CN108795252A - A kind of preparation formula of antibacterial transfer powdery paints - Google Patents
A kind of preparation formula of antibacterial transfer powdery paints Download PDFInfo
- Publication number
- CN108795252A CN108795252A CN201810627049.8A CN201810627049A CN108795252A CN 108795252 A CN108795252 A CN 108795252A CN 201810627049 A CN201810627049 A CN 201810627049A CN 108795252 A CN108795252 A CN 108795252A
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- CN
- China
- Prior art keywords
- powdery paints
- preparation formula
- antibacterial
- agent
- antiseptic
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Abstract
The present invention relates to the preparation formula that a kind of antibacterial transfers powdery paints, raw material includes：Polyester resin, antiseptic, B1530 curing agent, isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and color stuffing.The technical solution has high-efficiency antimicrobial effect.
Description
Technical field
The present invention relates to the preparation formulas that a kind of antibacterial transfers powdery paints.
Background technology
As country increasingly payes attention to environmental protection, in coatings industry, powdery paints and powder coating and their application have low energy consumption,
Nuisanceless, labor productivity is high and the advantages that convenient for carrying out automated production, is widely used in household electrical appliance, construction material, family
Front yard articles for use, transportation equipment etc., the ratio that the decorative painting of household electrical appliance and other indoor articles uses in China are maximum.
High speed development with industry and the improvement of people's living standards, in the crowd is dense area, public place, house address, medical field
Etc. requirement to living environment increasingly promoted, and anti-biotic material is one of important component in environment-friendly materials, extensive to use
In live and work place.Since the 1980s, start in hospital, house, public field in beautiful, Deng developed countries
Institute, daily necessities etc. largely use anti-biotic material, improve demand of the people to life and enhancement of environment.
In coating industry, pushes environment persistently to improve, constantly advocate " paint changes water ", " paint is disguised " project action, Guangdong
Carry out full aluminium furniture energetically in aluminum material factory --- Green Home system is widely used in communal facility place decoration, and Home furniture is done
The state has, medical space etc., and full aluminium furniture " with aluminium generation wood ", fungus resistance in use also can be closed increasingly by people
Note develops a transfer powdery paints with high-efficiency antimicrobial effect, is the indispensable demand of full aluminium furniture industry development.
Invention content
Present invention aims at a kind of preparations that a kind of antibacterial with high-efficiency antimicrobial effect transfers powdery paints of offer to match
Side.
The technical scheme is that：
A kind of preparation formula of antibacterial transfer powdery paints, raw material include：Polyester resin, antiseptic, B1530 solidifications
Agent, isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and color stuffing.
Preferably, the preparation formula of above-mentioned a kind of antibacterial transfer powdery paints, wherein the polyester resin, isocyanuric acid
Three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and the color stuffing mass fraction be 99%.
Preferably, the preparation formula of above-mentioned a kind of antibacterial transfer powdery paints, wherein the antiseptic is inorganic antibacterial
Agent.
Preferably, the preparation formula of above-mentioned a kind of antibacterial transfer powdery paints, wherein the inorganic antiseptic be silver from
Sub- antiseptic.
Preferably, the preparation formula of above-mentioned a kind of antibacterial transfer powdery paints, wherein material rate are the polyester tree
Fat 55-70%, the isocyanuric acid three-glycidyl ester TGIC and B1530 curing agent conjunction account for 3-5.5%, the levelling
Agent, styrax and the wetting agent and antiseptic conjunction account for 1-5%, the color stuffing 10-35%.
Preferably, the preparation formula of above-mentioned a kind of antibacterial transfer powdery paints, wherein：
Compared with the prior art, beneficial effects of the present invention are as follows：The technical solution antibacterial transfers formulation for coating material mainly by polyester
Resin, antiseptic, B1530 curing agent, isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and face are filled out
Material composition, product are charged by friction by high-pressure electrostatic, and the modes such as fluid bed are uniformly covered on film-forming on base material, in tide
Under conditions of wet, which slowly releases metal ion.Since bacterium surface carries negative electrical charge, positive charge is carried
Metal ion be attracted to bacterium surface, and then destroy its electrolyte balance, cause bacterium impaired and dead due to cell wall
It dies.In addition, metal ion enters inside bacterium, cell enzyme reaction and chemical combination with bacterium, it is suppressed that the activity of cellular enzymes and thin
The breeding of bacterium regenerates, and has the function that kill bacterium.Metal ion haptoreaction causes microorganism to share composition and destroys or produce
Raw dysfunction.
Description of the drawings
Fig. 1：Anti-bacteria test result figure.
Specific implementation mode
Technical scheme of the present invention will be clearly and completely described below, it is clear that described embodiment is this hair
Bright a part of the embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art exist
The every other embodiment obtained under the premise of creative work is not made, shall fall within the protection scope of the present invention.
