CN108705054A - A kind of zinc and kirsite bar produce towed crystallizer - Google Patents

A kind of zinc and kirsite bar produce towed crystallizer Download PDF

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Publication number
CN108705054A
CN108705054A CN201810946649.0A CN201810946649A CN108705054A CN 108705054 A CN108705054 A CN 108705054A CN 201810946649 A CN201810946649 A CN 201810946649A CN 108705054 A CN108705054 A CN 108705054A
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CN
China
Prior art keywords
kirsite
zinc
crystallizer
towed
wall
Prior art date
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Pending
Application number
CN201810946649.0A
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Chinese (zh)
Inventor
戴登峰
沈铁军
傅珠荣
闫鸣
薛建平
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SHAOXING TIANLONG TIN MATERIALS CO Ltd
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SHAOXING TIANLONG TIN MATERIALS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by SHAOXING TIANLONG TIN MATERIALS CO Ltd filed Critical SHAOXING TIANLONG TIN MATERIALS CO Ltd
Priority to CN201810946649.0A priority Critical patent/CN108705054A/en
Publication of CN108705054A publication Critical patent/CN108705054A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/07Lubricating the moulds

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The present invention relates to a kind of zinc and kirsite bar to produce towed crystallizer, for producing zinc and kirsite bar, it includes ontology, the ontology includes inner and outer wall, water-cooling channel is equipped between the inner and outer wall, and crystallization cavity and cooling chamber are equipped in inner wall, kirsite liquid draws crystallizer by liquid phase solid phase in crystallization cavity and after cooling chamber further cools down, the crystallization cavity built-in type is equipped with the graphite guide tube for preventing its cavity wall of zinc and kirsite liquid corrosion, it is provided with to graphite guide tube immersion oil in the cavity wall of the crystallization cavity and positioned at the outside of graphite guide tube to reduce the immersion cell of the frictional force between solid phase kirsite.The present invention significantly extends the service life of crystallizer.

