CN108835711A - A kind of filter and its application based on polymer multicore fibre pipe - Google Patents

A kind of filter and its application based on polymer multicore fibre pipe Download PDF

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Publication number
CN108835711A
CN108835711A CN201810451941.5A CN201810451941A CN108835711A CN 108835711 A CN108835711 A CN 108835711A CN 201810451941 A CN201810451941 A CN 201810451941A CN 108835711 A CN108835711 A CN 108835711A
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Prior art keywords
fibre pipe
polymer
multicore
multicore fibre
filter
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CN201810451941.5A
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Inventor
黄小军
黄赋
张清程
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Zhejiang University ZJU
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Zhejiang University ZJU
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Priority to CN201810451941.5A priority Critical patent/CN108835711A/en
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Filtering Materials (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

The present invention relates to tobacco plug manufacturing technology fields, it is desirable to provide a kind of filter and its application based on polymer multicore fibre pipe.The filter, including lapping and polymer multicore fibre pipe, tight at least one polymer multicore fibre pipe forms uniform cylindrical body bar in lapping;Inside polymer multicore fibre pipe dense distribution it is several along axial elongated orifices arranged in parallel, duct forms gas flow;Polymer multicore fibre pipe is lower than 200 DEG C less than 100 DEG C, fusing point by glass transition temperature and specific heat capacity is greater than 1.5kJkg‑1·K‑1Thermoplastic resin be made, the filter be applied to tobacco product in.Product of the present invention greatly improves filter and exchanges specific surface with smoke contacts, to promote exchange rate, quickly reduces the transient temperature of high-temperature flue gas;Multicore fibre pipe is prepared using once-forming method, it can be achieved that full-automatic production.

Description

A kind of filter and its application based on polymer multicore fibre pipe
Technical field
The invention belongs to tobacco plug manufacturing technology fields, and in particular to a kind of filtering based on polymer multicore fibre pipe Device and its application.
Background technique
In recent years, electronic cigarette, heating do not burn the new tobacco productses such as tobacco product just in rapid rising.Electronic cigarette is not The tobacco of pipe tobacco form is directly used, mainly will be atomized to form vaporous object from the nicotine liquid of tobacco.It heats non-ignitable Burning tobacco product is to heat tobacco using external heat source rather than light tobacco to generate with tobacco flavor gas, has charcoal to add The modes such as heat, electric heating.Novel tobacco is known as a healthier substitute of traditional tobacco product, the nuisance in flue gas Matter is relatively fewer.But since novel tobacco is by the way of airtight heating, and cigarette is shorter, leads to entrance flue gas temperature mistake It scalds, still has larger gap with traditional cigarette in terms of suction experience is with suction.Therefore, suitable cooling material is chosen Have great importance to reducing flue-gas temperature, improving flue gas mouthfeel.
Patent 201210336384, which discloses one kind, can reduce filter rod of flue-gas temperature and preparation method thereof, in package material Micropore aluminium layer is adhered to by glue-line in material front, reduces flue-gas temperature using the condensation of micropore aluminium, but the invention is only used for Traditional tobacco, novel tobacco effect higher for exit gas temperature are unknown.
Patent 201710785910.9 discloses a kind of perfuming temperature-lowering base rod, and a certain proportion of diameter is adulterated in filter stick and is The acid fiber by polylactic particle or acetate fiber particle of 0.45~0.6mm.Patent 201710785572.9 discloses a kind of cooling increasing Fragrant film gathers base rod, and zigzag and the folding with the irregular exhaust gases passes of several size and shapes are wrapped up in filter stick Shape acid fiber by polylactic film or acetate film.Whether granular materials or thin-film material, common problem are that accumulation is close Spend smaller, material and smoke contacts limited area, it is difficult to realize the effect to flue gas fast cooling.
Summary of the invention
The technical problem to be solved by the present invention is to overcome deficiency in the prior art, provide a kind of based on polymer multicore The filter of fibre pipe is provided in particular in a kind of filter that high-temperature flue gas may be implemented and instantaneously cool down.Base provided by the invention It is lower than 45 DEG C in the exit gas temperature of the filter of polymer multicore fibre pipe, cooling extent is greater than 30%.
