CN108851004A - The preparation method and applications of carbohydrate metal complex - Google Patents

The preparation method and applications of carbohydrate metal complex Download PDF

Info

Publication number
CN108851004A
CN108851004A CN201810502036.8A CN201810502036A CN108851004A CN 108851004 A CN108851004 A CN 108851004A CN 201810502036 A CN201810502036 A CN 201810502036A CN 108851004 A CN108851004 A CN 108851004A
Authority
CN
China
Prior art keywords
carbohydrate
metal complex
salt
application
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810502036.8A
Other languages
Chinese (zh)
Inventor
陈留平
陈虎
迟韵
李冰
祁志文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Salt Jintan Co Ltd
Original Assignee
China Salt Jintan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Salt Jintan Co Ltd filed Critical China Salt Jintan Co Ltd
Priority to CN201810502036.8A priority Critical patent/CN108851004A/en
Publication of CN108851004A publication Critical patent/CN108851004A/en
Priority to CN201910424540.5A priority patent/CN110200257A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/40—Table salts; Dietetic salt substitutes
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/125—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives containing carbohydrate syrups; containing sugars; containing sugar alcohols; containing starch hydrolysates
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/16—Inorganic salts, minerals or trace elements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H1/00—Processes for the preparation of sugar derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H23/00—Compounds containing boron, silicon, or a metal, e.g. chelates, vitamin B12

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Molecular Biology (AREA)
  • Organic Chemistry (AREA)
  • Nutrition Science (AREA)
  • Polymers & Plastics (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Mycology (AREA)
  • Biochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The present invention relates to the preparation method of carbohydrate metal complex and its as the application of salt anticaking agent；The described application is：Using the combination liquid of carbohydrate metal complex powder or carbohydrate metal complex as being added in salt, it is sufficiently mixed uniformly, as salt anti-caking agent；Carbohydrate metal complex not only has suitable fitment stability as replenishers in the present invention, but also after it discharges iron, ligand carbohydrate has various bioactivity, is the ingredient beneficial to body, can be absorbed and used, Nantural non-toxic；The present invention has found a kind of new anti-salt agglomeration agent, and the development for biological carbohydrate metal complex opens new road, also provides an important foundation for the research and development of anticaking agent and application.

