CN108813809A - Antibacterial insoles and preparation method thereof - Google Patents
Antibacterial insoles and preparation method thereof Download PDFInfo
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- CN108813809A CN108813809A CN201810680037.1A CN201810680037A CN108813809A CN 108813809 A CN108813809 A CN 108813809A CN 201810680037 A CN201810680037 A CN 201810680037A CN 108813809 A CN108813809 A CN 108813809A
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
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Abstract
The invention discloses antibacterial insoles, including insole body, the insole body is made of sweat-absorbing layer, antibiotic layer and base, the upper end of the base is connected with antibiotic layer, the upper end of antibiotic layer is connected with sweat-absorbing layer, the position of the insole body heel offers L-type air dispelling hole, and multiple ventholes are offered in the sweat-absorbing layer, and the antibiotic layer is collectively formed by being plugged with multiple antibacterial balls in elastic filler.Foul smell in shoes is discharged air dispelling hole on insole from the sidewall extrusion of insole, and venthole is conducive to foul smell, sweat, Fungal contact in antibacterial ball and shoes, and latex package, gas permeability is strong, improves antibacterial effect, and gel-like structure, increases the elasticity of insole.
Description
Technical field
The present invention relates to insole correlative technology fields, specially antibacterial insoles and preparation method.
Background technique
Tinea pedis, foot odour are illnesss common in daily life, are the skin diseases as caused by fungal infection, infectivity and are controlled
Treat difficult, easy recurrent exerbation.It is shown according to related statistics, 70% to 80% people has tinea pedis in adult, and only weight is different
?.It is often aggravated in summer, winter mitigates, and also someone is not cured throughout the year.Therefore, occur on the market Da Kelin frost, pregnant fine jade ointment,
JIAOXIAN YICIJING etc., but using after drug therapy, it can often be recurred again within some months.It is had become so thoroughly curing tinea pedis
People's a great problem urgently to be solved.
Summary of the invention
The purpose of the present invention is to provide a kind of antibacterial insoles and preparation method thereof, to solve to propose in above-mentioned background technique
The problem of.
To achieve the above object, the present invention provides the following technical solutions：
Antibacterial insoles, including insole body, the insole body are made of sweat-absorbing layer, antibiotic layer and base, the base
Upper end is connected with antibiotic layer, and the upper end of antibiotic layer is connected with sweat-absorbing layer, and the position of the insole body heel offers L-type and dissipates
Stomata offers multiple ventholes in the sweat-absorbing layer, and the antibiotic layer is total to by being plugged with multiple antibacterial balls in elastic filler
With composition.
Preferably, the sweat-absorbing layer is grass layer or layer of cloth.
Preferably, the base is made of hard material.
Preferably, the antibacterial ball is made of following raw material according to parts by weight：
20-30 parts of fibrous radix of coptis, 30-40 parts of natural milk gelatin, 25-40 parts of Swamp Mahogany Leaf, 15-25 parts of shrub althea flower, 5-12 parts of Radix Angelicae Sinensis,
6-10 parts of lycopodium calvatum, 3-5 parts of Radix Salviae Miltiorrhizae, 5-8 parts of kaffir lily leaf, 12-18 parts of bentonite, 12-16 parts of stabilizer, gelling agent 15-30
Part.
Preferably, the stabilizer is that one or both of hydrotalcite, perchlorate and rare earth material mixing forms.
Preferably, the gelling agent is that one or both of alginate, gelatin and starch material mixing form.