In order to solve the technical problem, solution of the invention is:
A kind of filter based on polymer multicore fibre pipe, including lapping are provided, further include that polymer multicore is fine Dimension is managed, and tight at least one polymer multicore fibre pipe forms uniform cylindrical body bar in lapping;Polymer is more Inside core fibre pipe dense distribution it is several along axial elongated orifices arranged in parallel, duct forms gas flow;Polymer is more Core fibre pipe is lower than 200 DEG C less than 100 DEG C, fusing point by glass transition temperature and specific heat capacity is greater than 1.5kJkg-1·K-1Thermoplastic Property resin is made.
As an improvement thermoplastic resin is polysulfones, polyether sulfone, polyethersulfone ketone, sulfonated polysulfone, Kynoar, gathers Tetrafluoroethene, poly- perfluorocarboxylic acid, poly- perfluorinated sulfonic acid, cellulose acetate, nitrocellulose, carboxymethyl cellulose, ethyl cellulose, Regenerated cellulose, polyimides, polyphenylsulfone terephthalamide, aromatic polyamides hydrazides, polypropylene, polyethylene, gathers polyamide Acrylonitrile, polyvinyl chloride, polyacrylic acid, polyvinyl alcohol, polyacrylamide, polystyrene, ethylene-vinyl alcohol copolymer, poly- ammonia Ester, polyethylene terephthalate, polybutylene terephthalate (PBT), polymethyl methacrylate, polybenzimidazoles, poly- pyrrole Carboxamide dihydrochloride, chitosan, chitin, polylactic acid, polyelectrolyte, polyether block copolymer, polyvinylpyrrolidone, poly- isophthalic diformazan One or more of mixtures of acyl m-phenylene diamine (MPD), organosilicon, preferably polypropylene, polyethylene, polylactic acid, poly terephthalic acid second Diol ester, polyamide, organosilicon, Kynoar, polyvinyl alcohol, polyvinylpyrrolidone, polystyrene, polymethylacrylic acid One or more of mixtures of methyl esters.
As an improvement polymer multicore fibre pipe, multicore fiber pipe diameter is 0.9~10.0mm, multicore fibre pipe On duct internal diameter be 0.1~2.0mm, duct volume accounts for multicore fiber pipe volume 20~80%.
As an improvement the preparation method of above-mentioned multicore fibre pipe is:
(1) thermoplastic resin is put into screw extruder, it is at 120~320 DEG C, thermoplastic resin is continuous through spinning head Melting extrusion;
(2) nascent multicore fibre pipe obtained above is handled and is cut out by gradually cooling, stretching, thermal finalization respectively, And then obtain the multicore fibre pipe.
Wherein, draw ratio is 1~20 times, and heat treatment temperature is 70~130 DEG C.
As an improvement multicore fiber jet pipe silk head includes resin channels and gas passage, gas passage is elongated Hollow metal needle is densely arranged in cylindrical resin channels, wherein and hollow metal needle internal diameter 0.1~2.0mm is adjacent Hollow metal center of pin spacing is 0.12~4.0mm, and resin channels diameter is 0.9~10.0mm.
As an improvement lapping is cigarette paper.
As an improvement filter length is 2~20mm.
The present invention also provides a kind of application of filter based on polymer multicore fibre pipe in tobacco product.
Inventive principle:
Multicore fibre pipe structure not only greatly improves filter and exchanges specific surface with smoke contacts, but also its is elongated Play the role of throttling cooling in duct.In the present invention, multicore fibre pipe plays a part of similar porous plug, and high-temperature flue gas can only be from Pass through in densely covered elongated orifice inside multicore fibre pipe.Since channel is shunk rapidly, flow of flue gas is hindered, and pressure is gradually Become smaller, temperature also declines therewith.In general, duct is thinner, length is longer, and restriction effect is also more obvious, but correspondingly Meeting is so that flow of flue gas is unsmooth.So the size of adjustment multicore fibre pipe internal gutter is a big key of the invention.
Multicore fibre pipe bulk material is also powerful heat energy accumulator.The heat of multicore fibre pipe is used to prepare in the present invention Plastic resin, glass transition temperature is lower than 200 DEG C less than 100 DEG C, fusing point and specific heat capacity is greater than 1.5kJkg-1·K-1, sensible heat value Much higher than general polymerization object material, there is very wide absorption heat but indeformable temperature model near human body comfortable taste temperature It encloses, can largely absorb the incidental heat of high-temperature flue gas.
Compared with prior art, the beneficial effects of the invention are as follows:
1, multicore fibre pipe bulk material sensible heat value with higher, glass transition temperature are lower than 200 DEG C less than 50 DEG C, fusing point And specific heat capacity is greater than 1.5kJkg-1·K-1, there is very wide absorption heat but indeformable near human body comfortable taste temperature Temperature range, can largely absorb the incidental heat of high-temperature flue gas.
