CN108825074A - A kind of hollow glass system of interior outstanding electrochromic intelligent film - Google Patents
A kind of hollow glass system of interior outstanding electrochromic intelligent film Download PDFInfo
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- CN108825074A CN108825074A CN201810852301.5A CN201810852301A CN108825074A CN 108825074 A CN108825074 A CN 108825074A CN 201810852301 A CN201810852301 A CN 201810852301A CN 108825074 A CN108825074 A CN 108825074A
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- hollow glass
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Classifications
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- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/404—Multi-coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The present invention provides the hollow glass system for hanging electrochromic intelligent film in one kind, which is layered composite structure, and layered composite construction successively includes：Glass outer；Flexible electrochromism smart membranes；Inner layer glass；And it is fixedly connected with the interior outstanding film fixed frame at each layer edge；The flexibility electrochromism smart membranes are at least one layer；The flexibility electrochromism film is electrically connected with electrical control wiring, and the electrical control wiring passes through the interior outstanding film fixed frame and extends to the interior outstanding film fixed outer frame；The setting of flexibility electrochromism smart membranes weight compared with existing double layer glass does not dramatically increase, and energy-saving effect improves 50% or more；Compared with existing three glass, two chamber, four glass, three chamber hollow glass, energy-saving effect is close, but weight saving 30%-50%；It is powered by the electric controling line or no power can change the coefficients of heat insulation of the flexible electrochromism smart membranes, can according to need and adjust.
Description
Technical field
The present invention relates to a kind of energy saving door and window glass.
Specifically, being the hollow glass system for being related to hanging electrochromic intelligent film in one kind.
Background technique
Building energy conservation is the Important Problems of current environment protection field concern, and building energy consumption has occupied human society total energy consumption
30% or more, wherein occupying 50% or more of building total energy consumption by the energy consumption that door glass is lost.Therefore, novel energy-conserving door is developed
Glazing material, it has also become reduce the maximally efficient solution of building energy consumption.Pass through two sheet glass（Including low-E Low emissivity
Coated glass）Hollow glass structure is formed, the heat insulation effect of glass door and window is improved using the thermal insulation of cavity.
Continuous improvement with modern architecture to power conservation requirement, the heat insulation of single-chamber hollow glass have been increasingly difficult to full
Sufficient actual demand.Double cavitys as a result,（Three glass, two chamber）Or three cavity（Four glass, three chamber）The multiple cavity hollow glass of structure starts to obtain
Using energy-saving effect is obviously improved compared with single-chamber hollow glass.However, multiple cavity hollow glass is due to using three pieces
The weight of above glass, glass door and window and curtain wall can dramatically increase, the building such as reinforcing bar needed for supported glass curtain wall, concrete
The consumption of material will be significantly increased, and the consumption of resource is but increased while reducing energy consumption.
The 80s and 90s in last century, Switzerland scientist have invented interior outstanding film hollow glass, substitute multi-cavity with plastics thermal isolation film
The intermediate glass of hollow glass hangs a piece of or two panels thermal isolation film by interior, can obtain and three glass, two chamber, four glass, three chamber glass phase
When energy-saving effect, and effectively prevent the increase of glass overall weight.
On the basis of membrane technology is hanged in Switzerland in Wei Shi curtain wall Co., Ltd, it is successfully realized interior outstanding film hollow glass system
Mass production and business application, the relevant technologies Chinese patent CN103498624B, CN103498622A,
It is disclosed in CN204451212U.
Existing interior outstanding film hollow glass technology still uses traditional Low emissivity thermal isolation film, although to solar ultraviolet and infrared waves
Section radiation has excellent regulation barrier property, but to the ability of regulation and control of solar visible radiation deficiency.Heat-insulated membrane system is general
There is high transparency to visible light, to adjust sun level can only be using dark base film, but if the too deep meeting of substrate color
Indoor lighting is influenced, the excessively shallow shaded effect of color is again unobvious.
Currently, flexible electrochomeric films are still in research and small-size product application stage, large scale flexible electrical mutagens
The batch preparation problem of color film is still unresolved.
Chinese patent CN102540610A discloses a kind of flexible electrochromic film, and electrochromism film layer uses polymer
Material, electrolyte layer are formed using the porous membrane of absorption liquid electrolyte.The problem of technical solution：Organic electrochromic material
All there is stability deficiency in material and liquid electrolyte, while being also difficult to prepare large scale electrochromism fenestrated membrane.
Chinese patent CN104932168A and CN103969904A individually disclose a kind of flexible electro-chromic device, are related to
Inorganic and organic electrochromic material, but electrolyte uses liquid electrolyte, however it remains stability and large scale preparation are tired
Difficult problem.
