CN108708021A - A kind of efficient radiation-proof fabric - Google Patents

A kind of efficient radiation-proof fabric Download PDF

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Publication number
CN108708021A
CN108708021A CN201810756289.8A CN201810756289A CN108708021A CN 108708021 A CN108708021 A CN 108708021A CN 201810756289 A CN201810756289 A CN 201810756289A CN 108708021 A CN108708021 A CN 108708021A
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China
Prior art keywords
parts
efficient radiation
radiation
efficient
yarn
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CN201810756289.8A
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Chinese (zh)
Inventor
李德喜
陈宗明
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Suzhou City Tianao Special Embroidery Co Ltd
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Suzhou City Tianao Special Embroidery Co Ltd
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Priority to CN201810756289.8A priority Critical patent/CN108708021A/en
Publication of CN108708021A publication Critical patent/CN108708021A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12—Threads containing metallic filaments or strips
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/49—Oxides or hydroxides of elements of Groups 8, 9, 10 or 18 of the Periodic System; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Abstract

The present invention provides a kind of efficient radiation-proof fabric, the fabric uses yarn with efficient radiation proof function and stainless steel fibre is blended forms：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；The liquid with efficient radiation proof function is prepared by following component with parts by weight：Nano oxidized gadolinium 4-6 parts, samarium 2-5 parts nano oxidized, 2-3 parts of ZnO microsphere, 2-5 parts of thickener, 3-5 parts of polycrystalline iron fiber, 10-20 parts of aqueous polyurethane, 5-10 parts of pentaerythrite, glucose grafting 2-4 parts of soybean protein, 100-150 parts of distilled water.The efficient radiation-proof fabric of the present invention has efficient anti-electromagnetic radiation performance, and people can be made effectively to avoid the harm of radiation.

