CN108807555A - A kind of schottky diode device - Google Patents

A kind of schottky diode device Download PDF

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Publication number
CN108807555A
CN108807555A CN201810899042.1A CN201810899042A CN108807555A CN 108807555 A CN108807555 A CN 108807555A CN 201810899042 A CN201810899042 A CN 201810899042A CN 108807555 A CN108807555 A CN 108807555A
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CN
China
Prior art keywords
type semiconductor
schottky diode
semiconductor nano
schottky
wire
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Pending
Application number
CN201810899042.1A
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Chinese (zh)
Inventor
任敏
何文静
杨梦琦
李泽宏
高巍
张金平
张波
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University of Electronic Science and Technology of China
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University of Electronic Science and Technology of China
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Priority to CN201810899042.1A priority Critical patent/CN108807555A/en
Publication of CN108807555A publication Critical patent/CN108807555A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/872Schottky diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0657Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
    • H01L29/0665Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body the shape of the body defining a nanostructure
    • H01L29/0669Nanowires or nanotubes

Abstract

A kind of Schottky diode belongs to semiconductor power technical field.The present invention includes the metallization cathode set gradually from bottom to top, N+ semiconductor substrates, N-type semiconductor nano-wire array, schottky metal and metallization anode, and compound inslation dielectric layer is filled between N-type semiconductor nano wire gap.Since the compound interface that the insulating medium layer of differing dielectric constant is formed can introduce peak electric field, and the dielectric constant of the insulating medium layer close to metallization anode side is higher, so surface field at schottky junction can be reduced effectively so that the field distribution inside semiconductor nanowires is more uniform.Thus it improves the breakdown voltage of device and can suitably increase the doping concentration of semiconductor nanowires to reduce conducting resistance, reduce conduction loss, so as to improve the breakdown voltage of Schottky diode and the contradictory relation of forward conduction voltage drop.

