CN108794223A - High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling(Soil conditioner)And preparation method thereof - Google Patents

High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling(Soil conditioner)And preparation method thereof Download PDF

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Publication number
CN108794223A
CN108794223A CN201811069660.XA CN201811069660A CN108794223A CN 108794223 A CN108794223 A CN 108794223A CN 201811069660 A CN201811069660 A CN 201811069660A CN 108794223 A CN108794223 A CN 108794223A
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CN
China
Prior art keywords
recycling
wollastonite
high dissolubility
dust
siliceous fertilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811069660.XA
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Chinese (zh)
Inventor
张梦显
姜山
张昕
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Dalian Global Mineral Ltd By Share Ltd
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Dalian Global Mineral Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201811069660.XA priority Critical patent/CN108794223A/en
Publication of CN108794223A publication Critical patent/CN108794223A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00Fertilisers containing potassium
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The present invention relates to a kind of high dissolubility siliceous fertilizers (soil conditioner) and preparation method thereof prepared by the ultrafine dust using processing wollastonite recycling, belong to agricultural technology field.High dissolubility siliceous fertilizer of the present invention includes the dust for processing wollastonite recycling.The present invention belongs to mineral fertilizer using high dissolubility siliceous fertilizer (soil conditioner) prepared by the ultrafine dust of processing wollastonite recycling, the ultrafine dust of discarded processing wollastonite recycling is set to be fully used, it is environmentally protective, simultaneously, high dissolubility siliceous fertilizer (soil conditioner) can improve soil, promote plant growth, rice, fruit and vegetable etc. are widely used in, the yield of crops is significantly increased, improves the quality of crops, and absorption of the plant to heavy metal can be prevented.

