CN108704454A - A kind of purifying processing device of organic exhaust gas absorbent and environment-friendly type organic exhaust gas - Google Patents
A kind of purifying processing device of organic exhaust gas absorbent and environment-friendly type organic exhaust gas Download PDFInfo
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- CN108704454A CN108704454A CN201810688023.4A CN201810688023A CN108704454A CN 108704454 A CN108704454 A CN 108704454A CN 201810688023 A CN201810688023 A CN 201810688023A CN 108704454 A CN108704454 A CN 108704454A
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1431—Pretreatment by other processes
- B01D53/145—Pretreatment by separation of solid or liquid material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/608—Sulfates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/50—Combinations of absorbents
- B01D2252/504—Mixtures of two or more absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
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Abstract
The present invention provides a kind of organic exhaust gas absorbents and the purifying processing device of environment-friendly type organic exhaust gas, the absorbent to be made of the raw material including following parts by weight:10-15 parts of plant extraction liquid, 20-30 parts of organic absorbent liquid, 1-5 parts of inorganic absorbent powder, 5-10 parts of Physical Absorption powder, 3-5 parts of activating agent, 20-50 parts of water;The organic absorbent liquid is at least one of alkane, alkene, cyclic hydrocarbon, halogenated hydrocarbons, fatty amine, fatty alcohol, alicyclic ring alcohol or aliphatic acid;The inorganic absorbent powder is at least one of sulphite, carbonate, silicate or meta-aluminate.The combination of Multiple components in organic exhaust gas absorbent of the present invention makes the organic exhaust gas absorbent have excellent assimilation effect to organic exhaust gas, reduces environmental pollution.
Description
Technical field
The invention belongs to chemical fields, more particularly, to the purification of a kind of organic exhaust gas absorbent and environment-friendly type organic exhaust gas
Processing unit.
Background technology
The industries such as furniture, shoemaking, automobile, machinery, household electrical appliances, electromechanics, plastic products, hardware all must to product surface into
Row processing, it is most effective at present and most efficiently method is exactly to produce motley product by painted surface processing, it can be with
Greatly improve the aesthetic feeling of product.But the release that can volatilize in paint production, dilution, spraying process and during subsequent cure has
Machine exhaust emission.The comparison of ingredients of Organic Waste Gas Pollution object is complicated, mainly has low-molecular-weight organic compound and macromolecule organic
Compound, the water solubility and degradability of height organic compound differ greatly, especially as surface spraying, plastic processing, chemical industry,
The organic exhaust gas of the generations such as rubber, pharmacy, chemical fertilizer, printing, weaving, the solvent and diluent of surface spraying have benzene, toluene, diformazan
Benzene etc. is insoluble in the stronger water of polarity, and benzene,toluene,xylene is non-polar high polymer organic compound substance, also there is readily soluble water
The low poles low-molecular-weight organic compound such as methanol, ethyl alcohol, acetone, aliphatic ketone, formaldehyde, acetaldehyde.Most organic exhaust gas has carcinogenic, cause
Abnormal, mutagenic effect and genetoxic directly endanger the life and healths such as the mankind and other biological, such as benzene,toluene,xylene class pair
The nerve and hemopoietic system of human body cause great harm.
In China during high speed development, the environmental issue of getting worse receives the concern of social each side, has expedited the emergence of very much
The equipment for administering volatile organic matter (VOCs), such as common active carbon adsorption, plasma, ultraviolet light equipment.But
For the cleaning equipment of VOCs, there are certain limitations, such as active carbon adsorption equipment for these:Adsorption capacity is low, absorption is easy to reach
Saturation, short life, regeneration cost is high, ultimately forms dangerous waste;If equipment is out of service, due to losing negative pressure, adsorb
Release VOCs can be desorbed in activated carbon;Its operation is also influenced by humidity, dust and the temperature when working, and humidity is bigger, and dust is more,
Adsorption effect is poorer;Temperature is higher (China's summer temperature is higher for a long time), is more unfavorable for adsorbing.And non-thermal plasma trap, by
Steam, dust to exhaust gas influence also reduce treatment effeciency.In addition, if using the plasma of low energy, it is existing so-called
Plasma process mostly uses kitchen ventilator oil removing principle, is not suitable for administering substantially and contains phenyl ring class VOCs, if using big work(
There is also drawbacks for rate plasma technique, and equipment is expensive, such as plasma such as excitation generation electric arc, are inevitably generated smelly
The secondary pollutions such as the intermediate by-products of oxygen, nitrogen oxides and organic exhaust gas Partial digestion, more seriously, due to organic exhaust gas
Mostly inflammable, explosive compound, VOCs treatment engineering slightly flaw in design, when plasma operation
Arc electrode easily causes explosion accident, and the explosive incident of Tianjin has informed its security risk of everybody, this technology forbidden time
It is few.And can be influenced by dust when the application of ultraviolet photolysis technology, make radiation energy that can constantly weaken, and 185nm wavelength
Ultraviolet light will produce a large amount of ozone, cause secondary pollution, and existing treating method is substantially without moment reaction effect (with the country
Certain famous quartz burner supply enterprise is introduced, and in photocatalytic region, it is anti-such as without the sufficient time hydroxyl radical free radical to occur for organic exhaust gas
It answers, to organic exhaust gas degradation rate less than 10%), in addition, the titanic oxide material now used, if not being Detitanium-ore-type titanium dioxide
Titanium photocatalyst, it is basic without catalysis photodissociation effect.