Description

A kind of zinc and kirsite bar produce towed crystallizer
Technical field
The present invention relates to zinc and kirsite to produce and process field, and especially a kind of zinc and kirsite bar produce towed knot Brilliant device.
Background technology
(wherein aluminium mass fraction is 0~22%, the mass fraction of other various improvement elements for zinc and zinc alloy material To be 0~0.5%, surplus is zinc) it is the novel lead-free electronic material researched and developed successfully and promoted the use of in recent years, it is mainly used for gold The unleaded metal spraying in categoryization thin film capacitor end face.With the fast development of new energy technology, the market of this kind of leadless electronic material It expands rapidly.China is mainly produced by two methods at present, is that three-dimensional pressure is answered due to squeezing one is being produced by extrusion The plastic processing method of power, thus it is high using the legal system line taking base consistency, and wire-drawing performance protrudes.But due to pressing method There is also many defects for being difficult to overcome, as carried bubble in line base, because the Crack of folder oil formation and two squeeze billet ends Core etc. is wrapped up in caused by face soldering is bad.Another method is horizontal continuous-casting legal system line taking base, although horizontal continuous casting billet can give birth to The blank of endless is produced, but since the line base quality in graphite crystallizer service life later stage is substantially reduced, and due to the shadow of gravity It rings, the alloy solidified in graphite crystallizer be easy to cause the unilateral uneven wear in graphite bottom, further reduces graphite knot The service life of brilliant device, horizontal continuous-casting method need blowing out to replace crystallizer, and the period for replacing graphite crystallizer is long, and at least 4 Hour or more, it needs to restart melting furnace after replacement, at least wants 24 hours.Therefore, horizontal continuous-casting legal system line taking base is deposited In high energy consumption, the problem of replacement graphite crystallizer inconvenience, manufacturing cost is improved.Upper initiation continuously casting, which produces line base, is A kind of routine techniques, commonly used in copper, aluminium and its alloy processing, but existing upper initiation continuously casting technology be not used to zinc and Kirsite produces line base, and mainly existing upper initiation continuously casting technology uses dry-type traction, i.e., graphite crystallizer is not outer adds Add lubricant, service life is short, and graphite crystallizer consumption is high.
Invention content
The technical problems to be solved by the invention are to overcome the deficiencies in the prior art and providing one kind can make The zinc and kirsite bar that graphite crystallizer is replaced with long lifespan, without blowing out produce towed crystallizer.
In order to solve the above technical problems, present invention employs following technical schemes:
A kind of zinc and kirsite bar produce towed crystallizer, for producing zinc and kirsite bar comprising ontology, this Ontology includes inner and outer wall, water-cooling channel is equipped between the inner and outer wall, and crystallization cavity and cooling chamber are equipped in inner wall, Zinc and kirsite liquid draw crystallizer, the knot by liquid phase solid phase in crystallization cavity and after cooling chamber further cools down Brilliant intracavitary installation by adhering has a graphite guide tube for preventing its cavity wall of zinc and kirsite liquid corrosion, in the cavity wall of the crystallization cavity and It is provided with to graphite guide tube immersion oil positioned at the outside of graphite guide tube to reduce the immersion oil of the frictional force between solid phase zinc and kirsite Slot.
The present invention can also be advanced optimized by following technical measures:
As a further improvement, zinc is arranged in crystallization cavity for the immersion cell and kirsite solid-liquid mixes at the above position, And at least one.The immersion cell is the annular groove being opened in the cavity wall of crystallization cavity, and is equipped with to annular in ontology The oiling channel of injection lubricating oil in groove.The outside of the ontology is provided with fuel reserve tank, and the fuel reserve tank is through oiling channel and leaching Oil groove is connected to.It is connected through a screw thread between the graphite guide tube and ontology, and there is therebetween immersion oil gap.
As a further improvement, the water-cooling channel includes intake tunnel and exhalant canal, the intake tunnel and water outlet are logical Internal partition is equipped between road, the two is connected in the bottom of internal partition, and the intake tunnel is located at the outside of exhalant canal.It is described into The communicating position of aquaporin and exhalant canal is less than the position of immersion cell.Cooling water in the intake tunnel flows from the top down Dynamic, the cooling water in the exhalant canal flows from bottom to top, and is set to the water inlet of intake tunnel less than being set to water outlet The position of the water outlet in channel.The ontology is copper ontology.
As a result of above technical scheme, the advantageous effects that the present invention has are as follows:
The invention is mounted with graphite guide tube in the crystallization cavity of crystallizer, so that it is completely cut off liquid phase using the chemical inertness of graphite Zinc and kirsite and body contacts avoid the corrosion of zinc and kirsite to ontology, substantially increase the service life of crystallizer.But Since graphite is softer, it is easy to be generated abrasion by the frictional force of solid phase zinc and kirsite, therefore the present invention is in the cavity wall of crystallization cavity The upper immersion cell that is provided with carries out immersion oil to graphite guide tube, and fluid is entered between the crystal gap of graphite inside it, in stone Oil film is formed between black conduit and solid phase zinc and kirsite to be lubricated, and then substantially reduces the abrasion of graphite, extends stone The replacement cycle of black conduit further improves the service life and use cost of crystallizer.
