Multi-medium high-temperature filtering device, pyrolysis system and filtering method
Technical Field
The invention relates to the field of pyrolysis treatment equipment, in particular to a multi-medium high-temperature filtering device and a filtering method.
Background
Biomass, coal and solid waste pyrolysis gasification are one of important ways for converting primary energy into clean secondary energy, and the product is mainly combustible gas and can be deeply processed into high-quality gas such as synthesis gas, hydrogen and the like. The pyrolysis gasification technology has wide application prospect in the aspects of heat supply, electric power, synthetic liquid fuel and the like. However, there is a general problem that a pyrolysis gasification process always generates a certain amount of tar and carries a lot of fine ash particles, which causes difficulty in gas purification, blocks and corrodes pipes, and seriously affects the stable operation of related combustion equipment.
Cyclone separation dust removal technology is mainly reported in the technology of purifying biomass, coal and solid waste crude gas reported in the literature and is used for separation dust removal, water washing purification, filler type filtration, thermal cracking, catalytic cracking and the like. The cyclone separation dust removal technology is the simplest, but because the fluctuation of the gas production amount in the operation process of the biomass gasification furnace is larger, the ideal dust removal effect is difficult to achieve. The most commonly used method at present adopts simple water washing treatment to purify the fuel gas, but because of the existence of a large amount of tar in the pyrolyzed and gasified fuel gas, the sewage discharged by water washing contains more harmful substances such as phenols, benzenes and the like, and the serious pollution problem is brought to the environment. The tar content in the fuel gas is reduced by adopting a catalytic cracking or high-temperature thermal cracking technology at home and abroad, but the tar in the biomass, coal and solid waste crude gas is mainly a condensed ring compound with very complex composition, so that the nickel-based catalyst is easy to be deactivated in the catalytic cracking process, and the production cost of the pyrolysis gasification fuel gas is greatly increased by the application of the catalyst. Therefore, the ash and tar in the high-temperature fuel gas generated by pyrolysis gasification cannot be thoroughly removed by the technical method, and secondary pollution is easily formed due to the tar and the ash.
The problem of tar condensation can be effectively solved by adopting high-temperature combustion of pyrolysis gas, but in order to prevent the pipeline, accessory equipment and a gas burner from being blocked, dust needs to be removed during combustion of the pyrolysis gas, and the temperature of the gas pyrolysis gas is not lower than that of tar condensation before the gas pyrolysis gas enters the burner. Although the existing high-temperature filter container can effectively remove dust, when the filter container device is started, the temperature of a membrane tube of the filter container is lower, tar is extremely easy to condense and adhere to the membrane tube when high-temperature fuel gas hits the membrane tube, so that the membrane tube is blocked, meanwhile, pyrolysis gas generated by pyrolysis or gasification is easy to fluctuate, the temperature fluctuation is large, and the gas is possibly lower than the condensation temperature of the tar, so that the tar is condensed in the membrane tube. Therefore, the filter vessel is necessary to be preheated and maintained at a temperature such that the temperature of the membrane tube is maintained above the condensation temperature of tar while solving the problems of dust removal and prevention of condensation by refueling when the pyrolysis gas is introduced into the filter vessel. The high temperature filter container can effectively remove dust, but when filter container equipment starts, filter container membrane pipe temperature is lower, and when high temperature gas hit the membrane pipe, the tar extremely easily condenses and bonds on the membrane pipe, causes the membrane pipe to block up, and simultaneously, pyrolysis gas that pyrolysis or gasification produced easily fluctuates temperature fluctuation is great, and the gas volume is likely to be less than tar condensation temperature, causes the tar condensation at the membrane pipe. The most conceivable method is therefore to add a heating means to ensure that the temperature of the pyrolysis gas at the time of entering the filtration vessel and the temperature of the filtration vessel itself are maintained above the condensation temperature of the tar, but this necessarily increases the complexity of the apparatus, while at the same time necessarily increasing the energy consumption.
Disclosure of Invention
The technical problem to be solved by the invention is how to ensure that the temperature of the pyrolysis gas when entering the filter container and the temperature of the filter container are maintained above the condensation temperature of tar.
