CN108689456A - Double catalyst purifying apparatus and double catalyst food purification equipments - Google Patents

Double catalyst purifying apparatus and double catalyst food purification equipments Download PDF

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Publication number
CN108689456A
CN108689456A CN201810731656.9A CN201810731656A CN108689456A CN 108689456 A CN108689456 A CN 108689456A CN 201810731656 A CN201810731656 A CN 201810731656A CN 108689456 A CN108689456 A CN 108689456A
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water
air
double catalyst
purifying apparatus
catalyst
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CN108689456B (en
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欧锦锋
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FOSHAN SHUNDE HIGOLD HARDWARE PRODUCTS Co Ltd
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FOSHAN SHUNDE HIGOLD HARDWARE PRODUCTS Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/06Hydroxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46185Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3223Single elongated lamp located on the central axis of a turbular reactor

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Plant Pathology (AREA)
  • Hydrology & Water Resources (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Toxicology (AREA)
  • Physical Water Treatments (AREA)
  • Catalysts (AREA)

Abstract

The present invention provides double catalyst purifying apparatus, including shell, water catalyst device and photocatalyst device;Purify cavity is equipped in shell, water catalyst device and photocatalyst device are mounted in purify cavity, and shell is equipped with the water passage of connection purify cavity;Water catalyst device includes electrode unit, electrode unit is alternately arranged by several vertically arranged anode plate and cathode plate and is constituted, double catalyst catalytic domains are formed between anode plate and adjacent cathode plate, water catalyst device can carry out electro-catalysis after being powered to the water body of double catalyst catalytic domains;Photocatalyst device is used to carry out photocatalysis to the water body of double catalyst catalytic domains after being powered;The present invention provides double catalyst food purification equipments, using above-mentioned double catalyst purifying apparatus.Double catalyst food purification equipments of the present invention, safe, cleaning effect is reliable and stable;Save electric energy and water resource;It is used convenient for user installation;Double catalyst food purification equipments of the present invention, can thoroughly clean fruit and vegetable food.

Description

Double catalyst purifying apparatus and double catalyst food purification equipments
Technical field
The present invention relates to food purification apparatus field, refers in particular to double catalyst purifying apparatus and the purification of double catalyst food is set It is standby.
Background technology
The pollutants such as pesticide, hormone, dust and germ can be remained on fruit and vegetable food surface on the market, fruit and vegetable food is clear It is clean that the health that can influence people is eaten not unclean, therefore occur the food cleaning for cleaning fruit and vegetable food on the market Device, common food cleaning device can be divided into following a few classes:Mechanical agitation type, flow flushing type, ultrasonic type and ozone disappear Malicious formula.Mechanical agitation type is mechanically to be stirred to the fruit and vegetable food in clear water, makes fruit and vegetable food surface Dirt is fallen, and flow flushing type is rinsed using high-velocity flow fruit and vegetable food, and above two food cleaning device is to food The damage of object is larger, be easy to cause the nutrition leak of food, and cleaning effect is bad;And fruit and vegetable food is carried out using ultrasonic wave Clean ultrasonic type food cleaning device causes to generate noise dirt due to needing to send out high-frequency ultrasonic during cleaning Dye;And ozone sterilization-type is the dirt using ozone oxidation fruit and vegetable food surface, to play cleaning effect to fruit and vegetable food, But since ozone concentration is not easy control, and solubility is smaller in water for ozone, and extra ozone can be discharged into air, be inhaled by human body Human body can be damaged after entering.
In order to overcome the defect of above-mentioned food cleaning device, occurs hydroxyl oxidation-type food cleaning device on the market, be somebody's turn to do Hydroxyl generating means is provided on kind food cleaning device, when food cleaning device operates, hydroxyl generating means passes through electrolysis side Formula makes water body generate hydroxyl radical free radical, is aoxidized to the pollutant on fruit and vegetable food surface using hydroxyl radical free radical, to fruit Vegetable product plays cleaning action, but is limited by the prior art, the hydroxyl radical free radical generated in hydroxyl generating means unit volume Negligible amounts cause the cleaning effect of this kind of food cleaning device undesirable.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of double catalyst purifying apparatus, by combining electricity Catalysis and photocatalysis increase the content of water body hydroxyl radical free radical, to improve the cleaning effect to fruit and vegetable food.