A kind of preparation formula of antibacterial transfer powdery paints, raw material include：Polyester resin, antiseptic, B1530 solidifications
Agent, isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and color stuffing.
The wherein described polyester resin, isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and described
The mass fraction of color stuffing is 99%, specifically, polyester resin (Synthomer, DSM, Allnex mass fraction 99%)；
Isocyanuric acid three-glycidyl ester TGIC (Changzhou Niutang Chemical Industry Co., Ltd., mass fraction 99%)；Styrax (U.S. source,
99%)；Wetting agent (Ningbo South-sea Chemical Co., Ltd., mass fraction 99%)；Levelling agent (TROY, mass fraction 99%), face
Expect (Evonik, mass fraction 99%；LOMON, mass fraction 99%), antiseptic (IshiZuka Glass).
The wherein described antiseptic is inorganic antiseptic, specifically, antiseptic is generally divided into inorganic and organic two major classes.
With silver, zinc, copper etc., for main material, using inorganic filler as carrier, inorganic antiseptic is made, high temperature resistance is good in the former.The latter with
Esters, alcohols, phenols be primary raw material, heat-resisting quantity is relatively low, generally at 200 DEG C hereinafter, individually be 250 DEG C, sterilizing time
It is short, occasionally there is precipitation phenomenon, has certain influence to health.The technical solution uses inorganic antiseptic, the Antibacterial accessory ingredient that can do
Mixed, bonding or extrusion prepare transfer printing type powdery paints.
Inorganic antiseptic：Using the antibacterial ability of the metals such as silver, copper, zinc, by the methods of physical absorption ion exchange,
Antiseptic is made in the surface that the metals such as silver, copper, zinc (or its ion) are fixed on to the porous materials such as fluorite, silica gel, then by it
It is added in powdery paints and obtains the powdery paints with antibacterial ability.The metals such as mercury, cadmium, lead also have antibacterial ability,
But it is harmful；Copper, nickel bore plasma with color, will influence the beauty of product, zinc has certain antibiotic property, but it is anti-
Bacterium intensity is only the 1/1000 of silver ion.Therefore, inorganic antiseptic described in the technical solution is silver ion antimicrobial agent.
Silver ion class antiseptic is common antiseptic, white fine powdered, and heat resisting temperature is up to 270 DEG C or more, powder
During last coating is by 200 DEG C of melting and solidifications, silver ion active is not destroyed easily.
The silver ion antimicrobial agent of the inorganic type of import can be selected in actual production process as test material, this material is logical
FDA certifications are crossed, EPA certifications, there is no the hidden danger to health safety.
More specifically, wherein material rate is the polyester resin 55-70%, the isocyanuric acid three-glycidyl ester
TGIC and B1530 curing agent conjunction account for 3-5.5%, the levelling agent, styrax and the wetting agent and the antibacterial
Agent conjunction accounts for 1-5%, the color stuffing 10-35%.
More preferred embodiment is as follows, wherein：
The technology mode transferred by vacuum, utilizes the principle of ink heat sublimation：Powder prepared by the preferred embodiment
For coating by high pressure electrostatic painting mode, manufactured powder paint is to workpiece surface, then carries out 200 DEG C of X 15min of baking
(material temperature) takes out cooling after coating is fully cured；Select appropriate pattern (such as：Teak, cherry, gold is as wood etc.)
Transfer paper or transfer film, be posted on transfer paper or transfer film are smooth on the workpiece sprayed, put on high temperature gummed tape, take out
Good vacuum waits for that workpiece cools down, removes and used after being put into baking transfer in heating furnace (165 DEG C -185 DEG C, toast 10 minutes)
Transfer paper and high temperature membrane, the transfer of clear patterns is on coating；Its transfer performance is as follows：
In addition, the anti-bacteria test result that the preferred embodiment prepares antibacterial transfer product is as shown in Figure 1.
Test result is to meet JIS Z 2801 with efficient antibiotic property:2010 >=2.0 standard.
The technical solution antibacterial transfers formulation for coating material mainly by polyester resin, antiseptic, B1530 curing agent, isocyanuric acid
Three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and color stuffing composition, product are charged by friction by high-pressure electrostatic,
The modes such as fluid bed are uniformly covered on film-forming on base material, and under humid conditions, which slowly releases metal
Ion.Since bacterium surface carries negative electrical charge, the metal ion with positive charge is attracted to bacterium surface, and then broken
Its bad electrolyte balance causes bacterium impaired and dead due to cell wall.In addition, metal ion enters inside bacterium, with bacterium
Cell enzyme reaction and chemical combination, it is suppressed that cellular enzymes activity and bacterium breeding regenerate, have the function that kill bacterium.Gold
Belong to contacted with ions reaction, causes microorganism to share composition and destroy or generate dysfunction.