The preparation method of antibacterial insoles, comprises the steps of：
S1, fibrous radix of coptis, Swamp Mahogany Leaf, shrub althea flower, Radix Angelicae Sinensis, lycopodium calvatum, Radix Salviae Miltiorrhizae, kaffir lily leaf are crossed water and cleaned, be respectively put into and stir
It is blended in broken machine, crosses 60-100 molecules of interest sieve, take pulverized particles, it is spare；
S2, by Radix Angelicae Sinensis, lycopodium calvatum and Radix Salviae Miltiorrhizae carry out steam blasting, collect explosion particle, in mass ratio 1:3, which are added mass fractions, is
The ethanol solution of 75-80% is heated to 40-50 DEG C of immersion 1-2h, is then filtered with vacuum filtration machine, obtains pie mixture；
All 30-40 times of raw material weight dehydrated alcohols measured, stirring is added in S3, Swamp Mahogany Leaf, shrub althea flower and the mixing of kaffir lily leaf
It is cooling after boiling drops to half to volume, it is put into holding temperature in decanter centrifuge and is centrifuged 40- in the state of being 35-40 DEG C
50min takes lower sediment thing, is freeze-dried to aneroid, obtains mixture；
S4, bentonite is added into natural milk gelatin, after mixing evenly, will be obtained in pie mixture obtained in step S2 and S3
It is added in natural milk gelatin and is stirred to mixture, stabilizer and gelling agent, room temperature are successively added into natural milk gelatin
1-2h is stirred, is then filtered with suction filtration machine, obtains gelatinous mixture；
S5, the spherical gelinite that gelatinous mixture obtained in step S4 is pressed into same size with film laminator, will be spherical
The surface of gelinite sprinkles one layer of fibrous radix of coptis particulate matter, is finally wrapped with gauze, and antibacterial ball is obtained；
S6, antibacterial bulb stopper obtained in step S5 is entered in antibiotic layer, base is sticked to the lower end of antibiotic layer, sweat-absorbing layer with viscose
It is sticked to the upper end of antibiotic layer with viscose, with press compression moulding, obtains insole body.
Compared with prior art, the beneficial effects of the invention are as follows：
1, Radix Angelicae Sinensis plays relaxing tendons and activating collaterals, promoting qi circulation and relieving pain, the curative effect of warming and activating meridian, and lycopodium calvatum has the function of dispelling wind and eliminating dampness, relaxing tendons and activating collaterals
Effect, Radix Salviae Miltiorrhizae have the effect of promoting vola blood circulation, removing sole cold air, increase the absorption to health nutrient substance；
2, the gallic acid in Swamp Mahogany Leaf is inhibited to the various coccuses generated in shoes；Shrub althea flower：Clearing heat and promoting diuresis, it is cool
Blood removing toxic substances；Kaffir lily leaf：Contain lycorine and clivianine in vivo, also contain trace elements of selenium, has very big effect to inhibition fungi
Fruit；Fibrous radix of coptis：Heat-clearing and damp-drying drug, purging fire for removing toxin.For damp and hot feeling of fullness.
3, the insole is put into shoes, heel presses the corresponding position of sweat-absorbing layer, and the air dispelling hole on insole will be in shoes
Foul smell be discharged from the sidewall extrusion of insole, venthole is conducive to foul smell, sweat, Fungal contact in antibacterial ball and shoes, latex
Package, gas permeability is strong, improves antibacterial effect, and gel-like structure, increases the elasticity of insole.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention；
Fig. 2 is overlooking structure diagram of the present invention.
In figure：Insole body 1, sweat-absorbing layer 11, antibiotic layer 12, antibacterial ball 121, base 13.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution referring to FIG. 1-2,：
Embodiment 1
Antibacterial insoles, including insole body 1, insole body 1 are made of sweat-absorbing layer 11, antibiotic layer 12 and base 13, base 13
Upper end be connected with antibiotic layer 12, base 13 is made of hard material, and the upper end of antibiotic layer 12 is connected with sweat-absorbing layer 11, sweat-absorbing layer
11 be grass layer or layer of cloth, and the position of 1 heel of insole body offers L-type air dispelling hole, multiple ventilations are offered in sweat-absorbing layer 11
Hole, antibiotic layer 12 are collectively formed by being plugged with multiple antibacterial balls 121 in elastic filler.
Antibacterial ball 121 is made of following raw material according to parts by weight：
20 parts of fibrous radix of coptis, 30 parts of natural milk gelatin, 25 parts of Swamp Mahogany Leaf, 15 parts of shrub althea flower, 5 parts of Radix Angelicae Sinensis, 6 parts of lycopodium calvatum, Radix Salviae Miltiorrhizae 3
Part, 5 parts of kaffir lily leaf, 12 parts of bentonite, 12 parts of stabilizer, 15 parts of gelling agent.
