CN108794724A - A kind of tough pet toy and manufacturing method - Google Patents

A kind of tough pet toy and manufacturing method Download PDF

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Publication number
CN108794724A
CN108794724A CN201710303510.XA CN201710303510A CN108794724A CN 108794724 A CN108794724 A CN 108794724A CN 201710303510 A CN201710303510 A CN 201710303510A CN 108794724 A CN108794724 A CN 108794724A
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China
Prior art keywords
parts
mixture
pet toy
polyether
catalyst
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Withdrawn
Application number
CN201710303510.XA
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Chinese (zh)
Inventor
涂先斌
谢学军
涂万斌
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Zhangzhou City En Yang Arts & Crafts Co Ltd
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Zhangzhou City En Yang Arts & Crafts Co Ltd
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Priority to CN201710303510.XA priority Critical patent/CN108794724A/en
Publication of CN108794724A publication Critical patent/CN108794724A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6552—Compounds of group C08G18/63
    • C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6564—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

The present invention relates to toy material processing technique field, especially a kind of manufacturing method of pet toy materials, by being made according to the following raw material of mass percent meter when processing：High activity end hydroxy polyether（FA703）50 parts, high activity graft polyether（KGF545）50 parts, polyether modified siloxane（DC2525）0.25 part, 33% triethylenediamine solution（A-33）0.7 part, catalyst（A-300）0.8 part, 1.4- butanediols（1.4BD）8-12 parts, catalyst（A-1）0.15 part, water（H20）0.2 part, a fluorine dichloroethanes（141b）15-25 parts and more phenylmethane polyisocyanates（SUP-2433）；The material is not have good toughness, anti-tear stinging property, the short problem of service life existing for the material that solves used in current pet toy.

Description

A kind of tough pet toy and manufacturing method
Technical field
The present invention relates to toy material processing technique field, especially a kind of manufacturing method of pet toy materials.
Background technology
It is rubber, silica gel, lint etc. that the material of pet toy on the market is more at present, these materials do not have good Toughness, anti-tear stinging property is very limited, and service life is short.
Invention content
The present invention using one kind is special to solve the above problems, manufacture pet toy from skinning material, good toughness can be held Power is pullled by 60 kilograms of biting forces and 20 kilograms, service life is long.
The material of a kind of tough pet toy of the present invention, by being made according to the raw material of following proportioning：
By high activity end hydroxy polyether（FA703）50 parts, high activity graft polyether（KGF545）50 parts, polyether modified siloxane （DC2525）0.25 part, 33% triethylenediamine solution（A-33）0.7 part, catalyst（A-300）0.8 part, 1.4- butanediols （1.4BD）8-12 parts, catalyst（A-1）0.15 part, water（H20）0.2 part, a fluorine dichloroethanes（141b）15-25 parts composition Mixture A and more phenylmethane polyisocyanates（SUP-2433）, wherein mixture A and more phenylmethane polyisocyanates （SUP-2433）Ratio be 100:52-55.
A kind of manufacturing method of tough pet toy materials, includes the following steps：
Step 1：Every ingredient in mixture A is mixed 90 minutes according to the proportioning；
Step 2：By the mixture A stirred and more phenylmethane polyisocyanates（SUP-2433）With 100:The ratio of 52-55 It is uniformly mixed in polyurethane foaming machine；
Step 3：By mixture A and more phenylmethane polyisocyanates（SUP-2433）Mixture cast in a mold, pass through 45 degree of high temperature foaming in 6 minutes, can be obtained the product after die sinking.
Specific implementation mode
Below by specific implementation mode, the present invention is described in further detail, but the present invention is not only limited in these Example.
Step 1：By high activity end hydroxy polyether（FA703）50 parts, high activity graft polyether（KGF545）50 parts, polyethers Modified siloxane（DC2525）0.25 part, 33% triethylenediamine solution（A-33）0.7 part, catalyst（A-300）0.8 part, 1.4- butanediol（1.4BD）8-12 parts, catalyst（A-1）0.15 part, water（H20）0.2 part, a fluorine dichloroethanes（141b）15- 25 parts successively put into agitator tank in be mixed 90 minutes, obtain mixture A；
Step 2：By the mixture A stirred and more phenylmethane polyisocyanates（SUP-2433）With 100:The ratio of 52-55 It is uniformly mixed in polyurethane foaming machine；
Step 3：By mixture A and more phenylmethane polyisocyanates（SUP-2433）Mixture cast in a mold, pass through 45 degree of high temperature foaming in 6 minutes, can be obtained the product after die sinking.
According to the pet toy good toughness that step as above manufactures, the biting force that can bear 60 kilograms and 20 kilograms pull power, Service life is long.
The present invention is not limited to above-mentioned specific embodiment, those skilled in the art from above-mentioned design, Without performing creative labour, made various transformation are within the scope of the present invention.