Using each abatement equipment and combinations thereof mode as without quantitative analysis is carried out to processing, do not worked out specific aim solution
Scheme can not effectively administer Organic Waste Gas Pollution.Exhaust gas for different emission sources be also it is multifarious, VOCs treatment
Monotechnics have been difficult to make the discharge of organic exhaust gas to reach increasingly strict environmental requirement, therefore, to realize the new shape of environmental protection
Gesture needs to seek to meet environmental requirement and the higher group technology of cost performance, pushes the innovation and development of VOCs treatment technology.
Invention content
In view of this, the present invention is directed to propose a kind of organic exhaust gas absorbent, by plant component, with inorganic, organic compound
Object is combined, and effectively absorbs organic exhaust gas.
In order to achieve the above objectives, the technical proposal of the invention is realized in this way:
A kind of organic exhaust gas absorbent, the absorbent are made of the raw material including following parts by weight:
The organic absorbent liquid is alkane, alkene, cyclic hydrocarbon, halogenated hydrocarbons, fatty amine, fatty alcohol, alicyclic ring alcohol or aliphatic acid
At least one of;
The inorganic absorbent powder is at least one of sulphite, carbonate, silicate or meta-aluminate.
Preferably, the absorbent is made of the raw material including following parts by weight:
The organic absorbent liquid is alkane, alkene, cyclic hydrocarbon, halogenated hydrocarbons, fatty amine, fatty alcohol, alicyclic ring alcohol or aliphatic acid
At least one of;
The inorganic absorbent powder is at least one of sulphite, carbonate, silicate or meta-aluminate.
Preferably, the absorbent is made of the raw material including following parts by weight:
The organic absorbent liquid is alkane, alkene, cyclic hydrocarbon, halogenated hydrocarbons, fatty amine, fatty alcohol, alicyclic ring alcohol or aliphatic acid
At least one of;
The inorganic absorbent powder is at least one of sulphite, carbonate, silicate or meta-aluminate.
Further, the plant extraction liquid is that extract solution from aloe, Flos Lonicerae extractive solution, ginkgo extract or the fruit of glossy privet carry
Take at least one of liquid.
The preparation method of the extract solution from aloe, includes the following steps:It is removed the peel after Chinese aloe leaf is cleaned, then to pulp
Part carries out high-temperature process, squeezes the juice, filters to get the extract solution from aloe.The high temperature processing step is heating water bath
Or high-temperature vapour heat treatment.
The preparation method of the Flos Lonicerae extractive solution, includes the following steps:15-20 weight is added after honeysuckle is cleaned
Water again carries out primary decoction 30min, and first-time filtrate is obtained after then filtering, by filtered honeysuckle addition 15-20 weight
Water again carries out secondary decoction 30min, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate
The volume of one third is concentrated into get the Flos Lonicerae extractive solution.
The preparation method of the ginkgo extract, includes the following steps:10-15 times of weight is added after ginkgo leaf is cleaned
Water once decocted, then filter after obtain first-time filtrate, by filtered ginkgo leaf be added 10-15 times of weight water into
The secondary decoction of row, obtains secondary filtrate after then filtering, is concentrated to get described after first-time filtrate is mixed with secondary filtrate
Ginkgo biloba succi.
The preparation method of the fruit of glossy privet extracting solution, includes the following steps:It is added after the ripening fruits of glossy privet is cleaned
The water of 10-15 times of weight is once decocted, and first-time filtrate is obtained after then filtering, and 10-15 weights are added in filtered fruit
The water of amount times carries out secondary decoction, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate dense
Contracting is to get the fruit of glossy privet extracting solution.
Further, the Physical Absorption powder is activated carbon, and the activated carbon is peat-based activated carbon or coconut husk base
At least one of grain activated carbon;The grain size of the activated carbon is 0.1-5mm.
Further, the activating agent is one kind in Sodium Polyacrylate, polyacrylic acid or acetylenediol.
Preferably, the organic absorbent liquid is at least one of halogenated hydrocarbons, fatty alcohol or aliphatic acid;Described is organic
Absorbing liquid is one kind in carbon tetrafluoride, freon, ethyl alcohol, normal propyl alcohol, acetic acid or propionic acid.
Preferably, the inorganic absorbent powder is sodium sulfite, calcium sulfite, zinc carbonate, sodium carbonate, sodium metasilicate or inclined aluminium
At least one of sour sodium.