The stabilizer is that one or both of hydrotalcite, perchlorate and rare earth material mixing forms, the gel
Agent is that one or both of alginate, gelatin and starch material mixing form.
The preparation method of antibacterial insoles, comprises the steps of：
S1, fibrous radix of coptis, Swamp Mahogany Leaf, shrub althea flower, Radix Angelicae Sinensis, lycopodium calvatum, Radix Salviae Miltiorrhizae, kaffir lily leaf are crossed water and cleaned, be respectively put into and stir
It is blended in broken machine, crosses 60 molecules of interest sieve, take pulverized particles, it is spare；
S2, by Radix Angelicae Sinensis, lycopodium calvatum and Radix Salviae Miltiorrhizae carry out steam blasting, collect explosion particle, in mass ratio 1:3, which are added mass fractions, is
75% ethanol solution is heated to 40 DEG C of immersion 1h, is then filtered with vacuum filtration machine, obtains pie mixture；
The dehydrated alcohol of all 30 times of raw material weight amounts is added in S3, Swamp Mahogany Leaf, shrub althea flower and the mixing of kaffir lily leaf, stirs boiling
It is cooling after dropping to half to volume, it is put into holding temperature in decanter centrifuge and is centrifuged 40min in the state of being 35 DEG C, remove
Layer sediment, is freeze-dried to aneroid, obtains mixture；
S4, bentonite is added into natural milk gelatin, after mixing evenly, will be obtained in pie mixture obtained in step S2 and S3
It is added in natural milk gelatin and is stirred to mixture, stabilizer and gelling agent, room temperature are successively added into natural milk gelatin
1h is stirred, is then filtered with suction filtration machine, obtains gelatinous mixture；
S5, the spherical gelinite that gelatinous mixture obtained in step S4 is pressed into same size with film laminator, will be spherical
The surface of gelinite sprinkles one layer of fibrous radix of coptis particulate matter, is finally wrapped with gauze, and antibacterial ball 121 is obtained；
S6, antibacterial ball 121 obtained in step S5 is filled in antibiotic layer 12, base 13 is sticked under antibiotic layer 12 with viscose
End, sweat-absorbing layer 11 are sticked to the upper end of antibiotic layer 12 with viscose, with press compression moulding, obtain insole body 1.
Embodiment 2
Antibacterial insoles, including insole body 1, insole body 1 are made of sweat-absorbing layer 11, antibiotic layer 12 and base 13, base 13
Upper end be connected with antibiotic layer 12, base 13 is made of hard material, and the upper end of antibiotic layer 12 is connected with sweat-absorbing layer 11, sweat-absorbing layer
11 be grass layer or layer of cloth, and the position of 1 heel of insole body offers L-type air dispelling hole, multiple ventilations are offered in sweat-absorbing layer 11
Hole, antibiotic layer 12 are collectively formed by being plugged with multiple antibacterial balls 121 in elastic filler.
Antibacterial ball 121 is made of following raw material according to parts by weight：
25 parts of fibrous radix of coptis, 35 parts of natural milk gelatin, 33 parts of Swamp Mahogany Leaf, 20 parts of shrub althea flower, 9 parts of Radix Angelicae Sinensis, 8 parts of lycopodium calvatum, Radix Salviae Miltiorrhizae 4
Part, 6 parts of kaffir lily leaf, 15 parts of bentonite, 14 parts of stabilizer, 23 parts of gelling agent.
The stabilizer is that one or both of hydrotalcite, perchlorate and rare earth material mixing forms, the gel
Agent is that one or both of alginate, gelatin and starch material mixing form.