Chinese patent CN105573001A discloses a kind of flexible electrochomeric films, relate generally to a kind of silver nanowires and
The nano wire electrochromism film layer that tungsten oxide nano assembles altogether, electrolyte provided by electrochromic device technical solution are
Copolymer solid electrolyte.The problem of technical solution：Nano wire electrochromic layer is difficult to realize that large area uniformly produces, simultaneously
Solid polyelectrolyte electrochromism response speed is slower.
In addition, above-mentioned flexibility electrochomeric films related patents are without reference to the fenestrated membrane application as energy saving door and window,
Film is not provided for the rejection rate data of different-waveband solar radiation energy, is applied to build so these films can not be assessed
Build the energy-saving effect of windowpane.Electrochomeric films are applied to energy saving fenestrated membrane, infrared spoke under also generally existing pellucidity simultaneously
The lower problem of rejection rate is penetrated, this can reduce the energy-saving effect of electrochomeric films.
Summary of the invention
It is an object of the invention to overcome the shortcoming of above-mentioned traditional technology, it is thin to provide outstanding electrochromic intelligent in one kind
The hollow glass system of film.
The purpose of the present invention is what is reached by following technical measures：A kind of interior outstanding electrochromic intelligent film it is hollow
Glass system, the hollow glass system are layered composite structure, and layered composite construction successively includes：
1）Glass outer；
2）Flexible electrochromism smart membranes；
3）Inner layer glass；
And it is fixedly connected with the interior outstanding film fixed frame at each layer edge；The glass outer and the inner layer glass respectively with it is described soft
Property electrochromic intelligent film between be separated with air layer, the flexibility electrochromism smart membranes are at least one layer；The flexibility
Electrochomeric films are electrically connected with electrical control wiring, and the electrical control wiring passes through the interior outstanding film fixed frame and extends to
The interior outstanding film fixed outer frame.
As an improvement the glass outer is common building glass or low radiation coated glass.
As a further improvement, the inner layer glass is common building glass or low radiation coated glass.
As a further improvement, the flexible electrochromism smart membranes are layered composite structure, successively include：
1) flexible parent metal film；
2) the first transparency conducting layer；
3) electrochromism functional layer；
4) ionic electrolytes layer；
5) ion storage；
6) the second transparency conducting layer.
As a further improvement, the flexible parent metal film is thin polymer film；The thin polymer film is optical grade
Pet film or Kapton or polyethylene naphthalate film or poly- second
Alkene film or polypropylene film or nylon film.
As a further improvement, first transparency conducting layer and second transparency conducting layer are transparent conductive material
Film；The transparent conductive material film is indium tin oxide films, aluminum-doped zinc oxide films, Ga-doped zinc oxide film, antimony are mixed
Miscellaneous SnO 2 thin film, fluorine-doped tin oxide film, nano metal grid film, nano-silver thread film any one or it is above-mentioned
A variety of in film are sequentially overlapped composition.
As a further improvement, the electrochromism functional layer is cathodic electrochromic sull；The cathode
Electrochromism sull is tungsten oxide film, vanadium oxide film, columbium oxide film, thin film of titanium oxide, bismuth oxide film
A variety of in any one or above-mentioned film are sequentially overlapped composition.
As a further improvement, the ionic electrolytes layer is lithium ion compound film；The lithium ion compound
Film is any one of lithium tantalate thin film, cobalt acid lithium film, LiMn2O4 film, lithium phosphate film, lithium titanate thin film.
As a further improvement, the ion storage is anode electrochromism tungsten oxide film；The anode is electroluminescent
Discoloration tungsten oxide film is any one of nickel oxide film, oxidation iridium film, rhodium oxide film.
As a further improvement, the visible light transmittance rate of first transparency conducting layer and second transparency conducting layer
More than or equal to 90%, sheet resistance is less than or equal to 20 Ω/.
As a further improvement, the thickness of the electrochromism functional layer is in 200-500nm.
As a further improvement, the thickness of the ionic electrolytes layer is in 500-1500nm.
As a further improvement, the thickness of the ion storage is in 100-200nm.
As a further improvement, the thickness of the flexible electrochromism smart membranes is at 50-500 μm, and width is in 1.2-
2.4m。
By adopting the above-described technical solution, hanging the hollow glass system of electrochromic intelligent film in one kind, this is hollow
Glass system is layered composite structure, and layered composite construction successively includes：1）Glass outer；2）Flexible electrochromic intelligent
Film；3）Inner layer glass；And it is fixedly connected with the interior outstanding film fixed frame at each layer edge；The glass outer and the inner layer glass
Air layer is separated between the flexible electrochromism smart membranes respectively, the flexibility electrochromism smart membranes are at least one
Layer；The flexibility electrochromism film is electrically connected with electrical control wiring, and the electrical control wiring is solid across the interior outstanding film
Determine frame and extends to the interior outstanding film fixed outer frame.