In order to solve the technical problems, the invention designs a multi-medium high-temperature filtering device which is characterized by comprising more than 2 filtering containers, wherein the more than 2 filtering containers are arranged in a staggered or nested way, and the two filtering containers are independently arranged and are isolated by a heat conducting material.
The multi-medium high-temperature filtering device is characterized in that each filtering container is respectively provided with a purifying cavity, a supporting plate and an upper cavity; the purifying cavity on each filtering container is separated from the upper cavity by a supporting plate, openings are arranged on the supporting plate and used for supporting a membrane tube and filtering gas in the purifying cavity through the membrane tube and then discharging the filtered gas to the upper cavity, the filtering membrane is a metal membrane or a high-temperature ceramic membrane, the upper cavity is provided with a back blowing tube, soot blowing openings are arranged at positions corresponding to the openings on each supporting plate, and the soot blowing openings are connected with the back blowing tube; the purifying cavity is provided with an inlet, the upper cavity is provided with an outlet, the inlets of the filtering containers are all provided with electric control valves, and the purifying cavities are isolated by a partition wall made of heat conducting materials.
The multi-medium high-temperature filtering device is characterized by comprising 2 filtering containers, wherein the two filtering containers are a first filtering container and a second filtering container respectively, the inlets of the two filtering containers are connected through a pipeline, and an electric control valve is arranged on the pipeline.
The multi-medium high-temperature filtering device is characterized in that the purifying cavities of the first filtering container are nested in the purifying cavities of the second filtering container, the purifying cavities are mutually independent, and the purifying cavities are isolated by a partition wall.
The multi-medium high-temperature filtering device is characterized in that the purifying cavities of the first filtering container and the second filtering container respectively comprise a plurality of sub-evolution cavities; the sub-purification cavities of the first filter container and the sub-purification cavities of the second filter container are arranged in a staggered mode, are mutually independent and are isolated through a partition wall.
The multi-medium high-temperature filtering device is characterized by further comprising a third filtering container, wherein the purifying cavity of the second filtering container is arranged in the purifying cavity of the third purifying cavity, and the purifying cavities are mutually independent and are isolated by a partition wall.
The multi-medium high-temperature filtering device is characterized in that at least one filtering container is internally provided with a membrane tube.
The pyrolysis system comprises a pyrolysis system and a filtering subsystem, and is characterized in that the filtering subsystem adopts a multi-medium high-temperature filtering device as a filter.
A filtering method is characterized in that the purifying cavities of more than 2 filtering containers are nested or staggered together, and each filtering container is mutually independent; selecting tar-free gas from the gas to be filtered as preheated gas, opening an electric control valve on a filter container connected with the preheated gas, simultaneously respectively monitoring the temperature of the outlet of a membrane tube of other filter containers, and opening the electric control valve on the filter container where the membrane tube is positioned when the temperature of the outlet of the membrane tube reaches or exceeds a preset threshold value.
The filtering method is characterized in that a connecting container is further arranged between the filtering containers, the electric control valves on the filtering containers connected with the preheating gas are opened, meanwhile, the electric control valves on the connecting containers between the filtering containers are also opened, the preheating gas preheats all the filtering containers, meanwhile, the temperatures of the membrane tube outlets of other filtering containers are respectively monitored, when the temperatures of the membrane tube outlets reach or exceed a preset threshold value, the electric control valves on the connecting containers between the filtering containers are closed, meanwhile, high-temperature nitrogen for a period of time is input to the filtering containers except for the preheating gas, and then the electric control valves on the other filtering containers start normal filtering operation.
The implementation of the invention has the following beneficial effects: the high-temperature gas of one filter container is fully utilized to preheat the other filter containers, so that the temperature of the gas containing tar components at the inlet of the membrane tube reaches a preset value when the gas enters the inlet of the membrane tube, the problem that the membrane tube is blocked due to condensation and adhesion of tar on the membrane tube is solved, and the continuous maintenance temperature of the membrane tube is continuously ensured to be higher than the preset value.
