CN108863403A - A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile and preparation method thereof - Google Patents
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile and preparation method thereof Download PDFInfo
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- CN108863403A CN108863403A CN201810795357.1A CN201810795357A CN108863403A CN 108863403 A CN108863403 A CN 108863403A CN 201810795357 A CN201810795357 A CN 201810795357A CN 108863403 A CN108863403 A CN 108863403A
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Abstract
The present invention proposes a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile and preparation method thereof, including the following raw material：Waste ceramic, graphite, calcite, diatomite, kaolin, modified silica flour, bamboo charcoal fiber, nitrile rubber, carbon fluorubber, auxiliary agent, nickel chromium triangle-chromium carbide；Preparation method is：1）Waste ceramic, graphite, calcite, diatomite, kaolin, bamboo charcoal fiber mix grinding, obtain material A；2）It takes nitrile rubber and carbon fluorubber to heat, adds stabilizer, obtain material B；3）Material A, material B, modified silica flour are poured into reaction kettle, binder, fungicide is poured into, adds water, mix, obtain slurry；4）Compression moulding obtains idiosome；5）Being dried to water content is 20%, uniformly smears nickel chromium triangle-chromium carbide to idiosome outer surface, then is dried to idiosome moisture lower than 8%；6）Glazing, firing, edging, cooling.The present invention has stronger wearability by scientific and simple preparation method, using ceramic tile prepared by more cheap cost, is convenient for industrialized production.
Description
Technical field
The present invention relates to ceramic tile technical fields, and in particular to a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile and preparation method thereof.
Background technique
Ceramic tile, also known as ceramic tile, are metal oxide and half-metal oxide with fire resisting, via grinding, mixing, compacting,
The processes such as glazing, firing, and the building decoration materials of a kind of porcelain of the acid and alkali-resistance formed or stone matter, referred to as ceramic tile.It is former
Material is mostly mixed by clay, quartz sand etc..Often surface is extremely smooth for finished product ceramic tile, when ceramic tile surface be stained with water it
Afterwards, if there is pedestrian's walking is then easy to fall, there are great security risks.
Chinese patent CN1709822A discloses a kind of composition of raw materials of ceramic tile, is made pottery by golden bank clay 50-70wt%, Hu Shan
Native 10-25wt% and bamboo charcoal powder 15-35wt% is fired, and the glazed tile lacquer black light made of this formula is bright, and color is naturally simple, ceramic tile
Intensity and hardness are high." development that no glaze burns black ceramic tile fastly "（Zhang Xudong, no glaze burn the development of black ceramic tile fastly, ceramic engineering, and the 32nd
It rolled up for the 3rd phase, in June, 1998：29-31）Have studied the formula composition for preparing using natural chromite as colorant and burning black ceramic tile fastly without glaze
And firing condition, and the black optimal technological parameter of porcelain blackness has been determined.But the product as weathering in 1 years --- Jin Antao
Natural chromite native and as colorant, resource is limited, and production cost is higher.
Chinese patent CN201210514108.3 discloses a kind of black ceramic tiles and preparation method thereof of two cm thicks, benefit
With vanadium titanium waste residue, by being reasonably formulated design, Optimizing Technical produces the black ceramic tiles of two cm thicks, solve with
The problem difficult toward the oxidation of existing ceramic tile blank；Products obtained therefrom blackness is pure, quality is fine and close hard, can be used as marmorean replace
Dai Pin has saved cost, but the wear resistance of the ceramic tile is bad, cannot be used for a long time.
Summary of the invention
The purpose of the present invention is to solve the higher cost of ceramic tile in the prior art and the poor disadvantages of wear resistance, and mention
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile out and preparation method thereof.
To achieve the goals above, present invention employs following technical solutions：
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile is designed, is made of the raw material of following weight proportion：80-100 parts of waste ceramic, graphite 30-
40 parts, 30-40 parts of calcite, 15-20 parts of diatomite, 5-10 parts of kaolin, modified silica flour 10-12 parts, bamboo charcoal fiber 3-5
Part, 0.5-1.2 parts of nitrile rubber, 1-2 parts of carbon fluorubber, 1-2 parts of auxiliary agent, nickel chromium triangle -8-12 parts of chromium carbide.
