CN108854500A - A kind of furfural exhaust gas recycling and processing device - Google Patents

A kind of furfural exhaust gas recycling and processing device Download PDF

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Publication number
CN108854500A
CN108854500A CN201810910983.0A CN201810910983A CN108854500A CN 108854500 A CN108854500 A CN 108854500A CN 201810910983 A CN201810910983 A CN 201810910983A CN 108854500 A CN108854500 A CN 108854500A
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CN
China
Prior art keywords
gas
pipeline
recycling
flow container
slag separation
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810910983.0A
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Chinese (zh)
Inventor
范子久
贺乾龙
王帅
彭兴凯
杨昌宝
崔云峰
杜曙源
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Henan Gran Energy Ltd By Share Ltd
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Henan Gran Energy Ltd By Share Ltd
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Publication date
Application filed by Henan Gran Energy Ltd By Share Ltd filed Critical Henan Gran Energy Ltd By Share Ltd
Priority to CN201810910983.0A priority Critical patent/CN108854500A/en
Publication of CN108854500A publication Critical patent/CN108854500A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0225Other waste gases from chemical or biological warfare

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of furfural exhaust gas recycling and processing devices,Including hydrolyzer and processing unit,Hydrolyzer is connected by pipeline with the first gas-slag separation device,First gas-slag separation device is connected with air accumulator by pipeline,Air accumulator is connected by pipeline with blower,Blower and pipeline is connected with recyclable device,Blower is connected with the entrance of condenser,Condenser is connected by pipeline with recycling flow container,Recycling flow container is connected with spray adsorption tower,Recycling flow container inside pipeline and absorption tower body by being connected,Circulation flow container one end is connected with absorption tower body bottom inner portion,The other end is provided with drawing liquid pump,Drawing liquid pump is connected by pipeline with the spray head being set to inside absorption tower body top,Adsorption tower top is connected by pipeline with the entrance of activated carbon adsorber,The present invention,The waste residue and pernicious gas being discharged from hydrolyzer can be effectively recycled,Reduce the cost of manual recovery waste residue.