2, multicore fibre pipe structure greatly improves filter and exchanges specific surface with smoke contacts, to promote heat exchange Rate quickly reduces the transient temperature of high-temperature flue gas.
3, squeezed out using continuous fusion, gradually it is cooling, stretch, thermal finalization handles and cuts out once-forming method and prepares multicore fibre Dimension pipe is, it can be achieved that full-automatic production.
Detailed description of the invention
Fig. 1 is a kind of radial cross section of the filter based on polymer multicore fibre pipe of the present invention;
Fig. 2 is the temperature measuring point position view in embodiment 1-10;
Fig. 3 is multicore fibre pipe spinneret schematic diagram.
In figure, 1- lapping;2- polymer multicore fibre pipe;3- flue gas flow channel;4- tobacco-containing material section;5- tri compound Mouth stick;The first temperature measuring point of 6-;The second temperature measuring point of 7-;8- third temperature measuring point;9- resin channels;10- gas passage.
Specific embodiment
Embodiment below can make the technical staff of this professional skill field more fully understand the present invention, but not to appoint Where formula limitation is of the invention.
A kind of filter based on polymer multicore fibre pipe, length are 2~20mm, including lapping 1 and polymer Multicore fibre pipe 2.Lapping 1 is cigarette paper, and tight one or several polymer arranged in parallel are more in lapping 1 Core fibre pipe, multicore fiber pipe diameter are 0.9~10.0mm.Inside polymer multicore fibre pipe dense distribution axial parallel The elongated orifice 3 of column, duct internal diameter are 0.1~2.0mm, and duct volume accounts for multicore fiber pipe volume 20~80%, all ducts Form gas flow.
Thermoplastic resin is polysulfones, polyether sulfone, polyethersulfone ketone, sulfonated polysulfone, Kynoar, polytetrafluoroethylene (PTFE), gathers entirely Carboxylic acid fluoride, cellulose acetate, nitrocellulose, carboxymethyl cellulose, ethyl cellulose, regenerated cellulose, gathers poly- perfluorinated sulfonic acid Amide, polyimides, polyphenylsulfone terephthalamide, aromatic polyamides hydrazides, polypropylene, polyethylene, polyacrylonitrile, polychlorostyrene second Alkene, polyacrylic acid, polyvinyl alcohol, polyacrylamide, polystyrene, ethylene-vinyl alcohol copolymer, polyurethane, poly- terephthaldehyde Sour glycol ester, polybutylene terephthalate (PBT), polymethyl methacrylate, polybenzimidazoles, polypyrazine amide, shell are poly- Sugar, chitin, polylactic acid, polyelectrolyte, polyether block copolymer, polyvinylpyrrolidone, poly, One or more of mixtures of organosilicon.
Multicore fiber tube preparation method is as follows:Thermoplastic resin is put into screw extruder, at 120~320 DEG C, thermoplastic Property resin squeezed out through spinning head continuous fusion, respectively by gradually it is cooling, stretch, thermal finalization processing and cut out, and then obtain more Core fibre pipe;Wherein, draw ratio is 1~20 times, and heat treatment temperature is 70~130 DEG C.Spinning head includes resin channels 9 and gas Body channel 10, gas passage 10 are elongated hollow metal needle, are densely arranged in cylindrical resin channels 9, wherein in 0.1~2.0mm of empty metal needle internal diameter, adjacent hollow metal center of pin spacing are 0.12~4.0mm, and 9 diameter of resin channels is 0.9 ~10.0mm.
Embodiment 1
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a root polypropylene multicore by cigarette paper Fibre pipe, formation length are the cylindrical body bar of 2mm.Polypropylene multicore fiber pipe diameter 7.8mm, duct internal diameter are 0.1mm, hole Road volume accounts for multicore fiber pipe volume 80%.
The preparation step of polypropylene multicore fibre pipe is:
(1) polypropylene is put into screw extruder, at 180 DEG C, thermoplastic resin is squeezed out through spinning head continuous fusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 20 times of stretching, in 100 DEG C of conditions It lower progress thermal finalization processing and cuts out, and then obtains polypropylene multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.1mm, and adjacent hollow metal center of pin spacing is 0.12mm, resin channels diameter are 7.8mm.
