CN108691401A - A kind of UV fluorine carbon plate - Google Patents

A kind of UV fluorine carbon plate Download PDF

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Publication number
CN108691401A
CN108691401A CN201710135145.6A CN201710135145A CN108691401A CN 108691401 A CN108691401 A CN 108691401A CN 201710135145 A CN201710135145 A CN 201710135145A CN 108691401 A CN108691401 A CN 108691401A
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CN
China
Prior art keywords
fluorine carbon
photocurings
carbon plate
fibre reinforced
roller coating
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710135145.6A
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Chinese (zh)
Inventor
刘伟芹
宋正红
李会平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Rare Talent's Development In Science And Technology Co Ltd
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Tianjin Rare Talent's Development In Science And Technology Co Ltd
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Application filed by Tianjin Rare Talent's Development In Science And Technology Co Ltd filed Critical Tianjin Rare Talent's Development In Science And Technology Co Ltd
Priority to CN201710135145.6A priority Critical patent/CN108691401A/en
Publication of CN108691401A publication Critical patent/CN108691401A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0871Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/141Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of concrete
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2251Oxides; Hydroxides of metals of chromium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of UV fluorine carbon plate be using special fibre reinforced cement board as base material, surface through being polished for a plurality of times, permeating, after waterproof roller coating or showering colour UV F-C paints made of ultraviolet light solidification with the novel UV fluorine carbon plate such as water-fast, fire resisting, resistant, scratch resistance, rub resistance, impact resistance, UV resistant, weather-proof.Reticular structure made of UV fluororine-carbon coatings are the acrylate being modified by fluoric ether and monomer is cross-linked with each other, coating is fine and close, and coating surface tension is low, and anti-pollution is not easy dust accumulation.It since F-C key bond energys are strong, is difficult to be broken under the action of light and heat, UV degradation, anti-powdering under rugged environment, keeps inherent colour and gloss, be not in explosion, peel off, there is the weatherability of overlength, service life to be up to 25 years or more.Fluorine atom volume is big in fluorocarbon chain section and tight C-C chains, in the shape of a spiral structure, forms very strong space Folding-Screen and covers effect, any atom or atomic group are all difficult intrusion, show high chemical inertness, have fabulous acid and alkali resistance and solvent corrosion performance.