The preparation method of the organic exhaust gas absorbent, includes the following steps:By the inorganic absorbent powder and physics
It absorbs powder to be dissolved in the plant extraction liquid, then carries out high-speed stirred, it is after mixing, organic as described in being wherein added
Absorbing liquid and activating agent, then after mixing to obtain the final product.
Another object of the present invention is to propose a kind of environment-friendly type organic exhaust gas using the organic exhaust gas absorbent
Purifying processing device, the organic gas in exhaust gas is adequately absorbed by three absorption plants.
In order to achieve the above objectives, the technical proposal of the invention is realized in this way:
A kind of purifying processing device using the environment-friendly type organic exhaust gas, including absorption tower, absorber, absorption cell,
The absorption tower is connected by pipeline with the absorber, and the absorber passes through pipeline and the absorption cell phase
Even;
The absorption tower is internally provided with first filter layer, packing layer, jet pipe, several nozzles, spray tube, fixed gear
Plate, return line, a drain pipe, the packing layer between the first filter layer and jet pipe, the nozzle with
The jet pipe is connected, and the spray tube is between the nozzle and the fixed baffle, the primary row
One end of liquid pipe passes through the fixed baffle, is placed in the outside on the absorption tower, and the both ends of the return line are equal
It is connected with the absorption tower, one end of the return line is between the nozzle and spray tube, other end position
Between the spray tube and fixed baffle;
The absorption tower is equipped with an air inlet, an inlet, an exhaust outlet, described air inlet position
In the top of the first filter layer, described one time inlet is connected with the jet pipe with spray tube respectively, and described is primary
Exhaust outlet is located at the top of the fixed baffle;
The spray tube is equipped with several spray apertures.Absorption tower carries out double spraying by nozzle and spray tube, makes
Liquid adequately absorbs gas.Spray tube structure in the shape of a spiral, can to greatest extent spray gas.
Further, being internally provided with for the absorber sprays casing, surge chamber, and the surge chamber is located at described
The lower section of casing is sprayed, one end of the spray casing is connected with the surge chamber;
The spray casing includes snorkel, fluid-through tube, and the snorkel is located at the inside of the fluid-through tube, institute
Several ventholes is uniformly equipped on the snorkel stated;
The absorber is equipped with secondary air inlet mouth, secondary inlet, the secondary gas import and the air inlet
Pipe is connected, and the secondary inlet is connected with the inlet tube, and the surge chamber is equipped with secondary leakage fluid dram, described
The side of surge chamber be equipped with secondary exhaust mouth, the secondary air inlet mouth is connected by pipeline with an exhaust outlet.
Surge chamber can be such that the liquid that absorption is completed is detached with the gas that can not be absorbed to the flow of liquid and gas into row buffering.
The double-layer structure design of spray casing can reduce the distance between liquid and gas to greatest extent, improve the absorption effect of liquid
Rate.Liquid is flowed into from venthole in snorkel, is absorbed to gas.
Further, the absorption cell is internally provided with organic exhaust gas absorber layer, ultrasonic transducer, rabbling mechanism,
The organic exhaust gas absorber layer is located at the top of the ultrasonic transducer, and the rabbling mechanism has positioned at described
In machine waste gas absorption oxidant layer;
The rabbling mechanism includes shaft, electric rotating machine, several flabellums, one end of the shaft and the rotation
Rotating motor is connected, and the flabellum is both secured in the shaft, the shaft and organic exhaust gas absorber layer bottom it
Between distance be 1.1-1.5 times of flabellum width;
The absorption cell be equipped with three times air inlet, three times exhaust outlet, flow back gas port three times, the air inlet three times
It is connected with the secondary exhaust mouth by pipeline, the gas port of reflux three times is located at the top of the absorption cell, and leads to
It crosses pipeline with the secondary air inlet mouth to be connected, the exhaust outlet three times is located at the lower section of the gas port that flows back three times.It is super
Electrical power can be converted into mechanical output (i.e. ultrasonic wave) and passed again by acoustic wave transducer, make gas in organic exhaust gas absorbent
It adequately washed, absorbed in layer, improve the absorption efficiency of absorbent.Rabbling mechanism is stirred absorbent, makes it
Uniform state is kept, Physical Absorption powder is made adequately to absorb gas.
Further, the purifying processing device of the environment-friendly type organic exhaust gas, it is characterised in that:Inlet
The mass ratio of the mixed liquor of inorganic absorbent powder and water described in middle inflow, the inorganic absorbent powder and water is 1:(4-10);Institute
The organic absorbent liquid is flowed into the secondary inlet stated;The organic exhaust gas absorber layer is the organic waste aspiration
Receive agent.
One end of the gas port of reflux three times is provided with gas-liquid separation layer, and the gas-liquid separation layer is located at the suction
The inside of receives pond.
Exhaust fan, one end of the exhaust fan and the secondary row are provided between the absorber and absorption cell
Gas port is connected, and the other end is connected with the air inlet three times.