Description

The preparation method and applications of carbohydrate metal complex
Technical field
The present invention relates to the preparation method of carbohydrate metal complex and its as the application of salt anticaking agent.
Background technique
Currently, the salt used in life and industry is largely graininess both at home and abroad, and this salt particle was storing The moisture in environment is easily absorbed in journey or attracting each other and generating consolidation between crystal grain occurs, by original loose graininess Become hard bulk.There is the phenomenon that a large amount of agglomerations during transportation in purified salt, this phenomenon has seriously affected subsequent Packaging, transport, sale, use, to life and industrial production bring inconvenience, in most cases salt agglomeration after just it is complete Full life, industrial production and industry development cannot be seriously affected using production.With the increasing of purified salt annual requirement and usage amount Greatly, salt agglomeration problems always are the historic problem of scientific circles and Salt Industry, urgently to be resolved.
Currently, ferrocyanide salt is the anti-salt agglomeration agent of world standard.But in film electrolysis production process, ferrocyanide Salt has apparent ill-effect, because iron can be deposited in the surface or inside of film and cathode as ferric hydroxide.This is just The energy consumption of film electrolysis process is increased, and cyanide can also be partially converted to the agene of explosion danger.? In world wide, the use of film electrolysis process gradually increases, to expand to the potent anticaking agent for being free of ferrocyanide salt Demand.
Unexpectedly, it has been found that the anticaking agent of not disadvantages mentioned above, i.e. carbohydrate metal complex can be produced.
Iron, calcium, magnesium are required microelements in human body, during body various physiology and biochemistries from emphatically It acts on.When internal asiderosis, it may appear that iron deficiency or hypoferric anemia.Calcium, magnesium are the important components for constituting bone, tooth. Carbohydrate metal complex not only has suitable fitment stability as replenishers, but also after its release of trace elements, matches Body sugar has various bioactivity, is the ingredient beneficial to body, can be absorbed and used, Nantural non-toxic.
Summary of the invention
The purpose of the present invention is：Overcome it is insufficient in the prior art, provide a kind of carbohydrate metal complex preparation method and Its application as salt anticaking agent, the present invention in carbohydrate metal complex salt particle can be made to be evenly distributed, good dispersion, Salt caking phenomenon is effectively prevented in storage, transportational process.
In order to solve the above technical problems, the technical solution adopted by the present invention is as follows：
A kind of application of carbohydrate metal complex as salt anticaking agent, the application are：Using carbohydrate metal complex as Anti-caking agent is added in salt.
Preferably, the additive amount of the carbohydrate metal complex is 5~150ppm of salt weight, carbohydrate metal complex Additive amount is with elemental metal.
Preferably, the salt selects one or both of sodium chloride and potassium chloride.
Preferably, the carbohydrate in the carbohydrate metal complex selects one of monosaccharide, oligosaccharide and polysaccharide or a variety of.
Preferably, the monosaccharide selects glucose, and the oligosaccharide selects galactooligosaccharide, oligofructose, oligomeric different wheat Bud sugar, xylo-oligosaccharide, the polysaccharide select tea polysaccharide, glucose, rhamnose, trehalose, polyfructosan, polydextrose, cottonseed Sugar, L-arabinose, fucose.
Preferably, the carbohydrate in the carbohydrate metal complex selects glucose.
Preferably, the metal in the carbohydrate metal complex selects one of iron, calcium and magnesium.
Preferably, the metal in the carbohydrate metal complex selects iron.
The method for preparing carbohydrate metal complex, the carbohydrate metal complex are carbohydrate-iron complex, the method packet Include following steps：
（1）1~4g of glucide, 0.1~1g of trisodium citrate are taken, 40~80ml of water is added, is heated to 20~80 DEG C, is delayed simultaneously It is slow that NaOH solution and FeCl is added dropwise3Solution controls the pH value of solution in 8~8.5 ranges, when occurring brownish red in reaction solution not When insoluble precipitate, stop that FeCl is added dropwise3And NaOH solution, continue to be stirred to react 1h, prepares carbohydrate-iron complex combination Liquid.
The method for preparing carbohydrate metal complex, the carbohydrate metal complex are carbohydrate-iron complex powder, the side Method includes the following steps：
（1）1~4g of glucide, 0.1~1g of trisodium citrate are taken, 40~80ml of water is added, range of reaction temperature is 20~80 DEG C, while NaOH solution and FeCl is slowly added dropwise3Solution controls the pH value of solution in 7.5~8.5 ranges, when in reaction solution When there is brownish red infusible precipitate, stop that FeCl is added dropwise3And NaOH solution, continue to be stirred to react 1h, prepares carbohydrate-iron Complex compound combines liquid；
（2）Carbohydrate-iron complex powder preparation：After reaction solution is cooled to room temperature, centrifugation takes supernatant liquid body, is added about 2 95% ethyl alcohol of~4 times of volumes, occurs red-brown precipitation substance in solution, and standing keeps precipitating complete；Centrifuge separation, precipitating difference It is respectively washed once with 95% ethyl alcohol, dehydrated alcohol, dry amorphous Red-brown powder, is carbohydrate-iron complex.