Embodiment 2
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a polyethylene multicore by cigarette paper Fibre pipe, formation length are the cylindrical body bar of 4mm.Polyethylene multicore fiber pipe diameter 7.8mm, duct internal diameter are 0.2mm, hole Road volume accounts for multicore fiber pipe volume 76%.
The preparation step of polyethylene multicore fibre pipe is:
(1) polyethylene is put into screw extruder, at 120 DEG C, thermoplastic resin is squeezed out through spinning head continuous fusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 15 times of stretching, under conditions of 70 DEG C It carries out thermal finalization processing and cuts out, and then obtain polyethylene multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.2mm, and adjacent hollow metal center of pin spacing is 0.24mm, resin channels diameter are 7.8mm.
Embodiment 3
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a polylactic acid multicore by cigarette paper Fibre pipe, formation length are the cylindrical body bar of 6mm.Polylactic acid multicore fiber pipe diameter 7.7mm, duct internal diameter are 0.3mm, hole Road volume accounts for multicore fiber pipe volume 74%.
The preparation step of polylactic acid multicore fibre pipe is:
(1) polylactic acid is put into screw extruder, at 160 DEG C, thermoplastic resin is squeezed out through spinning head continuous fusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 10 times of stretching, under conditions of 90 DEG C It carries out thermal finalization processing and cuts out, and then obtain polylactic acid multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.3mm, and adjacent hollow metal center of pin spacing is 0.36mm, resin channels diameter are 7.7mm.
Embodiment 4
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a Kynoar by cigarette paper Multicore fibre pipe, formation length are the cylindrical body bar of 8mm.Polyvinylidene fluoride multi-core fiber pipe diameter 7.7mm, duct internal diameter are 0.4mm, duct volume account for multicore fiber pipe volume 72%.
The preparation step of polyvinylidene fluoride multi-core fibre pipe is:
(1) Kynoar is put into screw extruder, at 200 DEG C, by thermoplastic resin through spinning head continuous fusion It squeezes out;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 8 times of stretching, under conditions of 100 DEG C It carries out thermal finalization processing and cuts out, and then obtain polyvinylidene fluoride multi-core fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.4mm, and adjacent hollow metal center of pin spacing is 0.48mm, resin channels diameter are 7.7mm.
Embodiment 5
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a poly- terephthaldehyde by cigarette paper Sour glycol ester multicore fibre pipe, formation length are the cylindrical body bar of 10mm.Polyethylene terephthalate multicore fiber Pipe diameter 8.5mm, duct internal diameter are 0.5mm, and duct volume accounts for multicore fiber pipe volume 70%.
The preparation step of polyethylene terephthalate multicore fibre pipe is:
(1) polyethylene terephthalate is put into screw extruder, at 320 DEG C, by thermoplastic resin through spinneret Head continuous fusion squeezes out;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 6 times of stretching, under conditions of 130 DEG C It carries out thermal finalization processing and cuts out, and then obtain polyethylene terephthalate multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.5mm, and adjacent hollow metal center of pin spacing is 0.6mm, resin channels diameter are 8.5mm.
Embodiment 6
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a polyamide multicore by cigarette paper Fibre pipe, formation length are the cylindrical body bar of 15mm.Polyamide multicore fiber pipe diameter 9.2mm, duct internal diameter are 0.6mm, Duct volume accounts for multicore fiber pipe volume 60%.
The preparation step of polyamide multicore fibre pipe is:
(1) polyamide is put into screw extruder, at 280 DEG C, thermoplastic resin is squeezed out through spinning head continuous fusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 4 times of stretching, under conditions of 110 DEG C It carries out thermal finalization processing and cuts out, and then obtain polyamide multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.6mm, and adjacent hollow metal center of pin spacing is 0.72mm, resin channels diameter are 9.2mm.
Embodiment 7
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a polyvinylidene fluoride by cigarette paper Alkene-polylactic acid multicore fibre pipe, formation length are the cylindrical body bar of 20mm.Kynoar-polylactic acid multicore fibre pipe is straight Diameter 10.0mm, duct internal diameter are 2.0mm, and duct volume accounts for multicore fiber pipe volume 20%.
Kynoar-polylactic acid multicore fibre pipe preparation step is:
(1) Kynoar and polylactic acid are put into screw extruder, at 200 DEG C, by thermoplastic resin through spinning head Continuous fusion squeezes out;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 1 times of stretching, under conditions of 90 DEG C It carries out thermal finalization processing and cuts out, and then obtain Kynoar-polylactic acid multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 2.0mm, and adjacent hollow metal center of pin spacing is 4.0mm, resin channels diameter are 10.0mm.