Preferably, the auxiliary agent includes binder, fungicide, stabilizer.
Preferably, the fungicide is dodecyl dimethyl Benzylmagnesium chloride amine, quaternary ammonium salt and isothiazolinone with quality
Than being 1:1：0.7 mixture.
Preferably, the binder is poly- carbonic acid vinegar, and the stabilizer is lead salt stabilizer.
Preferably, the preparation method of the modified silica flour is：Quartz is utilized into ultrasonic grind to nanoscale；Take silicon
The hydrolysis of alkane coupling agent is poured into the silica flour that processing is completed and is stirred under conditions of 70-80 DEG C with the revolving speed of 1000-1500r/min
It mixes, handles 8-10h；Then using corundum ball as mix grinding 1h in the ball mill of abrasive body, vacuum drying to get.
Preferably, it is made of the raw material of following weight proportion：80 parts of waste ceramic, 30 parts of graphite, 30 parts of calcite, diatom
15 parts of soil, 5 parts of kaolin, modified 10 parts of silica flour, 3 parts of bamboo charcoal fiber, 0.5 part of nitrile rubber, 1 part of carbon fluorubber, auxiliary agent 1
Part, 8 parts of nickel chromium triangle-chromium carbide.
Preferably, it is made of the raw material of following weight proportion：100 parts of waste ceramic, 40 parts of graphite, 40 parts of calcite, silicon
20 parts of diatomaceous earth, 10 parts of kaolin, modified 12 parts of silica flour, 5 parts of bamboo charcoal fiber, 1.2 parts of nitrile rubber, 2 parts of carbon fluorubber, auxiliary agent
2 parts, 12 parts of nickel chromium triangle-chromium carbide.
Preferably, it is made of the raw material of following weight proportion：90 parts of waste ceramic, 35 parts of graphite, 35 parts of calcite, diatom
18 parts of soil, 8 parts of kaolin, modified 11 parts of silica flour, 4 parts of bamboo charcoal fiber, 1 part of nitrile rubber, 1.5 parts of carbon fluorubber, auxiliary agent 1.5
Part, 10 parts of nickel chromium triangle-chromium carbide.
The present invention also provides a kind of preparation methods of Environment-friendlywear-resistant wear-resistant type ceramic tile, include the following steps：
1）Waste ceramic, graphite, calcite, diatomite, kaolin, the bamboo charcoal fiber of formula ratio is taken to be added with silica ball as grinding
Mix grinding to material particles reach 700-900 mesh in the ball mill of body, material A of being sieved to obtain；
2）The nitrile rubber of formula ratio and carbon fluorubber is taken to be heated to melting mixing, the stabilizer being added in auxiliary agent is uniformly mixed,
Obtain material B；
3）Material A and material B and modified silica flour are poured into reaction kettle, pour into binder and fungicide at the same time, then
Water is added, ultrasonic wave auxiliary is mixed evenly, and obtains slurry；
4）Slurry is put into molding machine, the compression moulding under the pressure condition of 65-75MPa obtains idiosome；
5）It is 20% that idiosome is dried to moisture content under vacuum conditions, uniformly smears nickel chromium triangle-chromium carbide to idiosome outer surface,
Then idiosome moisture is dried under vacuum conditions again lower than 8%；
6）The idiosome that drying is completed carries out glazing, firing, edging, cooling to get Environment-friendlywear-resistant wear-resistant type ceramic tile.
Preferably, the step 5）Nickel chromium triangle-chromium carbide of middle smearing is with a thickness of 0.3-0.5mm.
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile proposed by the present invention and preparation method thereof, beneficial effect is：
1, the fungicide added in the present invention is the compound of dodecyl dimethyl Benzylmagnesium chloride amine, quaternary ammonium salt and isothiazolinone
Fungicide, dodecyl dimethyl Benzylmagnesium chloride amine have broad-spectrum, efficient sterilizing ability, it is numerous to efficiently control bacterium algae in water
It grows and is produced with foundry loam, used suitable for more moist environment, bactericidal effect is significant；Quaternary ammonium salt can penetrate glutinous mud and dirt, because
This is particularly useful to produce glutinous mud and breeds killing for anaerobic bacteria under sludge；Isothiazolinone is a kind of wide spectrum, efficient, low
Poison, non-oxidative bactericide, therefore there is very strong inhibition and killing effect to common bacteria, fungi, algae etc..It kills livestock efficiency
Height, degradability is good, and with not generating, residual, safe operation, compatibility are good, stability is strong, use cost is low；Therefore the present invention is set
The compound disinfectant of meter can guarantee that ceramic tile has stronger sterilizing ability under various circumstances, and then guarantee the safety of environment.