Compared with prior art, it is an advantage of the invention that：The setting of the flexibility electrochromism smart membranes and existing double
Layer hollow glass is not dramatically increased compared to weight, and energy-saving effect improves 50% or more；In existing three glass, two chamber, four glass, three chamber
Empty glass phase ratio, energy-saving effect is close, but weight saving 30%-50%；It is powered by the electric controling line or no power can
To change the coefficient of heat insulation of the flexible electrochromism smart membranes, it can according to need and adjust.
Present invention will be further explained below with reference to the attached drawings and specific embodiments.
Detailed description of the invention
Attached drawing 1 is a kind of structural schematic diagram of the invention.
Attached drawing 2 is another structural schematic diagram of the invention.
Attached drawing 3 is the structural schematic diagram of flexible electrochromism smart membranes in the present invention.
Specific embodiment
Embodiment one：As shown in attached drawing 1, attached drawing 3, a kind of hollow glass system of interior outstanding electrochromic intelligent film should
Hollow glass system is layered composite structure, and layered composite construction successively includes：
1）Glass outer 1；The glass outer 1 is common building glass；
2）Flexible electrochromism smart membranes 2；The flexibility electrochromism smart membranes 2 are layered composite structure, successively include：
Flexible parent metal film 21；First transparency conducting layer 22；Electrochromism functional layer 23；Ionic electrolytes layer 24；Ion storage 25；
Second transparency conducting layer 26.
3）Inner layer glass 3；The inner layer glass 3 is common building glass；
The common building glass is normal transparent white glass；And it is fixedly connected with the interior outstanding film fixed frame 4 at each layer edge；It is described
Glass outer 1 and the inner layer glass 3 are separated with air layer between the flexible electrochromism smart membranes 2 respectively, described soft
Property electrochromic intelligent film 2 be one layer；The flexibility electrochromism smart membranes 2 are electrically connected with electrical control wiring 5, described
Electrical control wiring 5 passes through the interior outstanding film fixed frame 4 and extends to outside the interior outstanding film fixed frame 4.Pass through the electric-controlled
The energization of line 5 processed or no power can change the coefficient of heat insulation of the flexible electrochromism smart membranes 2, and user can be according to need
Select energization or no power.
The flexible parent metal film 21 is thin polymer film；The thin polymer film is the poly terephthalic acid second of optical grade
Terephthalate films or Kapton or polyethylene naphthalate film or polyethylene film or polypropylene
Film or nylon film；The light transmittance of the thin polymer film>90%.
First transparency conducting layer 22 and second transparency conducting layer 26 are transparent conductive material film；It is described transparent
Conductive material membrane is tin indium oxide（ITO）Film, aluminium-doped zinc oxide (AZO) film, Ga-doped zinc oxide（GZO）, Sb doped
Tin oxide (ATO) film, fluorine-doped tin oxide（FTO）Film, nano metal grid film, nano-silver thread film it is any
It is a kind of.
Aluminium-doped zinc oxide (AZO) film, Ga-doped zinc oxide（GZO）, antimony-doped tin oxide (ATO) film, fluorine
Doped stannum oxide（FTO）The doping ratio of film etc. is well-known technique in the industry, is repeated no more.
The electrochromism functional layer 23 is cathodic electrochromic sull；The cathodic electrochromic oxide is thin
Film is any one of tungsten oxide film, vanadium oxide film, columbium oxide film, thin film of titanium oxide, bismuth oxide film.
The ionic electrolytes layer 24 is lithium ion compound film；The lithium ion compound film is that lithium tantalate is thin
Any one of film, cobalt acid lithium film, LiMn2O4 film, lithium phosphate film, lithium titanate thin film.
The ion storage 25 is anode electrochromism tungsten oxide film；The anode electrochromism tungsten oxide film is
Any one of nickel oxide film, oxidation iridium film, rhodium oxide film.
The visible light transmittance rate of first transparency conducting layer 22 and second transparency conducting layer 26 is 92%, and sheet resistance is
15Ω/□。
The thickness of the electrochromism functional layer 23 is in 280nm.The thickness of the ionic electrolytes layer 24 is in 600nm.Institute
The thickness of ion storage 25 is stated in 100nm.The thickness of the flexibility electrochromism smart membranes 2 is at 51 μm, and width is in 1.2m.