Embodiment 8
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, it is poly- to wrap up 20 organosilicons-by cigarette paper Vinylidene-polyethylene terephthalate multicore fibre pipe, formation length are the cylindrical body bar of 6mm.Organosilicon-is poly- inclined Vinyl fluoride-polyethylene terephthalate multicore fiber pipe diameter is 0.9mm, and duct internal diameter is 0.2mm, and duct volume accounts for more Core fibre pipe volume 80%.
Organosilicon-Kynoar-polyethylene terephthalate multicore fibre pipe preparation step is:
(1) organosilicon, Kynoar and polyethylene terephthalate are put into screw extruder, at 270 DEG C, Thermoplastic resin is squeezed out through spinning head continuous fusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 15 times of stretching, in 120 DEG C of conditions It lower progress thermal finalization processing and cuts out, and then obtains organosilicon-Kynoar-polyethylene terephthalate multicore fiber Pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.2mm, and adjacent hollow metal center of pin spacing is 0.24mm, resin channels diameter are 0.9mm.
Embodiment 9
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a polyvinyl alcohol-by cigarette paper Organosilicon-polyvinylpyrrolidone-polystyrene multicore fibre pipe, formation length are the cylindrical body bar of 8mm.Polyvinyl alcohol- Organosilicon-polyvinylpyrrolidone-polystyrene multicore fiber pipe diameter 8.5mm, duct internal diameter are 0.3mm, and duct volume accounts for Multicore fiber pipe volume 76%.
Polyvinyl alcohol-organosilicon-polyvinylpyrrolidone-polystyrene multicore fibre pipe preparation step is:
(1) polyvinyl alcohol, organosilicon, polyvinylpyrrolidone and polystyrene are put into screw extruder, at 200 DEG C Under, thermoplastic resin is squeezed out through spinning head continuous fusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 10 times of stretching, in 100 DEG C of conditions It lower progress thermal finalization processing and cuts out, and then it is fine to obtain polyvinyl alcohol-organosilicon-polyvinylpyrrolidone-polystyrene multicore Dimension pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.3mm, and adjacent hollow metal center of pin spacing is 0.36mm, resin channels diameter are 8.5mm.
Embodiment 10
As shown in Figure 1, a kind of filter based on polymer multicore fibre pipe, wraps up a polymethyl by cigarette paper Sour methyl esters multicore fibre pipe, formation length are the cylindrical body bar of 10mm.Polymethyl methacrylate multicore fiber pipe diameter is 9.2mm, duct internal diameter are 0.4mm, and duct volume accounts for multicore fiber pipe volume 74%.
The preparation step of polymethyl methacrylate multicore fibre pipe is:
(1) polymethyl methacrylate is put into screw extruder, at 250 DEG C, thermoplastic resin is connected through spinning head Continuous melting extrusion;
(2) by nascent multicore fibre pipe obtained above respectively by gradually cooling, 6 times of stretching, under conditions of 110 DEG C It carries out thermal finalization processing and cuts out, and then obtain polymethyl methacrylate multicore fibre pipe.
Wherein, spinning head (as shown in Figure 3) hollow metal needle internal diameter is 0.4mm, and adjacent hollow metal center of pin spacing is 0.48mm, resin channels diameter are 9.2mm.
It is worth noting that:Than the above described, industry technical staff is not the case where making the creative labor Under, polymer multicore fibre pipe is replaced with into following material:Polysulfones, polyether sulfone, polyethersulfone ketone, sulfonated polysulfone, polytetrafluoroethylene (PTFE), Poly- perfluorocarboxylic acid, poly- perfluorinated sulfonic acid, cellulose acetate, nitrocellulose, carboxymethyl cellulose, ethyl cellulose, regenerated fiber Element, polyimides, polyphenylsulfone terephthalamide, aromatic polyamides hydrazides, polyacrylonitrile, polyvinyl chloride, polyacrylic acid, poly- third Acrylamide, ethylene-vinyl alcohol copolymer, polyurethane, polybutylene terephthalate (PBT), polybenzimidazoles, polypyrazine amide, shell Glycan, chitin, polyelectrolyte, polyether block copolymer, poly one or more mixture, Remaining condition copies above-described embodiment to be arranged, and can achieve the desired results.
The above-mentioned resulting filter based on polymer multicore fibre pipe of each embodiment, through following test method progressive Energy test evaluation, test result are shown in Table 1.