2, raw material of the invention select waste ceramic, waste reclamation, low in cost and advocate green ecological, reach
The purpose of environmental protection.
3, the present invention can be into one by adding modified silica flour, graphite, nitrile rubber, carbon fluorubber, nickel chromium triangle-chromium carbide
The wearability of the enhancing ceramic tile of step.
To sum up, the present invention is by scientific and simple preparation method, using ceramic tile prepared by more cheap cost have compared with
Strong wearability, is convenient for industrialized production, and is suitble to promote.
Specific embodiment
It is clearly and completely described below in conjunction with the technical solution in the embodiment of the present invention, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.
Embodiment 1
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile, is made of the raw material of following weight proportion：80 parts of waste ceramic, 30 parts of graphite, calcite
30 parts, 15 parts of diatomite, 5 parts of kaolin, modified 10 parts of silica flour, 3 parts of bamboo charcoal fiber, 0.5 part of nitrile rubber, carbon fluorubber 1
Part, 1 part of auxiliary agent, 8 parts of nickel chromium triangle-chromium carbide.
Wherein, auxiliary agent includes binder, fungicide, stabilizer.Fungicide is dodecyl dimethyl Benzylmagnesium chloride amine, season
Ammonium salt and isothiazolinone are with mass ratio for 1:1：0.7 mixture, binder are poly- carbonic acid vinegar, and stabilizer is stablized for lead salts
Agent.
Wherein, the preparation method of modified silica flour is：Quartz is utilized into ultrasonic grind to nanoscale；It takes silane coupled
The silica flour that processing is completed is poured into agent hydrolysis, under conditions of 70-80 DEG C, is stirred with the revolving speed of 1000r/min, handles 8h；So
Afterwards using corundum ball as mix grinding 1h in the ball mill of abrasive body, vacuum drying to get.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant type ceramic tile, includes the following steps：
1）Waste ceramic, graphite, calcite, diatomite, kaolin, the bamboo charcoal fiber of formula ratio is taken to be added with silica ball as grinding
Mix grinding to material particles reach 700 mesh in the ball mill of body, material A of being sieved to obtain；
2）The nitrile rubber of formula ratio and carbon fluorubber is taken to be heated to melting mixing, the stabilizer being added in auxiliary agent is uniformly mixed,
Obtain material B；
3）Material A and material B and modified silica flour are poured into reaction kettle, pour into binder and fungicide at the same time, then
Water is added, ultrasonic wave auxiliary is mixed evenly, and obtains slurry；
4）Slurry is put into molding machine, the compression moulding under the pressure condition of 65MPa obtains idiosome；
5）It is 20% that idiosome is dried to moisture content under vacuum conditions, and uniformly smearing a layer thickness to idiosome outer surface is
Then nickel chromium triangle-chromium carbide of 0.4mm is dried to idiosome moisture lower than 8% under vacuum conditions again；
6）The idiosome that drying is completed carries out glazing, firing, edging, cooling to get Environment-friendlywear-resistant wear-resistant type ceramic tile.
Embodiment 2
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile, is made of the raw material of following weight proportion：100 parts of waste ceramic, 40 parts of graphite, calcite
40 parts, 20 parts of diatomite, 10 parts of kaolin, modified 12 parts of silica flour, 5 parts of bamboo charcoal fiber, 1.2 parts of nitrile rubber, carbon fluorubber 2
Part, 2 parts of auxiliary agent, 12 parts of nickel chromium triangle-chromium carbide.
Wherein, auxiliary agent includes binder, fungicide, stabilizer.Fungicide is dodecyl dimethyl Benzylmagnesium chloride amine, season
Ammonium salt and isothiazolinone are with mass ratio for 1:1：0.7 mixture, binder are poly- carbonic acid vinegar, and stabilizer is stablized for lead salts
Agent.