Preferably, the mass fraction of the NaOH solution is 20%, FeCl3The molar concentration of solution is 2mol/L.
It is using the beneficial effect of technical solution of the present invention：
1, carbohydrate metal complex not only has suitable fitment stability as replenishers in the present invention, but also when it discharges iron Later, ligand carbohydrate has various bioactivity, is the ingredient beneficial to body, can be absorbed and used, Nantural non-toxic；
2, the present invention has found a kind of new anti-salt agglomeration agent, and the development for biological carbohydrate metal complex opens new road Road also provides an important foundation for the research and development of anticaking agent and application.
Specific embodiment
The following examples can make those skilled in the art that the present invention be more completely understood, but therefore will be not of the invention It is limited among the embodiment described range.
Carbohydrate-iron complex powder and the preparation for combining liquid：
1~4g of glucide, 0.1~1g of trisodium citrate are taken, 40~80ml of water is added, is heated to 20~80 DEG C, the present embodiment In preferably：Glucide 2g, trisodium citrate 0.5g are taken, water 60ml is added, is heated to 70 DEG C, while being slowly added dropwise 20% NaOH solution and 2mol/L FeCl3Solution controls the pH value of solution in 8~8.5 ranges, when occurring brownish red in reaction solution When infusible precipitate, stop that FeCl is added dropwise3And NaOH solution, continue to be stirred to react 1h, obtains carbohydrate-iron and combine liquid.Wait react Liquid cooling but after, centrifugation takes upper layer dark red liquid, and 95% ethyl alcohol of about 3 times of volumes is added, red-brown precipitation object occurs in solution Matter, standing keep precipitating complete.Centrifuge separation, precipitating is respectively washed once with 95% ethyl alcohol, dehydrated alcohol respectively, amorphous redly dry Brown powder is carbohydrate-iron.
Glucide is preferably the glucose in monosaccharide in the present invention, remaining carbohydrate is for example：It is low in tea polysaccharide, oligosaccharide Poly- galactolipin, oligofructose, oligoisomaltose, xylo-oligosaccharide, rhamnose, trehalose, polyfructosan, poly- grape in polysaccharide Sugar, raffinose, L-arabinose, fucose are suitable for the embodiment of the present invention, and carbohydrate-iron network is made by above-mentioned glucide The method for closing object is same as above.
Carbohydrate metal complex in the present invention is preferably glucose-iron complex.
Embodiment 1：
In the dry salt sodium chloride that 100g does not add anticaking agent, 15ppm glucose-iron complex powder is added（In terms of Fe）, sufficiently Anti-caking salt is made in mixing.
Embodiment 2：
In the dry salt sodium chloride that 100g does not add anticaking agent, 40ppm glucose-iron complex powder is added（In terms of Fe）, sufficiently Anti-caking salt is made in mixing.
Embodiment 3：
In the dry salt sodium chloride that 100g does not add anticaking agent, 55ppm glucose-iron complex is added and combines liquid（In terms of Fe）, fill Divide mixing, anti-caking salt is made.
Embodiment 4：
In the dry salt sodium chloride that 100g does not add anticaking agent, 65ppm glucose-iron complex is added and combines liquid（In terms of Fe）, fill Divide mixing, anti-caking salt is made.
Embodiment 5：
In the dry salt sodium chloride that 100g does not add anticaking agent, 55ppm polyfructosan-iron complex powder is added（In terms of Fe）, fill Divide mixing, anti-caking salt is made.
Embodiment 6：
In the dry salt sodium chloride that 100g does not add anticaking agent, 55ppm raffinose-iron complex is added and combines liquid（In terms of Fe）, fill Divide mixing, anti-caking salt is made.
Embodiment 7：
In the dry salt sodium chloride that 100g does not add anticaking agent, 75ppm L-arabinose-iron complex powder is added（In terms of Fe）, It is sufficiently mixed, anti-caking salt is made.
Embodiment 8：
In the dry salt sodium chloride that 100g does not add anticaking agent, 40ppm fucose-iron complex is added and combines liquid（In terms of Fe）, fill Divide mixing, anti-caking salt is made.
Blocking test：
Anti-caking salt obtained and not plus the sodium chloride salt of any anti-caking agent is weighed in Examples 1 to 8 respectively（As blank Control）Each 7g, pure water is added into each sample respectively makes the moisture of each sample salt acquisition 2.1%, with the pressure of 2Mpa on tablet press machine It forces reality and releases print after stopping 30s, in 4h dry in 80 DEG C of air dry ovens, then test and be crushed in pressure testing machine Power is repeated 3 times test, is averaged, and agglomeration resistance degree is indicated with caking rate, and the smaller expression agglomeration resistance degree of caking rate is better （Caking rate=sample broke power/kgf ÷ blank salt crushing force/kgf）.
The results show that anti-caking salt obtained by Examples 1 to 8 all has different degrees of resistive connection block effect, experiment is surveyed Examination data are shown in Table 1.
Table 1
Embodiment Crushing force/kgf Blank/kgf Caking rate/%
1 26.903 54.012 49.81
2 19.644 54.012 36.37
3 16.16 54.012 29.92
4 23.856 71.252 33.48
5 25.632 71.252 35.97
6 24.645 71.252 34.59
7 31.346 64.139 48.87
8 51.834 64.139 80.82
The above results show that glucose-iron complex is the preferred anti-caking agent of salt.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.It is all in essence of the invention Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should all be included in the protection scope of the present invention.This The technical scope of item invention is not limited to the contents of the specification, it is necessary to its technology is determined according to scope of the claims Property range.