Description

A kind of schottky diode device
Technical field
The invention belongs to power semiconductor technologies fields, and in particular to a kind of Schottky diode.
Background technology
Diode is widely used in each electronic product, is a kind of indispensable electronic component.Power diode In it is most widely used include PN junction diode, Schottky diode (SBD), junction barrier diode (JBS) etc..Wherein, Xiao Te Based diode is also known as Schottky-barrier diode, is grown up based on Semiconductor Physics Metals-semiconductor contacts theory A kind of both ends semiconductor devices, between metal and semiconductor formed electrical nonlinearity contact, have lower cut-in voltage And conduction voltage drop;Again because being monopole conduction, carrier-free storage effect, thus reverse recovery time is short, switching speed quickly, It is widely used in various high frequencies, microwave, rectification, Switching Power Supply and high speed circuit.But the reversed leakage of Schottky diode Electric current is larger, and temperature characterisitic is poor, and traditional planarized structure is easy to happen surface breakdown.Since Schottky diode is single Pole device, there is also " the silicon limit " problems between breakdown voltage and forward conduction voltage drop, i.e., such as to improve two pole of Schottky The breakdown voltage of pipe then needs the thickness for reducing its drift doping concentration, increasing drift region, this will necessarily cause conduction voltage drop Increase and forward conduction loss increase.
Invention content
In view of described above, the present invention is for there are contradiction passes between the breakdown reverse voltage and forward conduction voltage drop of SBD It is this technological deficiency, a kind of two pole of Schottky based on filled composite insulating medium layer between longitudinal nano-wire array is provided It manages, compound inslation dielectric layer can introduce the peak electric field for reducing electric field at schottky junction in device body in the structure, realize Its adjusting to nanowires body internal electric field so that nano wire can be completely depleted quickly, is further increasing breakdown reverse voltage While also reduce forward conduction voltage drop.
To achieve the goals above, the present invention adopts the following technical scheme that:
A kind of Schottky diode, structure include the metallization cathode 1 set gradually from bottom to top, N+ semiconductor substrates 2, N-type semiconductor nano-wire array, schottky metal 5 and metallization anode 6, it is characterised in that:The N-type semiconductor nano wire Array is made of mutual indepedent, non-touching N-type semiconductor nano wire 3;Filled with multiple between N-type semiconductor nano-wire array Close insulating medium layer 4;The compound inslation dielectric layer 4 is passed from bottom to top according to dielectric constant by least two layers of insulating medium layer The rule of increasing is stacked;The lower surface of the compound inslation dielectric layer 4 is in contact with N+ semiconductor substrates 2, and compound inslation is situated between The upper surface of matter layer 4 and N-type semiconductor nano-wire array is in contact with schottky metal 5.
Further, the present invention in N-type semiconductor nano wire 3 a diameter of 10nm~1000nm.
Further, the present invention in N-type semiconductor nano wire 3 shape be cylinder, cube, hexagonal prisms or it is any can The solid of realization.
Further, N-type semiconductor nano wire 3 arranges squarely, bar shaped, isosceles triangle, hexagon or any in the present invention The array for the mode of can be achieved.
Further, the material of semiconductor nanowires 3 is silicon, germanium silicon (SiGe), silicon carbide (SiC), arsenic in the present invention Gallium (GaAs), gallium nitride (GaN) or other any suitable semi-conducting materials.
Compared with prior art, the beneficial effects of the present invention are:
The present invention by the filled composite insulating medium layer between the gap of the semiconductor nanowires of Schottky diode, due to Contact interface between the insulating medium layer of high low-k can introduce peak electric field, therefore compound exhausted by rationally adjusting The position of contact interface in edge dielectric layer, and then the peak electric field for being minimized electric field at schottky junction is introduced in device body, So that the field distribution inside semiconductor nanowires is more uniform.Thus, it is possible to improve the breakdown voltage of device and can fit by the present invention When increase semiconductor nanowires doping concentration with reduce conducting resistance, reduce conduction loss, so as to improve Schottky diode Contradictory relation of the breakdown voltage (BV) between forward conduction voltage drop.
Description of the drawings
Fig. 1 is a kind of cross-sectional view for Schottky diode that the embodiment of the present invention 1 provides.
Fig. 2 be the embodiment of the present invention 1 provide a kind of Schottky diode when adding backward voltage, nanowire edge AA ' The field distribution schematic diagram at place.
Fig. 3 is a kind of cross-sectional view for Schottky diode that the embodiment of the present invention 2 provides.
Fig. 4 is the 1st kind of arrangement mode schematic diagram of conductor nano tube/linear array in Schottky diode provided by the invention.
Fig. 5 is the 2nd kind of arrangement mode schematic diagram of conductor nano tube/linear array in Schottky diode provided by the invention.
Fig. 6 is the 3rd kind of arrangement mode schematic diagram of conductor nano tube/linear array in Schottky diode provided by the invention.
Fig. 7 to Figure 11 is that a kind of structure of the technological process manufacture for Schottky diode that the embodiment of the present invention 3 provides is shown It is intended to.
In figure, 1 is metallization cathode, and 2 be N+ semiconductor substrates, and 3 be semiconductor nanowires, and 4 be compound inslation dielectric layer, 41 be the first insulating medium layer, and 42 be the second insulating medium layer, and 43 be third insulating medium layer, and 5 be schottky metal, and 6 be gold Categoryization anode.
Specific implementation mode
In order to enable one of ordinary skill in the art can more understand the present invention program and principle, below in conjunction with the accompanying drawings and have Body embodiment is described in detail.Present disclosure is not limited to any specific embodiment, and it is most preferred embodiment also not represent, General replacement well-known to those skilled in the art is also encompassed within the scope of the invention.
Embodiment 1;
The present embodiment provides a kind of Schottky diodes, as shown in Figure 1, its structure includes the gold set gradually from bottom to top Categoryization cathode 1, N+ semiconductor substrates 2, N-type semiconductor nano-wire array, schottky metal 5 and metallization anode 6, feature exists In:The N-type semiconductor nano-wire array is made of mutual indepedent, non-touching N-type semiconductor nano wire 3, this implementation N-type The diameter range of semiconductor nanowires 3 is 10nm~1000nm;Compound inslation Jie is provided between N-type semiconductor nano-wire array Matter layer 4;The compound inslation dielectric layer 4 be stacked from bottom to top by the first insulating medium layer 41 and the second insulating medium layer 42 and At the dielectric constant of first insulating medium layer 41 is less than the dielectric constant of second insulating medium layer 42;It is described compound The lower surface of insulating medium layer 4 is in contact with N+ semiconductor substrates 2, compound inslation dielectric layer 4 and N-type semiconductor nano-wire array Upper surface be in contact with schottky metal 5.
