CN108892393A - A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles - Google Patents
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles Download PDFInfo
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- CN108892393A CN108892393A CN201810584670.0A CN201810584670A CN108892393A CN 108892393 A CN108892393 A CN 108892393A CN 201810584670 A CN201810584670 A CN 201810584670A CN 108892393 A CN108892393 A CN 108892393A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/012—Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/17—Deposition methods from a solid phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Ceramic Engineering (AREA)
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Abstract
The present invention provides the preparation method that a kind of automatically-controlled door disables high-strength antimicrobial textiles,It is formed using ethyl orthosilicate under the system of gel and adds barium ions,Zinc ion and boron ion,Obtain glass material system,And add the compactness and conductivity of silver powder enhancing system,Then it is covered on silane-modified glass substrate surface,Good dense coating can be formed in glass substrate surface,Also there is good antibacterial,Demisting,High-strength and high anti-shot ability,Enhance polyvinyl butyral using modified aluminum oxide simultaneously,Improve its heating conduction,The preparation method of antibiotic glass provided by the invention solves the problems, such as that traditional direct addition antibacterial agent reduces glass quality into the technique of glass preparation,Dense coating is formed in glass substrate surface at high temperature using the glass material system of generation,Improve the intensity and anti-microbial property of glass,Preparation process of the present invention is simple,It is at low cost,Application prospect is good,It is worth large-scale promotion.
Description
Technical field
The present invention relates to the preparation sides that glass manufacturing area more particularly to a kind of automatically-controlled door disable high-strength antimicrobial textiles
Method.
Background technique
Glass is applied extremely wide in modern society, for example mobile phone used in life, tablet computer, various instruments be aobvious
Display screen and automatic door unit etc., they are glass material.Since there is many bacterium, virus etc., Ren Men in air
Summer, which perspires, mostly directly contacts glass materials, causes grease to be attached to glass surface, this is just provided favorably for the growth of bacterium
Condition, more people's contacts will cause the mutual propagation of bacterium, and be entered in vivo by hand strap, so the glass occurred in public place
Product often may require that cleaning, disinfection, is just avoided that the cross transmission of bacterium, but if cleans one at regular intervals daily
It is secondary to will increase labour and cost, if glass has anti-microbial property automatically, then such issues that can avoid.But in actual production
In the process, the intensity of glass and anti-microbial property tend not to meet actual use needs simultaneously, can not meet in automatic door unit
Performance requirement high-strength to glass, wear-resisting, shock proof, therefore the high glass of a kind of antibacterial, intensity is developed, there is important meaning
Justice.
Summary of the invention
The purpose of the present invention is to provide the preparation methods that a kind of automatically-controlled door disables high-strength antimicrobial textiles, on solving
State technical problem.
The present invention using following technical scheme in order to solve the above technical problems, realized：
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, including step in detail below：
(1) silver nitrate solution is made with deionized water dissolving in silver nitrate, is added dropwise to diallyl dimethyl chlorination
In ammonium salt solution, magnetic agitation is uniformly mixed, and is then added in the sodium borohydride solution that concentration is 0.36mol/L brand-new, wherein nitre
The volume ratio of sour silver, diallyl dimethyl ammoniumchloride solution and sodium borohydride solution is 1:2:1, magnetic agitation reacts 0.5h
After to obtain silver sol spare；
(2) by ethyl orthosilicate, ethyl alcohol and acetic acid according to molar ratio 1：7:It is vigorously stirred 0.5h under 0.07 room temperature, then will
Boric acid, barium acetate and zinc acetate use 75% ethanol solution to dissolve respectively, obtain respective clear solution, are then all added to positive silicic acid
The mixing of ethyl ester pre-hydrolyzed solution, is uniformly mixed, and regulation system pH value obtains vitreosol, add step to 5 under magnetic stirring
Suddenly the silver sol prepared in (1) is aged 4h in 80 DEG C of water-bath after being stirred, it is solidifying that mixing is washed with deionized in filtering
Glue, it is then dry at 100 DEG C in an oven to be transferred in electric furnace the calcining at 500 DEG C afterwards for 24 hours and obtain mixed gel powder, Zhi Houjia
Enter aluminum oxide, silver powder and sodium nitrate and mix and carry out high speed dispersion, is subsequently placed in grinding in ball grinder and obtains superfine powder,
Last vacuum degassing is spare；