Claims (10)

1. a kind of application of carbohydrate metal complex, it is characterised in that：The described application is：By carbohydrate metal complex powder or The combination liquid of carbohydrate metal complex is sufficiently mixed as being added in salt uniformly, as salt anti-caking agent.
2. the application of carbohydrate metal complex according to claim 1, it is characterised in that：The carbohydrate metal complex Additive amount is 5~150ppm of salt weight, and the additive amount of carbohydrate metal complex is with elemental metal.
3. the application of carbohydrate metal complex according to claim 1, it is characterised in that：The salt selects sodium chloride and chlorine Change one or both of potassium.
4. the application of carbohydrate metal complex according to claim 1, it is characterised in that：In the carbohydrate metal complex Carbohydrate select one of monosaccharide, oligosaccharide and polysaccharide or a variety of.
5. the application of carbohydrate metal complex according to claim 4, it is characterised in that：The monosaccharide selects glucose, The oligosaccharide selects galactooligosaccharide, oligofructose, oligoisomaltose, xylo-oligosaccharide, and the polysaccharide selects glucose, mouse Lee's sugar, trehalose, polyfructosan, polydextrose, raffinose, L-arabinose, fucose.
6. the application of carbohydrate metal complex according to claim 5, it is characterised in that：In the carbohydrate metal complex Carbohydrate select glucose.
7. the application of carbohydrate metal complex according to claim 1, it is characterised in that：In the carbohydrate metal complex Metal select one of iron, calcium and magnesium.
8. the application of carbohydrate metal complex according to claim 7, it is characterised in that：In the carbohydrate metal complex Metal select iron.
9. the method for preparation such as carbohydrate metal complex of any of claims 1-8, it is characterised in that：The carbohydrate Metal complex is carbohydrate-iron complex combination liquid, be the described method comprises the following steps：
（1）1~4g of glucide, 0.1~1g of trisodium citrate are taken, 40~80ml of water is added, range of reaction temperature is 20~80 DEG C, while NaOH solution and FeCl is slowly added dropwise3Solution controls the pH value of solution in 7.5~8.5 ranges, when in reaction solution When there is brownish red infusible precipitate, stop that FeCl is added dropwise3And NaOH solution, continue to be stirred to react 1h, prepares carbohydrate-iron Complex compound combines liquid.
10. the method for preparation such as carbohydrate metal complex of any of claims 1-8, it is characterised in that：The sugar Metalloid complex compound is carbohydrate-iron complex powder, be the described method comprises the following steps：
（1）1~4g of glucide, 0.1~1g of trisodium citrate are taken, 40~80ml of water is added, range of reaction temperature is 20~80 DEG C, while NaOH solution and FeCl is slowly added dropwise3Solution controls the pH value of solution in 7.5~8.5 ranges, when in reaction solution When there is brownish red infusible precipitate, stop that FeCl is added dropwise3And NaOH solution, continue to be stirred to react 1h, prepares carbohydrate-iron Complex compound combines liquid；
（2）Carbohydrate-iron complex powder preparation：After reaction solution is cooled to room temperature, centrifugation takes supernatant liquid body, is added about 2 95% ethyl alcohol of~4 times of volumes, occurs red-brown precipitation substance in solution, and standing keeps precipitating complete；Centrifuge separation, precipitating difference It is respectively washed once with 95% ethyl alcohol, dehydrated alcohol, dry amorphous Red-brown powder, is carbohydrate-iron complex.
CN201810502036.8A 2018-05-23 2018-05-23 The preparation method and applications of carbohydrate metal complex Pending CN108851004A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201810502036.8A CN108851004A (en) 2018-05-23 2018-05-23 The preparation method and applications of carbohydrate metal complex
CN201910424540.5A CN110200257A (en) 2018-05-23 2019-05-21 Anticaking agent and its preparation method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810502036.8A CN108851004A (en) 2018-05-23 2018-05-23 The preparation method and applications of carbohydrate metal complex

Publications (1)

Publication Number Publication Date
CN108851004A true CN108851004A (en) 2018-11-23

Family

ID=64333056

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201810502036.8A Pending CN108851004A (en) 2018-05-23 2018-05-23 The preparation method and applications of carbohydrate metal complex
CN201910424540.5A Pending CN110200257A (en) 2018-05-23 2019-05-21 Anticaking agent and its preparation method and application