Description

A kind of furfural exhaust gas recycling and processing device
Technical field
The present invention relates to furfural production technical fields, and in particular to a kind of furfural exhaust gas recycling and processing device.
Background technique
During furfural production, reacted to obtain furfural in hydrolyzer by corncob, sulfuric acid and high-temperature steam, A large amount of waste residue and organic mixed waste gas can be generated during reaction, if existing waste residue and exhaust gas be directly discharged to it is outdoor It is collected, what is wasted when collecting waste residue is a large amount of artificial, while what is given off mainly includes acetone, acetic acid, formaldehyde, sulfide The organic mixed waste gas of gas, furfural gas, hydride gas etc. is directly discharged in atmosphere without recovery processing, is caused tight The environmental pollution of weight.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of structurally reasonable, easy to use, furfural production can be effectively recycled The waste residue of middle generation and the furfural exhaust gas recycling and processing device of organic mixed waste gas.
To realize above-mentioned target, the technical scheme is that:A kind of furfural exhaust gas recycling and processing device, including hydrolyzer And processing unit, it is characterised in that:Processing unit includes the first gas-slag separation device, air accumulator, blower and recyclable device, hydrolyzer Exhaust outlet be connected by pipeline with the first gas-slag separation device entrance, the gas vent and gas storage at the top of the first gas-slag separation device Tank is connected by pipeline, and the outlet of air accumulator is connected by pipeline with blower, and blower and pipeline is connected with recyclable device It connects, recyclable device includes condenser, recycling flow container, spray adsorption tower and activated carbon adsorber, the entrance phase of blower and condenser The outlet of connection, condenser is connected by pipeline with recycling flow container, and recycling flow container is connected with spray adsorption tower, spray absorption Tower includes absorption tower body, circulation flow container, drawing liquid pump and spray head, and recycling flow container passes through the inside phase of pipeline and absorption tower body bottom end Connection, circulation flow container one end are connected with absorption tower body bottom inner portion, and the other end is provided with drawing liquid pump, drawing liquid pump by pipeline and It is set to the spray head inside absorption tower body top to be connected, adsorption tower top passes through the entrance phase of pipeline and activated carbon adsorber Connection, absorption tower bottom are provided with processing liquid layer, and processing liquid layer is higher than the company that recycling flow container passes through pipeline and absorption tower body bottom end Interface.
Further, the second gas-slag separation device, the second gas-slag separation are provided between the first gas-slag separation device and air accumulator The entrance of device is connected by pipeline with the gas vent at the top of the first gas-slag separation device, and the outlet of the second gas-slag separation device passes through pipe Road is connected with the entrance of air accumulator.
Further, be provided with belt conveyor at the waste residue outlet of the first separator bottom, belt conveyor it is another End extends to the entrance of boiler.
Further, pressure gauge is provided on air accumulator.
Further, recycling flow container is connected by pipeline with waste drains pump.
Further, the first pneumatic operated valve, the second gas slag are provided on the pipeline between hydrolyzer and the first gas-slag separation device The second pneumatic operated valve is provided on pipeline between separator and air accumulator.
Structure of the invention is reasonable, easy to use, can effectively be recycled the waste residue being discharged from hydrolyzer and harmful gas Body reduces the cost of manual recovery waste residue, solves the problems, such as that pernicious gas pollutes environment.
Detailed description of the invention
Fig. 1 the structural representation of present invention.
Drawing explanation:1, hydrolyzer, the 2, first gas-slag separation device, 3, air accumulator, 4, blower, 5, condenser, 6, recovered liquid Tank, 7, spray adsorption tower, 8, activated carbon adsorber, 9, absorption tower body, 10, circulation flow container, 11, drawing liquid pump, the 12, second gas slag point From device, 13, belt conveyor, 14, boiler, 15, waste drains pump, the 16, first pneumatic operated valve, the 17, second operated pneumatic valve.
Specific embodiment
In the description of the present invention, it is to be understood that, term " longitudinal direction ", " transverse direction ", "upper", "lower", "front", "rear", The orientation or positional relationship of the instructions such as "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outside" is based on attached drawing institute The orientation or positional relationship shown is merely for convenience of the description present invention, rather than the device or element of indication or suggestion meaning must There must be specific orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.
In conjunction with attached drawing, the technical schemes of the invention are described in detail, a kind of furfural exhaust gas recycling and processing device, including hydrolyzer 1 And processing unit, it is characterised in that:Processing unit includes the first gas-slag separation device 2, air accumulator 3, blower 4 and recyclable device, water Solution pot exhaust outlet be connected by pipeline with the first gas-slag separation device entrance, the gas vent at the top of the first gas-slag separation device and Air accumulator is connected by pipeline, and the outlet of air accumulator is connected by pipeline with blower, blower and pipeline and recyclable device It is connected, recyclable device includes condenser 5, recycling flow container 6, spray adsorption tower 7 and activated carbon adsorber 8, blower and condenser Entrance be connected, the outlet of condenser is connected by pipeline with recycling flow container, and recycling flow container is connected with adsorption tower is sprayed, Spray adsorption tower includes absorption tower body 9, circulation flow container 10, drawing liquid pump 11 and spray head, and recycling flow container passes through pipeline and adsorption tower The inside of body bottom end is connected, and circulation flow container one end is connected with absorption tower body bottom inner portion, and the other end is provided with drawing liquid pump, takes out Liquid pump is connected by pipeline with the spray head being set to inside absorption tower body top, and adsorption tower top passes through pipeline and active carbon The entrance of adsorption tower is connected, and absorption tower bottom is provided with processing liquid layer, and processing liquid layer is higher than recycling flow container by pipeline and inhales The connector of attached tower body bottom end, hydrolyzer produce furfural during, the waste residue of generation and mainly include furfural gas, acetone, When the organic mixed waste gas of acetic acid, formaldehyde, sulfide gas, furfural gas, hydride gas etc. is discharged from hydrolyzer, gas slag is mixed It closes object to enter in the first waste residue separator using the pressure in hydrolyzer, carries out solid gas separation, exhaust gas is from the first gas-slag separation The gas vent of device is expelled in air accumulator, and waste residue is discharged from the bottom solid outlet of the first waste residue separator, is received for convenience Collection utilizes waste residue, can be provided with belt conveyor 13 at the waste residue outlet of the first separator bottom, belt conveyor it is another End extends to the entrance of boiler 14, and waste residue is delivered in boiler by belt conveyor and is burned, make waste residue treat as fuel into Row burning, effectively recycles waste residue, while having saved the fuel of boiler, passes through wind after the exhaust gas storage entered in air accumulator Machine transports exhaust gas into condenser, and pressure gauge, the pressure in energy effective monitoring air accumulator are provided on air accumulator, and exhaust gas enters In condenser, using the difference of the boiling point of gas each in exhaust gas, by the furfural gas in organic mixed waste gas, acetone, acetic acid Gas is condensed into enter in recovered liquid tank after liquid and be recycled, and recycling flow container is connected by pipeline with waste drains pump 15, waste liquid The liquid recycled in flow container can be delivered in production system again and be recycled by pump, and not condensed gas is arranged from pipeline It puts into adsorption tower, recycles in flow container and processing liquid layer is added with akaline liquid and deodorant, sulfide and first in exhaust gas Aldehyde enters the intracorporal processing liquid layer of adsorption tower from absorption tower bottom and carries out reaction treatment, then drifts from processing liquid layer to absorption In tower body, the liquid with akaline liquid and deodorant is delivered in spray head by drawing liquid pump be sprayed into absorption tower body with The exhaust gas for drifting the intracorporal sulfide of adsorption tower and formaldehyde carries out reaction recycling, and remaining gas is arranged from adsorption tower top Pipeline enters in activated carbon adsorber, and the gas that activated carbon adsorber crosses purified treatment after recycling to hydride gas is discharged into greatly In gas.
When the exhaust gas being discharged from the first gas-slag separation device can be mingled with the waste residue suspended matter of lightweight, waste residue suspended matter is rear Recycling can not be handled in continuous process, therefore the second gas-slag separation device is provided between the first gas-slag separation device and air accumulator 12, the entrance of the second gas-slag separation device is connected by pipeline with the gas vent at the top of the first gas-slag separation device, the second gas slag Separator outlet is connected by pipeline with the entrance of air accumulator, when hydrolyzer carries out deslagging, needs to keep hydrolyzer at this time It is connected to the first gas-slag separation device, the first gas-slag separation device is connected to the second gas-slag separation device, the second gas-slag separation device and gas storage Separate between tank, therefore control connection and partition for convenience, is arranged on the pipeline between hydrolyzer and the first gas-slag separation device There is the first pneumatic operated valve 16, the second pneumatic operated valve 17, the first gas slag are provided on the pipeline between the second gas-slag separation device and air accumulator The suspended matter of exhaust gas and waste residue in separator enters in the second gas-slag separation device from the first gas-slag separation device, the second gas slag point The exhaust gas and waste residue aerosol stream in the first gas-slag separation device are received from device, and by the pressure reduction of this air-flow, exhaust gas and useless Slag suspended matter secondary separation, and stream pressure is made to be unlikely to excessively high, it is then turned on the second pneumatic operated valve, exhaust gas enters in air accumulator and leads to Blower to be crossed to be delivered in condenser, waste residue suspended matter goes out to be discharged after being separated from the waste residue outlet of the second waste residue separator bottom, Herein outlet can direct emission waste residue, can also exit be arranged dust-removal cloth-bag be recycled.
Basic principle of the invention, main feature and advantage has been shown and described above, do not depart from spirit of that invention and Under the premise of range, there are also various changes and modifications, these changes and improvements to both fall within claimed invention by the present invention Range.

