CN108691240A - A kind of preparation method of electrostatic prevented corrugated paper plate - Google Patents
A kind of preparation method of electrostatic prevented corrugated paper plate Download PDFInfo
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- CN108691240A CN108691240A CN201810367748.3A CN201810367748A CN108691240A CN 108691240 A CN108691240 A CN 108691240A CN 201810367748 A CN201810367748 A CN 201810367748A CN 108691240 A CN108691240 A CN 108691240A
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- corrugated paper
- paper plate
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of preparation methods of electrostatic prevented corrugated paper plate, in corrugated board surface coating substrate glue, after drying again on glue-line be coated with anti-static coatings to get;The substrate glue is made of carragheen, bentonite, cornstarch, citric acid, polylactic acid and water;The anti-static coatings are made of graphene, ethoxylated alkyl ammonium sulfate, epoxy resin, polyacrylamide, sodium alkyl benzene sulfonate, diatomite, antifoaming agent, levelling agent and water.The present invention is first coated with jelly using the method for coating and is coated anti-static coatings using graphene and ethoxylated alkyl ammonium sulfate collaboration as antistatic agent, the suction-operated using jelly enhancing antistatic agent on paper surface, to enhance anti-static electrification.
Description
Technical field
The invention belongs to field of packaging material, and in particular to a kind of preparation method of electrostatic prevented corrugated paper plate.
Background technology
Packaging industry is after the pros and cons course that experienced plastics, glass, metal material, and paper products have its wide finally
Market is played, corrugated case is a kind of important transportation package holds, its manufacture craft is roughly divided into combined corrugated board, print
Brush, in conjunction with etc.;It is made of fluting medium and boxboard respectively.Corrugated board is used as most representative environmentally friendly packing material institute
The container of making, it has also become most widely used material in all packagings, it applies to during the entire process of storing and transporting, existing
Very important effect is played in the commodity packaging in generation.
Along with the raising of the development and the level of consumption of society, commodity outer packing is more and more taken seriously.Therefore corrugated case
As a kind of goods packing container, not only to ensure transporting safely for cargo, but also also need to publicity beautification commodity, promote pin
It sells, increases the function of surcharge.In public idea, corrugated case is the production for needing to serve special performance requirement
Product, so moisture-proof in needs, the outlet of the extra packages product such as mould proof and antistatic more uses iron, plastics, glass and wood
Packing box processed etc., and these packaging for corrugated board, raw material are more expensive and waste is not disposable, the feature of environmental protection compared with
Difference;Occupied space is big when storage and transportation, difficult with post-processing;Wooden case outlet need to fumigate.To solve this problem, insider's research
With develop functional tile corrugated paper board, and have the packaging of the product applied to all kinds of functional property demands in mind.
Currently, with computer and household electrical appliance fast development and popularizing, the application of integrated circuit is also more and more extensive, close
Intensity also goes up very fast, and therefore, the harm in terms of electrostatic is also just more exposed to attention, carries the corrugated board of electrostatic function
Also it receives more and more attention and payes attention to.
Invention content
The object of the present invention is to provide a kind of preparation methods of electrostatic prevented corrugated paper plate.
A kind of preparation method of electrostatic prevented corrugated paper plate, in corrugated board surface coating substrate glue, again in glue-line after drying
Upper coating anti-static coatings to get;
The substrate glue is made of carragheen, bentonite, cornstarch, citric acid, polylactic acid and water;
The anti-static coatings are by graphene, ethoxylated alkyl ammonium sulfate, epoxy resin, polyacrylamide, benzene sulfonamide
Sour sodium, diatomite, antifoaming agent, levelling agent and water are made.
Further, the dosage of each component is in parts by weight in the substrate glue:1-3 parts of carragheen, bentonite
0.5-1 parts, 2-5 parts of cornstarch, 0.2-0.4 parts of citric acid, 0.1-0.5 parts of polylactic acid, 100 parts of water.
Further, the preparation method of the substrate glue, includes the following steps:
Step 1, carragheen, cornstarch and polylactic acid are added to and aqueous solution is made in water;
Step 2, bentonite is dispersed in water and dispersion liquid is made;
Step 3, the aqueous solution of step 1 and the dispersion liquid of step 2 are mixed, citric acid are added, be uniformly mixed to get.