In general, antibacterial transfer powdery paints film has the good mechanical performance of conventional products, does not influence to transfer
The clarity of effect does not influence paper-tear picture effect during transfer printing process, and antibiotic rate also gets a desired effect.With
The raising of people's living standard demand, the demand to healthy household are paid more attention to, and are pushed away with " aluminium generation wood " market in full aluminium furniture
Extensively, innovation and new opplication, antibacterial transfers powdery paints in the use of full aluminium furniture, keeps product more environmentally friendly, healthier, can be more next
More favored by consumer.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that：Its according to
It so can be with technical scheme described in the above embodiments is modified, either to which part or all technical features
Carry out equivalent replacement；And these modifications or replacements, various embodiments of the present invention skill that it does not separate the essence of the corresponding technical solution
The range of art scheme.
Claims (6)
1. a kind of preparation formula of antibacterial transfer powdery paints, raw material include：Polyester resin, antiseptic, B1530 curing agent,
Isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and color stuffing.
2. a kind of preparation formula of antibacterial transfer powdery paints according to claim 1, it is characterised in that：The polyester tree
Fat, isocyanuric acid three-glycidyl ester TGIC, levelling agent, styrax, wetting agent and the color stuffing mass fraction be
99%.
3. a kind of preparation formula of antibacterial transfer powdery paints according to claim 1, it is characterised in that：The antiseptic
For inorganic antiseptic.
4. a kind of preparation formula of antibacterial transfer powdery paints according to claim 3, it is characterised in that：It is described inorganic anti-
Microbial inoculum is silver ion antimicrobial agent.
5. a kind of preparation formula of antibacterial transfer powdery paints according to claim 1, it is characterised in that：Material rate is
The polyester resin 55-70%, the isocyanuric acid three-glycidyl ester TGIC and B1530 curing agent conjunction account for 3-5.5%,
The levelling agent, styrax and the wetting agent and antiseptic conjunction account for 1-5%, the color stuffing 10-35%.
6. a kind of preparation formula of antibacterial transfer powdery paints according to claim 1 or 5, it is characterised in that：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810627049.8A CN108795252A (en) | 2018-06-19 | 2018-06-19 | A kind of preparation formula of antibacterial transfer powdery paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810627049.8A CN108795252A (en) | 2018-06-19 | 2018-06-19 | A kind of preparation formula of antibacterial transfer powdery paints |
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| Publication Number | Publication Date |
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| CN108795252A true CN108795252A (en) | 2018-11-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810627049.8A Pending CN108795252A (en) | 2018-06-19 | 2018-06-19 | A kind of preparation formula of antibacterial transfer powdery paints |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988490A (en) * | 2019-04-18 | 2019-07-09 | 佛山市南海嘉多彩粉末涂料有限公司 | A kind of antibacterial sublimation transfer wood grain powder paint compositions |
| CN111440514A (en) * | 2020-04-26 | 2020-07-24 | 常州市碳索新材料科技有限公司 | Powder coating for building aluminum pinch plate and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747830A (en) * | 2008-12-08 | 2010-06-23 | 李新春 | Outdoor and indoor transfer powder |
| CN103265874A (en) * | 2013-05-23 | 2013-08-28 | 浙江超浪新材料有限公司 | High-toughness powder coating specially used for security door |
| CN104231872A (en) * | 2013-06-24 | 2014-12-24 | 江苏长松科技发展有限公司 | Anti-adhesion powder coating for wooden transfer |
| CN104497808A (en) * | 2014-12-31 | 2015-04-08 | 山东朗法博粉末涂装科技有限公司 | Powder coating for MDF transfer printing and application method of powder coating |
-
2018
- 2018-06-19 CN CN201810627049.8A patent/CN108795252A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747830A (en) * | 2008-12-08 | 2010-06-23 | 李新春 | Outdoor and indoor transfer powder |
| CN103265874A (en) * | 2013-05-23 | 2013-08-28 | 浙江超浪新材料有限公司 | High-toughness powder coating specially used for security door |
| CN104231872A (en) * | 2013-06-24 | 2014-12-24 | 江苏长松科技发展有限公司 | Anti-adhesion powder coating for wooden transfer |
| CN104497808A (en) * | 2014-12-31 | 2015-04-08 | 山东朗法博粉末涂装科技有限公司 | Powder coating for MDF transfer printing and application method of powder coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988490A (en) * | 2019-04-18 | 2019-07-09 | 佛山市南海嘉多彩粉末涂料有限公司 | A kind of antibacterial sublimation transfer wood grain powder paint compositions |
| CN111440514A (en) * | 2020-04-26 | 2020-07-24 | 常州市碳索新材料科技有限公司 | Powder coating for building aluminum pinch plate and preparation method thereof |
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Application publication date: 20181113 |