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201910424540.5A Pending CN110200257A (en) 2018-05-23 2019-05-21 Anticaking agent and its preparation method and application

Country Status (1)

Country Link
CN (2) CN108851004A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109851803A (en) * 2018-12-27 2019-06-07 天津理工大学 A kind of preparation method and application of the metal porous coordination polymer of glycosyl
CN110200257A (en) * 2018-05-23 2019-09-06 中盐金坛盐化有限责任公司 Anticaking agent and its preparation method and application
CN110305233A (en) * 2019-07-19 2019-10-08 武汉轻工大学 A kind of lotus root polysaccharide iron complexes and its preparation method and application
CN113234107A (en) * 2021-06-02 2021-08-10 风之虎研盐实验室科技(江苏)有限公司 Salt-proof caking agent, salt-proof caking agent intermediate and preparation method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115918885B (en) * 2022-12-08 2024-02-27 益盐堂（应城）健康盐制盐有限公司 Anti-caking edible salt and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5997937A (en) * 1996-05-06 1999-12-07 Kraft Foods, Inc. Quick-setting gel mix
CA2763581C (en) * 2009-06-02 2018-02-27 Akzo Nobel Chemicals International B.V. Non-caking salt composition, preparation process and use thereof
CN106071643A (en) * 2016-06-20 2016-11-09 中盐金坛盐化有限责任公司 A kind of tea polysaccharide iron complexes is as the application of salt anti-caking agent
CN108851004A (en) * 2018-05-23 2018-11-23 中盐金坛盐化有限责任公司 The preparation method and applications of carbohydrate metal complex

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110200257A (en) * 2018-05-23 2019-09-06 中盐金坛盐化有限责任公司 Anticaking agent and its preparation method and application
CN109851803A (en) * 2018-12-27 2019-06-07 天津理工大学 A kind of preparation method and application of the metal porous coordination polymer of glycosyl
CN110305233A (en) * 2019-07-19 2019-10-08 武汉轻工大学 A kind of lotus root polysaccharide iron complexes and its preparation method and application
CN113234107A (en) * 2021-06-02 2021-08-10 风之虎研盐实验室科技(江苏)有限公司 Salt-proof caking agent, salt-proof caking agent intermediate and preparation method

Also Published As

Publication number Publication date
CN110200257A (en) 2019-09-06

Similar Documents

Publication Publication Date Title
CN108851004A (en) The preparation method and applications of carbohydrate metal complex
CA1167378A (en) Dry dialysate products
US11578194B2 (en) Thickening composition improved in viscosity development
CN103876158A (en) Elemental selenium and sugar compound and preparation method thereof
KR102082752B1 (en) Powder compositions of a complex between an acid and a metal and method for preparing same
JP5918058B2 (en) Dialysis agent and method for producing dialysis agent
WO2018181006A1 (en) Anhydrous dibasic calcium phosphate, and method for producing same
CN112715916A (en) Low-density microporous spherical edible salt and preparation method thereof
CN102885243A (en) High-content particle honey and preparation method thereof
CA2893813C (en) Method for making mineral salt and mineral salt product
CN102626217B (en) Method for preparing iodised salt and special device thereof
CN103536623B (en) Potassium magnesium aspartate composition freeze-dried powder for injection
CN101669610B (en) Method for manufacturing moisture-free granular flavoring
CN102106870B (en) Method for preparing high-density calcium carbonate granules
CN102349643A (en) Salt
CN101433333B (en) Salt taste additive agent, low-sodium salt taste agent and preparation thereof
CN107616970A (en) A kind of carbasalate calcium soluble powder and preparation method thereof
CN103930199A (en) Oxygen absorbent
CN103271900B (en) Zinc citrate tablet and preparation method thereof
CN113142453A (en) Composite electrolyte solid beverage and preparation method thereof
CN108125193A (en) A kind of preparation method of food additive citric acid iron
CN106954778A (en) A kind of suitable pregnancy period supplement Sugarless type Biocal and preparation method thereof
CN103155945B (en) Retarding gas chlorine dioxide solid generating preparation
CN109965176A (en) Agar-agar eats suspending agent and preparation method thereof
CN102415550A (en) Table salt

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181123

WD01 Invention patent application deemed withdrawn after publication