The return line, a drain pipe, is both provided with valve on the gas port that flows back three times at exhaust outlet.
Compared with the existing technology, the purified treatment dress of organic exhaust gas absorbent and environment-friendly type organic exhaust gas of the present invention
It sets and has the advantage that:
(1) in organic exhaust gas absorbent of the present invention include plant extraction liquid, organic absorbent liquid, inorganic absorbent
Powder, Physical Absorption powder, plant extraction liquid can effectively absorb or the pernicious gases such as decomposing formaldehyde, benzene, and organic absorbent liquid passes through
Similar compatibility principle absorbs organic exhaust gas, and inorganic absorbent powder is chemically reacted with organic gas, makes having in exhaust gas
Machine gas is converted, and Physical Absorption powder absorbs organic gas by its porous structure, and activating agent makes reaction more
Rapidly, effective to carry out, the combination of Multiple components makes the organic exhaust gas absorbent have excellent absorption to organic exhaust gas
Effect reduces environmental pollution.
(2) purifying processing device of environment-friendly type organic exhaust gas of the present invention passes through absorption tower, absorber, absorption cell pair
Organic gas carry out three reabsorptions, to greatest extent on organic exhaust gas is handled.
Description of the drawings
The attached drawing for constituting the part of the present invention is used to provide further understanding of the present invention, schematic reality of the invention
Example and its explanation are applied for explaining the present invention, is not constituted improper limitations of the present invention.In the accompanying drawings:
Fig. 1 is the schematic diagram of the purifying processing device of the environment-friendly type organic exhaust gas described in the embodiment of the present invention;
Fig. 2 is the sectional view of the spray casing described in the embodiment of the present invention.
Reference sign:
The absorption towers 1-;2- absorbers;3- absorption cells;4- exhaust fans;5- valves;11- first filter layers;12- packing layers;13- sprays
Pipe;14- nozzles;15- spray tubes;151- spray apertures;16- fixed baffles;Air inlet of 17-;Inlet of 18-;19- is returned
Flow tube road;Exhaust outlet of 110-;Drain pipe of 111-;21- sprays casing;22- secondary air inlet mouths;Bis- inlets of 23-;
Bis- leakage fluid drams of 24-;25- secondary exhaust mouths;26- surge chambers;31- organic exhaust gas absorber layers;32- ultrasonic transducers;33-
Shaft;34- electric rotating machines;35- flabellums;36- air inlets three times;37- exhaust outlets three times;38- flows back gas port three times;381- gas-liquids
Separating layer;211- snorkels;212- fluid-through tubes;2111- ventholes.
Specific implementation mode
In addition to being defined, technical term used in following embodiment has universal with those skilled in the art of the invention
The identical meanings of understanding.Test reagent used in following embodiment is unless otherwise specified conventional biochemical reagent;It is described
Experimental method is unless otherwise specified conventional method.
With reference to embodiment and attached drawing, the present invention will be described in detail.
Embodiment 1
A kind of organic exhaust gas absorbent, the absorbent are made of the raw material including following parts by weight:13 parts of plant extraction liquid,
28 parts of organic absorbent liquid, 4 parts of inorganic absorbent powder, 8 parts of Physical Absorption powder, 3 parts of activating agent;45 parts of water;
The plant extraction liquid is extract solution from aloe, Flos Lonicerae extractive solution, ginkgo extract, fruit of glossy privet extracting solution, reed
Luxuriant growth extracting solution, Flos Lonicerae extractive solution, ginkgo extract, fruit of glossy privet extracting solution mass ratio be:3:2:5:3.
The preparation method of the extract solution from aloe, includes the following steps:It is removed the peel after Chinese aloe leaf is cleaned, then to pulp
Part carries out high-temperature process, squeezes the juice, filters to get the extract solution from aloe.The high temperature processing step is heating water bath
Or high-temperature vapour heat treatment.
The preparation method of the Flos Lonicerae extractive solution, includes the following steps:15-20 weight is added after honeysuckle is cleaned
Water again carries out primary decoction 30min, and first-time filtrate is obtained after then filtering, by filtered honeysuckle addition 15-20 weight
Water again carries out secondary decoction 30min, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate
The volume of one third is concentrated into get the Flos Lonicerae extractive solution.
The preparation method of the ginkgo extract, includes the following steps:10-15 times of weight is added after ginkgo leaf is cleaned
Water once decocted, then filter after obtain first-time filtrate, by filtered ginkgo leaf be added 10-15 times of weight water into
The secondary decoction of row, obtains secondary filtrate after then filtering, is concentrated to get described after first-time filtrate is mixed with secondary filtrate
Ginkgo biloba succi.
The preparation method of the fruit of glossy privet extracting solution, includes the following steps:It is added after the ripening fruits of glossy privet is cleaned
The water of 10-15 times of weight is once decocted, and first-time filtrate is obtained after then filtering, and 10-15 weights are added in filtered fruit
The water of amount times carries out secondary decoction, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate dense
Contracting is to get the fruit of glossy privet extracting solution.
