is 7 that product, which is washed to pH value, obtains Fe after dry3O4；
Step 2 weighs Sr (NO3)2, then weigh Fe (NO3)3·9H2O, so that n (Fe)：N (Sr)=11.5:1, by above-mentioned two Kind substance is dissolved in 30ml distilled water, is made the concentration 0.25mol/L of the iron ion in solution, is heated and stir on magnetic stirring apparatus It mixes to being completely dissolved, by metal ion and citric acid molar ratio 1:1 is added citric acid, adjusts pH value with ammonium hydroxide after mixing and is 6, after continuing heating stirring 2h, surplus solution is blotted with absorbent cotton, then absorbent cotton is finally put in 90 DEG C of dry 12h Enter and calcine 2h in 1090 DEG C of Muffle furnace, after Temperature fall, obtains SrFe12O19；
Step 3, according to mass ratio, by SiO2Nanoparticle, Fe2O3Nanoparticle, Fe3O4Nanoparticle, SrFe12O19Nanometer Pipe, CuO nanoparticle, TiO2Nanoparticle and SnO2Nanoparticle is uniformly mixed, and dehydrated alcohol is then added, and is sufficiently stirred It is even, compound additive slurry is obtained, is then baked to, under nitrogen protection in 440 DEG C of calcining 3h, 870 DEG C of calcining 5h, grinding At powder to get compound additive；
Step 4 prepares the antistatic far-infrared polyester fiber.
CN201810780816.9A 2018-07-17 2018-07-17 A kind of scribbled with anti-static function Pending CN108893816A (en)

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