The preparation method of antibacterial insoles, comprises the steps of：
S1, fibrous radix of coptis, Swamp Mahogany Leaf, shrub althea flower, Radix Angelicae Sinensis, lycopodium calvatum, Radix Salviae Miltiorrhizae, kaffir lily leaf are crossed water and cleaned, be respectively put into and stir
It is blended in broken machine, crosses 80 molecules of interest sieve, take pulverized particles, it is spare；
S2, by Radix Angelicae Sinensis, lycopodium calvatum and Radix Salviae Miltiorrhizae carry out steam blasting, collect explosion particle, in mass ratio 1:3, which are added mass fractions, is
77% ethanol solution is heated to 45 DEG C of immersion 1.5h, is then filtered with vacuum filtration machine, obtains pie mixture；
The dehydrated alcohol of all 35 times of raw material weight amounts is added in S3, Swamp Mahogany Leaf, shrub althea flower and the mixing of kaffir lily leaf, stirs boiling
It is cooling after dropping to half to volume, it is put into holding temperature in decanter centrifuge and is centrifuged 45min in the state of being 37 DEG C, remove
Layer sediment, is freeze-dried to aneroid, obtains mixture；
S4, bentonite is added into natural milk gelatin, after mixing evenly, will be obtained in pie mixture obtained in step S2 and S3
It is added in natural milk gelatin and is stirred to mixture, stabilizer and gelling agent, room temperature are successively added into natural milk gelatin
1.5h is stirred, is then filtered with suction filtration machine, obtains gelatinous mixture；
S5, the spherical gelinite that gelatinous mixture obtained in step S4 is pressed into same size with film laminator, will be spherical
The surface of gelinite sprinkles one layer of fibrous radix of coptis particulate matter, is finally wrapped with gauze, and antibacterial ball 121 is obtained；
S6, antibacterial ball 121 obtained in step S5 is filled in antibiotic layer 12, base 13 is sticked under antibiotic layer 12 with viscose
End, sweat-absorbing layer 11 are sticked to the upper end of antibiotic layer 12 with viscose, with press compression moulding, obtain insole body 1.
Embodiment 3
Antibacterial insoles, including insole body 1, insole body 1 are made of sweat-absorbing layer 11, antibiotic layer 12 and base 13, base 13
Upper end be connected with antibiotic layer 12, base 13 is made of hard material, and the upper end of antibiotic layer 12 is connected with sweat-absorbing layer 11, sweat-absorbing layer
11 be grass layer or layer of cloth, and the position of 1 heel of insole body offers L-type air dispelling hole, multiple ventilations are offered in sweat-absorbing layer 11
Hole, antibiotic layer 12 are collectively formed by being plugged with multiple antibacterial balls 121 in elastic filler.
Antibacterial ball 121 is made of following raw material according to parts by weight：
30 parts of fibrous radix of coptis, 40 parts of natural milk gelatin, 40 parts of Swamp Mahogany Leaf, 25 parts of shrub althea flower, 12 parts of Radix Angelicae Sinensis, 10 parts of lycopodium calvatum, pellet
Join 5 parts, 8 parts of kaffir lily leaf, 18 parts of bentonite, 16 parts of stabilizer, 30 parts of gelling agent.
The stabilizer is that one or both of hydrotalcite, perchlorate and rare earth material mixing forms, the gel
Agent is that one or both of alginate, gelatin and starch material mixing form.
The preparation method of antibacterial insoles, comprises the steps of：
S1, fibrous radix of coptis, Swamp Mahogany Leaf, shrub althea flower, Radix Angelicae Sinensis, lycopodium calvatum, Radix Salviae Miltiorrhizae, kaffir lily leaf are crossed water and cleaned, be respectively put into and stir
It is blended in broken machine, crosses 100 molecules of interest sieve, take pulverized particles, it is spare；
S2, by Radix Angelicae Sinensis, lycopodium calvatum and Radix Salviae Miltiorrhizae carry out steam blasting, collect explosion particle, in mass ratio 1:3, which are added mass fractions, is
80% ethanol solution is heated to 50 DEG C of immersion 2h, is then filtered with vacuum filtration machine, obtains pie mixture；
The dehydrated alcohol of all 40 times of raw material weight amounts is added in S3, Swamp Mahogany Leaf, shrub althea flower and the mixing of kaffir lily leaf, stirs boiling
It is cooling after dropping to half to volume, it is put into holding temperature in decanter centrifuge and is centrifuged 50min in the state of being 40 DEG C, remove
Layer sediment, is freeze-dried to aneroid, obtains mixture；
S4, bentonite is added into natural milk gelatin, after mixing evenly, will be obtained in pie mixture obtained in step S2 and S3
It is added in natural milk gelatin and is stirred to mixture, stabilizer and gelling agent, room temperature are successively added into natural milk gelatin
2h is stirred, is then filtered with suction filtration machine, obtains gelatinous mixture；
S5, the spherical gelinite that gelatinous mixture obtained in step S4 is pressed into same size with film laminator, will be spherical
The surface of gelinite sprinkles one layer of fibrous radix of coptis particulate matter, is finally wrapped with gauze, and antibacterial ball 121 is obtained；
S6, antibacterial ball 121 obtained in step S5 is filled in antibiotic layer 12, base 13 is sticked under antibiotic layer 12 with viscose
End, sweat-absorbing layer 11 are sticked to the upper end of antibiotic layer 12 with viscose, with press compression moulding, obtain insole body 1.