The Physical Absorption powder is coconut husk base granular activated carbon;The grain size of the coconut husk base granular activated carbon is 0.1-
2mm。
The activating agent is polyacrylic acid and acetylenediol, and the mass ratio of polyacrylic acid and acetylenediol is 1:1.5.
The organic absorbent liquid be carbon tetrafluoride, freon, propionic acid, the carbon tetrafluoride, freon, propionic acid matter
Amount is than being 2:3:2.
The inorganic absorbent powder be sodium carbonate, sodium metasilicate, sodium metaaluminate, sodium carbonate, sodium metasilicate, sodium metaaluminate quality
Than being 1:0.8:1.2.
The preparation method of the organic exhaust gas absorbent, includes the following steps:By the inorganic absorbent powder and physics
It absorbs powder to be dissolved in the plant extraction liquid, then carries out high-speed stirred, it is after mixing, organic as described in being wherein added
Absorbing liquid and activating agent, then after mixing to obtain the final product.
A kind of purifying processing device using the environment-friendly type organic exhaust gas, including absorption tower, absorber, absorption cell,
The absorption tower is connected by pipeline with the absorber, and the absorber passes through pipeline and the absorption cell phase
Even;
The absorption tower is internally provided with first filter layer, packing layer, jet pipe, several nozzles, spray tube, fixed gear
Plate, return line, a drain pipe, the packing layer between the first filter layer and jet pipe, the nozzle with
The jet pipe is connected, and the spray tube is between the nozzle and the fixed baffle, the primary row
One end of liquid pipe passes through the fixed baffle, is placed in the outside on the absorption tower, and the both ends of the return line are equal
It is connected with the absorption tower, one end of the return line is between the nozzle and spray tube, other end position
Between the spray tube and fixed baffle;
The absorption tower is equipped with an air inlet, an inlet, an exhaust outlet, described air inlet position
In the top of the first filter layer, described one time inlet is connected with the jet pipe with spray tube respectively, and described is primary
Exhaust outlet is located at the top of the fixed baffle;
The spray tube is equipped with several spray apertures.Packing layer uses Raschig ring.First filter layer selects sponge material.
The absorber is internally provided with spray casing, surge chamber, and the surge chamber is located at the spray set
One end of the lower section of pipe, the spray casing is connected with the surge chamber;
The spray casing includes snorkel, fluid-through tube, and the snorkel is located at the inside of the fluid-through tube, institute
Several ventholes is uniformly equipped on the snorkel stated;
The absorber is equipped with secondary air inlet mouth, secondary inlet, the secondary gas import and the air inlet
Pipe is connected, and the secondary inlet is connected with the inlet tube, and the surge chamber is equipped with secondary leakage fluid dram, described
The side of surge chamber be equipped with secondary exhaust mouth, the secondary air inlet mouth is connected by pipeline with an exhaust outlet.
The absorption cell is internally provided with organic exhaust gas absorber layer, ultrasonic transducer, rabbling mechanism, and described has
Machine waste gas absorption oxidant layer is located at the top of the ultrasonic transducer, and the rabbling mechanism is located at the organic waste aspiration
It receives in oxidant layer;
The rabbling mechanism includes shaft, electric rotating machine, several flabellums, one end of the shaft and the rotation
Rotating motor is connected, and the flabellum is both secured in the shaft, the shaft and organic exhaust gas absorber layer bottom it
Between distance be 1.1 times of flabellum width;
The absorption cell be equipped with three times air inlet, three times exhaust outlet, flow back gas port three times, the air inlet three times
It is connected with the secondary exhaust mouth by pipeline, the gas port of reflux three times is located at the top of the absorption cell, and leads to
It crosses pipeline with the secondary air inlet mouth to be connected, the exhaust outlet three times is located at the lower section of the gas port that flows back three times.
The purifying processing device of the environment-friendly type organic exhaust gas, it is characterised in that:It is flowed into inlet
The mass ratio of the mixed liquor of the inorganic absorbent powder and water, the inorganic absorbent powder and water is 1:10;It is described it is secondary into
The organic absorbent liquid is flowed into liquid mouth;The organic exhaust gas absorber layer is the organic exhaust gas absorbent.
One end of the gas port of reflux three times is provided with gas-liquid separation layer, and the gas-liquid separation layer is located at the suction
The inside of receives pond.Gas-liquid separation layer uses silica gel material.It is provided with exhaust fan between the absorber and absorption cell, it is described
One end of exhaust fan is connected with the secondary exhaust mouth, and the other end is connected with the air inlet three times.The return duct
Road, an exhaust outlet, a drain pipe, three times flow back gas port on be both provided with valve.