Description

A kind of efficient radiation-proof fabric
Technical field
The present invention relates to textile material fields, and in particular to a kind of efficient radiation-proof fabric.
Background technology
Being constantly progressive and develop with science and technology, shared ratio is also more and more in people's lives for electronic equipment Height, each class of electronic devices brings greatly help and facility to people's lives, but has also brought electromagnetic wave simultaneously Radiation, also known as electromagnetic radiation.The 40's of last century, the U.S. and the former Soviet Union just have electromedical equipment operating personnel to feel body The report of body discomfort, they generally feel the symptoms such as insomnia and dreamful sleep, headache and dizzy and the rising of white blood cell sum.Electromagnetic radiation pair The influence of human body is clinically mainly shown as that neurasthenia disease group, patient will appear uncomfortable in chest, palpitaition, headache, hidrosis, nothing The symptoms such as power, memory loss.Meanwhile electromagnetic radiation can also inhibit the generation of red blood cell, cause the quantity of white blood cell to decline, cancer The incidence of disease rises.Electromagnetic radiation is with cumulative effect to another harm of human body.Human body is in exposure to electromagnetic radiation Afterwards, to pass through prolonged self-regeneration, if when not yet repairing herein by electromagnetic radiation, injury will be accumulated, or even danger And arrive life.Therefore, efficient radiation-proof fabric is developed, ensures production, living safety, health is protected, is just weaved The extensive attention of industry, it may have vast potential for future development.
Invention content
Technical problems to be solved：The object of the present invention is to provide a kind of efficient radiation-proof fabrics, have efficient anti-electric Magnetic radiation performance can make people effectively avoid the harm of radiation.
Technical solution：A kind of efficient radiation-proof fabric, the fabric is using the yarn with efficient radiation proof function and not Becoming rusty, steel fibre is blended to be formed：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described to have The liquid of efficient radiation proof function is prepared by following component with parts by weight：Nano oxidized gadolinium 4-6 parts, nano oxidized samarium 2-5 Part, 2-3 parts of ZnO microsphere, 2-5 parts of thickener, 3-5 parts of polycrystalline iron fiber, 10-20 parts of aqueous polyurethane, pentaerythrite 5-10 Part, 2-4 parts of soybean protein of glucose grafting, 100-150 parts of distilled water.
Further, the ratio of the yarn and stainless steel fibre with efficient radiation proof function is 30:1.
Further, the yarn is cotton fiber, polyester fiber or silk fiber.
Further, the thickener is methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl One or more of cellulose, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, polyacrylic acid or Sodium Polyacrylate.
Further, the preparation method of the ZnO microsphere is：
The first step：5-7 parts of pollen, 1-2 parts of zinc acetates and 15-20 parts of methanol are mixed, is placed in vacuum tank and take out very Manage 3-4h in vacancy；
Second step：Take out, temperature be 70-75 DEG C at carry out ultrasonic wave decentralized processing 2-3h, after place 48-50h；
Third walks：In the case where rotating speed is 8000rpm, centrifugation is dry at being placed on 100 DEG C；
4th step：Take out, be placed in Muffle furnace, temperature be 650-680 DEG C at calcining 2h to obtain the final product, heating rate be 3 DEG C/ min。。
Further, the preparation method of the liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, thickener, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20- 30min；
Second step：Pentaerythrite is added to continue to stir 5-10min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1-2h to obtain the final product.
Further, the preparation method of the glucose grafting soybean protein is：
Step（1）：By soybean protein isolate and glucose with mass ratio for 1:1 amount is dissolved in distilled water, uses magnetic agitation Machine stirs
Mix 30-40 min；
Step（2）：It is placed in 6 h of pre-freeze at -60 DEG C, is put into freeze drier and is dried in vacuo to obtain freeze-dried powder；
Step（3）：The aluminium box for filling freeze-dried powder is placed in bottom to fill in the drier of saturation KBr solution, is put into drying box, 55 DEG C of temperature is reacted under relative humidity 79% to obtain the final product.
Advantageous effect：
1. pentaerythrite can increase hydroxy radical content, aqueous polyurethane is improved by the binding performance of radiation protection ingredient and yarn, is made Radiation-proof effect is obtained to increase.
2. the efficient radiation-proof fabric of the present invention has good anti-electromagnetic radiation performance, the electricity of regular handset and computer Magnetic radiation is respectively：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test As a result it is respectively：3.4μW/cm2With 7.3 μ W/cm2。
Specific implementation mode
Embodiment 1
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and At：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described that there is efficient radiation proof function Liquid be prepared with parts by weight by following component：4 parts of nano oxidized gadolinium, 2 parts of nano oxidized samarium, 2 parts of ZnO microsphere, first 2 parts of base cellulose, 10 parts of aqueous polyurethane, 5 parts of pentaerythrite, 2 parts of soybean protein of glucose grafting, steams 3 parts of polycrystalline iron fiber 100 parts of distilled water；The yarn is cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20min；
Second step：Pentaerythrite is added to continue to stir 5min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively For：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished For：1.5μW/cm2With 4.1 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Embodiment 2
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and At：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described that there is efficient radiation proof function Liquid be prepared with parts by weight by following component：5 parts of nano oxidized gadolinium, 4 parts of nano oxidized samarium, 2.5 parts of ZnO microsphere, 3.5 parts of carboxymethyl cellulose, 4 parts of polycrystalline iron fiber, 15 parts of aqueous polyurethane, 8 parts of pentaerythrite, glucose are grafted soybean protein 3 parts, 130 parts of distilled water；The yarn is polyester fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, carboxymethyl cellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 25min；
Second step：Pentaerythrite is added to continue to stir 8min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1.5h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively For：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished For：1.3μW/cm2With 3.9 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Embodiment 3
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and At：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described that there is efficient radiation proof function Liquid be prepared with parts by weight by following component：6 parts of nano oxidized gadolinium, 5 parts of nano oxidized samarium, 3 parts of ZnO microsphere, hydroxyl 5 parts of ethyl cellulose, 5 parts of polycrystalline iron fiber, 20 parts of aqueous polyurethane, 10 parts of pentaerythrite, glucose are grafted soybean protein 4 Part, 150 parts of distilled water；The yarn is silk fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, hydroxyethyl cellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 30min；
Second step：Pentaerythrite is added to continue to stir 10min；
Third walks：Remaining ingredient is added, continues magnetic agitation 2h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively For：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished For：1.4μW/cm2With 4.1 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Comparative example 1
Difference lies in replace nano oxidized samarium with nano oxidized gadolinium with embodiment 1 for the present embodiment.Specifically：
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and At：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described that there is efficient radiation proof function Liquid be prepared with parts by weight by following component：It is 6 parts of nano oxidized gadolinium, 2 parts of ZnO microsphere, 2 parts of methylcellulose, more 3 parts of brilliant iron fiber, 10 parts of aqueous polyurethane, 5 parts of pentaerythrite, 2 parts of soybean protein of glucose grafting, 100 parts of distilled water；It is described Yarn be cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20min；
Second step：Pentaerythrite is added to continue to stir 5min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively For：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished For：5.0μW/cm2With 15.5 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Comparative example 2
Difference lies in replace glucose to be grafted soybean protein with aqueous polyurethane with embodiment 1 for the present embodiment.Specifically：
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and At：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described that there is efficient radiation proof function Liquid be prepared with parts by weight by following component：4 parts of nano oxidized gadolinium, 2 parts of nano oxidized samarium, 2 parts of ZnO microsphere, first 2 parts of base cellulose, 3 parts of polycrystalline iron fiber, 2 parts of aqueous polyurethane, 5 parts of pentaerythrite, 100 parts of distilled water；The yarn is Cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20min；
Second step：Pentaerythrite is added to continue to stir 5min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively For：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished For：3.4μW/cm2With 7.3 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Comparative example 3
Difference lies in without containing pentaerythrite with embodiment 1 for the present embodiment.Specifically：
A kind of efficient radiation-proof fabric, the fabric use with efficient radiation proof function yarn and stainless steel fibre it is blended and At：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described that there is efficient radiation proof function Liquid be prepared with parts by weight by following component：4 parts of nano oxidized gadolinium, 2 parts of nano oxidized samarium, 2 parts of ZnO microsphere, first 2 parts of base cellulose, 10 parts of aqueous polyurethane, 5 parts of pentaerythrite, 2 parts of soybean protein of glucose grafting, steams 3 parts of polycrystalline iron fiber 100 parts of distilled water；The yarn is cotton fiber.
The preparation method of the above-mentioned liquid with efficient radiation proof function：
The first step：Aqueous polyurethane, methylcellulose, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20min；
Second step：Pentaerythrite is added to continue to stir 5min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1h to obtain the final product.
Anti-electromagnetic-radiation performance test is carried out to produced fabric using electromagnetic radiation tester, test fabric is in difference Electromagnet shield effect in electromagnetic regime carries out electromagnetic radiation test, test result difference to regular handset and computer respectively For：116μW/cm2With 2374 μ W/cm2, when carrying out shielding test to mobile phone and computer with produced fabric, test result is distinguished For：3.2μW/cm2With 5.1 μ W/cm2, it can be seen that this fabric has good anti-electromagnetic radiation performance.
Above-mentioned experimental result is measured using following standard：
HJ/T10.2- 1996《Radiation environment management guideline electromagnetic radiation monitoring instrument and method》.