1, cooling effect is tested
Filter and tobacco-containing material by gained based on polymer multicore fibre pipe form quaternary composite construction (tobacco-containing material Section 3+ ternary composite rod 4), wherein the interlude of ternary composite rod is the filter based on polymer multicore fibre pipe.It is real It tests and chooses 3 temperature measuring points 6,7,8, be located at the center of circle of corresponding position cigarette cross section, as shown in Figure 1.
Temperature drop calculation method:X=(TFirst temperature measuring point-TSecond temperature measuring point)/TFirst temperature measuring point
Table 1 uses the cigarette temperature test result of different embodiment filters
The actual scope of the present invention not only includes the disclosed embodiments, further include under claims implement or Execute all equivalent schemes of the invention.

Claims (9)

1. a kind of filter based on polymer multicore fibre pipe, including lapping, which is characterized in that further include that polymer is more Core fibre pipe, tight at least one polymer multicore fibre pipe forms uniform cylindrical body bar in the lapping; Inside the polymer multicore fibre pipe dense distribution it is several along axial elongated orifices arranged in parallel, the duct forms gas Body runner;The polymer multicore fibre pipe is by glass transition temperature less than 100 DEG C, fusing point are lower than 200 DEG C and specific heat capacity is greater than 1.5kJ·kg-1·K-1Thermoplastic resin be made.
2. filter according to claim 1, which is characterized in that the thermoplastic resin is polysulfones, polyether sulfone, polyether sulfone Ketone, sulfonated polysulfone, Kynoar, polytetrafluoroethylene (PTFE), poly- perfluorocarboxylic acid, poly- perfluorinated sulfonic acid, cellulose acetate, cellulose nitrate Element, carboxymethyl cellulose, ethyl cellulose, regenerated cellulose, polyamide, polyimides, polyphenylsulfone terephthalamide, fragrance Polyamide hydrazides, polypropylene, polyethylene, polyacrylonitrile, polyvinyl chloride, polyacrylic acid, polyvinyl alcohol, polyacrylamide, polyphenyl Ethylene, ethylene-vinyl alcohol copolymer, polyurethane, polyethylene terephthalate, polybutylene terephthalate (PBT), poly- first Base methyl acrylate, polybenzimidazoles, polypyrazine amide, chitosan, chitin, polylactic acid, polyelectrolyte, polyether block copolymerization The mixtures of the one or more of object, polyvinylpyrrolidone, poly, organosilicon.
3. filter according to claim 1, which is characterized in that the polymer multicore fibre pipe, diameter be 0.9~ 10.0mm, duct internal diameter are 0.1~2.0mm, and duct volume accounts for the polymer multicore fiber pipe volume 20~80%.
4. filter according to claim 1, which is characterized in that the preparation method of the polymer multicore fibre pipe is:
(1) thermoplastic resin is put into screw extruder, at 120~320 DEG C, by thermoplastic resin through spinning head continuous fusion It squeezes out;
(2) nascent multicore fibre pipe obtained above is handled and is cut out by gradually cooling, stretching, thermal finalization respectively, in turn Obtain the multicore fibre pipe.
5. filter according to claim 4, which is characterized in that the spinning head includes resin channels and gas passage, Gas passage is elongated hollow metal needle, is densely arranged in cylindrical resin channels, wherein hollow metal needle internal diameter 0.1~2.0mm, adjacent hollow metal center of pin spacing are 0.12~4.0mm, and resin channels diameter is 0.9~10.0mm.
6. filter according to claim 4, which is characterized in that draw ratio is 1~20 times, and thermal finalization treatment temperature is 70~130 DEG C.
7. filter according to claim 1, which is characterized in that the lapping is cigarette paper.
8. filter according to claim 1, which is characterized in that the filter length is 2~20mm.
9. a kind of application of the filter based on polymer multicore fibre pipe according to claims 1-8 in tobacco product.
CN201810451941.5A 2018-05-12 2018-05-12 A kind of filter and its application based on polymer multicore fibre pipe Pending CN108835711A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN109938403A (en) * 2019-04-02 2019-06-28 云南瑞升烟草技术(集团)有限公司 The preparation method of integrally formed honeycomb cigarette filter tip rod
CN110292207A (en) * 2019-03-21 2019-10-01 重庆中烟工业有限责任公司 Aerosol cooling filter element and low temperature cigarette
CN113907416A (en) * 2021-11-11 2022-01-11 南通烟滤嘴有限责任公司 Preparation facilities of multiaxis multicore filter rod

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