Using with a thickness of 50 μm, light transmittance >=90%, mist degree≤0.5% optics polyethylene terephthalate（PET）
Film is flexible parent metal film 21, prepares the flexible electrochromism smart membranes 2 according to following processing step：
Step 1：To 21 ethylene terephthalate of flexible parent metal film（PET）Film carries out plasma surface cleaning and lives
Change processing.
Step 2：Using roll-to-roll magnetron sputtering technique, in polyethylene terephthalate（PET）Surface d.c. sputtering
Tin indium oxide（ITO）First transparency conducting layer 22；Tin indium oxide（ITO）Thin film layer thickness 100nm, it is seen that light transmittance 92%, side
Hinder 15 Ω/.
Step 3：In tin indium oxide（ITO）Film surface, further using oxidation tungsten target material, mid frequency sputtering tungsten oxide
（WO3）Electrochromism functional layer 23, thicknesses of layers 280nm.
Step 4：In tungsten oxide（WO3）Film surface uses roll-to-roll magnetron sputtering technique, further with lithium tantalate
（LiTaO3）Ceramics are target, and radio-frequency sputtering prepares lithium tantalate（LiTaO3）Solid electrolyte film forms ionic electrolytes layer
24, film thickness 600nm.
Step 5：On 24 surface of ionic electrolytes layer, nickel oxide is further used（NiO）Target radio-frequency sputtering preparation oxidation
Nickel（NiO）Ion storage 25, thicknesses of layers 100nm.
Step 6：In nickel oxide（NiO）Film surface continues to prepare nickel oxide using magnetron sputtering technique（NiO）Top electricity
Pole forms the second transparency conducting layer 26, thicknesses of layers 100nm.
After obtaining above-mentioned flexible electrochromism smart membranes 2, according to outstanding flexible electrical mutagens in the preparation of following processing step
The hollow glass system of color smart membranes 2：
Step 1：Glass outer 1 uses normal transparent white glass, with a thickness of 6mm.
Step 2：Inner layer glass 3 uses normal transparent white glass, with a thickness of 6mm.
Step 3：Cavity thickness between two sheet glass is 12mm, and a piece of flexible electrochromism intelligence is hanged in the centre of cavity
Energy film 2, forms the cavity of two 6mm thickness.
Step 4：The interior of flexible electrochromism smart membranes hangs, fixed by the interior outstanding film fixed frame 4, and draws electricity
Cavity both ends are sealed heat-insulating and sealing by gas wiring, the interior outstanding film fixed frame 4.It is of course also possible to close by individually adding
Envelope heat insulating strip seals cavity both ends.
Experiment discovery, the coefficient of heat insulation of above-mentioned interior outstanding flexible electrochromism smart membranes hollow glass（U value）For 1.41W/
m2K, the coefficient of heat insulation that the hollow glass of interior outstanding film is not used in the same terms is 2.75W/m2·K。
Embodiment two：As shown in attached drawing 2, attached drawing 3, glass outer 1 described in the present embodiment is low radiation coated glass；Institute
Stating inner layer glass 3 is low radiation coated glass, and the low radiation coated glass is Low emissivity low-E coated glass.The flexibility
Electrochromic intelligent film 2 is two layers；The visible light of first transparency conducting layer 22 and second transparency conducting layer 26 is saturating
Light rate is 90%, and sheet resistance is 10 Ω/.The thickness of the electrochromism functional layer 23 is in 500nm.The ionic electrolytes layer 24
Thickness in 1500nm.The thickness of the ion storage 25 is in 200nm.The thickness of the flexibility electrochromism smart membranes 2
At 40 μm, width is in 2.4m.Rest part is same as Example 1 in the present embodiment.
Using with a thickness of 38 μm, light transmittance >=90%, mist degree≤0.5% optics polyethylene terephthalate（PET）
Film is flexible parent metal film 21, prepares flexible electrochromism smart membranes according to following processing step：
Step 1：To 21 polyethylene terephthalate of flexible parent metal film（PET）Film carries out plasma surface cleaning
With activation processing.
Step 2：Polyethylene terephthalate（PET）Film substrate surface, using roll-to-roll magnetron sputtering technique,
D.c. sputtering tin indium oxide（ITO）First transparency conducting layer 22.Tin indium oxide（ITO）Thicknesses of layers 150nm, it is seen that light transmittance
90%, 10 Ω of sheet resistance/.