Description of the drawings
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art Embodiment or attached drawing needed to be used in the description of the prior art are briefly described, it should be apparent that, in being described below Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor It puts, other drawings may also be obtained based on these drawings.
Fig. 1 is the solid block mold topology view of the present invention.
Fig. 2 is the section view in Fig. 1.
Fig. 3 is the partial view of Fig. 2.
Fig. 4 is the structure sectional view of the crystallizer ontology of the present invention.
Fig. 5 is the partial view of Fig. 4.
Reference numeral:
1. ontology;2. graphite guide tube;3. lower bracket;4. upper bracket;5. fuel reserve tank;101. outer wall;102. inner wall;103. interior Partition board;104. cooling chamber;105. oiling channel;106. immersion cell;107. water outlet;108. water inlet;110. crystallization cavity;111. Intake tunnel;112. exhalant canal.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with attached drawing to the present invention It is described in further details.The component of embodiments of the present invention, which are generally described and illustrated herein in the accompanying drawings can be a variety of different It configures to arrange and design.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work Under the premise of the every other embodiment that is obtained, shall fall within the protection scope of the present invention.
It should be noted that:Similar label and letter indicate similar terms in following attached drawing, therefore, once a certain Xiang Yi It is defined, then it further need not be defined and explained in subsequent attached drawing in a attached drawing.
In the description of the present invention, it should be noted that term "center", "upper", "lower", "left", "right", "vertical", The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" be based on the orientation or positional relationship shown in the drawings, merely to Convenient for the description present invention and simplify description, do not indicate or imply the indicated device or element must have a particular orientation, With specific azimuth configuration and operation, therefore it is not considered as limiting the invention.In addition, term " first ", " second ", " third " is used for description purposes only, and is not understood to indicate or imply relative importance.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can Can also be electrical connection to be mechanical connection;It can be directly connected, can also indirectly connected through an intermediary, Ke Yishi Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood at this with concrete condition Concrete meaning in invention.
Below in conjunction with the accompanying drawings, it elaborates to some embodiments of the present invention.In the absence of conflict, following Feature in embodiment can be combined with each other.
Embodiment:
As shown in Figure 1 to Figure 2 a kind of zinc and kirsite bar produce towed crystallizer, for being produced into zinc and zinc conjunction Golden bar, alloying component:Aluminium is 5%, and surplus is zinc comprising ontology 1, which includes inner wall 102 and outer wall 101, described interior It is equipped with water-cooling channel between wall 102 and outer wall 101, and is equipped with crystallization cavity 110 and cooling chamber 104, zinc and kirsite in inner wall 102 Liquid draws crystallizer, the crystallization cavity by liquid phase solid phase in crystallization cavity 110 and after cooling chamber 104 is further cooling 110 built-in types are equipped with the graphite guide tube 2 for preventing its cavity wall of zinc and kirsite liquid corrosion, the cavity wall of the crystallization cavity 110 Upper and positioned at graphite guide tube 2 outside is provided with to 2 immersion oil of graphite guide tube to reduce the frictional force between solid phase zinc and kirsite Immersion cell 106.
It should be noted that ontology 1 is copper ontology, with good heat conductivility, the extreme lower position of water-cooling channel To be by liquid phase to be crystallized in graphite guide tube 2 in zinc and kirsite liquid in the lower position of graphite guide tube 2 Solid phase, the zinc and kirsite of solid phase are then not easy to chemically react with copper alloy, cause crystallizer inner wall 102 generate corrosion and Damage.Ontology 1 is fixed by upper bracket 4 and lower bracket 3, and in order to ensure the smooth extraction of zinc and kirsite bar, ontology 1 It is installed to be vertical direction.
It should also be noted that, after zinc and kirsite liquid enter graphite guide tube 2, in the cooling effect of water-cooling channel Under, solid phase is gradually changed by liquid phase, solid-liquid mixing again, cooling chamber 104 is entered after being changed into solid phase, in the work of water-cooling channel With lower further cooling, draft gear draws the zinc of solid phase and kirsite bar from cooling chamber 104.In addition, graphite guide The feed inlet connection zinc and kirsite fluid infusion apparatus of pipe 2, which will melt the zinc generated after stove heat and zinc closes Golden liquid is injected into graphite guide tube 2 and is crystallized.Graphite guide tube partial denudation in the outside of lower bracket 3,
It should also be noted that, it is mounted with graphite guide tube 2 in the crystallization cavity 110 of crystallizer, it is lazy using the chemistry of graphite Property, completely cut off the contact of liquid phase zinc and kirsite and copper alloy body 1, avoids the corrosion of zinc and kirsite to ontology 1, carry significantly The high service life of crystallizer.But since graphite is softer, it is easy to be generated abrasion by the frictional force of solid phase zinc and kirsite, therefore The present embodiment is provided with immersion cell 106 in the cavity wall of crystallization cavity 110 and carries out immersion oil, crystalline substance of the fluid from graphite to graphite guide tube 2 Body enters between gap inside it, forms oil film between the tube wall and solid phase zinc and kirsite of graphite guide tube 2 and is lubricated, into And the abrasion of graphite is substantially reduced, the replacement cycle of graphite guide tube 2 is extended, the service life of crystallizer is further improved And use cost.
