CN108863645A - A kind of soil conditioner and its method of administration - Google Patents
A kind of soil conditioner and its method of administration Download PDFInfo
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- CN108863645A CN108863645A CN201810702759.2A CN201810702759A CN108863645A CN 108863645 A CN108863645 A CN 108863645A CN 201810702759 A CN201810702759 A CN 201810702759A CN 108863645 A CN108863645 A CN 108863645A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01B—SOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
- A01B79/00—Methods for working soil
- A01B79/02—Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
- C05D1/04—Fertilisers containing potassium from minerals or volcanic rocks
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Mechanical Engineering (AREA)
- Environmental Sciences (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Fertilizers (AREA)
Abstract
The present invention provides a kind of soil conditioner and its method of administration, the raw material including following parts by weight:0-50 parts of calcareous fertilisers, 0-30 parts of fertiliser containing magnesium, 0-40 parts of potash fertilizer, 5-50 parts of siliceous fertilizer, 5-10 parts and 5-10 parts of attapulgite of humic acid.Compared with prior art, a kind of soil conditioner raw materials for production of offer of the invention are mostly natural minerals composition, inexpensive, materials simplicity.The soil conditioner of production contains calcium, magnesium, potassium, siliceous fertilizer etc., and effective activation simultaneously supplements soil because being acidified the nutrients such as fixed calcium, phosphorus, potassium, can achieve the effect of balance fertilizing in use.This soil conditioner production method is simple, it is easy, with the prospect being widely popularized.
Description
Technical field
The invention belongs to farmland site remediation technology fields, and in particular to a kind of soil conditioner and its method of administration.
Background technique
Most of cadmium exists all in the form of greenockite in nature, but with the continuous development of society, cadmium is extensive
Applied to nuclear industry, battery industry, electroplating industry, plastics industry etc..Some scientists study discovery soil cadmium content both at home and abroad
It is exceeded, it will lead to agricultural output and quality decline, limit the sustainable development of planting industry.Animal and most people are come
It says, diet intake is the primary approach of cadmium exposure.The World Health Organization provides that human body is 1ug/ to the maximum permissible intake (MPI) of cadmium
(Kgd), various countries also all define the limitation index of the cadmium content in cereal crops.
In the research that Environmental Cadmium Pollution damages human health, general artificial urine cadmium is the important indicator of interior exposed cadmium.People
The dosage of contained cadmium can lead to people's death up to 0.35-0.50g in vivo.Cadmium has larger harm to human body, can by respiratory system and
Digestive system, which enters human body, leads to slow poisoning and acute poisoning.Cadmium is classified as tool by 20th century United Nations Environment Programme (UNEP)
There are the dangerous chemicals of global meaning.
Therefore it provides a kind of soil conditioner processing passivation chromium is necessary.
Summary of the invention
The purpose of the present invention is to provide a kind of soil conditioners, can effectively inhibit the migration of heavy metal in soil,
The heavy metal being passivated in soil, farmland site remediation effect is obvious, effectively facilitates rice absorbing microelement.Moreover, raw material is simple
Single, improvement soil significant effect.
The present invention also provides a kind of method of administration of soil conditioner.
Specific technical solution of the present invention is as follows:
A kind of soil conditioner, the raw material including following parts by weight:
0-50 parts of calcareous fertilisers, 0-30 parts of fertiliser containing magnesium, 0-40 parts of potash fertilizer, 5-50 parts of siliceous fertilizer, 5-10 parts of humic acid and attapulgite
5-10 parts.
Preferably, the calcareous fertilisers include dolomite dust, calcium oxide, conch meal, potassium feldspar, land plaster, zeolite powder, calcium carbonate
Or one or more of calcium hydroxide.
The conch meal refers to shell by the smashed powder of high-temperature calcination, and 95% main component is calcium carbonate.
Preferably, the fertiliser containing magnesium includes dolomite dust, magnesia, magnesia, magnesium chloride, magnesium hydroxide, dolomite containing magnesium
Or one or more of magnesite.
The main component of the magnesia is magnesia, using magnisite as raw material, is forged at a temperature of 800~850 DEG C
It burns, is a kind of air-setting cementing material of fine-powdered.