Claims (7)

1. a kind of efficient radiation-proof fabric, it is characterised in that：The fabric is using the yarn with efficient radiation proof function and not Becoming rusty, steel fibre is blended to be formed：The yarn is to be soaked into before spinning in the liquid with efficient radiation proof function；It is described to have The liquid of efficient radiation proof function is prepared by following component with parts by weight：Nano oxidized gadolinium 4-6 parts, nano oxidized samarium 2-5 Part, 2-3 parts of ZnO microsphere, 2-5 parts of thickener, 3-5 parts of polycrystalline iron fiber, 10-20 parts of aqueous polyurethane, pentaerythrite 5-10 Part, 2-4 parts of soybean protein of glucose grafting, 100-150 parts of distilled water.
2. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that：It is described that there is efficient radiation proof function Yarn and stainless steel fibre ratio be 30:1.
3. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that：The yarn is cotton fiber, washs Synthetic fibre fiber or silk fiber.
4. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that：The thickener is Methyl cellulose Element, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, polyoxygenated One or more of ethylene, polyacrylic acid or Sodium Polyacrylate.
5. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that：The preparation of the ZnO microsphere Method is：
The first step：5-7 parts of pollen, 1-2 parts of zinc acetates and 15-20 parts of methanol are mixed, is placed in vacuum tank and take out very Manage 3-4h in vacancy；
Second step：Take out, temperature be 70-75 DEG C at carry out ultrasonic wave decentralized processing 2-3h, after place 48-50h；
Third walks：In the case where rotating speed is 8000rpm, centrifugation is dry at being placed on 100 DEG C；
4th step：It takes out, is placed in Muffle furnace, to obtain the final product, heating rate is 3 DEG C/min to calcining 2h at being 650-680 DEG C in temperature.
6. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that：It is described that there is efficient radiation protection work( The preparation method of the liquid of energy：
The first step：Aqueous polyurethane, thickener, glucose grafting soybean protein and distilled water are mixed, magnetic agitation 20- 30min；
Second step：Pentaerythrite is added to continue to stir 5-10min；
Third walks：Remaining ingredient is added, continues magnetic agitation 1-2h to obtain the final product.
7. a kind of efficient radiation-proof fabric according to claim 1, it is characterised in that：The glucose is grafted soybean egg White preparation method is：
Step（1）：By soybean protein isolate and glucose with mass ratio for 1:1 amount is dissolved in distilled water, uses magnetic agitation Machine stirs
Mix 30-40 min；
Step（2）：It is placed in 6 h of pre-freeze at -60 DEG C, is put into freeze drier and is dried in vacuo to obtain freeze-dried powder；
Step（3）：The aluminium box for filling freeze-dried powder is placed in bottom to fill in the drier of saturation KBr solution, is put into drying box, 55 DEG C of temperature is reacted under relative humidity 79% to obtain the final product.
CN201810756289.8A 2018-07-11 2018-07-11 A kind of efficient radiation-proof fabric Pending CN108708021A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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