Drawings
FIG. 1 is a system block diagram of a multi-media high temperature filtration device comprising two filtration vessels;
FIG. 2 is a system block diagram of a multi-media high temperature filtration device with only one filtration vessel having membrane tubes;
FIG. 3 is a system block diagram of a multi-media high temperature filtration device comprising three filtration vessels;
FIG. 4 is a system block diagram of a multi-media high temperature filtration device with an intermediate filtration vessel without a membrane tube.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
FIG. 1 is a system block diagram of a multi-media high temperature filtration device comprising two filtration vessels; the filter comprises a first filter container 1 and a second filter container 2, wherein an inlet of the second filter container is connected with a second pipeline 24, an inlet of the first filter container is connected with a first pipeline 14, the first pipeline 14 is connected with the second pipeline 24 through a pipeline, a first electric control valve 15 is arranged on the pipeline, and a second electric control valve 25 is also arranged on the second pipeline 24. The whole purifying cavity of the first filtering container 1 is cylindrical, the whole purifying cavity of the second filtering container 2 is circular, and the purifying cavity of the first filtering container 1 is arranged in the purifying cavity of the second filtering container and is isolated by a partition wall made of high-temperature ceramic materials. The first filtering container 1 and the second filtering container 2 are separated by a supporting plate 4, the upper part is respectively an upper cavity 18 of the first filtering container and an upper cavity 28 of the second filtering container, and the lower part is a purifying cavity; the support plate 4 is provided with openings in both the first filter vessel 1 and the second filter vessel 2 for supporting the membrane tubes. The upper cavity is provided with a back-blowing pipe; the purifying cavity is provided with an inlet, the upper cavity is provided with an outlet, and the inlet of each filtering container is provided with an electric control valve; the bottom of the first filtering container 1 is provided with a conical first ash discharging device 16, a plurality of membrane pipes are uniformly arranged on the purifying cavity to form a first matched membrane pipe 13, the upper cavity 18 of the first filtering container is provided with a plurality of first matched ash blowing openings 11 corresponding to the first matched membrane pipe 13, the first matched ash blowing openings 11 are connected with a back blowing pipeline, and the first air outlet 12 is arranged on the side wall of the purifying cavity and is higher than the first matched membrane pipe 13; the bottom of the second filtering container 2 is a conical second ash discharging device 26, a plurality of membrane pipes are uniformly arranged on the purifying cavity to form a second matched membrane pipe 23, an upper cavity 28 of the second filtering container is provided with a plurality of second matched ash blowing openings 21 corresponding to the second matched membrane pipe 23, the second matched ash blowing openings 21 are connected with a back blowing pipeline, and a second air outlet 22 is arranged on the side wall of the purifying cavity and is higher than the second matched membrane pipe 23.
It is assumed that there are two high temperature gases to be filtered at the same time, the two gases cannot be mixed, there is no dust, in particular no tar, on the first gas and the temperature is higher.
The first method of filtration is to connect one gas to the second conduit and the other gas to the first conduit. The implementation method is that the second electric control valve 25 is opened first, the first gas enters the purifying cavity of the second filtering container first, the high temperature gas preheats the purifying cavity of the first filtering container through the side wall, when the inlet of the first matched film tube 13 in the purifying cavity of the first filtering container reaches the preset temperature, the temperature is related to the condensation temperature of tar, and the tar is ensured not to be condensed. After the temperature is reached, the gas in the first filtering container is started to be filtered.
The second filtering method is as follows: one gas is connected to the second pipe and the other gas is connected to the first pipe. The implementation method is that the second electric control valve 25 is firstly opened, the first gas firstly enters the purifying cavity of the second filtering container, meanwhile, the first electric control valve 15 is opened, the high-temperature gas directly enters the purifying cavity of the first filtering container for preheating, and when the inlet of the first matched film tube 13 in the purifying cavity of the first filtering container reaches the preset temperature, the first electric control valve 15 is closed. For safety, the high-temperature N2 gas is input into the first filtering container to clean the gas in front, and then the gas in the first filtering container is started to start filtering.
FIG. 2 is a system block diagram of a multi-media high temperature filtration device having only one filtration vessel with membrane tubes, wherein if there is no dust on the high temperature gas on the second filtration vessel, the second matched membrane tube 23 and the second matched soot blowing port 21 on the second filtration vessel, and the matched device, can be omitted, so the component is provided in a detachable structure, and thus, different requirements can be met flexibly to a greater extent.