(3) it will be dried after substrate glasses dehydrated alcohol and deionized water alternating washes clean, then in mixed acid solution
30-50min is impregnated in middle heating, and taking-up is dried after being rinsed well with a large amount of deionized waters, then coats one surface of glass baseplate
The ethanol solution of one layer of 2% silane coupling agent impregnates 2-2.5h；
(4) pretreated glass baseplate is placed in suitable environment, superfine powder prepared by step (2) is uniformly coated
In the one side of the ethanol solution of pretreated glass substrate surface silane coating coupling agent, it is molten to be subsequently placed in drying removing in baking oven
Agent is subsequently transferred to increase temperature in electric furnace to 550-620 DEG C of isothermal holding 4-6h, is then fed into annealing furnace and carries out at tempering
Reason；
(5) silane coupling agent is made to the silane coupler solution of 1wt% of 50% ethanol solution dissolution, three oxygen are added
Change two aluminium ultrasonic disperse 1h, be subsequently placed in baking oven and dry at 115 DEG C to constant weight, then by polyvinyl butyral, plasticizer
It is placed in high-speed mixer and mixes with treated aluminum oxide, be then transferred in rubber mixing machine and be kneaded, rod temperature is 80
DEG C, then extrusion forming, discharging obtain modified polyvinyl butyral particle；
(6) the unprocessed one side of frit being prepared in step (5) is mutually fitted, step is added in intermediate gaps part
Suddenly the modified polyvinyl butyral particle of (6) preparation, conjunction piece is placed in vacuum bag takes out 3min in advance, is then transferred to autoclave
In, the cold pumping 2h of room temperature, heating increases temperature to 150 DEG C of heat and takes out 1.5h, and constant temperature pressurization keeps 1.5h, and then cooling decompression can obtain
It arrives.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, silver nitrate solution described in step (1)
Concentration is 0.09mol/L.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, polydiene propyl two described in step (1)
The concentration of methyl chloride ammonium salt solution is 0.18mol/L.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, ethyl orthosilicate, boron described in step (2)
The molar ratio of acid, barium acetate and zinc acetate is 1-2：3.8-4.4:1.8-2.3：2.9-3.3.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, preparation in (1) the step of described in step (2)
Silver sol additive amount be silica dioxide gel weight 1/3-1/2.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, aluminum oxide described in step (2)
Additive amount is the 4-7wt% of mixed gel powder weight.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, the additive amount of silver powder described in step (2)
For the 2.8-3.6wt% of mixed gel powder weight.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, the addition of sodium nitrate described in step (2)
Amount is the 4.2-5.1wt% of mixed gel powder weight.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, tempering treatment temperature described in step (4)
It is 700 DEG C, tempering heating time is 240-250s, temperature fall time 140-150s.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, aluminum oxide described in step (5)
Additive amount is the 22-30wt% of silane coupler solution weight.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, polyvinyl alcohol contracting fourth described in step (4)
The mass ratio of aldehyde, plasticizer and treated aluminum oxide is 80-100:2-3:33-40.
The beneficial effects of the invention are as follows：
The present invention is that the nano silver colloidal sol that surfactant is prepared is positively charged using diallyl dimethyl ammoniumchloride
Lotus, and using barium ions, zinc ion and boron ion is added under the system of presoma ethyl orthosilicate formation gel, obtain glass
Material system, and the compactness and conductivity of glass material system in silver powder enhancing high-temperature sintering process are added, then cover
In silane-modified glass substrate surface, good dense coating is formed in glass substrate surface at high temperature, is had good anti-
Bacterium, demisting, high-strength and high anti-shot ability, the formation very good adhesion with glass baseplate is not easily to fall off, while utilizing modification
Aluminum oxide enhances polyvinyl butyral, improves its heating conduction, prevents in access control system because internal and external temperature unevenness causes
The problem of inside glass stress distribution unevenness bursts, the preparation method of antibiotic glass provided by the invention solves traditional
The problem of directly addition antibacterial agent reduces glass quality into the technique of glass preparation, using the glass material system of generation in height
Dense coating is formed in glass substrate surface under temperature, improves the intensity and anti-microbial property of glass, preparation process of the present invention is simple, at
This is low, and application prospect is good, is worth large-scale promotion.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained, and however, the following embodiments are merely preferred embodiments of the present invention, and not all.
