CN108753030A - A kind of preparation method of mould proof sensitive ink - Google Patents
A kind of preparation method of mould proof sensitive ink Download PDFInfo
- Publication number
- CN108753030A CN108753030A CN201810403206.7A CN201810403206A CN108753030A CN 108753030 A CN108753030 A CN 108753030A CN 201810403206 A CN201810403206 A CN 201810403206A CN 108753030 A CN108753030 A CN 108753030A
- Authority
- CN
- China
- Prior art keywords
- preparation
- mould proof
- sensitive ink
- prepared
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of preparation methods of mould proof sensitive ink, absolute ethyl alcohol is dissolved under the auxiliary of dispersant using silver chlorate, nanoscale chlorination Ag films are made using lacquering technique, and and chitosan, cinnaldehydrum carries out compound in supercritical reaction kettle, the method for causing photopolymerization through nanoparticle surface again is prepared into the fibre-grade antibacterial microballoon of nanometer covered composite yarn microballoon, with reactive diluent, photoinitiator and filler are prepared into ink semi-finished product jointly using curing process, finished product is prepared after finally using surface high pressure sided corona treatment, compared with prior art, with excellent bacteriostasis, effectively reduce its probability that goes mouldy.
Description
Technical field
The present invention relates to the preparation method of printing ink more particularly to a kind of preparation methods of mould proof sensitive ink.
Background technology
Ink is by chromoplast, link stuff, the homogeneous mixture for filling out and (filling) material compositions such as material, additional material；It can be printed
Brush, and it is dry in printed body；It is to have color, the pulpous state adherent with certain fluidity；Ink is to be used for packaging material
The important materials of printing, it by printing by pattern, word show stock curing ink include main component and assist at
Point, they equably mix and form a kind of sticky colloidal fluid through repeat-rolling.
In billboard is applicable in, especially when used outdoors, in drenching with rain, in the environment such as water splashes, humidity, ink holds
Easily mildew long spot, influences the expression of figure in billboard, is unfavorable for the propagation of advertisement.
For this purpose, it is proposed that a kind of preparation method for printing mould proof sensitive ink.
Invention content
Goal of the invention：In order to solve the problems of prior art, the present invention provides a kind of systems of mould proof sensitive ink
Preparation Method；The ink being prepared has excellent antibacterial and mouldproof ability.
Technical solution：In order to achieve the above objectives, the present invention uses following technical scheme：
A kind of preparation method of mould proof sensitive ink, includes the following steps：
(1) preparation of anti-mildew antibacterial microballoon：Silver chlorate is dissolved in absolute ethyl alcohol, the collodion that 10 times of its quality is added stirs
It mixes, and 0.5g/L dispersants is added, be film-made with lacquering technique, nanometer is made in rapid thermal treatment 8minz at 700 DEG C after the completion of film
Grade chlorination Ag films；By in chitosan, cinnaldehydrum merging supercritical reaction kettle device, it is passed through air, it is 8 to adjust pH, and temperature is
450 DEG C, pressure is 8 atmospheric pressure, reacts and opens after 15min after pressure is reduced to normal pressure by pressure relief opening, total by chitosan, cinnaldehydrum
The nanoscale chlorination Ag films of step (1) preparation are added in 2-3 times of amount, are warming up to 600 DEG C, continue with 1-2h, finally obtain
Nano silver/silver chloride composite material；The method that nano silver/silver chloride composite material is caused to photopolymerization using nanoparticle surface is prepared into
The anti-mildew antibacterial microballoon of nanometer covered composite yarn microballoon；
(2) by above-mentioned anti-mildew antibacterial microballoon, it is added to the preparation of ink with the ratio of coloring matter quality 10%-20%
In raw material, and ink semi-finished product are prepared into using curing process jointly with reactive diluent, photoinitiator and filler；It is wherein living
Property diluent, photoinitiator and filler are respectively 1%, 3% and the 70% of coloring matter quality；
(3) ink semi-finished product are used and is heated to molten condition postcooling after carrying out surface high pressure sided corona treatment to 80 DEG C of guarantors
Mould proof sensitive ink needed for being obtained after warm 1.5h.
More preferably, the mass ratio of the silver chlorate and absolute ethyl alcohol is 3:4.