To embody beneficial effects of the present invention, following experiment is made：
One：Improvement experiment is carried out to clinical patient；
1, Liu Lei, male, 35 years old, itches, breach bleeding with tinea pedis, foot, with foot odour, insole of the present invention is used continuously and fullys recover from an illness after 21 days
More.
2, Zhao Jian, male 55 years old, suffer from intractable beriberi, foot is itched, and do not eradicate after treating for many years, and shoes of the present invention are used continuously
Pad is fully recovered after 40 days, and also foot is ice-cold before, the symptom of sole night sweat, the symptom of taste void, is using insole of the present invention
It is also eased after 40 days, symptom mitigates.
3, Wang Peng, male 28 years old, suffer from tinea pedis, foot is itched, breach bleeding, and with foot odour, insole of the present invention is used continuously after 18 days
Recovery from illness.
Patient in above-described embodiment, recovery from illness later six months investigate display again, do not recur, thoroughly eradicate.
Two, carry out absorption of perspiration experiment, choose the antibacterial insoles as a comparison case 1 produced on the market by Guangzhou, upper marine products it is anti-
Bacterium insole as a comparison case 2.
Absorption of perspiration test：GB/T3903.11-2005 carries out absorption of perspiration test according to national standards.The formula of synthetic perspiration
For：One water hydroxylamine hydrochloride 5.00g, sodium chloride 5.00g, phosphate dihydrate disodium hydrogen 2.50g, distilled water 1L, and with 0.1mol/L's
It is 8.0 that sodium hydroxide, which adjusts pH,.Antibacterial insoles obtained in each embodiment and comparative example are put into and fill synthetic perspiration's
In 1000mL beaker, insole is fully immersed in synthetic perspiration by adding extra weight on insole, then puts beaker
It sets and stands 12h in 35 DEG C of insulating boxs, take out insole and be washed with distilled water and dry, tested as 1 sweat proof.After antimicrobial treatment
Insole has carried out 10 times and 20 sweat proof tests respectively, dries the bacteriostasis rate of rear test sample, and test strain is golden yellow grape
Coccus, test result such as table 1.
Table 1
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| 10 times sweat proof tests bacteriostasis rate（Unit：%） | 98.69 | 99.42 | 98.01 | 85.24 | 84.71 |
| 20 times sweat proof tests bacteriostasis rate（Unit：%） | 97.75 | 98.26 | 97.16 | 81.03 | 80.19 |
| Stink | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour | There is stink | There is stink |
In conclusion antibacterial insoles fungistatic effect of the invention is more preferable, it is worth of widely use.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. antibacterial insoles, including insole body（1）, it is characterised in that：The insole body（1）It is by sweat-absorbing layer（11）, antibacterial
Layer（12）And base（13）Composition, the base（13）Upper end be connected with antibiotic layer（12）, antibiotic layer（12）Upper end connection
There is sweat-absorbing layer（11）, the insole body（1）The position of heel offers L-type air dispelling hole, the sweat-absorbing layer（11）On open up
There are multiple ventholes, the antibiotic layer（12）It is by being plugged with multiple antibacterial balls in elastic filler（121）It collectively forms.
2. antibacterial insoles according to claim 1, it is characterised in that：The sweat-absorbing layer（11）For grass layer or layer of cloth.
3. antibacterial insoles according to claim 1, it is characterised in that：The base（13）It is made of hard material.