In order to achieve the above object, the present invention uses following technical scheme:Double catalyst purifying apparatus, including shell, water touch Medium/device and photocatalyst device;Purify cavity is equipped in the shell, the water catalyst device and photocatalyst device are mounted on described In purify cavity, the shell is equipped with the water passage of connection purify cavity;The water catalyst device includes electrode unit, electrode unit It is alternately arranged and is constituted by several vertically arranged anode plate and cathode plate, form double catalyst between anode plate and adjacent cathode plate Catalytic domain, water catalyst device can carry out electro-catalysis after being powered to the water body of double catalyst catalytic domains;After the photocatalyst device is powered Photocatalysis is carried out for the water body to double catalyst catalytic domains.
Compared with prior art, double catalyst purifying apparatus of the invention have the advantages that:
(1) present invention generates hydroxyl radical free radical by decomposing water body, and hydroxyl radical free radical has extremely strong acquisition electronics With organic matter (such as agriculture residual, hormone) oxidation reaction can occur for ability, by oxidation operation at harmless substance, such as oxygen Gas, carbon dioxide, water, mineral salt etc., therefore the present invention is safe, cleaning effect is reliable and stable, can fully meet daily life The cleaning and disinfection of middle fruit and vegetable food, vessel;
(2) band curvature can be occurred after being irradiated by light due to water body, and water body is decomposed reaction (H after powered up20 =H++0H-), the present invention by the way that water catalyst device and photocatalyst device is arranged, realize electro-catalysis and it is light-catalysed be combined, make water Body quickly generates hydroxyl radical free radical under electro-catalysis and light-catalysed collective effect, to make the hydroxyl radical free radical in water body in finger Number increases, and then improves cleaning effect of the present invention to fruit and vegetable food and vessel;
(3) present invention improves the efficiency that double catalyst purifying apparatus generate hydroxyl radical free radical by the way that photocatalyst device is arranged, therefore It is shorter with the time that existing food cleaning device reaches needed for identical cleaning effect, to save electric energy and water resource, drop The cleaning fruit and vegetable food of low user, the cost of vessel;
(4) structure of the invention is compact, makes full use of the internal structure of shell, effectively reduces what double catalyst purifying apparatus occupied Space uses convenient for user installation.
Preferably, the photocatalyst device includes UV lamp, and the UV lamp setting is at purify cavity lower part, the UV lamp work To double catalyst catalytic domain irradiating ultraviolet lights.By the way that the UV lamp is arranged, photocatalysis can be carried out to the water body flowed into shell, separately Outside, since water body is the upward spill-over in auto purification chamber lower part, by UV lamp setting in purify cavity lower part, it can ensure that and flow into purify cavity Water body receives the irradiation of UV lamp light.
Preferably, the photocatalyst device further includes air-dispersing item, and air-dispersing item is equipped with can be to the logical of double catalyst catalytic domains ventilation Gas portion, air-dispersing one end are equipped with the air feed interface being connected to ventilating part, and air feed interface with air supply source for connecting;The UV lamp edge The length direction of air-dispersing item is set on the air-dispersing item.
When double catalyst purifying apparatus work, gas is supplied to from the air feed interface in air-dispersing item by air supply source, and from Ventilating part sprays, and gas and the water formation of ejection are shoved, and are flowed to the upper part of the housing, to promote double catalyst purifying apparatus The flowing of interior water body.
In the above-mentioned double catalyst purifying apparatus of gas-powered using the discharge of air-dispersing item the set-up mode of water body flow have with Lower advantage:
(1) by controlling the airflow direction and air velocity of the gas of air-dispersing item discharge, to the cycle of the water body in shell Mechanical booster action is generated, the purified water containing disinfecting substance in double catalyst purifying apparatus is promoted to be followed with the quick of extraneous water body Ring exchanges;
(2) the air-dispersing item is integrally placed in double catalyst purifying apparatus, can make the internal structure of double catalyst purifying apparatus more It is compact, to reduce double occupied spaces of catalyst purifying apparatus, convenient for the installation and removal of double catalyst purifying apparatus;
(3) gas-powered water body flow is utilized, compared to other power sources, required number of components is less, and power consumption is less, effect Rate higher can effectively reduce the production cost and operating cost of double catalyst purifying apparatus.