Step 3：In tin indium oxide（ITO）Film surface further uses metal tungsten target material, is passed through argon Ar and oxygen O2
Mixed gas, DC reactive sputtering tungsten oxide（WO3）Electrochromism functional film layer, thicknesses of layers 500nm.
Step 4：In tungsten oxide（WO3）Film surface further uses roll-to-roll vacuum evaporation process, prepares lithium tantalate
（LiTaO3）Ionic electrolytes layer 24, film thickness 1500nm.
Step 5：In electrolyte membrane surface, nickel oxide is further used（NiO）Target radio-frequency sputtering prepares nickel oxide
（NiO）Solid electrolyte film forms ionic electrolytes layer 24, thicknesses of layers 200nm.
Step 6：In nickel oxide（NiO）Film surface continues to prepare nickel oxide using magnetron sputtering technique（NiO）Top electricity
Pole forms the second transparency conducting layer 26, thicknesses of layers 150nm.
After obtaining above-mentioned flexible electrochromism smart membranes 2, according to outstanding flexible electrical mutagens in the preparation of following processing step
The hollow glass system of color smart membranes 2：
Step 1：Outer sheet glass uses Low emissivity low-E coated glass, with a thickness of 6mm；
Step 2：Interior sheet glass uses Low emissivity low-E coated glass, with a thickness of 6mm；
Step 3：Cavity thickness between two sheet glass is 18mm, and it is thin to hang two panels flexibility electrochromic intelligent in the centre of cavity
Film 2 forms the cavity of two 6mm thickness；
Step 4：The interior of flexible electrochromism smart membranes hangs, fixed by the interior outstanding film fixed frame 4, and draws and electrically connect
Cavity both ends are sealed heat-insulating and sealing by line, the interior outstanding film fixed frame 4.It is of course also possible to by individually addition sealing every
Hot item seals cavity both ends.
Experiment discovery, the coefficient of heat insulation of above-mentioned interior outstanding flexible electrochromism smart membranes hollow glass（U value）For 0.70W/
m2K, the coefficient of heat insulation that the Low emissivity low-E film-coated hollow glass of interior outstanding film is not used in the same terms is 1.79W/m2·K。
Embodiment three：As shown in attached drawing 1, attached drawing 3, in the present embodiment, the transparent conductive material film is tin indium oxide
（ITO）Film, aluminium-doped zinc oxide (AZO) film, Ga-doped zinc oxide（GZO）, nano-silver thread film be sequentially overlapped composition；Or
Person is antimony-doped tin oxide (ATO) film, fluorine-doped tin oxide（FTO）Film, nano metal grid film are sequentially overlapped structure
At；It or is tin indium oxide（ITO）Film, antimony-doped tin oxide (ATO) film, nano-silver thread film are sequentially overlapped composition, or
The above-mentioned other combinations of person are sequentially overlapped composition in the present embodiment protection scope.
The cathodic electrochromic sull is tungsten oxide film, vanadium oxide film, columbium oxide film are sequentially overlapped
It constitutes；Or thin film of titanium oxide, bismuth oxide film are sequentially overlapped composition；Or tungsten oxide film, vanadium oxide film, titanium oxide are thin
Film is sequentially overlapped composition；Or above-mentioned other combinations are sequentially overlapped composition in the present embodiment protection scope.
The visible light transmittance rate 90% of first transparency conducting layer 22 and second transparency conducting layer 26,20 Ω of sheet resistance/
□。
The thickness of the electrochromism functional layer 23 is in 350nm.The thickness of the ionic electrolytes layer 24 is in 1000nm.Institute
The thickness of ion storage 25 is stated in 120nm.The thickness of the flexibility electrochromism smart membranes 2 is at 51 μm, and width is in 2m.
Rest part is same as Example 1 in the present embodiment.
Using with a thickness of 50 μm, light transmittance >=90%, mist degree≤0.5% optics polyethylene terephthalate（PET）
Film is flexible parent metal film 21, prepares the flexible electrochromism smart membranes 2 according to following processing step：
Step 1：To 21 polyethylene terephthalate of flexible parent metal film（PET）Film carries out plasma surface cleaning
With activation processing.
Step 2：Polyethylene terephthalate（PET）Substrate surface, using roll-to-roll magnetron sputtering technique, direct current
Sputter tin indium oxide（ITO）First transparent conductive film.Tin indium oxide（ITO）Thicknesses of layers 100nm, it is seen that light transmittance 92%,
15 Ω of sheet resistance/.
Step 3：In tin indium oxide（ITO）Film surface further uses metal tungsten target material, DC reactive sputtering oxidation
Tungsten（WO3）Electrochromism functional film layer, thicknesses of layers 350nm.