Claims (6)

1. a kind of furfural exhaust gas recycling and processing device, including hydrolyzer and processing unit, it is characterised in that:Processing unit includes the The exhaust outlet of one gas-slag separation device, air accumulator, blower and recyclable device, hydrolyzer passes through pipeline and the first gas-slag separation device entrance It is connected, the gas vent at the top of the first gas-slag separation device is connected with air accumulator by pipeline, and the outlet of air accumulator passes through pipe Road is connected with blower, and blower and pipeline is connected with recyclable device, and recyclable device includes condenser, recycling flow container, spray Adsorption tower and activated carbon adsorber, blower are connected with the entrance of condenser, and the outlet of condenser passes through pipeline and recycling flow container It is connected, recycling flow container is connected with spray adsorption tower, and spray adsorption tower includes absorption tower body, circulation flow container, drawing liquid pump and spray Head is drenched, recycling flow container is connected by pipeline with the inside of absorption tower body bottom end, in circulation flow container one end and absorption tower body bottom end Portion is connected, and the other end is provided with drawing liquid pump, and drawing liquid pump passes through pipeline and the spray head phase that is set to inside absorption tower body top Connection, adsorption tower top are connected by pipeline with the entrance of activated carbon adsorber, and absorption tower bottom is provided with processing liquid layer, are located It manages liquid layer and is higher than the connector that recycling flow container passes through pipeline and absorption tower body bottom end.
2. a kind of furfural exhaust gas recycling and processing device according to claim 1, it is characterised in that:First gas-slag separation device and gas storage The second gas-slag separation device is provided between tank, the entrance of the second gas-slag separation device passes through at the top of pipeline and the first gas-slag separation device Gas vent is connected, and the outlet of the second gas-slag separation device is connected by pipeline with the entrance of air accumulator.
3. a kind of furfural exhaust gas recycling and processing device according to claim 1, it is characterised in that:The waste residue of first separator bottom Exit is provided with belt conveyor, and the other end of belt conveyor extends to the entrance of boiler.
4. a kind of furfural exhaust gas recycling and processing device according to claim 1, it is characterised in that:Pressure is provided on air accumulator Table.
5. a kind of furfural exhaust gas recycling and processing device according to claim 1, it is characterised in that:Flow container is recycled by pipeline and is given up Liquid pump is connected.
6. a kind of furfural exhaust gas recycling and processing device according to claim 2, it is characterised in that:Hydrolyzer and the first gas-slag separation It is provided with the first pneumatic operated valve on pipeline between device, is provided with the second gas on the pipeline between the second gas-slag separation device and air accumulator Dynamic valve.
CN201810910983.0A 2018-08-10 2018-08-10 A kind of furfural exhaust gas recycling and processing device Pending CN108854500A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109569203A (en) * 2018-12-10 2019-04-05 安徽金禾实业股份有限公司 A kind of processing method and processing device of furfural dregs and tail gas

