CN108752677A - A kind of tread band composition and a kind of cold-resistant cover tire of bicycle - Google Patents

A kind of tread band composition and a kind of cold-resistant cover tire of bicycle Download PDF

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Publication number
CN108752677A
CN108752677A CN201810424379.7A CN201810424379A CN108752677A CN 108752677 A CN108752677 A CN 108752677A CN 201810424379 A CN201810424379 A CN 201810424379A CN 108752677 A CN108752677 A CN 108752677A
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CN
China
Prior art keywords
parts
tread band
band composition
mark glue
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810424379.7A
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Chinese (zh)
Inventor
李锦镇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Feixuan Rubber Co Ltd
Original Assignee
Guangzhou Feixuan Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Feixuan Rubber Co Ltd filed Critical Guangzhou Feixuan Rubber Co Ltd
Priority to CN201810424379.7A priority Critical patent/CN108752677A/en
Publication of CN108752677A publication Critical patent/CN108752677A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L17/00Compositions of reclaimed rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to the cold-resistant cover tires of bicycle of a kind of tread band composition and application the tread band composition.A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:45~65 parts, butadiene-styrene rubber SBR1500:15~25 parts, cis-butadiene cement BR:30~50 parts, reclaimed rubber:70~90 parts, plasticizer A:0.53~0.75 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine:1.5~2.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:1~2 part;Protection wax:1~2 part, softening agent dibutyl phthalate:5~10 parts, carbon black N220:60~70 parts, sulphur:1.5~2.5 parts, captax:0.8~1.2 part, accelerator CBS:0.6~0.9 part, zinc oxide:4~5 parts, stearic acid:2~3 parts.The present invention has the characteristics that low temperature resistant, anti-slippery, and grip performance is effectively improved.