Preferably, the UV lamp is set to the downside of the ventilating part of the air-dispersing item along the length direction of air-dispersing item.
The UV lamp is arranged below the ventilating part and is had the following advantages:
(1) this setup is avoided that the water body that lower part of the housing is flowed into from the water passage is directly discharged by ventilating part Air mass ejection to upper part of the housing flow, cause the time that water body is irradiated by UV lamp too short, the disinfecting substance of generation is less;
(2) since UV lamp can carry out disinfection to water body sterilization, and catalysis oxidation can be carried out to the pollutant in water body, this Kind set-up mode can ensure that from the water body that the water passage flows into the shell flows to institute again after UV lamp is fully irradiated State upper part of the housing, to reduce the water body recycled between extraneous and double catalyst purifying apparatus pollutant content.
Preferably, the ventilating part includes the air-dispersing slot being arranged along the length direction of air-dispersing item, and is filled in described dissipate Gas exhausting stone in air drain;The double catalyst catalytic domains of opening direction of the air-dispersing slot;The air-dispersing item is located under the opening of air-dispersing slot Side is equipped with UV lamp slot, and the UV lamp is mounted in the UV lamp slot.
It is had the following advantages filled with gas exhausting stone on the air-dispersing slot:
(1) air mass being discharged from the air-dispersing slot can be dispersed into uniform minute bubbles by gas exhausting stone, and a large amount of minute bubbles The dispersion for being conducive to water body is generated, is conducive to the raising of the catalytic decomposition efficiency of double catalyst purifying apparatus after water body is fully dispersed, And then increase the content of disinfecting substance in water body;
(2) by using the minute bubbles feature slower compared to the big air mass rate of climb, extend water body and filled in double catalytic controls Interior flowing time is set, the time of contact of water body and cathode plate, anode plate, ultraviolet light is on the one hand extended, to increase water body On the other hand the content of middle disinfecting substance can reduce circulation rate of the water body between extraneous and double catalyst purifying apparatus, make Water body containing disinfecting substance comes into full contact with extraneous fruit and vegetable food, promotes cleaning effect of the present invention to fruit and vegetable food.
Preferably, the photocatalyst device further includes no pipe water pump, and the no pipe water pump is arranged in the purify cavity, institute No pipe water pump is stated equipped with the inlet and outlet towards the water passage.
The no pipe water pump is integrally placed in the shell, is avoided external connection power device and pipeline of the present invention, is reduced The loss of water pump power pumps out efficiency to improve, energy saving, and avoids the purified water containing disinfecting substance by outside The pollution at water source.
Preferably, the area of Sole anode plate is 3500-5000mm2, the area of single cathode plate is 4000-5500mm2, And the area of Sole anode plate is less than the area of single cathode plate.
Under standard atmospheric pressure and temperature condition, the standard electrode EMF of oxygen evolution reaction is 1.23V on anode plate, but due to Chemical reaction on cathode plate and anode plate all involves the electronics transfer of multiple steps, and each electronic transfer process can draw Entering activation energy (kinetics energy barrier), the superposition of multiple activation energy can cause the virtual voltage of electrolysis much larger than 1.23V, and from The many factors such as the sub- rate of transform, electrical conductance, the patency of blibbing and reaction entropy also result in the virtual voltage needed for electrolysis Increase;The voltage applied than standard electrode EMF in electrochemical field is referred to as overpotential more;Due to hydrogen ion (H+) net Required overpotential is relatively small when change, and when the area of cathode plate is more than the area of anode plate, anion produces on anode plate Raw side reaction is to hydroxide ion (OH-) oxidation reaction be affected, and the pair that cation generates on cathode plate is anti- Cope with hydrogen ion (H+) influence it is opposite want small, contribute to hydrogen ion (H in water body in this way+) increase, to improve water body to having The cleaning capacity of machine pollutant.