Description

A kind of UV fluorine carbon plate
One, technical field
The present invention relates to a kind of UV fluorine carbon plates, have water-fast, fire resisting, resistant, scratch resistance, rub resistance, acid-alkali-corrosive-resisting, resistance to punching It hits, UV resistant, the characteristics such as weather-proof, it is related decorating outer wall of building plank.
Two, background technology
A kind of F-C paint that UV fluorine carbon plate uses refers to the coating using fluororesin as main film forming substance;Also known as F-C paint, Fluoro coatings, fluorine resin coating etc..Among various coating, fluorine resin coating is since the fluorine element electronegativity of introducing is big, carbon-fluorine bond Can be strong, there are especially advantageous properties.Weatherability, heat resistance, lower temperature resistance, chemical resistance, and with uniqueness Non-stick and low abrasiveness.By the fast development of decades, fluoro coatings are in building, chemical industry, electric appliance and electronic industry, machine Tool industry, aerospace industries, household supplies every field be used widely.As after acrylic coating, polyurethane painting After the high performance coating such as material, organosilicon coating, the highest coating brand of comprehensive performance.Currently, using more extensive fluorine tree Grease coating material mainly has the three categories type such as PTFE, PVDF, PEVE, and F-C paint has following several big excellent compared with other traditional coatings Point:(1) excellent Corrosion Protection-has benefited from chemical substances and a variety ofization such as fabulous chemical inertness, paint film acid and alkali resistance, salt Solvent is learned, protective barrier is provided for base material;The paint film is tough and tensile-and case hardness height, impact resistance, anti-buckling, wearability be good, display Go out splendid physical mechanical property.(2) non-maintaining, automatically cleaning-fluororine-carbon coating has extremely low surface energy, surface dirt that can pass through Rainwater is self-cleaning, fabulous hydrophobicity (maximum water absorption rate is less than 5%) and reprimand oil, minimum friction coefficient (0.15-0.17), no Meeting non-dust absorption and non-fouling, soil resistance are good.(3) strong adhesion-the plastics such as the metals such as copper, stainless steel, polyester, polyurethane, vinyl chloride, All there is its excellent adhesive force, basic display to go out preferably to invest the characteristic of any material on the surfaces such as cement, composite material.Height decoration Property --- in 60 degree of gloss meters, 80% or more high glaze can be reached.(4) containing a large amount of in overlength weatherability-coating F--C keys, determine its superpower stability, not dusting, colour-fast, and service life is up to 20 years, is had and is applied than any other class Expect more excellent performance.Excellent application property-bi-component package, storage period are long, easy for construction.
A kind of special fibre reinforced cement board that UV fluorine carbon plate is voluntarily developed using company as base material, surface through being polished for a plurality of times, It, will be in advance through being derived from lithotome color made of polychrome printing after two layers of UV fluorine carbon priming paint of roller coating or showering after infiltration, waterproof With the UV fluorocarbon films of decorative pattern, the transfer of UV fluorocarbon films is solidificated on base material by caloric transfer printing technology, then two layers of UV of roller coating or showering Fluorocarbon varnish passes through novel inorganic flame-proof finishing plate made of ten three times ultraviolet light solidification.
Three, invention content
It is an object of the invention to using use be using special fibre reinforced cement board as base material, surface through being polished for a plurality of times, Infiltration, after waterproof, roller coating or showering colour UV F-C paints are made of ultraviolet light solidification with water-fast, fire resisting, resistant, resistance to Scrape, rub resistance, acid-alkali-corrosive-resisting, impact resistance, UV resistant, the novel UV fluorine carbon plate such as weather-proof.UV fluororine-carbon coatings are by fluoroalkane Reticular structure made of the acrylate and monomer that hydrocarbon is modified are cross-linked with each other, coating is fine and close, and coating surface tension is low, anti-pollution, It is not easy dust accumulation.Since F-C key bond energys are strong, be difficult to be broken under the action of light and heat, under rugged environment UV degradation, Anti-powdering keeps inherent colour and gloss, is not in explosion, peels off, and has the weatherability of overlength, service life to be up to 25 years or more. Fluorine atom volume is big in fluorocarbon chain section and tight C-C chains, and structure, forms very strong space Folding-Screen and cover effect in the shape of a spiral, Any atom or atomic group are all difficult intrusion, show high chemical inertness, have fabulous acid and alkali resistance and solvent corrosion Energy.
According to a kind of UV fluorine carbon plate in summary, it is characterised in that:Special fibre reinforced cement board is with preferred natural Reinforcing fiber, high strength portland cement, flyash, SILICA FUME, additive composition pass through compression moulding, and density domination is 1.4 ~1.6g/cm3
According to a kind of UV fluorine carbon plate in summary, it is characterised in that:Colored F-C paint is mainly made of following proportioning:
According to a kind of UV fluorine carbon plate in summary, it is characterised in that:A kind of UV fluorine carbon plate preparation process is:A. prefabricated first Special fibre reinforced cement board, according to a certain ratio by natural reinforcing fiber, high strength portland cement, flyash, SILICA FUME, add Agent etc. is added to be sufficiently mixed, b. is made after the saturated vapor of 7000 tons of press compression mouldings, 10 atmospheric pressure conserves 10-20d Special fibre reinforced cement board is used as the substrate of UV fluorine carbon plates.Substrate automatic wire charging → bottom water-protected enclosure → UV light is solid Finely polishing → plate face infiltration closing → UV photocurings → two layers of the roller coating putty → UV photocurings → fine polishing of change → plate surface The roller coating of → plate face, two layers of priming paint of showering → UV photocurings → fine polishing → transfer height emulation UV fluorocarbon films → UV photocurings → rolling Classify stacking → sampling Detection → qualification of (showering) two layers of finishing coat → UV photocurings → appearance test → overlay film is protected → is applied to be put in storage.