Description

A kind of tread band composition and a kind of cold-resistant cover tire of bicycle
Technical field
The present invention relates to bicycle art more particularly to a kind of tread band composition and apply the tread band composition Bicycle resist cold cover tire.
Background technology
With society and expanding economy, the vehicles that bicycle acts not only as environmental protection are used for riding instead of walk, going on a journey, Itself is also a sports campaign, there is road race, Mountain bike, Track cycling, stunt bicycle Match etc., people are higher and higher to the performance requirement of bicycle tyre, and especially under extremely cold environment, common tire is Through the demand that cannot be satisfied bicycle running, braking.Existing bicycle tyre is all conventional tyre, therefore there is an urgent need to one kind Cold-resistant cover tire is adapted to outdoor arctic weather.
Invention content
In view of the deficiencies of the prior art, the present invention intends to provide a kind of cold-resistant tread band composition and Using the cycle casing of the tread band composition.
To achieve the above object, the present invention can be achieved by the following technical programs:
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:45~65 parts, butadiene-styrene rubber SBR1500: 15~25 parts, cis-butadiene cement BR:30~50 parts, reclaimed rubber:70~90 parts, plasticizer A:0.53~0.75 part, the first anti-aging agent N- Phenyl-N '-isopropyl p-phenylenediamine:1.5~2.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:1~2 part;Protection wax:1~2 Part, softening agent dibutyl phthalate:5~10 parts, carbon black N220:60~70 parts, sulphur:1.5~2.5 parts, captax: 0.8~1.2 part, accelerator CBS:0.6~0.9 part, zinc oxide:4~5 parts, stearic acid:2~3 parts.
Further, it is composed of the following raw materials by weight:Mark glue:55 parts, butadiene-styrene rubber SBR:15 parts, cis-butadiene cement BR:40 parts, Reclaimed rubber:80 parts, plasticizer A:0.53 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine:2.5 parts, second is anti-old Agent 9,9-dimethylacridan:1.5 parts, protection wax:1.5 parts, softening agent dibutyl phthalate:10 parts, carbon black N220:70 Part, sulphur:2.2 parts, captax:1.2 parts, accelerator CBS:0.6 part, zinc oxide:5 parts, stearic acid:3 parts.
Further, the mark glue is No. 10 mark glue.
Further, the mark glue is No. 20 mark glue.
Further, the protection wax is protection wax RPW.
A kind of cold-resistant cover tire of bicycle, including casing play and the tread band for being covered in skeleton layer surface, the tread rubber Layer is above-mentioned tread band composition.
Further, the mark glue is No. 10 mark glue.
Further, the mark glue is No. 20 mark glue.
Further, the protection wax is protection wax RPW.
The tread band composition selection preferable BR and noncrystalline rubber SBR of cryogenic property of the present invention is used in combination, and improves rubber The wet-sliding resistant performance of glue is conducive to tire and walks in snow face.Plasticizer is added, rubber glass temperature can be made to decline, improves The cold tolerance of vulcanizate.Because plasticizer can increase rubber molecule flexibility, intermolecular force is reduced, molecule segment is made to be easy to Movement.It is protruded using resist cold cover tire performance of the bicycle of the tread band composition, has the characteristics that low temperature resistant, anti-slippery, grabbed Ground performance is effectively improved, and meets the requirement that bicycle is walked on snowfield in winter.
Specific implementation mode
Below in conjunction with specific implementation mode, the present invention is further illustrated:
Embodiment 1
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:50 parts, butadiene-styrene rubber SBR1500:20 parts, Cis-butadiene cement BR:30 parts, reclaimed rubber:70 parts, plasticizer A:0.53 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine:2 Part, the second anti-aging agent 9,9- dimethyl acridiniums:1 part, protection wax:1.5 parts, softening agent dibutyl phthalate:8 parts, carbon black N220:65 parts, sulphur:2.0 parts, captax:1 part, accelerator CBS:0.6 part, zinc oxide:4 parts, stearic acid:2.5 part.
A kind of cold-resistant cover tire of bicycle, including casing play and the tread band for being covered in skeleton layer surface, the tread rubber Layer is the tread band composition of above-mentioned raw material composition.
Embodiment 2
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:60 parts, butadiene-styrene rubber SBR1500:15 parts, Cis-butadiene cement BR:35 parts, reclaimed rubber:80 parts, plasticizer A:0.53 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine:2 Part, the second anti-aging agent 9,9- dimethyl acridiniums:1.8 parts, protection wax:1.5 parts, softening agent dibutyl phthalate:10 parts, charcoal Black N220:70 parts, sulphur:2.2 parts, captax:1.2 parts, accelerator CBS:0.6 part, zinc oxide:5 parts, stearic acid:3 parts.
A kind of cold-resistant cover tire of bicycle, including casing play and the tread band for being covered in skeleton layer surface, the tread rubber Layer is the tread band composition of above-mentioned raw material composition.
Embodiment 3
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:45 parts, butadiene-styrene rubber SBR1500:20 parts, Cis-butadiene cement BR:45 parts, reclaimed rubber:80 parts, plasticizer A:0.53 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine: 2.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:2 parts, protection wax:1.5 parts, softening agent dibutyl phthalate:10 parts, Carbon black N220:60 parts, sulphur:2.2 parts, captax:1.2 parts, accelerator CBS:0.6 part, zinc oxide:5 parts, stearic acid:3 parts.
Embodiment 4
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:55 parts, butadiene-styrene rubber SBR1500:15 parts, Cis-butadiene cement BR:40 parts, reclaimed rubber:80 parts, plasticizer A:0.6 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine: 2.2 parts, the second anti-aging agent 9,9- dimethyl acridiniums:1.8 parts, protection wax:1 part, softening agent dibutyl phthalate:10 parts, Carbon black N220:70 parts, sulphur:1.5 parts, captax:1.2 parts, accelerator CBS:0.8 part, zinc oxide:5 parts, stearic acid:3 parts.
A kind of cold-resistant cover tire of bicycle, including casing play and the tread band for being covered in skeleton layer surface, the tread rubber Layer is the tread band composition of above-mentioned raw material composition.
Embodiment 5
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:55 parts, butadiene-styrene rubber SBR1500:15 parts, Cis-butadiene cement BR:40 parts, reclaimed rubber:80 parts, plasticizer A:0.53 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine: 2.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:1.5 parts, protection wax:1.5 parts, softening agent dibutyl phthalate:10 Part, carbon black N220:70 parts, sulphur:2.2 parts, captax:1.2 parts, accelerator CBS:0.6 part, zinc oxide:5 parts, stearic acid:3 Part.
A kind of cold-resistant cover tire of bicycle, including casing play and the tread band for being covered in skeleton layer surface, the tread rubber Layer is the tread band composition of above-mentioned raw material composition.
Embodiment 6
A kind of tread band composition, is composed of the following raw materials by weight:Mark glue:65 parts, butadiene-styrene rubber SBR1500:25 parts, Cis-butadiene cement BR:50 parts, reclaimed rubber:90 parts, plasticizer A:0.75 part, the first anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine: 1.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:2 parts, protection wax:2 parts, softening agent dibutyl phthalate:5 parts, carbon black N220:65 parts, sulphur:2.5 parts, captax:0.8 part, accelerator CBS:0.9 part, zinc oxide:4.5 parts, stearic acid:2 parts.
A kind of cold-resistant cover tire of bicycle, including casing play and the tread band for being covered in skeleton layer surface, the tread rubber Layer is the tread band composition of above-mentioned raw material composition.
Preferably, it is No. 10 mark glue or No. 20 mark glue, No. 10 glue and No. 20 glue one that glue is marked described in above-mentioned all embodiments As for making Outer Tyre;The protection wax is protection wax RPW.Optimal case is embodiment 5.
The quantitative measurement experimental data of tread band composition described in embodiment 5 is as follows:
As can be seen from the above table, the present invention not only possesses superior physical property, and shows superior cold tolerance.
The glass transition temperature of non-crystalline type rubber is relatively low, and cold resistance is preferable.So reducing crystal type mark glue, low temperature properties are selected The preferable BR and noncrystalline rubber SBR of energy is used in combination, and improves the wet-sliding resistant performance of rubber, is conducive to tire and walks in snow face.
Plasticizer is added, rubber glass temperature can be made to decline, improve the cold tolerance of vulcanizate.Because plasticizer can increase Add rubber molecule flexible, reduces intermolecular force, molecule segment is made to be easy to move.
For those skilled in the art, it is various corresponding that other can be made according to above technical scheme and design Change and deformation, and all these change and distortions should all belong within the protection domain of the claims in the present invention.