Embodiment 2
A kind of organic exhaust gas absorbent, the absorbent are made of the raw material including following parts by weight:18 parts of plant extraction liquid,
22 parts of organic absorbent liquid, 2 parts of inorganic absorbent powder, 6 parts of Physical Absorption powder, 5 parts of activating agent;25 parts of water;
The plant extraction liquid is extract solution from aloe, Flos Lonicerae extractive solution, ginkgo extract, fruit of glossy privet extracting solution, reed
Luxuriant growth extracting solution, Flos Lonicerae extractive solution, ginkgo extract, fruit of glossy privet extracting solution mass ratio be 3:2:5:3.
The preparation method of the extract solution from aloe, includes the following steps:It is removed the peel after Chinese aloe leaf is cleaned, then to pulp
Part carries out high-temperature process, squeezes the juice, filters to get the extract solution from aloe.The high temperature processing step is heating water bath
Or high-temperature vapour heat treatment.
The preparation method of the Flos Lonicerae extractive solution, includes the following steps:15-20 weight is added after honeysuckle is cleaned
Water again carries out primary decoction 30min, and first-time filtrate is obtained after then filtering, by filtered honeysuckle addition 15-20 weight
Water again carries out secondary decoction 30min, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate
The volume of one third is concentrated into get the Flos Lonicerae extractive solution.
The preparation method of the ginkgo extract, includes the following steps:10-15 times of weight is added after ginkgo leaf is cleaned
Water once decocted, then filter after obtain first-time filtrate, by filtered ginkgo leaf be added 10-15 times of weight water into
The secondary decoction of row, obtains secondary filtrate after then filtering, is concentrated to get described after first-time filtrate is mixed with secondary filtrate
Ginkgo biloba succi.
The preparation method of the fruit of glossy privet extracting solution, includes the following steps:It is added after the ripening fruits of glossy privet is cleaned
The water of 10-15 times of weight is once decocted, and first-time filtrate is obtained after then filtering, and 10-15 weights are added in filtered fruit
The water of amount times carries out secondary decoction, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate dense
Contracting is to get the fruit of glossy privet extracting solution.
The Physical Absorption powder is coconut husk base granular activated carbon;The grain size of the coconut husk base granular activated carbon is 0.1-
2mm。
The activating agent is polyacrylic acid and acetylenediol, and the mass ratio of polyacrylic acid and acetylenediol is 1:1.5.
The organic absorbent liquid be carbon tetrafluoride, freon, propionic acid, the carbon tetrafluoride, freon, propionic acid matter
Amount is than being 2:3:2.
The inorganic absorbent powder be sodium carbonate, sodium metasilicate, sodium metaaluminate, sodium carbonate, sodium metasilicate, sodium metaaluminate quality
Than being 1:0.8:1.2.
The preparation method of the organic exhaust gas absorbent, includes the following steps:By the inorganic absorbent powder and physics
It absorbs powder to be dissolved in the plant extraction liquid, then carries out high-speed stirred, it is after mixing, organic as described in being wherein added
Absorbing liquid and activating agent, then after mixing to obtain the final product.
A kind of purifying processing device using the environment-friendly type organic exhaust gas is same as Example 1.
Embodiment 3
A kind of organic exhaust gas absorbent, the absorbent are made of the raw material including following parts by weight:18 parts of plant extraction liquid,
22 parts of organic absorbent liquid, 2 parts of inorganic absorbent powder, 6 parts of Physical Absorption powder, 5 parts of activating agent;25 parts of water;
The plant extraction liquid be extract solution from aloe, Flos Lonicerae extractive solution, extract solution from aloe, Flos Lonicerae extractive solution matter
Amount is than being 3:4.
The preparation method of the extract solution from aloe, includes the following steps:It is removed the peel after Chinese aloe leaf is cleaned, then to pulp
Part carries out high-temperature process, squeezes the juice, filters to get the extract solution from aloe.The high temperature processing step is heating water bath
Or high-temperature vapour heat treatment.
The preparation method of the Flos Lonicerae extractive solution, includes the following steps:15-20 weight is added after honeysuckle is cleaned
Water again carries out primary decoction 30min, and first-time filtrate is obtained after then filtering, by filtered honeysuckle addition 15-20 weight
Water again carries out secondary decoction 30min, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate
The volume of one third is concentrated into get the Flos Lonicerae extractive solution.
The Physical Absorption powder is coconut husk base granular activated carbon;The grain size of the coconut husk base granular activated carbon is 0.1-
2mm。
The activating agent is polyacrylic acid and acetylenediol, and the mass ratio of polyacrylic acid and acetylenediol is 1:1.5.
The organic absorbent liquid be carbon tetrafluoride, freon, propionic acid, the carbon tetrafluoride, freon, propionic acid matter
Amount is than being 2:3:2.
The inorganic absorbent powder be sodium carbonate, sodium metasilicate, sodium metaaluminate, sodium carbonate, sodium metasilicate, sodium metaaluminate quality
Than being 1:0.8:1.2.
The preparation method of the organic exhaust gas absorbent, includes the following steps:By the inorganic absorbent powder and physics
It absorbs powder to be dissolved in the plant extraction liquid, then carries out high-speed stirred, it is after mixing, organic as described in being wherein added
Absorbing liquid and activating agent, then after mixing to obtain the final product.