Similarly, the second filter vessel may be preheated by injecting the preheated gas into the first filter vessel. Meanwhile, the problem that the temperature fluctuation of single pyrolysis gas generated by pyrolysis is large, so that the temperature of the gas can be lower than the condensation temperature of tar at certain moments, and the tar is condensed on a membrane tube can be solved.
When larger accumulated ash exists on the filter container after the filter container is operated for a period of time, the filter can be cleaned simply by back blowing through the back blowing pipe to the back blowing through the matched soot blowing ports and discharging through the corresponding soot discharging ports.
More filtering containers can be contained, and the high-temperature filtering requirement of more media can be met simultaneously. FIG. 3 is a system block diagram of a multi-media high temperature filtration device comprising three filtration vessels; a third filter container 3 is added on the basis of two, the inlet of the third filter container is connected with a third pipeline 34, the third pipeline 34 is connected with a second pipeline 24 through a pipeline, and a third electric control valve 35 is arranged on the pipeline. The whole purifying cavity of the third filtering container 3 is in a circular ring shape, and the purifying cavity of the second filtering container 2 is arranged in the purifying cavity of the third filtering container 3 and is isolated by a partition wall made of high-temperature ceramic materials. Corresponding to the nesting arrangement of the first filter container, the second filter container and the third filter container. The first filtering container 1, the second filtering container 2 and the third filtering container 3 are all separated by a supporting plate 4, the upper parts are respectively an upper cavity 18 of the first filtering container, an upper cavity 28 of the second filtering container and an upper cavity 38 of the second filtering container, and the lower parts are purifying cavities; the support plate 4 is provided with openings for supporting the membrane tubes in the first filter vessel 1, the second filter vessel 2 and the third filter vessel 3. The upper cavity is provided with a back-blowing pipe; the purifying cavity is provided with an inlet, and the upper cavity is provided with an outlet. The third ash discharging device 36 with the conical bottom of the third filtering container 1 is uniformly provided with a plurality of membrane pipes on the purifying cavity to form a third matched membrane pipe 33, the upper cavity 38 of the third filtering container is provided with a plurality of third matched ash blowing ports 31 corresponding to the third matched membrane pipe 33, the third matched ash blowing ports 31 are connected with back blowing pipelines, and the third air outlet 32 is arranged on the side wall of the purifying cavity and is higher than the third matched membrane pipe 33.
The second filter vessel is preferably arranged in the middle as a preliminary heating vessel, and the gas having the highest temperature is generally selected to pass through the second filter vessel. If multiple filtering gases contain tar and dust, high-temperature gases without tar can be selected, N2 nitrogen is fed into the filtering device, the gases are pre-injected through the second filtering container, the gases can be simultaneously injected into the first filtering container and the third filtering container, the first filtering container, the second filtering container and the third filtering container are respectively used for preheating the purifying cavities, when the temperature of the membrane tube of each cavity reaches the preset temperature, the gas with the highest temperature is fed into the second filtering container in the middle, other gases are respectively fed into the first filtering container and the third filtering container for filtering, and in the process, the second filtering container continuously provides heat sources for the first filtering container and the third filtering container, so that the temperature of the membrane tube in the cavity is kept above the tar condensing temperature.
FIG. 4 is a system block diagram of a multi-media high temperature filtration device with an intermediate filtration vessel without a membrane tube. If the high-temperature gas on the second filtering container has no dust, the second matched film tube 23, the second matched soot blowing port 21 and the matched devices on the second filtering container can be omitted, so that the part is arranged into a detachable structure, and different requirements can be met flexibly to a greater extent. Of course, the removal of unnecessary membrane tubes and soot blowing openings in other filter vessels is also an option.
The above disclosure is illustrative of only one embodiment of the present invention and is not intended to limit the scope of the claims, and one of ordinary skill in the art will understand that all or a portion of the above embodiments may be implemented and equivalents may be substituted for elements thereof while the invention would be encompassed by the present claims.