Preferably, the potash fertilizer includes potassium feldspar, potassium dihydrogen phosphate, sylvite, carnallite, kainite, anhydrous potassium magnesium
One of alum, polyhalite, leonite, picromerite or potassium water glass are a variety of.
Preferably, the siliceous fertilizer includes flyash, red mud, trisiloxanes, disiloxane, polysiloxanes, sodium metasilicate or water
One of glass is a variety of.
The flyash is the fine ash that catching is got off from the flue gas after coal combustion, and flyash is the master of coal-burning power plant's discharge
Want solid waste.
The red mud is that aluminium industry extracts the waste residue being discharged when aluminium oxide.
The humic acid water solubility content of humic acid (butt) >=60%, granularity are 20-120 mesh.
The attapulgite granularity is 100-200 mesh.
The commercially available acquisition of above-mentioned all material, or can be obtained according to producer's self-condition by prior art preparation.
The preparation method of above-mentioned soil conditioner is:Each raw material is uniformly mixed through batch mixer according to formula ratio, crosses 100 mesh
Sieve to get.
A kind of method of administration of soil conditioner provided by the invention, specially:By soil conditioner spreading to be processed
Upper soll layer, then according to turn over agitating mode by soil to be processed together with the conditioner of spreading thereon turn over stirring 2-3 times, turn over
Turning depth is 18-25cm.
Further, the soil conditioner dosage is applied according to 100-200Kg/ mus.
Further, application soil conditioner is sowed again after handling soil 6-10 days.
It is right based on agricultural land soil and two aspect of crops provided by the present invention for administering in the formula of farmland site remediation
Heavy metal substance is passivated, to reduce cadmium content in crop and fruit.Improve soil pH value, cation exchange capacity (CEC) (CEC) etc.
Physicochemical property, by heavy metal in soil from, to not converting using state, reducing its activity and migration in the soil using state
Property, to reduce the biological toxicity of heavy metal-polluted soil and reduce its migration and accumulation in crop products.Firstly, institute
With soil conditioner in alkalinity, soil pH value can be effectively improved, the migration of heavy metal can be reduced.Secondly, containing a large amount of in formula
Calcium ions and magnesium ions, calcium ions and magnesium ions easily form competitive Adsorption with cadmium ion, facilitate crop and reduce absorption to cadmium, while calcium and magnesium is
The indispensable element of crop, the calcium ions and magnesium ions in formula can be sustained in agricultural land soil, and sustainable release calcium ions and magnesium ions improve agriculture
Field fertility persistently acts on crop;Again, attapulgite is contained in formula, attapulgite is porous structure, has huge ratio
Surface area, easily absorption passivation cadmium ion, obstruct absorption of the crop to cadmium;4th, contain humic acid in formula, it is mixed with potash fertilizer
Afterwards, it is easily absorbed by crops, has the function of fertilizer synergistic, improvement soil, stimulation plant growth, improvement agricultural product quality etc., in addition,
Humic acid also has preferable suction-operated to cadmium, can effectively reduce effective cadmium in soil;5th, it is appropriate in formula to joined
Siliceous fertilizer, siliceous fertilizer have important trophism to crop, are conducive to the photosynthesis for improving crop, and enhancing crop supports pest and disease damage
Anti- ability improves the lodging tolerance of crop, effectively prevents the root rot of crop, plays the role of improving crop quality, crop field
Each position silicon concentration in top increases, therefore silicon promotes crop overground part cadmium concentration to reduce in the Energy Deposition of crop overground part.
Compared with prior art, a kind of soil conditioner raw materials for production of offer of the invention are mostly natural minerals composition,
Inexpensive, materials are easy.The soil conditioner of production contains calcium, magnesium, potassium, siliceous fertilizer etc., and effective activation simultaneously supplements soil because of acid
Change the nutrients such as fixed calcium, phosphorus, potassium, can achieve the effect of balance fertilizing in use.The production of this soil conditioner
Mode is simple, it is easy, with the prospect being widely popularized.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is further described.
Embodiment 1
A kind of soil conditioner, the raw material including following parts by weight:35 parts of dolomite dust, 10 parts of magnesium chloride, land plaster 7
Part, 25 parts of dipotassium hydrogen phosphate, 8 parts of humic acid, 10 parts of attapulgite, 5 parts of sodium metasilicate.