A kind of purifying processing device using the environment-friendly type organic exhaust gas is same as Example 1.
Embodiment 4
A kind of organic exhaust gas absorbent, the absorbent are made of the raw material including following parts by weight:18 parts of plant extraction liquid,
22 parts of organic absorbent liquid, 2 parts of inorganic absorbent powder, 6 parts of Physical Absorption powder, 5 parts of activating agent;25 parts of water;
The plant extraction liquid is extract solution from aloe, Flos Lonicerae extractive solution, ginkgo extract, fruit of glossy privet extracting solution, reed
Luxuriant growth extracting solution, Flos Lonicerae extractive solution, ginkgo extract, fruit of glossy privet extracting solution mass ratio be:3:2:5:3.
The preparation method of the extract solution from aloe, includes the following steps:It is removed the peel after Chinese aloe leaf is cleaned, then to pulp
Part carries out high-temperature process, squeezes the juice, filters to get the extract solution from aloe.The high temperature processing step is heating water bath
Or high-temperature vapour heat treatment.
The preparation method of the Flos Lonicerae extractive solution, includes the following steps:15-20 weight is added after honeysuckle is cleaned
Water again carries out primary decoction 30min, and first-time filtrate is obtained after then filtering, by filtered honeysuckle addition 15-20 weight
Water again carries out secondary decoction 30min, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate
The volume of one third is concentrated into get the Flos Lonicerae extractive solution.
The preparation method of the ginkgo extract, includes the following steps:10-15 times of weight is added after ginkgo leaf is cleaned
Water once decocted, then filter after obtain first-time filtrate, by filtered ginkgo leaf be added 10-15 times of weight water into
The secondary decoction of row, obtains secondary filtrate after then filtering, is concentrated to get described after first-time filtrate is mixed with secondary filtrate
Ginkgo biloba succi.
The preparation method of the fruit of glossy privet extracting solution, includes the following steps:It is added after the ripening fruits of glossy privet is cleaned
The water of 10-15 times of weight is once decocted, and first-time filtrate is obtained after then filtering, and 10-15 weights are added in filtered fruit
The water of amount times carries out secondary decoction, obtains secondary filtrate after then filtering, is carried out after first-time filtrate is mixed with secondary filtrate dense
Contracting is to get the fruit of glossy privet extracting solution.
The Physical Absorption powder is coconut husk base granular activated carbon;The grain size of the coconut husk base granular activated carbon is 0.1-
2mm。
The activating agent is polyacrylic acid and acetylenediol, and the mass ratio of polyacrylic acid and acetylenediol is 1:1.5.
The organic absorbent liquid be carbon tetrafluoride, ethyl alcohol, propionic acid, the carbon tetrafluoride, ethyl alcohol, propionic acid mass ratio
It is 2:1:2.
The inorganic absorbent powder is sodium carbonate, sodium sulfite, sodium metaaluminate, sodium carbonate, sodium sulfite, sodium metaaluminate
Mass ratio is 1:1:1.2.
The preparation method of the organic exhaust gas absorbent, includes the following steps:By the inorganic absorbent powder and physics
It absorbs powder to be dissolved in the plant extraction liquid, then carries out high-speed stirred, it is after mixing, organic as described in being wherein added
Absorbing liquid and activating agent, then after mixing to obtain the final product.
A kind of purifying processing device using the environment-friendly type organic exhaust gas is same as Example 1.
The absorbent obtained in embodiment 1-4 absorbs exhaust gas, in exhaust gas after the initial content of component and absorption
Content is as shown in table 1.
Table 1 absorbs result data
Methane | Ethane | Methanol | Formaldehyde | Acetaldehyde | Toluene | Dimethylbenzene | Acetone | |
Initial content | 0.52 | 1.08 | 1.22 | 0.96 | 2.37 | 1.82 | 3.01 | 0.34 |
Embodiment 1 | 0.02 | 0.06 | 0.01 | 0.09 | 0.17 | 0.05 | 0.08 | 0.01 |
Embodiment 2 | 0.08 | 0.14 | 0.11 | 0.02 | 0.05 | 0.12 | 0.05 | 0.03 |
Embodiment 3 | 0.12 | 0.21 | 0.16 | 0.06 | 0.03 | 0.05 | 0.13 | 0.01 |
Embodiment 4 | 0.16 | 0.13 | 0.07 | 0.03 | 0.12 | 0.07 | 0.10 | 0.04 |
By can be seen that in table 1, absorbent has more significant assimilation effect to a variety of organic gas in exhaust gas, can drop
The purpose of environmental protection is played in pollution of the low exhaust gas to environment.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (10)
1. a kind of organic exhaust gas absorbent, it is characterised in that:The absorbent is made of the raw material including following parts by weight:
The organic absorbent liquid is in alkane, alkene, cyclic hydrocarbon, halogenated hydrocarbons, fatty amine, fatty alcohol, alicyclic ring alcohol or aliphatic acid
It is at least one;
The inorganic absorbent powder is at least one of sulphite, carbonate, silicate or meta-aluminate.