The operation principle of the present invention is described in detail with reference to embodiment 1:
When device forward conduction, the electric current of Schottky diode is flowed from metallization anode 6 through N-type semiconductor nano wire 3 To metallization cathode 1;When a reverse bias is applied, field distribution such as Fig. 2 institutes at the nanowire edge AA ' of Schottky diode Show, the dotted line wherein in reference axis indicates that the field distribution of Conventional Schottky diodes, solid line are Schottky diode of the present invention Field distribution.By the way that compound inslation dielectric layer 4 is arranged between N-type semiconductor nano wire 3 so that device is under reverse bias Depletion layer in N-type semiconductor nano wire 3 is extended to 1 side of metallization cathode, the metallization anode 6 and gold of Schottky diode Categoryization cathode 1 is separately positioned on the upper and lower surface contact of N-type semiconductor nano-wire array, is schottky junction at anode.Work as application When voltage is sufficiently large, because of the radial dimension very little of nano wire, using the insulating dielectric materials of surrounding to electric field in semiconductor body Adjustment effect, N-type semiconductor nano wire can be completely depleted quickly.Because the second insulation close to 6 side of metallization anode is situated between 42 dielectric constant of matter layer compares 41 higher of the first insulating medium layer, according to Gauss theorem it is found that close to 6 side of metallization anode Electric field between N-type semiconductor nano wire and the second insulating medium layer 42 compares its lower with the first insulating medium layer 41, general A peak electric field is introduced at two kinds of insulating medium layer contact interfaces, the peak electric field of introducing can make N-type semiconductor nano wire 3 Internal field distribution is more uniform, effectively reduces the surface field at schottky junction.Therefore N-type semiconductor nano wire 3 is mixed Miscellaneous concentration can be increased suitably, and the breakdown reverse voltage of device is further increased while realizing compared with low forward conduction voltage drop. Therefore a kind of nano wire Schottky diode with compound medium layer proposed by the present invention, improve the breakdown of Schottky diode The contradictory relation of voltage and forward conduction voltage drop further decreases the conduction loss of device.
Embodiment 2:
The present embodiment compared to embodiment 1 difference lies in:Compound inslation dielectric layer includes the first insulating medium layer 41, second Insulating medium layer 42, third insulating medium layer 43 ... wait multiple insulating medium layers, and the dielectric of multiple insulating medium layers is normal Number is sequentially reduced from top to bottom, remaining structure is same as Example 1.
The present embodiment enables to the electric field point inside N-type semiconductor nano wire due to being provided with multiple insulating medium layers Cloth is more uniform, further improves the contradictory relation of Schottky diode breakdown voltage and forward conduction voltage drop, reduces device Conduction loss.
Fig. 4 to fig. 6 gives three kinds of Schottky diodes with different N-type semiconductor nanometer wire shapeds and arrangement mode Three dimensional structure diagram schottky metal 5 and metallic electrode 6 are omitted in figure in order to protrude nano thread structure.Wherein, N-type semiconductor nano wire 3 is cylindrical structure, the array that is square arrangement in Fig. 4;N-type semiconductor nano wire 3 is cylinder in Fig. 5 Body structure is arranged in " isosceles triangle " array;N-type semiconductor nano wire 3 is hexagonal prisms structure in Fig. 6, is in hexagonal array.
Embodiment 3:
The present invention provides the manufacturing process flow of silicon nanowires Schottky diode as described in Example 1, main techniques Steps are as follows:
Step 1:Monocrystalline substrate prepares and semiconductor nanowires 3 are grown:
As shown in fig. 7, selecting N+ monocrystalline silicon as substrate material, N-type semiconductor nano wire 3 is defined using mask Region locally exposes monocrystalline substrate surface, is then grown mutually solely in the region surface selective vapor extension (VPE) Vertical, non-touching N-type semiconductor nano wire 3 is to form the conductor nano tube/linear array with certain arrangement;
Step 2:Deposit the first insulating medium layer 41:
As shown in figure 8, after forming 3 array of N-type semiconductor nano wire, based on CVD technology N-type semiconductor nano wire 3 it Between gap in deposit the first insulating medium layer 41, then etch the first extra insulating medium layer 41 so that the first dielectric The upper surface of layer 41 is arranged close to device anode side to ensure that the electric field spike introduced can be good at adjusting at schottky junction Electric field;
Step 3:Deposit the second insulating medium layer 42:
As shown in figure 8, after completing the deposit of the first insulating medium layer 41 and etching, deposit second is continued absolutely based on CVD technology Edge dielectric layer 42 is complete to fill head room clearance between N-type semiconductor nano wire 3, on the first insulating medium layer 41 At surface planarisation processing is carried out after deposit again;
Step 4:Deposit schottky metal 5:
As shown in Figure 10, in 42 surface deposition schottky metal 5 of the silicon of planarization and the second insulating medium layer, the Xiao Te Base Metal is preferably the alloy of arbitrary several formation in the metals such as titanium, nickel, cobalt, chromium, platinum or above-mentioned metal;
Step 5:Form metallic electrode:
As shown in figure 11, deposited metal is distinguished in device front and the back side, respectively as the metal of Schottky diode Change anode 6 and metallization cathode 1.
It should be strongly noted that Schottky diode making devices provided by the invention, it is also possible to silicon carbide, nitridation The semi-conducting materials such as gallium, GaAs, indium phosphide or germanium silicon replace body silicon;The growth of N-type semiconductor nano wire 3 both can be used first outer Prolong and the top-down preparation method such as etch again, the bottom-up preparation method such as self-assembled growth can also be used.
The embodiment of the present invention is elaborated above in association with attached drawing, but the invention is not limited in above-mentioned Specific implementation mode, above-mentioned specific implementation mode is only schematical, rather than restrictive, the ordinary skill people of this field Member under the inspiration of the present invention, can also make many in the case of not departing from present inventive concept and claimed range Deformation, these belong to the protection of the present invention.