It is weighed by formula each component, raw material is uniformly mixed through batch mixer to get soil conditioner.
Embodiment 2
A kind of soil conditioner, the raw material including following components by weight percent:40 parts of land plaster, 20 parts of magnesia, conch meal 10
Part, 15 parts of flyash, 5 parts of sodium metasilicate, 5 parts of humic acid, 5 parts of attapulgite.
It is weighed by formula each component, raw material is uniformly mixed through batch mixer to get soil conditioner.
Embodiment 3
A kind of soil conditioner, the raw material including following components by weight percent:32 parts of flyash, 20 parts of sylvite, polyhalite 5
Part, 15 parts of magnesium chloride, 10 parts of trisiloxanes, 7 parts of humic acid, 5 parts of attapulgite.
It is weighed by formula each component, raw material is uniformly mixed through batch mixer to get soil conditioner.
Embodiment 4
A kind of soil conditioner, the raw material including following components by weight percent:20 parts of Paris white, 10 parts of calcium oxide, zeolite powder
20 parts, 15 parts of magnesia, 5 parts of magnesia, 5 parts of waterglass, 10 parts of red mud, 5 parts of humic acid, 10 parts of attapulgite.
It is weighed by formula each component, raw material is uniformly mixed through batch mixer to get soil conditioner.
Embodiment 5
A kind of soil conditioner, the composition including following components by weight percent:10 parts of potassium water glass, 30 parts of leonite, land plaster
10 parts, 15 parts of magnesia, 7 parts of humic acid, 5 parts of attapulgite, 13 parts of flyash, 10 parts of red mud.
It is weighed by formula each component, raw material is uniformly mixed through batch mixer to get soil conditioner.
Embodiment 6
A kind of soil conditioner, the raw material including following components by weight percent:20 parts of carnallite powder, 10 parts of conch meal, calcium carbonate
20 parts, 5 parts of gypsum, 7 parts of humic acid, 15 parts of zeolite, 5 parts of red mud, 10 parts of polysiloxanes, 8 parts of attapulgite.
It is weighed by formula each component, raw material is uniformly mixed through batch mixer to get soil conditioner.
Effect test
1, test site:The Jiangxi Province town Pingxiang City Gao Keng
2, experimental field soil basic condition:Topography is flat, and fertility is uniform, and irrigation condition is good, loam, and soil is substantially physical and chemical
Character is:
pH | Soil matrix | The soil weight (g/kg) | Soil porosity (%) | Cadmium (mg/kg) |
5.97 | Middle earth | 1.03 | 60.20 | 0.73 |
Organic matter (g/kg) | Full nitrogen (g/kg) | Available potassium (mg/kg) | Available phosphorus (mg/kg) | |
43.4 | 2.37 | 91.02 | 9.00 |
Irrigation water cadmium concentration can satisfy《Agricultural irrigation water quality standard》(GB 5084-2005) standard requirements;
3, test period:On October 9,12 days~2017 June in 2017
4, experimental design:
2 processing of test setting, respectively:
Processing 1:Control, conventional fertilizer application;
Processing 2:Conventional fertilizer application+application Examples 1 to 6 soil conditioner.
Conventional fertilizer application is to be accustomed to by the dose and fertilising of local farmers, applies compound fertilizer (N-P per acre2O5-K2O:15-15-
9) 50Kg, base manure apply 35 kgs/acre of compound fertilizer, 15 kgs/acre of top dressing compound fertilizer.Every plot area 30m2Each processing repeats 3
It is secondary, take random district's groups to arrange.
1. fertilizing management:In addition to the difference of experimental design, fertilising is according to local habitual dose and fertilization mode.
2. insect pest preventing and controlling management:Each test field management is accustomed to cultural method using local rice, by testing carrier
Special messenger is arranged uniformly to carry out liquid manure and pest management.Each cell, in addition to the difference of experimental design, other insect pest preventing and controlling measures
It is consistent, it is ensured that all each breeding time normal growth and developments of experimental plot rice.All are disabled after the comprehensive medication of pregnant heading
Pesticide.
3. water management:In addition to the difference of experimental design, irrigated by habitual, i.e. shallow water tiller reaches seedling in tillering regularity
When drain dry field, water , Yun Miho and heading flowering period keep shoaling layer before water loses before and after booting, rear that field is kept to moisten to receipts
It cuts.