Further, the dosage of each component is in parts by weight in the anti-static coatings:1-3 parts of graphene, ethyoxyl
Change 2-5 parts of alkylsurfuric acid ammonium, 20-30 parts of epoxy resin, 2-5 parts of polyacrylamide, 1-3 parts of sodium alkyl benzene sulfonate, diatomite
0.5-1.2 parts, 0.1-0.3 parts of antifoaming agent, 30-50 parts of water.
Further, the preparation method of the anti-static coatings, includes the following steps:
Step 1, epoxy resin, polyacrylamide, diatomite are added in water, is stirred, is uniformly mixed;
Step 2, graphene, ethoxylated alkyl ammonium sulfate and sodium alkyl benzene sulfonate are added under agitation, continues to stir;
Step 3, be added antifoaming agent under agitation, grinding to get.
Further, the coating weight of substrate glue is 4-6g/m2, the coating weight of anti-static coatings is 10-14g/m2。
The present invention is first applied using graphene and ethoxylated alkyl ammonium sulfate collaboration as antistatic agent using the method for coating
Cloth jelly is coated anti-static coatings, the suction-operated using jelly enhancing antistatic agent on paper surface, to enhance antistatic
Effect.
Specific implementation mode
Embodiment 1
A kind of preparation method of electrostatic prevented corrugated paper plate applies on glue-line in corrugated board surface coating substrate glue after drying again
Cloth anti-static coatings to get.The coating weight of substrate glue is 4g/m2, the coating weight of anti-static coatings is 10g/m2。
The dosage of each component is in parts by weight in the substrate glue:1 part of carragheen, 0.5 part of bentonite, cornstarch
2 parts, 0.2 part of citric acid, 0.1 part of polylactic acid, 100 parts of water.
The dosage of each component is in parts by weight in the anti-static coatings:1 part of graphene, ethoxylated alkyl ammonium sulfate
2 parts, 20 parts of epoxy resin, 2 parts of polyacrylamide, 1 part of sodium alkyl benzene sulfonate, 0.5 part of diatomite, 0.1 part of antifoaming agent, water 30
Part.
Wherein, the preparation method of the substrate glue includes the following steps:
Step 1, carragheen, cornstarch and polylactic acid are added to and aqueous solution is made in water;
Step 2, bentonite is dispersed in water and dispersion liquid is made;
Step 3, the aqueous solution of step 1 and the dispersion liquid of step 2 are mixed, citric acid are added, be uniformly mixed to get.
The preparation method of the anti-static coatings, includes the following steps:
Step 1, epoxy resin, polyacrylamide, diatomite are added in water, is stirred, is uniformly mixed;
Step 2, graphene, ethoxylated alkyl ammonium sulfate and sodium alkyl benzene sulfonate are added under agitation, continues to stir;
Step 3, be added antifoaming agent under agitation, grinding to get.
Gained cardboard is under the conditions of 25 DEG C, relative humidity 65%, bursting strength 1156kPa, and side pressure strength is 398 kPa, is put down
Compressive Strength is 475 kPa, and Punctured Strength 4.35J, antistatic intensity is 12.7 × 103Ω.After rubbed 100 times, antistatic
Intensity is 13.7 × 103Ω。
Embodiment 2
A kind of preparation method of electrostatic prevented corrugated paper plate applies on glue-line in corrugated board surface coating substrate glue after drying again
Cloth anti-static coatings to get.The coating weight of substrate glue is 5g/m2, the coating weight of anti-static coatings is 12g/m2。
The dosage of each component is in parts by weight in the substrate glue:2 parts of carragheen, 0.5 part of bentonite, cornstarch
3 parts, 0.3 part of citric acid, 0.3 part of polylactic acid, 100 parts of water.
The dosage of each component is in parts by weight in the anti-static coatings:2 parts of graphene, ethoxylated alkyl ammonium sulfate
4 parts, 23 parts of epoxy resin, 4 parts of polyacrylamide, 2 parts of sodium alkyl benzene sulfonate, 0.7 part of diatomite, 0.2 part of antifoaming agent, water 40
Part.
Wherein, the preparation method of the substrate glue includes the following steps:
Step 1, carragheen, cornstarch and polylactic acid are added to and aqueous solution is made in water;
Step 2, bentonite is dispersed in water and dispersion liquid is made;
Step 3, the aqueous solution of step 1 and the dispersion liquid of step 2 are mixed, citric acid are added, be uniformly mixed to get.