Preferably, shell nozzle is equipped on front side of the shell, the shell nozzle is the water passage;After the shell Side wall is equipped with the connecting terminal being connect with electrode unit, and this setup can ensure that anode plate and cathode plate and the shell Rear wall fits closely, and water body is avoided to flow away from the shell rear wall and anode plate, cathode sheet separation, reduces participation catalysis The water body of reaction;It is equipped with the outer cover for covering the connecting terminal on the outside of the rear wall, connecting terminal is covered by the outer cover, It is avoided that connecting terminal is exposed, on the one hand improves the aesthetics of the present invention, on the other hand can improve the safety of the present invention, keep away Exempt from user and touch connecting terminal, causes safety accident.
Preferably, further include filter mechanism, the filter mechanism is arranged in the water passage;The filter mechanism packet Filter screen is included, the filter screen upper and lower part is provided with filter opening, guide part is formed in the middle part of the filter screen.
By the way that the filter mechanism is arranged, it is avoided that the pollutant remained in water body after cleaning fruit and vegetable food is brought into In double catalyst purifying apparatus, normal operation and the catalytic efficiency of double catalyst purifying apparatus are influenced;In addition, due in the filter screen The guide part in portion is closed state, can play guiding role to the water body in double catalyst purifying apparatus, keeps water body net from double catalyst Lower part Xiang Shuan catalyst purifying apparatus top directed flow is set in makeup, and on the one hand anti-water-stop body reflux, improves double catalyst purifying apparatus Working efficiency, on the other hand make the time of contact of water body and water catalyst device, photocatalyst device longer, improve water catalyst dress It sets, the catalytic efficiency of photocatalyst device.
It is set using double catalyst food purification of above-mentioned double catalyst purifying apparatus it is a further object to provide a kind of It is standby comprising sink and double catalyst purifying apparatus;The side-wall outer side in the sink, the side wall of sink is arranged in the purifier It was equipped with the mouth of a river, the mouth of a river of crossing is connected to water passage.
Compared with prior art, double catalyst food purification equipments of the invention, will be in sink by double catalyst purifying apparatus Water decomposition generate a large amount of disinfecting substances, to thoroughly be cleaned to fruit and vegetable food, with energy conservation and environmental protection, easy to use is excellent Point.
Description of the drawings
Fig. 1 is the first schematic diagram of double catalyst purifying apparatus of embodiment one;
Fig. 2 is the second schematic diagram of double catalyst purifying apparatus of embodiment one;
Fig. 3 is the third schematic diagram of double catalyst purifying apparatus of embodiment one;
Fig. 4 is the a-quadrant partial enlarged view of Fig. 3;
Fig. 5 is the sectional view of double catalyst purifying apparatus of embodiment one;
Fig. 6 is the B area partial enlarged view of Fig. 5;
Fig. 7 is the schematic diagram of air-dispersing item;
Fig. 8 is the schematic diagram of double catalyst purifying apparatus of embodiment two;
Fig. 9 is the schematic diagram of double catalyst purifying apparatus of embodiment three;
Figure 10 is the schematic diagram of the anode plate of embodiment three, cathode plate;
Figure 11 is the schematic diagram of example IV;
Figure 12 is the explosive view of example IV.
Label declaration:
1 sink, 10 levelling benches, 11 cross the mouths of a river, 2 water filling devices, 3 pairs of catalyst purifying apparatus, 4 shells, 40 shell nozzles, 400 purify cavities, 41 sealing rings, 42 pole plate mounting grooves, 43 installation feet, 44 mounting holes, 45 reinforcing ribs, 51 anode plates, 52 cathode plates, 53 pairs of catalyst catalytic domains, 54 anode regions, 55 cathodic regions, 56 connecting terminals, 57 grooves, 58 empty avoiding dog-ears, 6 air-dispersing items, 60 air-dispersings Slot, 600UV light troughs, 61UV lamps, 62 air feed interfaces, 63 electric wire mouths, 64 gas exhausting stones, 7 outer covers, 8 filter mechanisms, 80 filter openings, 81 mistakes Strainer, 82 guide parts, 83 flip-arms, 91 control panels, 92 control box, 93 water pump mounting grooves.