Wherein, the preparation method of modified silica flour is：Quartz is utilized into ultrasonic grind to nanoscale；It takes silane coupled
The silica flour that processing is completed is poured into agent hydrolysis, under conditions of 70-80 DEG C, is stirred with the revolving speed of 1500r/min, handles 8h；So
Afterwards using corundum ball as mix grinding 1h in the ball mill of abrasive body, vacuum drying to get.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant type ceramic tile, includes the following steps：
1）Waste ceramic, graphite, calcite, diatomite, kaolin, the bamboo charcoal fiber of formula ratio is taken to be added with silica ball as grinding
Mix grinding to material particles reach 900 mesh in the ball mill of body, material A of being sieved to obtain；
2）The nitrile rubber of formula ratio and carbon fluorubber is taken to be heated to melting mixing, the stabilizer being added in auxiliary agent is uniformly mixed,
Obtain material B；
3）Material A and material B and modified silica flour are poured into reaction kettle, pour into binder and fungicide at the same time, then
Water is added, ultrasonic wave auxiliary is mixed evenly, and obtains slurry；
4）Slurry is put into molding machine, the compression moulding under the pressure condition of 65-75MPa obtains idiosome；
5）It is 20% that idiosome is dried to moisture content under vacuum conditions, and uniformly smearing a layer thickness to idiosome outer surface is
Then nickel chromium triangle-chromium carbide of 0.3mm is dried to idiosome moisture lower than 8% under vacuum conditions again；
6）The idiosome that drying is completed carries out glazing, firing, edging, cooling to get Environment-friendlywear-resistant wear-resistant type ceramic tile.
Embodiment 3
A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile, is made of the raw material of following weight proportion：90 parts of waste ceramic, 35 parts of graphite, calcite
35 parts, 18 parts of diatomite, 8 parts of kaolin, modified 11 parts of silica flour, 4 parts of bamboo charcoal fiber, 1 part of nitrile rubber, carbon fluorubber 1.5
Part, 1.5 parts of auxiliary agent, 10 parts of nickel chromium triangle-chromium carbide.
Wherein, auxiliary agent includes binder, fungicide, stabilizer.Fungicide is dodecyl dimethyl Benzylmagnesium chloride amine, season
Ammonium salt and isothiazolinone are with mass ratio for 1:1：0.7 mixture, binder are poly- carbonic acid vinegar, and stabilizer is stablized for lead salts
Agent.
Wherein, the preparation method of modified silica flour is：Quartz is utilized into ultrasonic grind to nanoscale；It takes silane coupled
The silica flour that processing is completed is poured into agent hydrolysis, under conditions of 75 DEG C, is stirred with the revolving speed of 1200r/min, handles 10h；Then
Using corundum ball as mix grinding 1h in the ball mill of abrasive body, vacuum drying to get.
A kind of preparation method of Environment-friendlywear-resistant wear-resistant type ceramic tile, includes the following steps：
1）Waste ceramic, graphite, calcite, diatomite, kaolin, the bamboo charcoal fiber of formula ratio is taken to be added with silica ball as grinding
Mix grinding to material particles reach 700-900 mesh in the ball mill of body, material A of being sieved to obtain；
2）The nitrile rubber of formula ratio and carbon fluorubber is taken to be heated to melting mixing, the stabilizer being added in auxiliary agent is uniformly mixed,
Obtain material B；
3）Material A and material B and modified silica flour are poured into reaction kettle, pour into binder and fungicide at the same time, then
Water is added, ultrasonic wave auxiliary is mixed evenly, and obtains slurry；
4）Slurry is put into molding machine, the compression moulding under the pressure condition of 65MPa obtains idiosome；
5）It is 20% that idiosome is dried to moisture content under vacuum conditions, and uniformly smearing a layer thickness to idiosome outer surface is
Then nickel chromium triangle-chromium carbide of 0.5mm is dried to idiosome moisture lower than 8% under vacuum conditions again；
6）The idiosome that drying is completed carries out glazing, firing, edging, cooling to get Environment-friendlywear-resistant wear-resistant type ceramic tile.
Comparative example 1
Ceramic tile is prepared using method same as Example 1, except that not adding modified silica flour.
Comparative example 2
Ceramic tile is prepared using method same as Example 1, except that not smearing nickel chromium triangle-carbonization layers of chrome.