Based on the implementation example in the implementation mode, those skilled in the art's obtained other realities without making creative work
Example is applied, protection scope of the present invention is belonged to.Experimental method in following embodiments is unless otherwise specified conventional method,
The materials, reagents and the like used in the following examples is commercially available unless otherwise specified.
A kind of automatically-controlled door disables the preparation method of high-strength antimicrobial textiles, including step in detail below：
(1) 0.09mol/L silver nitrate solution is made with deionized water dissolving in silver nitrate, it is poly- is added dropwise to 0.18mol/L
In diallyldimethylammonium chloride solution, magnetic agitation is uniformly mixed, and the boron hydrogen that concentration is 0.36mol/L brand-new is then added
Change in sodium solution, wherein the volume ratio of silver nitrate, diallyl dimethyl ammoniumchloride solution and sodium borohydride solution is 1:2:
It is spare that silver sol is obtained after 1, magnetic agitation reaction 0.5h；
(2) by ethyl orthosilicate, ethyl alcohol and acetic acid according to molar ratio 1：7:It is vigorously stirred 0.5h under 0.07 room temperature, then will
Boric acid, barium acetate and zinc acetate use 75% ethanol solution to dissolve respectively, obtain respective clear solution, are then all added to positive silicic acid
The mixing of ethyl ester pre-hydrolyzed solution, wherein the molar ratio of ethyl orthosilicate, boric acid, barium acetate and zinc acetate is 1.1：4.1:1.9：3.2
It is uniformly mixed under magnetic stirring, and regulation system pH value obtains vitreosol, add silica dioxide gel weight 1/3 to 5
The step of (1) in silver sol for preparing, be aged 4h after being stirred in 80 DEG C of water-bath, filtering is washed with deionized mixed
Gel is closed, it is then dry at 100 DEG C in an oven to be transferred in electric furnace the calcining at 500 DEG C afterwards for 24 hours and obtain mixed gel powder, it
The aluminum oxide of mixed gel powder weight 4.8wt%, the silver powder and mixed gel of mixed gel powder weight 2.8wt% are added afterwards
The sodium nitrate of powder weight 4.3wt% mixes and carries out high speed dispersion, is subsequently placed in grinding in ball grinder and obtains superfine powder, finally
Vacuum degassing is spare；
(3) it will be dried after substrate glasses dehydrated alcohol and deionized water alternating washes clean, then in mixed acid solution
30min is impregnated in middle heating, and taking-up is dried after being rinsed well with a large amount of deionized waters, and one surface of glass baseplate is then coated one layer
The ethanol solution of 2% silane coupling agent impregnates 2h；
(4) pretreated glass baseplate is placed in suitable environment, superfine powder prepared by step (2) is uniformly coated
In the one side of the ethanol solution of pretreated glass substrate surface silane coating coupling agent, it is molten to be subsequently placed in drying removing in baking oven
Agent is subsequently transferred to increase temperature in electric furnace to 580 DEG C of isothermal holding 4h, is then fed into progress tempering processing, steel in annealing furnace
Changing treatment temperature is 700 DEG C, and tempering heating time is 240s, temperature fall time 150s；
(5) silane coupling agent is made to the silane coupler solution of 1wt% of 50% ethanol solution dissolution, silane is added
The aluminum oxide ultrasonic disperse 1h of coupling agent solution weight 23wt% is subsequently placed in baking oven and is dried at 115 DEG C to constant weight,
It is again 88 according to mass ratio by polyvinyl butyral, plasticizer and treated aluminum oxide:2.3:After 37 mixing
It is placed in high-speed mixer and mixes, be then transferred in rubber mixing machine and be kneaded, rod temperature is 80 DEG C, and then extrusion forming, discharging obtain
Modified polyvinyl butyral particle；
(6) the unprocessed one side of frit being prepared in step (5) is mutually fitted, step is added in intermediate gaps part
Suddenly the modified polyvinyl butyral particle of (6) preparation, conjunction piece is placed in vacuum bag takes out 3min in advance, is then transferred to autoclave
In, the cold pumping 2h of room temperature, heating increases temperature to 150 DEG C of heat and takes out 1.5h, and constant temperature pressurization keeps 1.5h, and then cooling decompression can obtain
It arrives.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
For personnel it should be appreciated that the present invention is not limited to the above embodiments, described in the above embodiment and specification is only the present invention
Preference, be not intended to limit the invention, without departing from the spirit and scope of the present invention, the present invention also has various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent thereof.