Step 4：In tungsten oxide（WO3）Film surface further uses roll-to-roll vacuum evaporation process, prepares lithium tantalate
（LiTaO3）Solid electrolyte film forms ionic electrolytes layer 24, film thickness 1000nm.
Step 5：In electrolyte membrane surface, nickel oxide is further used（NiO）Target radio-frequency sputtering prepares nickel oxide
（NiO）Ion storage 25, thicknesses of layers 120nm.
Step 6：In nickel oxide（NiO）Film surface continues to prepare tin indium oxide using magnetron sputtering technique（ITO）Top
Electrode, thicknesses of layers 100nm.
After obtaining above-mentioned flexible electrochromism smart membranes 2, according to outstanding flexible electrical mutagens in the preparation of following processing step
The hollow glass system of color smart membranes 2：
Step 1：Glass outer uses Low emissivity low-E coated glass, with a thickness of 6mm；
Step 2：Inner layer glass 3 uses Low emissivity low-E coated glass, with a thickness of 6mm；
Step 3：Cavity thickness between layer glass is 12mm, and it is thin that a piece of flexible electrochromic intelligent is hanged in the centre of cavity
Film forms the cavity of two 6mm thickness；
Step 4：The interior of flexible electrochromism smart membranes hangs, fixed by the interior outstanding film fixed frame 4, and draws and electrically connect
Cavity both ends are sealed heat-insulating and sealing by line, the interior outstanding film fixed frame 4.It is of course also possible to by individually addition sealing every
Hot item seals cavity both ends.
Experiment discovery, the coefficient of heat insulation of above-mentioned interior outstanding flexible electrochromism smart membranes hollow glass（U value）For 1.12W/
m2K, the coefficient of heat insulation that the low-E hollow glass of interior outstanding film is not used in the same terms is 1.79W/m2·K。
Example IV：As shown in attached drawing 2, attached drawing 3, the smart membranes of flexibility electrochromism described in this implementation 2 are two layers；Institute
Stating transparent conductive material film is tin indium oxide（ITO）Film, aluminium-doped zinc oxide (AZO) film are sequentially overlapped composition；Or it is
Antimony-doped tin oxide (ATO) film, fluorine-doped tin oxide（FTO）Film is sequentially overlapped composition；It or is Ga-doped zinc oxide
（GZO）, nano-silver thread film nano silver wire film is sequentially overlapped composition, or is indium tin oxide films, antimony-doped tin oxide
(ATO) film, nano metal grid film are sequentially overlapped composition or above-mentioned other combinations are sequentially overlapped composition in this implementation
In example protection scope.
The cathodic electrochromic sull is tungsten oxide film, vanadium oxide film, columbium oxide film are sequentially overlapped
It constitutes；Or thin film of titanium oxide, bismuth oxide film are sequentially overlapped composition；Or tungsten oxide film, vanadium oxide film, titanium oxide are thin
Film is sequentially overlapped composition；Or above-mentioned other combinations are sequentially overlapped composition in the present embodiment protection scope.
The visible light transmittance rate 93% of first transparency conducting layer 22 and second transparency conducting layer 26,18 Ω of sheet resistance/
□。
The thickness of the electrochromism functional layer 23 is in 200nm.The thickness of the ionic electrolytes layer 24 is in 500nm.Institute
The thickness of ion storage 25 is stated in 100nm.At 500 μm, width exists the thickness of the flexibility electrochromism smart membranes 2
1.8m。
Rest part is same as Example 1 in the present embodiment.
Using with a thickness of 499 μm, light transmittance >=90%, mist degree≤0.5% optics polyethylene terephthalate（PET）
Film is flexible parent metal film 21, prepares flexible electrochromism smart membranes according to following processing step：
Step 1：To 21 polyethylene terephthalate of flexible parent metal film（PET）Film carries out plasma surface cleaning
With activation processing.
Step 2：Polyethylene terephthalate（PET）Film substrate surface, using roll-to-roll magnetron sputtering technique,
D.c. sputtering tin indium oxide（ITO）First transparency conducting layer 22.Tin indium oxide（ITO）Thicknesses of layers 100nm, it is seen that light transmittance
90%, 10 Ω of sheet resistance/.
Step 3：In tin indium oxide（ITO）Film surface further uses metal tungsten target material, is passed through argon Ar and oxygen O2
Mixed gas, DC reactive sputtering tungsten oxide（WO3）Electrochromism functional film layer, thicknesses of layers 200nm.
Step 4：In tungsten oxide（WO3）Film surface further uses roll-to-roll vacuum evaporation process, prepares lithium tantalate
（LiTaO3）Solid electrolyte film forms ionic electrolytes layer 24, film thickness 500nm.