5, for testing kind:Middle rice varieties celebrate Feng You 306.
6, test method:The processing for applying soil conditioner was applied June 12 by 120Kg/ mus, 7 before rice transplanting
It, by soil conditioner spreading to upper soll layer to be processed, then according to turning over agitating mode for soil to be processed together with thereon
The conditioner of spreading turns over stirring 2 times, and overturning depth is 20cm.Rice October 9 harvest, measurement the effective cadmium of each processing soil with
The total cadmium content of brown rice.
The above is only a preferred embodiment of the present invention, it is not intended to limit the present invention in any form.It should
It points out, for those skilled in the art, without departing from the principle of the present invention, if can also make
Dry improvements and modifications, these modifications and embellishments should also be considered as the scope of protection of the present invention.
Claims (9)
1. a kind of soil conditioner, which is characterized in that the soil conditioner includes the raw material of following parts by weight:
0-50 parts of calcareous fertilisers, 0-30 parts of fertiliser containing magnesium, 0-40 parts of potash fertilizer, 5-50 parts of siliceous fertilizer, 5-10 parts of humic acid and attapulgite 5-
10 parts.
2. soil conditioner according to claim 1, which is characterized in that the calcareous fertilisers include dolomite dust, calcium oxide, shellfish
One or more of shell powder, potassium feldspar, land plaster, zeolite powder, calcium carbonate or calcium hydroxide.
3. soil conditioner according to claim 1, which is characterized in that the fertiliser containing magnesium includes dolomite dust, magnesia, water chestnut
One or more of magnesia, magnesium chloride, magnesium hydroxide, dolomite containing magnesium or magnesite.
4. soil conditioner according to claim 1, which is characterized in that the potash fertilizer include potassium feldspar, potassium dihydrogen phosphate,
One of sylvite, carnallite, kainite, langbeinite, polyhalite, leonite, picromerite or potassium water glass or
It is a variety of.
5. soil conditioner according to claim 1, which is characterized in that the siliceous fertilizer includes flyash, red mud, three silicon oxygen
One of alkane, disiloxane, polysiloxanes, sodium metasilicate or waterglass are a variety of.
6. soil conditioner according to claim 1, which is characterized in that the preparation method of the soil conditioner is:It presses
Each raw material is uniformly mixed through batch mixer according to formula ratio, sieve with 100 mesh sieve to get.
7. a kind of method of administration of soil conditioner described in any one of claims 1-6, which is characterized in that the method for administration
Specially:By soil conditioner spreading to upper soll layer to be processed, then according to turn over agitating mode by soil to be processed together with
The conditioner of spreading turns over stirring 2-3 times thereon, and overturning depth is 18-25cm.
8. the method for administration of soil conditioner according to claim 7, which is characterized in that the soil conditioner dosage is pressed
It is applied according to 100-200Kg/ mus.
9. the method for administration of soil conditioner according to claim 7 or 8, which is characterized in that at application soil conditioner
Reason is sowed again after soil 6-10 days.