The preparation method of the anti-static coatings, includes the following steps:
Step 1, epoxy resin, polyacrylamide, diatomite are added in water, is stirred, is uniformly mixed;
Step 2, graphene, ethoxylated alkyl ammonium sulfate and sodium alkyl benzene sulfonate are added under agitation, continues to stir;
Step 3, be added antifoaming agent under agitation, grinding to get.
Gained cardboard is under the conditions of 25 DEG C, relative humidity 65%, bursting strength 1217kPa, and side pressure strength is 403 kPa, is put down
Compressive Strength is 482 kPa, and Punctured Strength 4.43J, antistatic intensity is 12.6 × 103Ω.After rubbed 100 times, antistatic
Intensity is 13.5 × 103Ω。
Embodiment 3
A kind of preparation method of electrostatic prevented corrugated paper plate applies on glue-line in corrugated board surface coating substrate glue after drying again
Cloth anti-static coatings to get.The coating weight of substrate glue is 6g/m2, the coating weight of anti-static coatings is 14g/m2。
The dosage of each component is in parts by weight in the substrate glue:2 parts of carragheen, 0.7 part of bentonite, cornstarch
4 parts, 0.3 part of citric acid, 0.2 part of polylactic acid, 100 parts of water.
The dosage of each component is in parts by weight in the anti-static coatings:2 parts of graphene, ethoxylated alkyl ammonium sulfate
4 parts, 25 parts of epoxy resin, 4 parts of polyacrylamide, 2 parts of sodium alkyl benzene sulfonate, 0.8 part of diatomite, 0.2 part of antifoaming agent, water 40
Part.
Wherein, the preparation method of the substrate glue includes the following steps:
Step 1, carragheen, cornstarch and polylactic acid are added to and aqueous solution is made in water;
Step 2, bentonite is dispersed in water and dispersion liquid is made;
Step 3, the aqueous solution of step 1 and the dispersion liquid of step 2 are mixed, citric acid are added, be uniformly mixed to get.
The preparation method of the anti-static coatings, includes the following steps:
Step 1, epoxy resin, polyacrylamide, diatomite are added in water, is stirred, is uniformly mixed;
Step 2, graphene, ethoxylated alkyl ammonium sulfate and sodium alkyl benzene sulfonate are added under agitation, continues to stir;
Step 3, be added antifoaming agent under agitation, grinding to get.
Gained cardboard is under the conditions of 25 DEG C, relative humidity 65%, bursting strength 1213kPa, and side pressure strength is 387 kPa, is put down
Compressive Strength is 465 kPa, and Punctured Strength 4.29J, antistatic intensity is 12.1 × 103Ω.After rubbed 100 times, antistatic
Intensity is 13.4 × 103Ω。
Claims (6)
1. a kind of preparation method of electrostatic prevented corrugated paper plate, it is characterised in that:In corrugated board surface coating substrate glue, after drying
Again on glue-line be coated with anti-static coatings to get;
The substrate glue is made of carragheen, bentonite, cornstarch, citric acid, polylactic acid and water;
The anti-static coatings are by graphene, ethoxylated alkyl ammonium sulfate, epoxy resin, polyacrylamide, benzene sulfonamide
Sour sodium, diatomite, antifoaming agent, levelling agent and water are made.
2. the preparation method of electrostatic prevented corrugated paper plate according to claim 1, it is characterised in that:Each group in the substrate glue
Point dosage be in parts by weight:1-3 parts of carragheen, 0.5-1 parts of bentonite, 2-5 parts of cornstarch, citric acid 0.2-
0.4 part, 0.1-0.5 parts of polylactic acid, 100 parts of water.
3. the preparation method of electrostatic prevented corrugated paper plate according to claim 1, it is characterised in that:The preparation of the substrate glue
Method includes the following steps:
Step 1, carragheen, cornstarch and polylactic acid are added to and aqueous solution is made in water;
Step 2, bentonite is dispersed in water and dispersion liquid is made;
Step 3, the aqueous solution of step 1 and the dispersion liquid of step 2 are mixed, citric acid are added, be uniformly mixed to get.
4. the preparation method of electrostatic prevented corrugated paper plate according to claim 1, it is characterised in that:In the anti-static coatings
The dosage of each component is in parts by weight:1-3 parts of graphene, 2-5 parts of ethoxylated alkyl ammonium sulfate, 20-30 parts of epoxy resin,
2-5 parts of polyacrylamide, 1-3 parts of sodium alkyl benzene sulfonate, 0.5-1.2 parts of diatomite, 0.1-0.3 parts of antifoaming agent, 30-50 parts of water.