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Publication number Priority date Publication date Assignee Title
CN204182266U (en) * 2014-08-19 2015-03-04 衡水中科信能源有限公司 Low-boiling point substance in furfural production retracting device
CN204219998U (en) * 2014-10-16 2015-03-25 常州宝新防腐材料有限公司 A kind of off-gas cleaning equipment
CN105056695A (en) * 2015-08-11 2015-11-18 广西农垦糖业集团华盛化工有限公司 Furfural gas and residue separation and recovery device and recovery method
CN107321123A (en) * 2017-04-06 2017-11-07 浙江奇彩环境科技股份有限公司 A kind of processing method and processing system of chlorination reaction organic exhaust gas
CN107511023A (en) * 2017-09-12 2017-12-26 南通意特化工有限公司 A kind of retracting device and method of new dimethylaniline and acetic acid waste gas
CN206881453U (en) * 2017-02-24 2018-01-16 无锡市智慧环保技术监测研究院有限公司 One kind mixing organic waste-gas purification and energy processing system
CN207085382U (en) * 2017-06-07 2018-03-13 河南新天地药业股份有限公司 A kind of recycling and processing device of workshop mix waste gas
CN207412963U (en) * 2017-11-01 2018-05-29 邢台盛糠糠醛设备制造有限公司 A kind of gas-slag separation of furfural dregs is collected and automatic conveying device
CN207605559U (en) * 2017-10-31 2018-07-13 肥城金威机械有限公司 Emission-control equipment for producing furfural
CN208878261U (en) * 2018-08-10 2019-05-21 河南禾力能源股份有限公司 A kind of furfural exhaust gas recycling and processing device

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204182266U (en) * 2014-08-19 2015-03-04 衡水中科信能源有限公司 Low-boiling point substance in furfural production retracting device
CN204219998U (en) * 2014-10-16 2015-03-25 常州宝新防腐材料有限公司 A kind of off-gas cleaning equipment
CN105056695A (en) * 2015-08-11 2015-11-18 广西农垦糖业集团华盛化工有限公司 Furfural gas and residue separation and recovery device and recovery method
CN206881453U (en) * 2017-02-24 2018-01-16 无锡市智慧环保技术监测研究院有限公司 One kind mixing organic waste-gas purification and energy processing system
CN107321123A (en) * 2017-04-06 2017-11-07 浙江奇彩环境科技股份有限公司 A kind of processing method and processing system of chlorination reaction organic exhaust gas
CN207085382U (en) * 2017-06-07 2018-03-13 河南新天地药业股份有限公司 A kind of recycling and processing device of workshop mix waste gas
CN107511023A (en) * 2017-09-12 2017-12-26 南通意特化工有限公司 A kind of retracting device and method of new dimethylaniline and acetic acid waste gas
CN207605559U (en) * 2017-10-31 2018-07-13 肥城金威机械有限公司 Emission-control equipment for producing furfural
CN207412963U (en) * 2017-11-01 2018-05-29 邢台盛糠糠醛设备制造有限公司 A kind of gas-slag separation of furfural dregs is collected and automatic conveying device
CN208878261U (en) * 2018-08-10 2019-05-21 河南禾力能源股份有限公司 A kind of furfural exhaust gas recycling and processing device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109569203A (en) * 2018-12-10 2019-04-05 安徽金禾实业股份有限公司 A kind of processing method and processing device of furfural dregs and tail gas

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