Claims (5)

1. a kind of Schottky diode, structure includes the metallization cathode (1) set gradually from bottom to top, N+ semiconductor substrates (2), N-type semiconductor nano-wire array, schottky metal (5) and metallization anode (6), it is characterised in that:The N-type semiconductor Nano-wire array is made of mutual indepedent, non-touching N-type semiconductor nano wire (3);Between N-type semiconductor nano-wire array Filled with compound inslation dielectric layer (4);The compound inslation dielectric layer (4) is normal according to dielectric by least two layers of insulating medium layer Rule incremental from bottom to top is counted to be stacked;The lower surface of the compound inslation dielectric layer (4) and N+ semiconductor substrates (2) phase The upper surface of contact, compound inslation dielectric layer (4) and N-type semiconductor nano-wire array is in contact with schottky metal (5).
2. a kind of Schottky diode according to claim 1, which is characterized in that the N-type semiconductor nano wire (3) A diameter of 10nm~1000nm.
3. a kind of Schottky diode according to claim 1, which is characterized in that the N-type semiconductor nano wire (3) Shape includes cylinder, cube or hexagonal prisms.
4. a kind of Schottky diode according to claim 1, which is characterized in that N-type semiconductor nano wire (3) row Row squarely, bar shaped, isosceles triangle or hexagonal array.
5. a kind of Schottky diode according to claim 1, which is characterized in that the material of the semiconductor nanowires (3) Material includes silicon, germanium silicon, silicon carbide, GaAs or gallium nitride.
CN201810899042.1A 2018-08-08 2018-08-08 A kind of schottky diode device Pending CN108807555A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659353A (en) * 2018-12-05 2019-04-19 中国电子科技集团公司第十三研究所 The Schottky diode of low dead resistance
CN112201685A (en) * 2020-09-08 2021-01-08 浙江大学 Super junction device and dielectric combined terminal
CN113410110A (en) * 2021-05-07 2021-09-17 南通职业大学 Semiconductor vacuum diode
WO2023098343A1 (en) * 2021-12-02 2023-06-08 南京邮电大学 Full-surrounding multi-channel drift region transverse power device and manufacturing method therefor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1181559C (en) * 2001-11-21 2004-12-22 同济大学 Voltage-withstanding layer consisting of high dielectric coefficient medium and semiconductor
CN103137658A (en) * 2011-11-30 2013-06-05 成都成电知力微电子设计有限公司 Pressure-proof layer formed by insulator with conductive particles of semiconductor device and semiconductor
CN106129107A (en) * 2016-07-01 2016-11-16 电子科技大学 Semiconductor structure, semiconductor subassembly and power semiconductor
CN107393952A (en) * 2017-07-12 2017-11-24 电子科技大学 A kind of junction barrier schottky diode with complex media Rotating fields

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1181559C (en) * 2001-11-21 2004-12-22 同济大学 Voltage-withstanding layer consisting of high dielectric coefficient medium and semiconductor
CN103137658A (en) * 2011-11-30 2013-06-05 成都成电知力微电子设计有限公司 Pressure-proof layer formed by insulator with conductive particles of semiconductor device and semiconductor
CN106129107A (en) * 2016-07-01 2016-11-16 电子科技大学 Semiconductor structure, semiconductor subassembly and power semiconductor
CN107393952A (en) * 2017-07-12 2017-11-24 电子科技大学 A kind of junction barrier schottky diode with complex media Rotating fields

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659353A (en) * 2018-12-05 2019-04-19 中国电子科技集团公司第十三研究所 The Schottky diode of low dead resistance
CN109659353B (en) * 2018-12-05 2021-12-24 中国电子科技集团公司第十三研究所 Low parasitic resistance schottky diode
CN112201685A (en) * 2020-09-08 2021-01-08 浙江大学 Super junction device and dielectric combined terminal
CN112201685B (en) * 2020-09-08 2022-02-11 浙江大学 Super junction device and dielectric combined terminal
CN113410110A (en) * 2021-05-07 2021-09-17 南通职业大学 Semiconductor vacuum diode
CN113410110B (en) * 2021-05-07 2023-08-08 南通职业大学 Semiconductor vacuum diode
WO2023098343A1 (en) * 2021-12-02 2023-06-08 南京邮电大学 Full-surrounding multi-channel drift region transverse power device and manufacturing method therefor

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