4. antibacterial insoles according to claim 1, it is characterised in that：The antibacterial ball（121）By following raw material according to weight
Measure part composition：
20-30 parts of fibrous radix of coptis, 30-40 parts of natural milk gelatin, 25-40 parts of Swamp Mahogany Leaf, 15-25 parts of shrub althea flower, 5-12 parts of Radix Angelicae Sinensis,
6-10 parts of lycopodium calvatum, 3-5 parts of Radix Salviae Miltiorrhizae, 5-8 parts of kaffir lily leaf, 12-18 parts of bentonite, 12-16 parts of stabilizer, gelling agent 15-30
Part.
5. antibacterial insoles according to claim 4, it is characterised in that：The stabilizer is hydrotalcite, perchlorate and dilute
One or both of soil material mixing forms.
6. antibacterial insoles according to claim 4, it is characterised in that：The gelling agent is alginate, gelatin and starch
One or both of material mixing form.
7. the preparation method of antibacterial insoles described in -6 according to claim 1, which is characterized in that comprise the steps of：
S1, fibrous radix of coptis, Swamp Mahogany Leaf, shrub althea flower, Radix Angelicae Sinensis, lycopodium calvatum, Radix Salviae Miltiorrhizae, kaffir lily leaf are crossed water and cleaned, be respectively put into and stir
It is blended in broken machine, crosses 60-100 molecules of interest sieve, take pulverized particles, it is spare；
S2, by Radix Angelicae Sinensis, lycopodium calvatum and Radix Salviae Miltiorrhizae carry out steam blasting, collect explosion particle, in mass ratio 1:3, which are added mass fractions, is
The ethanol solution of 75-80% is heated to 40-50 DEG C of immersion 1-2h, is then filtered with vacuum filtration machine, obtains pie mixture；
All 30-40 times of raw material weight dehydrated alcohols measured, stirring is added in S3, Swamp Mahogany Leaf, shrub althea flower and the mixing of kaffir lily leaf
It is cooling after boiling drops to half to volume, it is put into holding temperature in decanter centrifuge and is centrifuged 40- in the state of being 35-40 DEG C
50min takes lower sediment thing, is freeze-dried to aneroid, obtains mixture；
S4, bentonite is added into natural milk gelatin, after mixing evenly, will be obtained in pie mixture obtained in step S2 and S3
It is added in natural milk gelatin and is stirred to mixture, stabilizer and gelling agent, room temperature are successively added into natural milk gelatin
1-2h is stirred, is then filtered with suction filtration machine, obtains gelatinous mixture；
S5, the spherical gelinite that gelatinous mixture obtained in step S4 is pressed into same size with film laminator, will be spherical
The surface of gelinite sprinkles one layer of fibrous radix of coptis particulate matter, is finally wrapped with gauze, and antibacterial ball is obtained（121）；
S6, by antibacterial ball obtained in step S5（121）Fill in antibiotic layer（12）In, by base（13）Antibiotic layer is sticked to viscose
（12）Lower end, sweat-absorbing layer（11）Antibiotic layer is sticked to viscose（12）Upper end obtain insole body with press compression moulding
（1）.
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| CN201810680037.1A CN108813809A (en) | 2018-06-27 | 2018-06-27 | Antibacterial insoles and preparation method thereof |
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| CN106360880A (en) * | 2016-08-28 | 2017-02-01 | 杭州锴越新材料有限公司 | Bacteriostatic negative ion shoe pad and preparation method thereof |
| CN106360879A (en) * | 2016-08-28 | 2017-02-01 | 杭州锴越新材料有限公司 | Multifunctional healthy negative-ion insoles and making method thereof |
| CN106263268A (en) * | 2016-08-28 | 2017-01-04 | 杭州锴越新材料有限公司 | Far infrared, warm, health care shoe pad and preparation method thereof |
| CN206528164U (en) * | 2017-01-08 | 2017-09-29 | 广州市永好塑胶鞋材有限公司 | A kind of refrigerant shoe-pad suitable for summer |
| CN207322819U (en) * | 2017-08-24 | 2018-05-08 | 李吉彬 | A kind of insole |
| CN108078072A (en) * | 2017-11-03 | 2018-05-29 | 新沂市申美达食品有限公司 | A kind of antibacterial deodorant insole |
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Application publication date: 20181116 |