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109913233A (en) * | 2019-04-28 | 2019-06-21 | 湖南省地球物理地球化学勘查院 | A kind of water paddy soil heavy metal passivation modifying agent |
CN110028367A (en) * | 2019-05-14 | 2019-07-19 | 烟台富慧农业科技有限公司 | A kind of multifunction soil compound fertilizer and preparation method |
CN110092695A (en) * | 2019-04-28 | 2019-08-06 | 格丰科技材料有限公司 | It is a kind of for repairing the soil conditioner and preparation method thereof in cadmium arsenic combined pollution farmland |
CN110257080A (en) * | 2019-07-15 | 2019-09-20 | 东华大学 | A kind of acid soil renovation agent and its preparation method and application |
CN110330978A (en) * | 2019-05-22 | 2019-10-15 | 深圳市深港产学研环保工程技术股份有限公司 | Soil-repairing agent and soil remediation method |
CN110373201A (en) * | 2019-09-04 | 2019-10-25 | 天津水泥工业设计研究院有限公司 | A kind of fast long-acting soil conditioner and preparation method thereof for repairing farmland cadmium pollution |
CN110698288A (en) * | 2019-10-31 | 2020-01-17 | 湖南省土壤肥料研究所 | Mineral substance nutrition balance soil conditioner and preparation method thereof |
CN112898979A (en) * | 2021-01-21 | 2021-06-04 | 中国科学院南京土壤研究所 | Application of potassium calcium magnesium sulfate as repair material in reducing bioavailability of Cd in weakly alkaline soil |
CN112997656A (en) * | 2021-03-08 | 2021-06-22 | 茂施农业科技有限公司 | Method for efficiently reducing standard exceeding of cadmium in rice by utilizing slow-release calcium |
CN113150787A (en) * | 2021-03-24 | 2021-07-23 | 河南农业大学 | Silicon-calcium-magnesium fertilizer soil conditioner and preparation method and application thereof |
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CN105712788A (en) * | 2016-01-21 | 2016-06-29 | 东莞一翔液体肥料有限公司 | Liquid organic soil conditioner and preparation method and application method thereof |
CN106631612A (en) * | 2016-12-29 | 2017-05-10 | 广东万山土壤修复技术有限公司 | Soil conditioner used for rice and preparation method and application method thereof |
CN106748503A (en) * | 2016-12-29 | 2017-05-31 | 广东万山土壤修复技术有限公司 | One planting fruit-trees special-purpose soil conditioner and preparation method thereof |
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CN105130695A (en) * | 2015-07-15 | 2015-12-09 | 中国科学院地理科学与资源研究所 | Composite fertilizer for repairing cadmium-polluted soil, preparation method and application thereof |
CN105712788A (en) * | 2016-01-21 | 2016-06-29 | 东莞一翔液体肥料有限公司 | Liquid organic soil conditioner and preparation method and application method thereof |
CN106631612A (en) * | 2016-12-29 | 2017-05-10 | 广东万山土壤修复技术有限公司 | Soil conditioner used for rice and preparation method and application method thereof |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109913233B (en) * | 2019-04-28 | 2024-02-02 | 湖南省地球物理地球化学调查所 | Rice field soil heavy metal passivation modifier |
CN110092695A (en) * | 2019-04-28 | 2019-08-06 | 格丰科技材料有限公司 | It is a kind of for repairing the soil conditioner and preparation method thereof in cadmium arsenic combined pollution farmland |
CN109913233A (en) * | 2019-04-28 | 2019-06-21 | 湖南省地球物理地球化学勘查院 | A kind of water paddy soil heavy metal passivation modifying agent |
CN110028367A (en) * | 2019-05-14 | 2019-07-19 | 烟台富慧农业科技有限公司 | A kind of multifunction soil compound fertilizer and preparation method |
CN110330978A (en) * | 2019-05-22 | 2019-10-15 | 深圳市深港产学研环保工程技术股份有限公司 | Soil-repairing agent and soil remediation method |
CN110330978B (en) * | 2019-05-22 | 2021-05-25 | 深圳市深港产学研环保工程技术股份有限公司 | Soil remediation agent and soil remediation method |
CN110257080A (en) * | 2019-07-15 | 2019-09-20 | 东华大学 | A kind of acid soil renovation agent and its preparation method and application |
CN110373201A (en) * | 2019-09-04 | 2019-10-25 | 天津水泥工业设计研究院有限公司 | A kind of fast long-acting soil conditioner and preparation method thereof for repairing farmland cadmium pollution |
CN110698288A (en) * | 2019-10-31 | 2020-01-17 | 湖南省土壤肥料研究所 | Mineral substance nutrition balance soil conditioner and preparation method thereof |
CN110698288B (en) * | 2019-10-31 | 2021-12-14 | 湖南省土壤肥料研究所 | Mineral substance nutrition balance soil conditioner and preparation method thereof |
CN112898979A (en) * | 2021-01-21 | 2021-06-04 | 中国科学院南京土壤研究所 | Application of potassium calcium magnesium sulfate as repair material in reducing bioavailability of Cd in weakly alkaline soil |
CN112997656A (en) * | 2021-03-08 | 2021-06-22 | 茂施农业科技有限公司 | Method for efficiently reducing standard exceeding of cadmium in rice by utilizing slow-release calcium |
CN113150787A (en) * | 2021-03-24 | 2021-07-23 | 河南农业大学 | Silicon-calcium-magnesium fertilizer soil conditioner and preparation method and application thereof |
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