Description

High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling (soil conditioner) and preparation method thereof
Technical field
The present invention relates to a kind of high dissolubility siliceous fertilizer (soil conditionings prepared by the ultrafine dust using processing wollastonite recycling Agent) and preparation method thereof, belong to agricultural technology field.
Background technology
Wollastonite belongs to a kind of chain metasilicate, chemical composition SiO2CaO, wherein SiO2Theoretical content 51.75%, It is a kind of in threadiness, acicular crystal, since its special crystal habit crystalline texture determines its extensive use.Wollastonite into A large amount of wollastonite ultrafine dust is generated in grinding machine cleaner in row milling process, due to these wollastonite ultrafine dusts Granularity is superfine, and specific surface area is also larger, so surface-active is higher, it can containing what is be activated in a large amount of process in dust Dissolubility silica, general wollastonite in powder soluble silica content is less than 5%, and these wollastonite ultrafine dusts are soluble Dioxide-containing silica is then more than 20%.
Invention content
The present invention prepares high dissolubility siliceous fertilizer (soil conditioner), Ke Yi great using the ultrafine dust of processing wollastonite recycling The big content for improving soluble silica in high dissolubility siliceous fertilizer (soil conditioner), to improve with using effect.
The present invention provides a kind of high dissolubility siliceous fertilizer (soil tune prepared by the ultrafine dust using processing wollastonite recycling Manage agent), the high dissolubility siliceous fertilizer includes the dust for processing wollastonite recycling.
The present invention is preferably that the granularity of dust D50 of the processing wollastonite recycling is 0-15 μm.
The present invention is preferably that the high dissolubility siliceous fertilizer includes the dust for processing wollastonite recycling, siliceous binder.
The present invention is preferably that the high dissolubility siliceous fertilizer is made of following components by weight percentage:
Process the dust 95-100% of wollastonite recycling
Siliceous binder 0-5%.
The present invention is preferably that the siliceous binder is at least one of potassium silicate, sodium metasilicate and bentonite.
Another object of the present invention is provide a kind of preparation method of above-mentioned high dissolubility siliceous fertilizer (soil conditioner), the system Preparation Method is:By predetermined weight percent, the dust mixing of wollastonite recycling will be processed, obtain high dissolubility siliceous fertilizer;Or by pre- Determine weight percent, will first process dust and the siliceous binder mixing of wollastonite recycling, and obtain mixture siccative, add water into The secondary mixing of row, amount of water account for the 10-50% of mixture siccative weight, are granulated, dry, obtain high dissolubility siliceous fertilizer.
The present invention is preferably that the condition of the secondary mixing is:10-120rpm stirs 3-30min.
The condition that the present invention is preferably granulated in the spray drying tower is:Atomisation pressure 1.0-1.8MPa.
The present invention is preferably that the condition being granulated in pan-pelletizer is:A diameter of 1800-2500mm of pan-pelletizer, pan-pelletizer Rotating speed is 15-25r/min.
The present invention has the beneficial effect that:
The present invention is belonged to using high dissolubility siliceous fertilizer (soil conditioner) prepared by the ultrafine dust of processing wollastonite recycling Mineral fertilizer makes the ultrafine dust of discarded processing wollastonite recycling be fully used, environmentally protective, meanwhile, high dissolubility silicon Fertile (soil conditioner) can improve soil, promote plant growth, be widely used in rice, fruit and vegetable etc., the production of crops is significantly increased Amount, the quality for improving crops, and absorption of the plant to heavy metal can be prevented.
Specific implementation mode
Following non-limiting embodiments can make those skilled in the art be more fully understood the present invention, but not with Any mode limits the present invention.
The granularity of dust D50 of following processing wollastonite recycling is 0-15 μm.
Embodiment 1
A method of preparing high dissolubility siliceous fertilizer (soil conditioner), institute using the ultrafine dust of processing wollastonite recycling Stating preparation method is:
By weight percentage, it by the dust mixing of 100% processing wollastonite recycling, weighs, packs, obtain high dissolubility silicon Fertilizer.
Embodiment 2
A method of preparing high dissolubility siliceous fertilizer (soil conditioner), institute using the ultrafine dust of processing wollastonite recycling Stating preparation method is:
By weight percentage, it is dry first to be obtained into mixture for the dust and 5% waterglass mixing of 95% processing wollastonite recycling Material adds water 100rpm stirring 30min, and amount of water accounts for the 15% of mixture siccative weight, in the pan-pelletizer of diameter 1800mm It is granulated, balling-up disk rotating speed 19r/min, heated-air drying, it is cooling, obtain particle wollastonite high dissolubility siliceous fertilizer (soil conditioner).
Embodiment 3
A method of preparing high dissolubility siliceous fertilizer (soil conditioner), institute using the ultrafine dust of processing wollastonite recycling Stating preparation method is:
By weight percentage, it is dry first to be obtained into mixture for the dust and 4% bentonite mixing of 96% processing wollastonite recycling Material, adds water 100rpm stirring 30min, and amount of water accounts for the 30% of mixture siccative weight, is granulated in the spray drying tower, sprays Pressure 1.8MPa, heated-air drying is cooling, obtains particle wollastonite high dissolubility siliceous fertilizer (soil conditioner).
Embodiment 4
A method of preparing high dissolubility siliceous fertilizer (soil conditioner), institute using the ultrafine dust of processing wollastonite recycling Stating preparation method is:
By weight percentage, it is dry first to be obtained into mixture for the dust and 5% potassium silicate mixing of 95% processing wollastonite recycling Material, adds water 100rpm stirring 30min, and amount of water accounts for the 50% of mixture siccative weight, is granulated in the spray drying tower, sprays Pressure 1.8MPa, heated-air drying is cooling, obtains particle wollastonite high dissolubility siliceous fertilizer (soil conditioner).
The particle wollastonite high dissolubility siliceous fertilizer (soil conditioner) prepared using embodiment 1-4 can make crops epidermis Cell siliceousization, cauline leaf is straight and upright, reduces shading, improves the photosynthesis of blade, meanwhile, after crops absorption element silicon in vivo Silicified cell is formed, cauline leaf cells of superficial layer wall is made to thicken, cuticula increases, to improve insect prevention disease resistance, due to crops Absorption silicon ensuing crop stalk is straight, and lodging tolerance can improve 80%.In addition, particle wollastonite height prepared by embodiment 1-4 can Dissolubility siliceous fertilizer (soil conditioner) can be with the phosphorus in activating soil, and promotes operating of the phosphorus in crop body, and that improves phosphorus has Utilization rate is limited, meanwhile, soil can be effectively improved, the acidity of soil is corrected, improves soil alkali, organic fertilizer is promoted to decompose, is inhibited Soil germ and mitigation heavy metal pollution.