Comparative example 3
The raw material components of use are identical as the raw material components in embodiment 1, except that preparation method is normal using the prior art
The method for preparing ceramic tile.
The embodiment 1-3 ceramic tile that Environment-friendlywear-resistant wear-resistant type ceramic tile and the obtained 1-3 of comparative example is made is tested for the property, test knot
Fruit such as the following table 1；
Table 1
| Test group | Water absorption rate（%） | Thermal coefficient（W/m·k） | Room temperature abrasion loss（cm3） | Breakdown strength（N） |
| Embodiment 1 | 0.1 | 9.7 | 2.8 | 2356 |
| Embodiment 2 | 0.08 | 9.5 | 2.9 | 2289 |
| Embodiment 3 | 0.09 | 10.1 | 3.0 | 2300 |
| Comparative example 1 | 0.15 | 10.4 | 6.5 | 2087 |
| Comparative example 2 | 0.18 | 10.2 | 6.8 | 2189 |
| Comparative example 3 | 0.19 | 10.4 | 4.7 | 2036 |
It can be seen that the present invention from the data of table 1 to have the following advantages that：
1, it is excellent to can be seen that Environment-friendlywear-resistant wear-resistant type ceramic tile of the present invention has for the data in comparative example 1-3 and comparative example 1-3
Breakdown strength, water absorption rate, thermal coefficient and room temperature abrasion loss are all smaller, and it is good to illustrate that Environment-friendlywear-resistant wear-resistant type ceramic tile of the invention has
Mechanical tenacity well, mechanical shock resistance.
2, the data of embodiment 1 and comparative example 1 are compared as can be seen that when removing modified silica flour in material component
Group timesharing, water absorption rate, thermal coefficient and the room temperature abrasion loss of ceramic tile will increase, and especially room temperature abrasion loss is with the biggest gap, card
Bright modified silica flour is affected to the room temperature abrasion loss of ceramic tile, i.e., is affected to the rub proofness of ceramic tile；It destroys simultaneously strong
Degree decline is also more significant, it was demonstrated that modified silica flour is on can influence the bonding degree of ceramic tile and the compactedness of material.
3, when the data of embodiment 1 and comparative example 2 being carried out can be seen that removal nickel chromium triangle-carbonization layers of chrome, the room temperature of ceramic tile
Abrasion loss significantly increases, and wear-resisting property significantly reduces, and illustrates that nickel chromium triangle-carbonization layers of chrome can protect ceramic tile, to ceramic tile
Wearability has more important role.
4, comparing the data of embodiment 1 and comparative example 3 can be seen that the various of the ceramic tile prepared in embodiment 1
Performance is significantly better than that the ceramic tile of the technique preparation used in comparative example 3, it can be seen that, suitable processing technology, which can be improved, fills out
The dispersibility of material, to be effectively improved the comprehensive mechanical property of material.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile, it is characterised in that：It is made of the raw material of following weight proportion：Waste ceramic 80-100
Part, 30-40 parts of graphite, 30-40 parts of calcite, 15-20 parts of diatomite, 5-10 parts of kaolin, modified silica flour 10-12 parts, bamboo
3-5 parts of Carbon fibe, 0.5-1.2 parts of nitrile rubber, 1-2 parts of carbon fluorubber, 1-2 parts of auxiliary agent, nickel chromium triangle -8-12 parts of chromium carbide.
2. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 1, it is characterised in that：The auxiliary agent includes binder, kills
Microbial inoculum, stabilizer.
3. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 2, it is characterised in that：The fungicide is dodecyl two
Methylbenzyl ammonium chloride, quaternary ammonium salt and isothiazolinone are with mass ratio for 1:1：0.7 mixture.
4. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 1, it is characterised in that：The binder is poly- carbonic acid vinegar,
The stabilizer is lead salt stabilizer.
5. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 1, it is characterised in that：The preparation side of the modified silica flour
Method is：Quartz is utilized into ultrasonic grind to nanoscale；It takes silane coupling agent to hydrolyze, pours into the silica flour that processing is completed,
It under conditions of 70-80 DEG C, is stirred with the revolving speed of 1000-1500r/min, handles 8-10h；Then using corundum ball as the ball of abrasive body
Mix grinding 1h in grinding machine, vacuum drying to get.
6. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 1, it is characterised in that：By the raw material system of following weight proportion
At：80 parts of waste ceramic, 30 parts of graphite, 30 parts of calcite, 15 parts of diatomite, 5 parts of kaolin, modified 10 parts of silica flour, bamboo charcoal
3 parts of fiber, 0.5 part of nitrile rubber, 1 part of carbon fluorubber, 1 part of auxiliary agent, 8 parts of nickel chromium triangle-chromium carbide.
7. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 1, it is characterised in that：By the raw material system of following weight proportion
At：100 parts of waste ceramic, 40 parts of graphite, 40 parts of calcite, 20 parts of diatomite, 10 parts of kaolin, modified 12 parts of silica flour, bamboo
5 parts of Carbon fibe, 1.2 parts of nitrile rubber, 2 parts of carbon fluorubber, 2 parts of auxiliary agent, 12 parts of nickel chromium triangle-chromium carbide.
8. a kind of Environment-friendlywear-resistant wear-resistant type ceramic tile according to claim 1, it is characterised in that：By the raw material system of following weight proportion
At：90 parts of waste ceramic, 35 parts of graphite, 35 parts of calcite, 18 parts of diatomite, 8 parts of kaolin, modified 11 parts of silica flour, bamboo charcoal
4 parts of fiber, 1 part of nitrile rubber, 1.5 parts of carbon fluorubber, 1.5 parts of auxiliary agent, 10 parts of nickel chromium triangle-chromium carbide.
9. the preparation method of Environment-friendlywear-resistant wear-resistant type ceramic tile described in a kind of claim 1-8 any one, it is characterised in that：Including such as
Lower step：
1）Waste ceramic, graphite, calcite, diatomite, kaolin, the bamboo charcoal fiber of formula ratio is taken to be added with silica ball as grinding
Mix grinding to material particles reach 700-900 mesh in the ball mill of body, material A of being sieved to obtain；
2）The nitrile rubber of formula ratio and carbon fluorubber is taken to be heated to melting mixing, the stabilizer being added in auxiliary agent is uniformly mixed,
Obtain material B；
3）Material A and material B and modified silica flour are poured into reaction kettle, pour into binder and fungicide at the same time, then
Water is added, ultrasonic wave auxiliary is mixed evenly, and obtains slurry；
4）Slurry is put into molding machine, the compression moulding under the pressure condition of 65-75MPa obtains idiosome；
5）It is 20% that idiosome is dried to moisture content under vacuum conditions, uniformly smears nickel chromium triangle-chromium carbide to idiosome outer surface,
Then idiosome moisture is dried under vacuum conditions again lower than 8%；
6）The idiosome that drying is completed carries out glazing, firing, edging, cooling to get Environment-friendlywear-resistant wear-resistant type ceramic tile.
10. preparation method according to claim 9, it is characterised in that：The step 5）Nickel chromium triangle-chromium carbide of middle smearing
With a thickness of 0.3-0.5mm.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111592370A (en) * | 2020-06-03 | 2020-08-28 | 朱振朋 | Preparation process of high-strength porous ceramic material |
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| CN103951398A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
| CN104087888A (en) * | 2014-06-19 | 2014-10-08 | 哈尔滨东安发动机（集团）有限公司 | Preparation method for nickel chromium-chromium carbide coating with high hardness and low porosity |
| CN106220144A (en) * | 2016-08-05 | 2016-12-14 | 佛山市寰田陶瓷有限公司 | A kind of wear-resistant ceramic brick and preparation method thereof |
| CN107285764A (en) * | 2017-07-26 | 2017-10-24 | 柳州金特新型耐磨材料股份有限公司 | Wear-resistant ceramic brick and preparation method thereof |
| CN107857569A (en) * | 2017-12-01 | 2018-03-30 | 合肥华福土工合成材料有限公司 | A kind of environment-friendly type ceramic tile and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103951398A (en) * | 2014-04-08 | 2014-07-30 | 安徽省亚欧陶瓷有限责任公司 | High-wear-resistant ceramic tile and preparation method thereof |
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| CN106220144A (en) * | 2016-08-05 | 2016-12-14 | 佛山市寰田陶瓷有限公司 | A kind of wear-resistant ceramic brick and preparation method thereof |
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