More preferably, the friendship dispersant is hydrolysate obtained from lignocellulosic materials are hydrolyzed
Dispersant.
More preferably, the chitosan, cinnaldehydrum mass ratio be 4:1.
More preferably, reactive diluent described in step (2) is epoxy active diluent.
More preferably, photoinitiator described in step (2) is photoinitiator 907.
More preferably, filler described in step (2) is titanium dioxide.
More preferably, pressure is 18 atmospheric pressure in surface high pressure sided corona treatment described in step (3).
Advantageous effect：A kind of preparation method of mould proof sensitive ink provided by the present invention, is dissolved in anhydrous second using silver chlorate
Nanoscale chlorination Ag films are made under the auxiliary of dispersant, using lacquering technique in alcohol, and with chitosan, cinnaldehydrum in overcritical anti-
Answer carried out in kettle it is compound, then through nanoparticle surface cause photopolymerization method be prepared into a nanometer fibre-grade for covered composite yarn microballoon
Antibacterial microballoon is prepared into ink semi-finished product using curing process with reactive diluent, photoinitiator and filler, finally uses jointly
Finished product is prepared after surface high pressure sided corona treatment, compared with prior art, there is excellent bacteriostasis, effectively reduce it and go mouldy generally
Rate.
Specific implementation mode
With reference to specific embodiment, invention is further explained：
Embodiment 1：
A kind of preparation method of mould proof sensitive ink, includes the following steps：
(1) preparation of anti-mildew antibacterial microballoon：Silver chlorate is dissolved in absolute ethyl alcohol, the collodion that 10 times of its quality is added stirs
It mixes, and 0.5g/L dispersants is added, be film-made with lacquering technique, nanometer is made in rapid thermal treatment 8min at 700 DEG C after the completion of film
Grade chlorination Ag films；By in chitosan, cinnaldehydrum merging supercritical reaction kettle device, it is passed through air, it is 8 to adjust pH, and temperature is
450 DEG C, pressure is 8 atmospheric pressure, reacts and opens after 15min after pressure is reduced to normal pressure by pressure relief opening, total by chitosan, cinnaldehydrum
2 times of addition nanoscale chlorination Ag films of amount, are warming up to 600 DEG C, continue with 1h, finally obtain nano silver/silver chloride composite wood
Material；The method that nano silver/silver chloride composite material is caused to photopolymerization using nanoparticle surface is prepared into a nanometer covered composite yarn microballoon
Anti-mildew antibacterial microballoon；The mass ratio of the silver chlorate and absolute ethyl alcohol is 3:4；The friendship dispersant is to lignocellulosic
The dispersant of hydrolysate obtained from substance is hydrolyzed；The chitosan, cinnaldehydrum mass ratio be 4:1；
(2) by above-mentioned anti-mildew antibacterial microballoon, raw material is prepared with what the ratio of coloring matter quality 10% was added to ink
In, and ink semi-finished product are prepared into using curing process jointly with reactive diluent, photoinitiator and filler；It is wherein active dilute
Release agent, photoinitiator and filler are respectively coloring matter quality 1%, 3% and 70%；The reactive diluent is epoxy-reactive
Diluent；The photoinitiator is photoinitiator 907；The filler is titanium dioxide；
(3) ink semi-finished product are used and is heated to molten condition postcooling after carrying out surface high pressure sided corona treatment to 80 DEG C of guarantors
Mould proof sensitive ink needed for being obtained after warm 1.5h；Pressure is 18 atmospheric pressure in the surface high pressure sided corona treatment.