Claims (10)
1. the preparation method that a kind of automatically-controlled door disables high-strength antimicrobial textiles, which is characterized in that including step in detail below：
(1) silver nitrate solution is made with deionized water dissolving in silver nitrate, it is molten is added dropwise to diallyl dimethyl ammoniumchloride
In liquid, magnetic agitation be uniformly mixed, then be added concentration be 0.36mol/L brand-new sodium borohydride solution in, wherein silver nitrate,
The volume ratio of diallyl dimethyl ammoniumchloride solution and sodium borohydride solution is 1:2:1, magnetic agitation obtains after reacting 0.5h
It is spare to silver sol；
(2) by ethyl orthosilicate, ethyl alcohol and acetic acid according to molar ratio 1：7:0.5h is vigorously stirred under 0.07 room temperature, then by boron
Acid, barium acetate and zinc acetate use 75% ethanol solution to dissolve respectively, obtain respective clear solution, are then all added to positive silicic acid second
The mixing of ester pre-hydrolyzed solution, is uniformly mixed, and regulation system pH value obtains vitreosol, add step to 5 under magnetic stirring
(1) silver sol prepared in is aged 4h in 80 DEG C of water-bath after being stirred, it is solidifying that mixing is washed with deionized in filtering
Glue, it is then dry at 100 DEG C in an oven to be transferred in electric furnace the calcining at 500 DEG C afterwards for 24 hours and obtain mixed gel powder, Zhi Houjia
Enter aluminum oxide, silver powder and sodium nitrate and mix and carry out high speed dispersion, is subsequently placed in grinding in ball grinder and obtains superfine powder,
Last vacuum degassing is spare；
(3) will substrate glasses dehydrated alcohol and deionized water alternating washes clean after dry, then in mixed acid solution plus
Heat soaking 30-50min, taking-up are dried after being rinsed well with a large amount of deionized waters, and one surface of glass baseplate is then coated one layer
The ethanol solution of 2% silane coupling agent impregnates 2-2.5h；
(4) pretreated glass baseplate is placed in suitable environment, superfine powder prepared by step (2) is coated uniformly on pre-
The one side of the ethanol solution of the glass substrate surface silane coating coupling agent of processing is subsequently placed in drying in baking oven and removes solvent,
It is subsequently transferred to increase temperature in electric furnace to 550-620 DEG C of isothermal holding 4-6h, is then fed into progress tempering processing in annealing furnace；
(5) silane coupling agent is made to the silane coupler solution of 1wt% of 50% ethanol solution dissolution, three oxidations two are added
Aluminium ultrasonic disperse 1h is subsequently placed in baking oven and is dried at 115 DEG C to constant weight, then by polyvinyl butyral, plasticizer and on
Aluminum oxide of stating that treated, which is placed in high-speed mixer, to be mixed, and is then transferred in rubber mixing machine and is kneaded, rod temperature is 80 DEG C, so
Extrusion forming afterwards, discharging obtain modified polyvinyl butyral particle；
(6) the unprocessed one side of frit being prepared in step (5) is mutually fitted, step is added in intermediate gaps part
(6) the modified polyvinyl butyral particle prepared, conjunction piece is placed in vacuum bag takes out 3min in advance, is then transferred to autoclave
In, the cold pumping 2h of room temperature, heating increases temperature to 150 DEG C of heat and takes out 1.5h, and constant temperature pressurization keeps 1.5h, and then cooling decompression can obtain
It arrives.
2. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
The concentration of silver nitrate solution described in step (1) is 0.09mol/L.
3. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
The concentration of diallyl dimethyl ammoniumchloride solution described in step (1) is 0.18mol/L.
4. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
Ethyl orthosilicate described in step (2), boric acid, barium acetate and zinc acetate molar ratio be 1-2：3.8-4.4:1.8-2.3：
2.9-3.3。
5. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
The additive amount of the silver sol prepared in the step of described in step (2) (1) is the 1/3-1/2 of silica dioxide gel weight.
6. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
The additive amount of aluminum oxide described in step (2) is the 4-7wt% of mixed gel powder weight.
7. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
The additive amount of silver powder described in step (2) is the 2.8-3.6wt% of mixed gel powder weight.
8. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
The additive amount of sodium nitrate described in step (2) is the 4.2-5.1wt% of mixed gel powder weight.
9. the preparation method that a kind of automatically-controlled door according to claim 1 disables high-strength antimicrobial textiles, which is characterized in that
Tempering treatment temperature described in step (4) is 700 DEG C, and tempering heating time is 240-250s, temperature fall time 140-150s.
10. a kind of automatically-controlled door according to claim 1 disables the preparation method of high-strength antimicrobial textiles, feature exists
In the additive amount of aluminum oxide described in step (5) is the 22-30wt% of silane coupler solution weight；In step (4)
The mass ratio of the polyvinyl butyral, plasticizer and treated aluminum oxide is 80-100:2-3:33-40.
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891395A (en) * | 2010-07-08 | 2010-11-24 | 江苏惠宇玻璃有限公司 | Method for preparing thermal-insulation, self-cleaning and film-coated toughened glass |
| CN102515560A (en) * | 2011-12-13 | 2012-06-27 | 江苏大学 | Method for preparing graphene/Ag composite conductive film |
| CN102513544A (en) * | 2011-12-13 | 2012-06-27 | 江苏大学 | Method for preparing nanometer silver sol |
| CN103642335A (en) * | 2013-11-29 | 2014-03-19 | 华南理工大学 | Polyvinyl butyral (PVB) heat conduction coating and preparation method thereof |
| CN103857484A (en) * | 2012-05-11 | 2014-06-11 | Lg化学株式会社 | Method for manufacturing hollow metal nanoparticles, and hollow metal nanoparticles manufactured thereby |
| CN104261695A (en) * | 2014-09-19 | 2015-01-07 | 武汉工程大学 | Preparation method of transparent super-hydrophobic zinc oxide coating |
| CN105439643A (en) * | 2015-11-16 | 2016-03-30 | 徐州中韵新材料科技有限公司 | Method for preparing copper/ceramic composite substrate on basis of low-melting-point glass powder |
| CN105957641A (en) * | 2016-06-08 | 2016-09-21 | 天津大学 | Preparation method for glass-coated copper paste used for LTCC substrate |
| CN106393887A (en) * | 2016-06-29 | 2017-02-15 | 朱洋丽 | A preparing process of Low-e bent laminated glass |
-
2018
- 2018-06-08 CN CN201810584670.0A patent/CN108892393A/en not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891395A (en) * | 2010-07-08 | 2010-11-24 | 江苏惠宇玻璃有限公司 | Method for preparing thermal-insulation, self-cleaning and film-coated toughened glass |
| CN102515560A (en) * | 2011-12-13 | 2012-06-27 | 江苏大学 | Method for preparing graphene/Ag composite conductive film |
| CN102513544A (en) * | 2011-12-13 | 2012-06-27 | 江苏大学 | Method for preparing nanometer silver sol |
| CN103857484A (en) * | 2012-05-11 | 2014-06-11 | Lg化学株式会社 | Method for manufacturing hollow metal nanoparticles, and hollow metal nanoparticles manufactured thereby |
| CN103642335A (en) * | 2013-11-29 | 2014-03-19 | 华南理工大学 | Polyvinyl butyral (PVB) heat conduction coating and preparation method thereof |
| CN104261695A (en) * | 2014-09-19 | 2015-01-07 | 武汉工程大学 | Preparation method of transparent super-hydrophobic zinc oxide coating |
| CN105439643A (en) * | 2015-11-16 | 2016-03-30 | 徐州中韵新材料科技有限公司 | Method for preparing copper/ceramic composite substrate on basis of low-melting-point glass powder |
| CN105957641A (en) * | 2016-06-08 | 2016-09-21 | 天津大学 | Preparation method for glass-coated copper paste used for LTCC substrate |
| CN106393887A (en) * | 2016-06-29 | 2017-02-15 | 朱洋丽 | A preparing process of Low-e bent laminated glass |
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