Claims (9)

1. high dissolubility siliceous fertilizer (soil conditioner) prepared by a kind of ultrafine dust using processing wollastonite recycling, feature exists In:The high dissolubility siliceous fertilizer includes the dust for processing wollastonite recycling.
2. high dissolubility siliceous fertilizer (the soil tune prepared according to claim 1 using the ultrafine dust of processing wollastonite recycling Manage agent), it is characterised in that:The granularity of dust D50 of the processing wollastonite recycling is 0-15 μm.
3. high dissolubility siliceous fertilizer (the soil tune prepared according to claim 2 using the ultrafine dust of processing wollastonite recycling Manage agent), it is characterised in that:The high dissolubility siliceous fertilizer includes the dust for processing wollastonite recycling, siliceous binder.
4. high dissolubility siliceous fertilizer (the soil tune prepared according to claim 3 using the ultrafine dust of processing wollastonite recycling Manage agent), it is characterised in that:The high dissolubility siliceous fertilizer is made of following components by weight percentage:
Process the dust 95-100% of wollastonite recycling
Siliceous binder 0-5%.
5. high dissolubility siliceous fertilizer (the soil tune prepared according to claim 4 using the ultrafine dust of processing wollastonite recycling Manage agent), it is characterised in that:The siliceous binder is at least one of potassium silicate, sodium metasilicate and bentonite.
6. the preparation method of the high dissolubility siliceous fertilizer (soil conditioner) of claim 1,2,3 or 4, it is characterised in that:It is described Preparation method is:
By predetermined weight percent, the dust mixing of wollastonite recycling will be processed, obtain high dissolubility siliceous fertilizer;
Or predetermined weight percent is pressed, first by the dust for processing wollastonite recycling and siliceous binder mixing, it is dry to obtain mixture Material adds water and carries out secondary mixing, and amount of water accounts for the 10-50% of mixture siccative weight, is granulated, dry, obtains high dissolubility Siliceous fertilizer.
7. preparation method according to claim 6, it is characterised in that:The condition of the secondary mixing is:10-120rpm is stirred Mix 3-30min.
8. preparation method according to claim 7, it is characterised in that:The condition being granulated in the spray drying tower is:Spraying Pressure 1.0-1.8MPa.
9. preparation method according to claim 8, it is characterised in that:The condition being granulated in pan-pelletizer is:Pan-pelletizer The rotating speed of a diameter of 1800-2500mm, pan-pelletizer are 15-25r/min.
CN201811069660.XA 2018-09-13 2018-09-13 High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling(Soil conditioner)And preparation method thereof Pending CN108794223A (en)

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CN201811069660.XA CN108794223A (en) 2018-09-13 2018-09-13 High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling(Soil conditioner)And preparation method thereof

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CN201811069660.XA CN108794223A (en) 2018-09-13 2018-09-13 High dissolubility siliceous fertilizer prepared by a kind of ultrafine dust using processing wollastonite recycling(Soil conditioner)And preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357683A (en) * 2019-07-25 2019-10-22 辽宁恒润农业有限公司 A kind of dedicated siliceous charcoal base organic fertilizer of saline-alkali soil rice and its preparation process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104788170A (en) * 2015-01-30 2015-07-22 姜明光 Weak alkaline slow-release compound fertilizer and silicon-based weak alkaline slow-release compound microbial fertilizer and preparation method thereof
CN107382535A (en) * 2017-09-04 2017-11-24 深圳瑞科天启科技有限公司 A kind of composite fertilizer and its production technology rich in mineral matter
CN107382609A (en) * 2017-03-31 2017-11-24 大连环球矿产股份有限公司 It is a kind of to utilize siliceous fertilizer (soil conditioner) of wollastonite mine tailing production and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104788170A (en) * 2015-01-30 2015-07-22 姜明光 Weak alkaline slow-release compound fertilizer and silicon-based weak alkaline slow-release compound microbial fertilizer and preparation method thereof
CN107382609A (en) * 2017-03-31 2017-11-24 大连环球矿产股份有限公司 It is a kind of to utilize siliceous fertilizer (soil conditioner) of wollastonite mine tailing production and preparation method thereof
CN107382535A (en) * 2017-09-04 2017-11-24 深圳瑞科天启科技有限公司 A kind of composite fertilizer and its production technology rich in mineral matter

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
金为民: "《土壤肥料》", 31 July 2001, 中国农业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357683A (en) * 2019-07-25 2019-10-22 辽宁恒润农业有限公司 A kind of dedicated siliceous charcoal base organic fertilizer of saline-alkali soil rice and its preparation process

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Application publication date: 20181113