Embodiment 2：
A kind of preparation method of mould proof sensitive ink, includes the following steps：
(1) preparation of anti-mildew antibacterial microballoon：Silver chlorate is dissolved in absolute ethyl alcohol, the collodion that 10 times of its quality is added stirs
It mixes, and 0.5g/L dispersants is added, be film-made with lacquering technique, nanometer is made in rapid thermal treatment 8minz at 700 DEG C after the completion of film
Grade chlorination Ag films；By in chitosan, cinnaldehydrum merging supercritical reaction kettle device, it is passed through air, it is 8 to adjust pH, and temperature is
450 DEG C, pressure is 8 atmospheric pressure, reacts and opens after 15min after pressure is reduced to normal pressure by pressure relief opening, total by chitosan, cinnaldehydrum
Nanoscale chlorination Ag films prepared by step (1) are added in 3 times of amount, are warming up to 600 DEG C, continue with 2h, finally obtain nanometer
Chlorination silver composite material；The method that nano silver/silver chloride composite material is caused to photopolymerization using nanoparticle surface is prepared into nanometer
The anti-mildew antibacterial microballoon of covered composite yarn microballoon；The mass ratio of the silver chlorate and absolute ethyl alcohol is 3:4；The friendship dispersant is
The dispersant of hydrolysate obtained from lignocellulosic materials are hydrolyzed；The mass ratio of the chitosan, cinnaldehydrum
It is 4:1；
(2) by above-mentioned anti-mildew antibacterial microballoon, raw material is prepared with what the ratio of coloring matter quality 20% was added to ink
In, and ink semi-finished product are prepared into using curing process jointly with reactive diluent, photoinitiator and filler；It is wherein active dilute
Release agent, photoinitiator and filler are respectively coloring matter quality 1%, 3% and 70%；The reactive diluent is epoxy-reactive
Diluent；The photoinitiator is photoinitiator 907；The filler is titanium dioxide；
(3) ink semi-finished product are used and is heated to molten condition postcooling after carrying out surface high pressure sided corona treatment to 80 DEG C of guarantors
Mould proof sensitive ink needed for being obtained after warm 1.5h；Pressure is 18 atmospheric pressure in the surface high pressure sided corona treatment.
Ink prepared by embodiment 1-2 carries out tinting strength, tinting power and attachment fastness, bacterium total testing, and carries out wet environment
Simulation place 38 DEG C, 100% humidity, for 24 hours after, tested, compared again, the results are shown in Table 1：
The 1 mould proof aptitude tests of embodiment 1-2 of table
As it can be seen from table 1 having excellent tinting strength, tinting power and attachment fastness in ink prepared by the present invention, it is mould to carry out time-out
After becoming simulated environment processing, two kinds of performances are not declined significantly, and hay bacillus sum incrementss are not obvious, explanation
It has anti-mildew performance.
It should be pointed out that the above specific implementation mode is only illustrative of the invention and is not intended to limit the scope of the invention,
After having read the present invention, those skilled in the art fall within appended by the application the modification of the various equivalent forms of the present invention and weigh
Profit requires limited range.
Claims (8)
1. a kind of preparation method of mould proof sensitive ink, it is characterised in that include the following steps：
(1) preparation of anti-mildew antibacterial microballoon：Silver chlorate is dissolved in absolute ethyl alcohol, the collodion stirring of 10 times of its quality is added,
And 0.5g/L dispersants are added, it is film-made with lacquering technique, nanoscale chlorine is made in rapid thermal treatment 8min at 700 DEG C after the completion of film
Change Ag films；By in chitosan, cinnaldehydrum merging supercritical reaction kettle device, it is passed through air, it is 8 to adjust pH, temperature 450
DEG C, pressure is 8 atmospheric pressure, reacts and opens after 15min after pressure is reduced to normal pressure by pressure relief opening, by chitosan, cinnaldehydrum total amount
The 2-3 times of nanoscale chlorination Ag films that preparation is added, be warming up to 600 DEG C, continue with 1-2h, finally obtain nano silver/silver chloride
Composite material；The method that nano silver/silver chloride composite material is caused to photopolymerization using nanoparticle surface is prepared into nanometer cladding again
Close the anti-mildew antibacterial microballoon of microballoon；
(2) by above-mentioned anti-mildew antibacterial microballoon, raw material is prepared with what the ratio of coloring matter quality 10%-20% was added to ink
In, and ink semi-finished product are prepared into using curing process jointly with reactive diluent, photoinitiator and filler；It is wherein active dilute
Release agent, photoinitiator and filler are respectively coloring matter quality 1%, 3% and 70%；
(3) ink semi-finished product are used and is heated to molten condition postcooling after carrying out surface high pressure sided corona treatment to 80 DEG C of heat preservations
Mould proof sensitive ink needed for being obtained after 1.5h.
2. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：The silver chlorate and absolute ethyl alcohol
Mass ratio be 3:4.
3. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：The friendship dispersant is to wooden
The dispersant of hydrolysate obtained from cellulosic material is hydrolyzed.
4. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：The chitosan, cinnaldehydrum
Mass ratio is 4:1.
5. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：Activity described in step (2) is dilute
It is epoxy active diluent to release agent.
6. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：It is light-initiated described in step (2)
Agent is photoinitiator 907.
7. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：Filler is described in step (2)
Titanium dioxide.
8. the preparation method of mould proof sensitive ink according to claim 1, it is characterised in that：Surface described in step (3) is high
It is 18 atmospheric pressure to press pressure in sided corona treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810403206.7A CN108753030A (en) | 2018-04-28 | 2018-04-28 | A kind of preparation method of mould proof sensitive ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810403206.7A CN108753030A (en) | 2018-04-28 | 2018-04-28 | A kind of preparation method of mould proof sensitive ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108753030A true CN108753030A (en) | 2018-11-06 |
Family
ID=64008780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810403206.7A Withdrawn CN108753030A (en) | 2018-04-28 | 2018-04-28 | A kind of preparation method of mould proof sensitive ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108753030A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11560487B2 (en) | 2020-09-22 | 2023-01-24 | Swimc Llc | Coating compositions containing low molecular weight chitosan composition |
-
2018
- 2018-04-28 CN CN201810403206.7A patent/CN108753030A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11560487B2 (en) | 2020-09-22 | 2023-01-24 | Swimc Llc | Coating compositions containing low molecular weight chitosan composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69206993T2 (en) | COMPOSITIONS FOR USING FILMS ON SEED | |
| US9074102B2 (en) | Cold transfer printing paste, printing colorant thereof, and preparation method thereof | |
| CN1388189A (en) | Dip-coating composition containing cellulose ether | |
| CN108753030A (en) | A kind of preparation method of mould proof sensitive ink | |
| CN106113968A (en) | A kind of UV quick-drying hectograph fountain solution compounding containing κ carrageenan Konjac glucomannan and preparation method thereof | |
| CN105922783A (en) | High-moisture-retention fountain solution compounded by k-carrageenan and konjac glucomannan and preparation method thereof | |
| WO2002053663A1 (en) | Proteins/starch paper coating compositions and method of use thereof | |
| CN106726629A (en) | A kind of method for preparing the compound edible face pack paper of polysaccharide collagen | |
| CN109897232A (en) | A kind of method of modified degradable thin-film material | |
| CN107889882A (en) | A kind of betel nut table glue compounding fruit glaze agent and its application | |
| CN110511415A (en) | Using epoxy soybean oil acrylate as waterproof starch film of coating and preparation method thereof | |
| CN108867196A (en) | A kind of environment-friendly type waterproof paper and preparation method thereof | |
| CN109571681A (en) | A kind of furfuryl alcohol timber optimization liquid and preparation method | |
| CN110272557B (en) | Laser hollowed-out pressure-sensitive unsealing stay wire and production method thereof | |
| CN108822793A (en) | A kind of preparation method of the soybean protein base without aldehyde adhesive | |
| CN108752644A (en) | A kind of the cation modifying nano-cellulose/composite membrane of polyvinyl alcohol and preparation method of high intensity | |
| CN110437764B (en) | Resin modified starch adhesive and preparation method thereof | |
| CN106995623A (en) | A kind of environment-friendlyink ink drier and preparation method thereof | |
| CN1665900A (en) | Procede de traitement d'ennoblissement d'une nappe fibreuse au moyen d'une composition adhesive a base de polymere(s), contenant une combinaison particuliere de saccharides | |
| CN108675857A (en) | Three praise application of the glue in slow-release or control-release fertilizer, the membrane material of slow-release or control-release fertilizer and the coating slow-release or control-release fertilizer and preparation method thereof of praising glue based on three | |
| CN108285650A (en) | A kind of barley grain base composite package film and preparation method thereof | |
| CN107142785A (en) | A kind of cation surface sizing agent and preparation method thereof | |
| CN113802417A (en) | Emulsion type mildew preventive, preparation process thereof, preparation process of mildew-proof impregnated bond paper and mildew-proof veneer | |
| CN104610582B (en) | A kind of full starch plant glue and its preparation method and application | |
| CN107030848A (en) | A kind of preparation method of environment protecting fiber board fungus resistant coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181106 |