In the present embodiment, zinc is arranged in crystallization cavity 110 in the immersion cell 106 and kirsite solid-liquid mixes the above position Place, and at least one.The immersion cell 106 is the annular groove being opened in the cavity wall of crystallization cavity 110, and in ontology 1 Equipped with the oiling channel 105 for injecting lubricating oil into annular groove.The outside of the ontology 1 is provided with fuel reserve tank 5, the fuel reserve tank 5 are connected to through oiling channel 105 with immersion cell 106.It is connected through a screw thread between the graphite guide tube 2 and ontology 1, and therebetween With immersion oil gap.
It should be noted that the installation position of immersion cell 106 preferably starts to produce certain proportion in crystallization cavity 110 Solid phase zinc and kirsite position above because the zinc and zinc alloy granules of solid phase just will produce abrasion to graphite guide tube 2, but The zinc and kirsite of liquid phase are then without this problem.Immersion cell 106 can be arranged one, can also be arranged it is multiple, in the present embodiment Provided with an immersion cell 106, it is arranged in crystallization cavity 110 at the position of a quarter from the bottom to top, passes through the more of applicant Secondary experiment and observation, since the position, solid phase zinc and kirsite and the ratio of liquid phase zinc and kirsite are more than 1:1, in this position Effective lubricating action can not only be played by installing immersion cell 106, but also can reduce the consumption of lubricating oil.Certainly it may also set up more It is a, such as an immersion cell 106 is respectively set again in the half of crystallization cavity 110,3/4ths positions, that is, it is arranged 3 A immersion cell 106, more preferably than one, but the consumption of lubricating oil a degree of can also increase effect, can also be closed to zinc and zinc The quality of golden bar generates certain negative effect.
It should also be noted that, using being threadedly coupled between graphite guide tube 2 and crystallization cavity 110, due to the public affairs of threaded connection Closing can not possibly be completely attached between box thread, and is between fragile material graphite and copper alloy metal, and the two will produce Certain gap, lubricating oil can be penetrated by the gap between screw thread to both sides out of immersion cell 106, and then penetrate into graphite guide 2 inside of pipe generates lubricating action.
It should also be noted that, oiling channel 105 is located in water-cooling channel, lubricating oil is by the fuel reserve tank 5 of top through oiling Channel 105 is flowed into immersion cell 106.
In the present embodiment, the water-cooling channel includes intake tunnel 111 and exhalant canal 112,111 He of intake tunnel Internal partition 103 is equipped between exhalant canal 112, the two is connected in the bottom of internal partition 103, and the intake tunnel 111 is located at The outside of aquaporin 112.The communicating position of the intake tunnel 111 and exhalant canal 112 is less than the position of immersion cell 106.Institute The cooling water stated in intake tunnel 111 flows from the top to the bottom, and the cooling water in the exhalant canal 112 flows from bottom to top, and The water inlet 108 for being set to intake tunnel 111 is less than the position for the water outlet 107 for being set to exhalant canal 112.
It should be noted that internal partition 103 is located between the inner wall 102 and outer wall 101 of ontology 1, and the upper end is fixed on There are gap Cooling Waters to flow through on ontology 1, between lower end and ontology 1, is connected to intake tunnel 111 and exhalant canal 112, namely Internal partition 103 will be divided into two cavitys, outside between inner wall 102 and outer wall 101 be intake tunnel 111, and inside is that water outlet is logical Road 112.Water inlet 108 is conducive to improve cooling effect less than water outlet 107.
The manufacturing method of zinc and kirsite bar in the present embodiment, starts melting furnace first, be 95%Zn by composition proportion, The kirsite material of 5%A (mass percent) is slowly added to from the feed inlet of melting furnace, and the kirsite material of addition is melted to regulation Liquid level, and by aluminium alloy control at 600 DEG C or so, by Yin Pi mechanisms crystallizer water inlet 108 and go out The mouth of a river 107 is opened, and cooling water is made to start to flow in water-cooling channel.Start Yin Pi mechanisms, graphite crystallizer device is installed in advance In Yin Pi mechanisms, it is inserted into graphite crystallizer device and draws base bar, make to draw 2 bottom of graphite guide tube that base bar reaches mould assembly Control Yin Pi mechanisms are declined, make end 50~80mm partial insertion aluminium alloys of crystallizer, the end of the crystallizer by end Without 2 exposed part of graphite guide tube, start automatic control device, it is ensured that the entire distraction procedure crystallizer end parts 50~80mm It is inserted into aluminium alloy, and speed governing draws base speed to 0.7m/min, draws base bar at this time and can carry and is frozen into the alloy wire base of solid together It is brought out crystallizer.Start crystallization as kirsite liquid enters in graphite guide tube 2 and be brought out, need constantly to add alloy material with Keep liquid level.To keep distraction procedure stable and extending the service life of graphite crystallizer, need constantly suitable to the addition of immersion cell 106 The lubricating oil of amount realizes the continuous production of high-quality kirsite bar base, and the bar base that this method is produced is crystallized without latent defect The advantages that device service life length, even wearing, replacement are without blowing out.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that:Its according to So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into Row equivalent replacement;And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme.