Claims (9)

1. a kind of tread band composition, which is characterized in that be composed of the following raw materials by weight:Mark glue:45~65 parts, butadiene-styrene rubber SBR1500:15~25 parts, cis-butadiene cement BR:30~50 parts, reclaimed rubber:70~90 parts, plasticizer A:0.53~0.75 part, first Anti-aging agent N- phenyl-N '-isopropyl p-phenylenediamine:1.5~2.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:1~2 part;It is anti- Protect wax:1~2 part, softening agent dibutyl phthalate:5~10 parts, carbon black N220:60~70 parts, sulphur:1.5~2.5 parts, Captax:0.8~1.2 part, accelerator CBS:0.6~0.9 part, zinc oxide:4~5 parts, stearic acid:2~3 parts.
2. tread band composition according to claim 1, which is characterized in that be composed of the following raw materials by weight:Mark glue: 55 parts, butadiene-styrene rubber SBR:15 parts, cis-butadiene cement BR:40 parts, reclaimed rubber:80 parts, plasticizer A:0.53 part, the first anti-aging agent N- benzene Base-N '-isopropyl p-phenylenediamine:2.5 parts, the second anti-aging agent 9,9- dimethyl acridiniums:1.5 parts, protection wax:1.5 parts, softening agent Dibutyl phthalate:10 parts, carbon black N220:70 parts, sulphur:2.2 parts, captax:1.2 parts, accelerator CBS:0.6 part, Zinc oxide:5 parts, stearic acid:3 parts.
3. tread band composition according to claim 1 or 2, it is characterised in that:The mark glue is No. 10 mark glue.
4. tread band composition according to claim 1 or 2, it is characterised in that:The mark glue is No. 20 mark glue.
5. tread band composition according to claim 1 or 2, it is characterised in that:The protection wax is protection wax RPW.
The cover tire 6. a kind of bicycle resists cold, it is characterised in that:Including casing play and the tread band for being covered in skeleton layer surface, institute It is tread band composition as claimed in claim 1 or 2 to state tread band.
7. tread band composition according to claim 6, it is characterised in that:The mark glue is No. 10 mark glue.
8. tread band composition according to claim 6, it is characterised in that:The mark glue is No. 20 mark glue.
9. tread band composition according to claim 6, it is characterised in that:The protection wax is protection wax RPW.
CN201810424379.7A 2018-05-07 2018-05-07 A kind of tread band composition and a kind of cold-resistant cover tire of bicycle Pending CN108752677A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810424379.7A CN108752677A (en) 2018-05-07 2018-05-07 A kind of tread band composition and a kind of cold-resistant cover tire of bicycle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810424379.7A CN108752677A (en) 2018-05-07 2018-05-07 A kind of tread band composition and a kind of cold-resistant cover tire of bicycle

Publications (1)

Publication Number Publication Date
CN108752677A true CN108752677A (en) 2018-11-06

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Application Number Title Priority Date Filing Date
CN201810424379.7A Pending CN108752677A (en) 2018-05-07 2018-05-07 A kind of tread band composition and a kind of cold-resistant cover tire of bicycle

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070221303A1 (en) * 2006-03-27 2007-09-27 Sandstrom Paul H Tire with rubber tread composed of a primary and at least one lateral tread portion containing a dispersion of short carbon fibers
CN101333307A (en) * 2008-06-27 2008-12-31 南京固柏橡塑制品有限公司 Cold resistant rubber
CN106046459A (en) * 2016-06-30 2016-10-26 肇庆骏鸿实业有限公司 Wet-skid-resistant snowfield tire tread rubber and preparation method thereof
CN106084361A (en) * 2016-08-19 2016-11-09 临海市五丰橡胶制品有限公司 Cold resistant rubber and production technology thereof and the production technology of rubber belt track

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070221303A1 (en) * 2006-03-27 2007-09-27 Sandstrom Paul H Tire with rubber tread composed of a primary and at least one lateral tread portion containing a dispersion of short carbon fibers
CN101333307A (en) * 2008-06-27 2008-12-31 南京固柏橡塑制品有限公司 Cold resistant rubber
CN106046459A (en) * 2016-06-30 2016-10-26 肇庆骏鸿实业有限公司 Wet-skid-resistant snowfield tire tread rubber and preparation method thereof
CN106084361A (en) * 2016-08-19 2016-11-09 临海市五丰橡胶制品有限公司 Cold resistant rubber and production technology thereof and the production technology of rubber belt track

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Application publication date: 20181106

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