Claims (4)

1. a kind of tough pet toy, which is characterized in that including by high activity end hydroxy polyether（FA703）50 parts, high activity connects Branch polyethers（KGF545）50 parts, polyether modified siloxane（DC2525）0.25 part, 33% triethylenediamine solution（A-33）0.7 Part, catalyst（A-300）0.8 part, 1.4- butanediols（1.4BD）8-12 parts, catalyst（A-1）0.15 part, water（H20）0.2 part, One fluorine dichloroethanes（141b）The 15-25 parts of mixture A formed and more phenylmethane polyisocyanates（SUP-2433）Group At.
2. tough pet toy according to claim 1, it is characterised in that mixture A and more phenylmethane polyisocyanates （SUP-2433）Ratio be 100:52-55.
3. the tough pet toy according to claim 1 and 2, it is characterised in that can bear 60 kilograms biting force and 20 kilograms Pull power.
4. a kind of manufacturing method of tough pet toy, which is characterized in that include the following steps：
Step 1：By high activity end hydroxy polyether（FA703）50 parts, high activity graft polyether（KGF545）It is 50 parts, polyether-modified Siloxanes（DC2525）0.25 part, 33% triethylenediamine solution（A-33）0.7 part, catalyst（A-300）0.8 part, 1.4- fourths Glycol（1.4BD）8-12 parts, catalyst（A-1）0.15 part, water（H20）0.2 part, a fluorine dichloroethanes（141b）15-25 parts according to It is mixed 90 minutes in secondary input agitator tank, obtains mixture A；
Step 2：By the mixture A stirred and more phenylmethane polyisocyanates（SUP-2433）With 100:The ratio of 52-55 It is uniformly mixed in polyurethane foaming machine；
Step 3：By mixture A and more phenylmethane polyisocyanates（SUP-2433）Mixture cast in a mold, pass through 45 degree of high temperature foaming in 6 minutes, can be obtained the product after die sinking.
CN201710303510.XA 2017-05-03 2017-05-03 A kind of tough pet toy and manufacturing method Withdrawn CN108794724A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104151519A (en) * 2014-08-13 2014-11-19 山东一诺威聚氨酯股份有限公司 Cellular polyurethane elastomer composite material for nude model and preparation method thereof
CN104558508A (en) * 2015-01-06 2015-04-29 福建大方海绵科技股份有限公司 All-water foamed molding slow-rebound bloating foamed cotton of MDI (polymethylene polyphenyl isocyanate) with density of 45kg/m<3> and preparation method
CN105315451A (en) * 2015-11-25 2016-02-10 山东一诺威新材料有限公司 Slow-recovery polyether polyol and preparation method thereof and slow-recovery foam and preparation method thereof
US20170037203A1 (en) * 2014-04-10 2017-02-09 Covestro Deutschland Ag Polyurethane composite material and process of preparing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170037203A1 (en) * 2014-04-10 2017-02-09 Covestro Deutschland Ag Polyurethane composite material and process of preparing same
CN104151519A (en) * 2014-08-13 2014-11-19 山东一诺威聚氨酯股份有限公司 Cellular polyurethane elastomer composite material for nude model and preparation method thereof
CN104558508A (en) * 2015-01-06 2015-04-29 福建大方海绵科技股份有限公司 All-water foamed molding slow-rebound bloating foamed cotton of MDI (polymethylene polyphenyl isocyanate) with density of 45kg/m<3> and preparation method
CN105315451A (en) * 2015-11-25 2016-02-10 山东一诺威新材料有限公司 Slow-recovery polyether polyol and preparation method thereof and slow-recovery foam and preparation method thereof

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Application publication date: 20181113