Claims (9)

1. a kind of zinc and kirsite bar produce towed crystallizer, for producing zinc and kirsite bar comprising ontology, this Body includes inner and outer wall, water-cooling channel is equipped between the inner and outer wall, and crystallization cavity and cooling chamber, zinc are equipped in inner wall And kirsite liquid draws crystallizer by liquid phase solid phase in crystallization cavity and after cooling chamber further cools down, feature exists In the crystallization cavity built-in type is equipped with the graphite guide tube for preventing its cavity wall of zinc and kirsite liquid corrosion, the crystallization cavity Cavity wall on and positioned at the outside of graphite guide tube be provided with and rubbed between solid phase zinc and kirsite to graphite guide tube immersion oil with reducing Wipe the immersion cell of power.
2. zinc according to claim 1 and kirsite bar produce towed crystallizer, which is characterized in that the immersion cell Zinc is set in crystallization cavity and kirsite solid-liquid mixes at the above position, and at least one.
3. zinc according to claim 1 or 2 and kirsite bar produce towed crystallizer, which is characterized in that the leaching Oil groove is the annular groove being opened in the cavity wall of crystallization cavity, and the note that lubricating oil is injected into annular groove is equipped in ontology Oily channel.
4. zinc according to claim 3 and kirsite bar produce towed crystallizer, which is characterized in that the ontology Outside is provided with fuel reserve tank, which is connected to through oiling channel with immersion cell.
5. zinc according to claim 1 or 2 and kirsite bar produce towed crystallizer, which is characterized in that the stone It is connected through a screw thread between black conduit and ontology, and there is therebetween immersion oil gap.
6. zinc according to claim 1 and kirsite bar produce towed crystallizer, which is characterized in that the water cooling is logical Road includes intake tunnel and exhalant canal, internal partition is equipped between the intake tunnel and exhalant canal, the two is at the bottom of internal partition Portion is connected to, and the intake tunnel is located at the outside of exhalant canal.
7. zinc according to claim 6 and kirsite bar produce towed crystallizer, which is characterized in that the water inlet is logical The communicating position of road and exhalant canal is less than the position of immersion cell.
8. zinc according to claim 6 and kirsite bar produce towed crystallizer, which is characterized in that the water inlet is logical Cooling water in road flows from the top to the bottom, and the cooling water in the exhalant canal flows from bottom to top, and is set to intake tunnel Water inlet be less than be set to exhalant canal water outlet position.
9. zinc according to claim 1 and kirsite bar produce towed crystallizer, which is characterized in that the ontology is Copper ontology.
CN201810946649.0A 2018-08-20 2018-08-20 A kind of zinc and kirsite bar produce towed crystallizer Pending CN108705054A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110117729A (en) * 2019-04-26 2019-08-13 厦门百路达高新材料有限公司 A method of producing graphene metal

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5785652A (en) * 1980-11-19 1982-05-28 Kawasaki Steel Corp Continuous casting method for hollow blank material for pipe making
CN202224613U (en) * 2011-09-30 2012-05-23 宁波正元铜合金有限公司 Metal horizontal continuous casting crystallizer
CN103691901A (en) * 2013-12-29 2014-04-02 山东亨圆铜业有限公司 Cored crystallizer for upwardly drawing continuous casting copper tubes and method for manufacturing high-performance copper alloy tubes
CN203853534U (en) * 2014-06-11 2014-10-01 史爱波 Upward-casting continuous casting crystallizer
CN105689667A (en) * 2016-03-10 2016-06-22 安徽鑫旭新材料股份有限公司 Tubular backflow copper material continuous up-casting crystallizer
CN206169215U (en) * 2016-11-14 2017-05-17 新利得(天津)焊接材料有限公司 Take splash ring crystallizer
CN210755017U (en) * 2018-08-20 2020-06-16 绍兴市天龙锡材有限公司 Traction type crystallizer for producing zinc and zinc alloy rods

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5785652A (en) * 1980-11-19 1982-05-28 Kawasaki Steel Corp Continuous casting method for hollow blank material for pipe making
CN202224613U (en) * 2011-09-30 2012-05-23 宁波正元铜合金有限公司 Metal horizontal continuous casting crystallizer
CN103691901A (en) * 2013-12-29 2014-04-02 山东亨圆铜业有限公司 Cored crystallizer for upwardly drawing continuous casting copper tubes and method for manufacturing high-performance copper alloy tubes
CN203853534U (en) * 2014-06-11 2014-10-01 史爱波 Upward-casting continuous casting crystallizer
CN105689667A (en) * 2016-03-10 2016-06-22 安徽鑫旭新材料股份有限公司 Tubular backflow copper material continuous up-casting crystallizer
CN206169215U (en) * 2016-11-14 2017-05-17 新利得(天津)焊接材料有限公司 Take splash ring crystallizer
CN210755017U (en) * 2018-08-20 2020-06-16 绍兴市天龙锡材有限公司 Traction type crystallizer for producing zinc and zinc alloy rods

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110117729A (en) * 2019-04-26 2019-08-13 厦门百路达高新材料有限公司 A method of producing graphene metal

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Application publication date: 20181026