The present invention is a kind of UV fluorine carbon plate, has water-fast, fire resisting, resistant, scratch resistance, rub resistance, acid-alkali-corrosive-resisting, resistance to punching It hits, UV resistant, the characteristics such as weather-proof, it is related decorating outer wall of building plank.
Four, specific implementation mode
Embodiment 1
It is base material that a kind of UV fluorine carbon plate of the present invention, which is special fibre reinforced cement board, surface through being polished for a plurality of times, permeating, After waterproof, roller coating or showering colour UV F-C paints are made up of ultraviolet light solidification.Wherein special fibre reinforced cement board is with excellent Natural reinforcing fiber, high strength portland cement, flyash, SILICA FUME, the additive composition of choosing pass through compression moulding, density control System is in 1.4g/cm3.Colored F-C paint is mainly formed according to following quality:
Preparation process is:A. special fibre reinforced cement board prefabricated first, according to a certain ratio by natural reinforcing fiber, height Strength silicate cement, flyash, SILICA FUME, additive etc. are sufficiently mixed, and b. is in 7000 tons of press compression mouldings, 10 atmospheric pressure Saturated vapor maintenance 10d after special fibre reinforced cement board has been made, be used as the substrate of UV fluorine carbon plates.On substrate is automatic Finely polishing → plate face permeates closing → UV photocurings → two layers of roller coating to line → bottom water-protected enclosure → UV photocurings → plate surface Putty → UV photocurings → fine polishing → plate face roller coating, two layers of priming paint of showering → UV photocurings → fine polishing → transfer Gao Fang The true colored F-C paint → UV photocurings → appearance test of UV fluorocarbon films → UV photocurings → two layers of roller coating (showering) → overlay film protection → classification stacking → sampling Detection → qualification storage.
Embodiment 2
It is base material that a kind of UV fluorine carbon plate of the present invention, which is special fibre reinforced cement board, surface through being polished for a plurality of times, permeating, After waterproof, roller coating or showering colour UV F-C paints are made up of ultraviolet light solidification.Wherein special fibre reinforced cement board is with excellent Natural reinforcing fiber, high strength portland cement, flyash, SILICA FUME, the additive composition of choosing pass through compression moulding, density control System is in 1.5g/cm3.Colored F-C paint is mainly formed according to following quality:
Preparation process is:A. special fibre reinforced cement board prefabricated first, according to a certain ratio by natural reinforcing fiber, height Strength silicate cement, flyash, SILICA FUME, additive etc. are sufficiently mixed, and b. is in 7000 tons of press compression mouldings, 10 atmospheric pressure Saturated vapor maintenance 20d after special fibre reinforced cement board has been made, be used as the substrate of UV fluorine carbon plates.On substrate is automatic Finely polishing → plate face permeates closing → UV photocurings → two layers of roller coating to line → bottom water-protected enclosure → UV photocurings → plate surface Putty → UV photocurings → fine polishing → plate face roller coating, two layers of priming paint of showering → UV photocurings → fine polishing → transfer Gao Fang The true colored F-C paint → UV photocurings → appearance test of UV fluorocarbon films → UV photocurings → two layers of roller coating (showering) → overlay film protection → classification stacking → sampling Detection → qualification storage.
Embodiment 3
It is base material that a kind of UV fluorine carbon plate of the present invention, which is special fibre reinforced cement board, surface through being polished for a plurality of times, permeating, After waterproof, roller coating or showering colour UV F-C paints are made up of ultraviolet light solidification.Wherein special fibre reinforced cement board is with excellent Natural reinforcing fiber, high strength portland cement, flyash, SILICA FUME, the additive composition of choosing pass through compression moulding, density control System is in 1.6g/cm3.Colored F-C paint is mainly formed according to following quality:
Preparation process is:A. special fibre reinforced cement board prefabricated first, according to a certain ratio by natural reinforcing fiber, height Strength silicate cement, flyash, SILICA FUME, additive etc. are sufficiently mixed, and b. is in 7000 tons of press compression mouldings, 10 atmospheric pressure Saturated vapor maintenance 15d after special fibre reinforced cement board has been made, be used as the substrate of UV fluorine carbon plates.On substrate is automatic Finely polishing → plate face permeates closing → UV photocurings → two layers of roller coating to line → bottom water-protected enclosure → UV photocurings → plate surface Putty → UV photocurings → fine polishing → plate face roller coating, two layers of priming paint of showering → UV photocurings → fine polishing → transfer Gao Fang The true colored F-C paint → UV photocurings → appearance test of UV fluorocarbon films → UV photocurings → two layers of roller coating (showering) → overlay film protection → classification stacking → sampling Detection → qualification storage.
Three of the above physical property is as follows:
Project Measured value 1 Measured value 2 Measured value 3
Full water flexural strength MPa 16 17 18
Moisture content % 10 9 8
Impact strength KJ/ ㎡ 2.8 2.9 3.0
After 75 Frozen-thawed cycleds Crack-free, layering Crack-free, layering Crack-free, layering
Acid resistance 168h 0.7 0.7 0.7
Alkali resistance 168h It is qualified It is qualified It is qualified
Water resistance 168h It is qualified It is qualified It is qualified
Solvent resistant Ca Shixing >100 times It is qualified It is qualified It is qualified
Combustibility A1 A1 A1