5. the preparation method of electrostatic prevented corrugated paper plate according to claim 1, it is characterised in that:The anti-static coatings
Preparation method includes the following steps:
Step 1, epoxy resin, polyacrylamide, diatomite are added in water, is stirred, is uniformly mixed;
Step 2, graphene, ethoxylated alkyl ammonium sulfate and sodium alkyl benzene sulfonate are added under agitation, continues to stir;
Step 3, be added antifoaming agent under agitation, grinding to get.
6. the preparation method of electrostatic prevented corrugated paper plate according to claim 1, it is characterised in that:The coating weight of substrate glue is
4-6g/m2, the coating weight of anti-static coatings is 10-14g/m2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810367748.3A CN108691240A (en) | 2018-04-23 | 2018-04-23 | A kind of preparation method of electrostatic prevented corrugated paper plate |
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| CN201810367748.3A CN108691240A (en) | 2018-04-23 | 2018-04-23 | A kind of preparation method of electrostatic prevented corrugated paper plate |
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| CN108691240A true CN108691240A (en) | 2018-10-23 |
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| CN201810367748.3A Pending CN108691240A (en) | 2018-04-23 | 2018-04-23 | A kind of preparation method of electrostatic prevented corrugated paper plate |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109403152A (en) * | 2018-11-22 | 2019-03-01 | 慈溪市圣保彩印包装有限公司 | A kind of corrugated board with effectiveness |
| CN109514867A (en) * | 2018-11-29 | 2019-03-26 | 南通理工学院 | Three-dimensional model data conversion device with 3D control unit |
| CN109808243A (en) * | 2019-02-28 | 2019-05-28 | 国腾彩色纸品(鹤山)有限公司 | A kind of corrugated paper plasticizing process |
| CN110258186A (en) * | 2019-06-28 | 2019-09-20 | 安徽紫江喷铝环保材料有限公司 | It is a kind of brilliant to bore credit and dodge laser anti-counterfeiting packaging material and its manufacturing method |
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| CN101418533A (en) * | 2008-12-08 | 2009-04-29 | 江南大学 | Electrostatic prevented corrugated paper plate coating and preparation method thereof |
| CN103193017A (en) * | 2013-04-27 | 2013-07-10 | 太仓环亚包装制品有限公司 | Moisture-proof anti-static corrugated carton |
| CN104611990A (en) * | 2014-12-18 | 2015-05-13 | 瑞辰星生物技术（广州）有限公司 | A surface sizing agent for papermaking, and a papermaking method for improving paper strength and water resistance |
| CN105542593A (en) * | 2016-02-03 | 2016-05-04 | 滁州卷烟材料厂 | Anti-static corrugated carton |
| CN106010091A (en) * | 2016-05-25 | 2016-10-12 | 中国科学院宁波材料技术与工程研究所 | Anticorrosive and conductive coating and preparation method thereof |
-
2018
- 2018-04-23 CN CN201810367748.3A patent/CN108691240A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418533A (en) * | 2008-12-08 | 2009-04-29 | 江南大学 | Electrostatic prevented corrugated paper plate coating and preparation method thereof |
| CN103193017A (en) * | 2013-04-27 | 2013-07-10 | 太仓环亚包装制品有限公司 | Moisture-proof anti-static corrugated carton |
| CN104611990A (en) * | 2014-12-18 | 2015-05-13 | 瑞辰星生物技术（广州）有限公司 | A surface sizing agent for papermaking, and a papermaking method for improving paper strength and water resistance |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109403152A (en) * | 2018-11-22 | 2019-03-01 | 慈溪市圣保彩印包装有限公司 | A kind of corrugated board with effectiveness |
| CN109403152B (en) * | 2018-11-22 | 2022-07-01 | 宁波依森纸制品有限公司 | Corrugated board with electromagnetic shielding effect |
| CN109514867A (en) * | 2018-11-29 | 2019-03-26 | 南通理工学院 | Three-dimensional model data conversion device with 3D control unit |
| CN109808243A (en) * | 2019-02-28 | 2019-05-28 | 国腾彩色纸品(鹤山)有限公司 | A kind of corrugated paper plasticizing process |
| CN110258186A (en) * | 2019-06-28 | 2019-09-20 | 安徽紫江喷铝环保材料有限公司 | It is a kind of brilliant to bore credit and dodge laser anti-counterfeiting packaging material and its manufacturing method |
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Application publication date: 20181023 |