2. organic exhaust gas absorbent according to claim 1, it is characterised in that:The plant extraction liquid extracts for aloe
At least one of liquid, Flos Lonicerae extractive solution, ginkgo extract or fruit of glossy privet extracting solution.
3. organic exhaust gas absorbent according to claim 1, it is characterised in that:The Physical Absorption powder is activated carbon,
The activated carbon is at least one of peat-based activated carbon or coconut husk base granular activated carbon;The grain size of the activated carbon is
0.1-5mm。
4. organic exhaust gas absorbent according to claim 1, it is characterised in that:The activating agent be Sodium Polyacrylate,
One kind in polyacrylic acid or acetylenediol.
5. organic exhaust gas absorbent according to claim 1, it is characterised in that:The organic absorbent liquid be halogenated hydrocarbons,
At least one of fatty alcohol or aliphatic acid;The organic absorbent liquid is carbon tetrafluoride, freon, ethyl alcohol, normal propyl alcohol, acetic acid
Or one kind in propionic acid.
6. organic exhaust gas absorbent according to claim 1, it is characterised in that:The inorganic absorbent powder is sulfurous acid
At least one of sodium, calcium sulfite, zinc carbonate, sodium carbonate, sodium metasilicate or sodium metaaluminate.
7. using the purifying processing device of the environment-friendly type organic exhaust gas described in any one of claim 1-6, it is characterised in that:Packet
Absorption tower, absorber, absorption cell are included, the absorption tower is connected by pipeline with the absorber, and the absorber is logical
Pipeline is crossed with the absorption cell to be connected;
The absorption tower is internally provided with first filter layer, packing layer, jet pipe, several nozzles, spray tube, fixed baffle, returns
Flow tube road, a drain pipe, the packing layer between the first filter layer and jet pipe, the nozzle with it is described
Jet pipe is connected, the spray tube between the nozzle and the fixed baffle, described drain pipe
One end passes through the fixed baffle, is placed in the outside on the absorption tower, the both ends of the return line with it is described
Absorption tower be connected, between the nozzle and spray tube, the other end is located at described for one end of the return line
Spray tube and fixed baffle between;
The absorption tower is equipped with an air inlet, an inlet, an exhaust outlet, and described one time air inlet is located at institute
The top for the first filter layer stated, described one time inlet is connected with the jet pipe with spray tube respectively, the primary exhaust
Mouth is located at the top of the fixed baffle;
The spray tube is equipped with several spray apertures.
8. the purifying processing device of environment-friendly type organic exhaust gas according to claim 7, it is characterised in that:The absorber
Be internally provided with spray casing, surge chamber, the surge chamber is located at the lower section of the described spray casing, the spray set
One end of pipe is connected with the surge chamber;
The spray casing includes snorkel, fluid-through tube, and the snorkel is located at the inside of the fluid-through tube, described
Several ventholes is uniformly equipped on snorkel;
The absorber is equipped with secondary air inlet mouth, secondary inlet, the secondary gas import and the air inlet pipe phase
Connection, the secondary inlet are connected with the inlet tube, and the surge chamber is equipped with secondary leakage fluid dram, and described is slow
The side for rushing room is equipped with secondary exhaust mouth, and the secondary air inlet mouth is connected by pipeline with an exhaust outlet.
9. the purifying processing device of environment-friendly type organic exhaust gas according to claim 8, it is characterised in that:The absorption cell
Be internally provided with organic exhaust gas absorber layer, ultrasonic transducer, rabbling mechanism, the organic exhaust gas absorber layer is located at institute
The top for the ultrasonic transducer stated, the rabbling mechanism are located in the organic exhaust gas absorber layer;
The rabbling mechanism includes shaft, electric rotating machine, several flabellums, one end of the shaft and the electric rotating
Machine is connected, and the flabellum is both secured in the shaft, between the shaft and organic exhaust gas absorber layer bottom
Distance is 1.1-1.5 times of flabellum width;
The absorption cell be equipped with three times air inlet, three times exhaust outlet, flow back gas port three times, the air inlet three times passes through
Pipeline is connected with the secondary exhaust mouth, and the gas port of reflux three times is located at the top of the absorption cell, and passes through pipe
Road is connected with the secondary air inlet mouth, and the exhaust outlet three times is located at the lower section of the gas port that flows back three times.
10. the purifying processing device of the environment-friendly type organic exhaust gas according to any one of claim 7-9, it is characterised in that:
The mixed liquor of the inorganic absorbent powder and water, the quality of the inorganic absorbent powder and water are flowed into inlet
Than being 1:(4-10);The organic absorbent liquid is flowed into the secondary inlet;The organic exhaust gas absorber layer is
The organic exhaust gas absorbent.
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