Claims (4)

1. a kind of UV fluorine carbon plate, it is characterised in that:It is using special fibre reinforced cement board as base material, surface is through being polished for a plurality of times, oozing Thoroughly, after waterproof, roller coating or showering colour UV F-C paints are made up of ultraviolet light solidification.
2. a kind of UV fluorine carbon plate according to claim 1, it is characterised in that:Special fibre reinforced cement board is with preferred day Right reinforcing fiber, high strength portland cement, flyash, SILICA FUME, additive composition pass through compression moulding, and density domination exists 1.4~1.6g/cm3
3. a kind of UV fluorine carbon plate according to claim 1, it is characterised in that:Colored F-C paint is mainly made of following proportioning:
4. a kind of UV fluorine carbon plate according to claim 1, it is characterised in that:A kind of UV fluorine carbon plate preparation process is:A. first Prefabricated special fibre reinforced cement board, according to a certain ratio by natural reinforcing fiber, high strength portland cement, flyash, micro- silicon Powder, additive etc. are sufficiently mixed, and b. makes after the saturated vapor of 7000 tons of press compression mouldings, 10 atmospheric pressure conserves 10-20d At special fibre reinforced cement board, it is used as the substrate of UV fluorine carbon plates.Substrate automatic wire charging → bottom water-protected enclosure → UV Fine polishing → plate face infiltration closing → UV photocurings → two layers of the roller coating putty → UV photocurings → fine of photocuring → plate surface Polishing → plate face roller coating, two layers of priming paint of showering → UV photocurings → fine polishing → transfer height emulation UV fluorocarbon films → UV photocurings Colored F-C paint → UV photocurings → the appearance test → overlay film is protected → of two layers of → roller coating (showering) is classified stacking → sampling Detection → qualification storage.
CN201710135145.6A 2017-03-08 2017-03-08 A kind of UV fluorine carbon plate Pending CN108691401A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710135145.6A CN108691401A (en) 2017-03-08 2017-03-08 A kind of UV fluorine carbon plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710135145.6A CN108691401A (en) 2017-03-08 2017-03-08 A kind of UV fluorine carbon plate

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CN108691401A true CN108691401A (en) 2018-10-23

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1337372A (en) * 2000-08-08 2002-02-27 北新建材(集团)有限公司 Vacuum extrusion process and equipment of fiber reinforced cement board
MXPA02010523A (en) * 2000-04-25 2003-03-10 Tarkett Sommer Sa Method for producing floor finish and wall finish with differential gloss decoration effect and resulting products.
CN101117484A (en) * 2007-08-28 2008-02-06 深圳市广田环保涂料有限公司 Metal-pseudo fluorine-carbon paint for building exterior wall and method for making same
CN101736853A (en) * 2009-12-11 2010-06-16 中国建筑材料科学研究总院 Fibre cement plate with high doping quantity of fly ash
CN103255889A (en) * 2013-04-24 2013-08-21 霍志明 Novel fluorine carbon plate
CN103321376A (en) * 2013-06-20 2013-09-25 四川航天拓鑫玄武岩实业有限公司 Reinforced foam cement insulation and decoration integrated plate and manufacture method thereof
CN104231858A (en) * 2014-09-18 2014-12-24 江苏海晟涂料有限公司 Water-based fluoride varnish and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA02010523A (en) * 2000-04-25 2003-03-10 Tarkett Sommer Sa Method for producing floor finish and wall finish with differential gloss decoration effect and resulting products.
CN1337372A (en) * 2000-08-08 2002-02-27 北新建材(集团)有限公司 Vacuum extrusion process and equipment of fiber reinforced cement board
CN101117484A (en) * 2007-08-28 2008-02-06 深圳市广田环保涂料有限公司 Metal-pseudo fluorine-carbon paint for building exterior wall and method for making same
CN101736853A (en) * 2009-12-11 2010-06-16 中国建筑材料科学研究总院 Fibre cement plate with high doping quantity of fly ash
CN103255889A (en) * 2013-04-24 2013-08-21 霍志明 Novel fluorine carbon plate
CN103321376A (en) * 2013-06-20 2013-09-25 四川航天拓鑫玄武岩实业有限公司 Reinforced foam cement insulation and decoration integrated plate and manufacture method thereof
CN104231858A (en) * 2014-09-18 2014-12-24 江苏海晟涂料有限公司 Water-based fluoride varnish and preparation method thereof

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