Step 5：In electrolyte membrane surface, nickel oxide is further used（NiO）Target radio-frequency sputtering prepares nickel oxide
（NiO）Ion storage 25, thicknesses of layers 100nm.
Step 6：In nickel oxide（NiO）Film surface continues to prepare nickel oxide using magnetron sputtering technique（NiO）Top electricity
Pole forms the second transparency conducting layer 26, thicknesses of layers 100nm.
After obtaining above-mentioned flexible electrochromism smart membranes 2, according to outstanding flexible electrical mutagens in the preparation of following processing step
The hollow glass system of color smart membranes 2：
Step 1：Glass outer 1 uses normal transparent white glass, with a thickness of 6mm.
Step 2：Inner layer glass 3 uses normal transparent white glass, with a thickness of 6mm.
Step 3：Cavity thickness between two sheet glass is 18mm, hangs two panels flexibility electrochromism intelligence in the centre of cavity
Energy film, forms the cavity of two 6mm thickness；
Step 4：The interior of flexible electrochromism smart membranes hangs, fixed by the interior outstanding film fixed frame 4, and draws and electrically connect
Cavity both ends are sealed heat-insulating and sealing by line, the interior outstanding film fixed frame 4.It is of course also possible to by individually addition sealing every
Hot item seals cavity both ends.
Experiment discovery, the coefficient of heat insulation of above-mentioned interior outstanding flexible electrochromism smart membranes hollow glass（U value）For 1.17W/
m2K, the coefficient of heat insulation that the hollow glass of interior outstanding film is not used in the same terms is 2.75W/m2·K。
Experimental data table is as follows in above-mentioned each embodiment：
The present invention solves the problems of existing flexible electrochromism smart membranes technology, including stability deficiency, big ruler
Very little preparation is difficult, energy-saving effect is not ideal enough etc., and the present invention also provides a kind of technique sides of flexible electrochromism smart membranes 2
Method wherein each layer function film is all made of the solid inorganic material of high stability, while providing a kind of suitable for large scale company
The roll-to-roll technique for vacuum coating of electrochromism thermal-insulation window film of continuous production obtains light transmittance and intelligent controllable, the efficiently resistance of color
Every solar radiation, explosion-proof, anti-splashing flexible electrochromism smart membranes 2 are had both simultaneously.On this basis, by flexible electrical mutagens
It hangs and is fixed among hollow glass in color smart membranes 2, form multi-cavity structure hollow glass energy conserving system.
Claims (13)
1. hanging the hollow glass system of electrochromic intelligent film in one kind, spy is：The hollow glass system is multiple for stratiform
Structure is closed, layered composite construction successively includes：
1）Glass outer；
2）Flexible electrochromism smart membranes；
3）Inner layer glass；
And it is fixedly connected with the interior outstanding film fixed frame at each layer edge；
The glass outer and the inner layer glass are separated with air layer between the flexible electrochromism smart membranes respectively, institute
It states flexible electrochromism smart membranes and is at least one layer；The flexibility electrochromism film is electrically connected with electrical control wiring, institute
Electrical control wiring is stated across the interior outstanding film fixed frame and extends to the interior outstanding film fixed outer frame.
2. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 1, it is characterised in that：Institute
Stating glass outer is common building glass or low radiation coated glass.
3. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 1, it is characterised in that：Institute
Stating inner layer glass is common building glass or low radiation coated glass.
4. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 1, it is characterised in that：Institute
Stating flexible electrochromism smart membranes is layered composite structure, successively includes：
1) flexible parent metal film；
2) the first transparency conducting layer；
3) electrochromism functional layer；
4) ionic electrolytes layer；
5) ion storage；
6) the second transparency conducting layer.
5. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：Institute
Stating flexible parent metal film is thin polymer film；The thin polymer film be optical grade pet film or
Kapton or polyethylene naphthalate film or polyethylene film or polypropylene film or nylon are thin
Film.
6. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：Institute
It states the first transparency conducting layer and second transparency conducting layer is transparent conductive material film；The transparent conductive material film is oxygen
It is thin to change indium tin thin film, aluminum-doped zinc oxide films, Ga-doped zinc oxide film, antimony-doped tin oxide film, fluorine-doped tin oxide
A variety of in any one or above-mentioned film of film, nano metal grid film, nano-silver thread film are sequentially overlapped composition.
7. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：Institute
Stating electrochromism functional layer is cathodic electrochromic sull；The cathodic electrochromic sull is that tungsten oxide is thin
In any one or above-mentioned film of film, vanadium oxide film, columbium oxide film, thin film of titanium oxide, bismuth oxide film it is a variety of according to
Secondary superposition is constituted.
8. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：Institute
Stating ionic electrolytes layer is lithium ion compound film；The lithium ion compound film be lithium tantalate thin film, cobalt acid lithium film,
Any one of LiMn2O4 film, lithium phosphate film, lithium titanate thin film.
9. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：Institute
Stating ion storage is anode electrochromism tungsten oxide film；The anode electrochromism tungsten oxide film be nickel oxide film,
Aoxidize any one of iridium film, rhodium oxide film.
10. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：
The visible light transmittance rate of first transparency conducting layer and second transparency conducting layer is more than or equal to 90%, and sheet resistance is less than or equal to
20Ω/□。
11. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：
The thickness of the electrochromism functional layer is in 200-500nm.
12. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：
The thickness of the ionic electrolytes layer is in 500-1500nm.
13. hanging the hollow glass system of electrochromic intelligent film in one kind according to claim 4, it is characterised in that：
The thickness of the ion storage is in 100-200nm.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112612167A (en) * | 2020-12-15 | 2021-04-06 | 南京国重新金属材料研究院有限公司 | Electrochromic intelligent window assembly |
| CN115157814A (en) * | 2022-08-01 | 2022-10-11 | 江苏双星彩塑新材料股份有限公司 | Light-adjusting internal suspension film |
| CN115162913A (en) * | 2022-07-06 | 2022-10-11 | 江苏双星彩塑新材料股份有限公司 | Inner suspension film base material for inner suspension film door and window and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2667122Y (en) * | 2003-10-31 | 2004-12-29 | 湖南三才光电信息材料有限公司 | Energy-saving soundproof double-hollow glass |
| CN2818733Y (en) * | 2005-09-01 | 2006-09-20 | 倪既民 | Hollow diaphragm glass |
| CN201439676U (en) * | 2009-07-20 | 2010-04-21 | 信义玻璃工程（东莞）有限公司 | Electrical control thermal-radiation heating glass |
| KR20150137246A (en) * | 2014-05-29 | 2015-12-09 | 주식회사 동우 이앤씨 건축사사무소 | Multi-layer glass window |
| CN107765490A (en) * | 2017-11-27 | 2018-03-06 | 怡通科技有限公司 | A kind of heat-insulated intelligent fenestrated membrane of flexible electrochromism and its preparation technology |
| CN208900009U (en) * | 2018-07-30 | 2019-05-24 | 怡通科技有限公司 | A kind of hollow glass system of interior outstanding electrochromic intelligent film |
-
2018
- 2018-07-30 CN CN201810852301.5A patent/CN108825074A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2667122Y (en) * | 2003-10-31 | 2004-12-29 | 湖南三才光电信息材料有限公司 | Energy-saving soundproof double-hollow glass |
| CN2818733Y (en) * | 2005-09-01 | 2006-09-20 | 倪既民 | Hollow diaphragm glass |
| CN201439676U (en) * | 2009-07-20 | 2010-04-21 | 信义玻璃工程（东莞）有限公司 | Electrical control thermal-radiation heating glass |
| KR20150137246A (en) * | 2014-05-29 | 2015-12-09 | 주식회사 동우 이앤씨 건축사사무소 | Multi-layer glass window |
| CN107765490A (en) * | 2017-11-27 | 2018-03-06 | 怡通科技有限公司 | A kind of heat-insulated intelligent fenestrated membrane of flexible electrochromism and its preparation technology |
| CN208900009U (en) * | 2018-07-30 | 2019-05-24 | 怡通科技有限公司 | A kind of hollow glass system of interior outstanding electrochromic intelligent film |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112612167A (en) * | 2020-12-15 | 2021-04-06 | 南京国重新金属材料研究院有限公司 | Electrochromic intelligent window assembly |
| CN115162913A (en) * | 2022-07-06 | 2022-10-11 | 江苏双星彩塑新材料股份有限公司 | Inner suspension film base material for inner suspension film door and window and preparation method thereof |
| CN115162913B (en) * | 2022-07-06 | 2024-03-15 | 江苏双星彩塑新材料股份有限公司 | Inner suspension film base material for inner suspension film doors and windows and preparation method thereof |
| CN115157814A (en) * | 2022-08-01 | 2022-10-11 | 江苏双星彩塑新材料股份有限公司 | Light-adjusting internal suspension film |
| CN115157814B (en) * | 2022-08-01 | 2023-10-31 | 江苏双星彩塑新材料股份有限公司 | Light-adjusting inner suspension film |
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