Specific implementation mode
Below in conjunction with description of the drawings embodiments of the present invention:
Embodiment one
Referring to Fig. 1 to Fig. 7, double catalyst purifying apparatus 3 of the present embodiment, including shell 4, water catalyst device and photocatalyst dress It sets;Purify cavity 400 is equipped in the shell 4, the water catalyst device and photocatalyst device are mounted in the purify cavity 400, The shell 4 is equipped with the water passage of connection purify cavity 400;The water catalyst device includes electrode unit, if electrode unit by It does vertically arranged anode plate 51 and cathode plate 52 and is alternately arranged composition, formed between anode plate 51 and adjacent cathode plate 52 double Catalyst catalytic domain 53, water catalyst device can carry out electro-catalysis after being powered to the water body of double catalyst catalytic domains 53;The photocatalyst dress It sets and carries out photocatalysis for the water body to double catalyst catalytic domains 53 after being powered.
Form anode region 54 between the anode plate 51 and double catalyst catalytic domains 53, the cathode plate 52 with it is described double Cathodic region 55 is formed between catalyst catalytic domain 53.
Can decompose reaction after water body energization, the hydrogen ion (H that decomposition reaction generates+) it is gathered in the generation of cathodic region 55 also Original reaction generates hydrogen, the hydroxide ion (0H that decomposition reaction generates-) it is gathered in what the generation oxidation reaction of anode region 54 generated Oxygen, but hydrogen is formed since hydrogen bond is easier opening than hydrogen-oxygen key, (such as disinfectant, mineral when containing electrolyte in water Matter etc.), anion (such as C1 in water-) the generation oxidation reaction of anode plate 51 can be shifted to, it generates containing hypochlorous acid double catalyst Water, and the cation (Ca in water2+,Mg2+,Na+) the generation reduction reaction of cathode plate 52 can be shifted to, generate the alkalinity containing sodium hydroxide Double catalyst water;Acid double catalyst water and the double catalyst water of alkalinity all have good Disinfection Effect, and disinfection speed is sodium hypochlorite 80 times, to more thoroughly carry out cleaning-sterilizing to fruit and vegetable food and vessel.
The top and/or lower part of 4 inner cavity of the shell are equipped with pole plate mounting groove 42, several anode plates 51 and several cathode plates 52 are arranged at intervals in the pole plate mounting groove 42;By being arranged the pole plate mounting groove 42, personnel easy to produce are by cathode plate 52, in the installation to shell 4 of anode plate 51, to improve production efficiency;The distance between adjacent pole plate mounting groove 42 is 1- 20mm。
The photocatalyst device includes UV lamp 61, and the setting of the UV lamp 61 works in 400 lower part of purify cavity, the UV lamp 61 53 irradiating ultraviolet light of Shi Xiangshuan catalyst catalytic domain.By the way that the UV lamp 61 is arranged, light can be carried out to the water body flowed into shell 4 and urged Change, in addition, since water body is the upward spill-over in 400 lower part of auto purification chamber, it, can be really by the setting of UV lamp 61 in 400 lower part of purify cavity It protects water body in inflow purify cavity 400 and receives the irradiation of 61 light of UV lamp.
The photocatalyst device further includes air-dispersing item 6, and air-dispersing item 6 is equipped with the ventilation that can be ventilated to double catalyst catalytic domains 53 Portion, 6 one end of air-dispersing item are equipped with the air feed interface 62 being connected to ventilating part, and air feed interface 62 with air supply source for connecting;The UV Lamp 61 is set to along the length direction of air-dispersing item 6 on the air-dispersing item 6.
Cable passage (not shown) is equipped in the air-dispersing item 6, the circuit of the UV lamp 61 is along the cable passage It lays, the electric wire mouth 63 of the cable passage is arranged in 62 side of the air feed interface.
Specifically, the jet length for the gas that the air-dispersing item 6 sprays is long no more than the level of 51/ cathode plate 52 of anode plate Degree, so that it is guaranteed that water body along 51/ cathode plate 52 of anode plate to 4 upper flow of shell.
When double catalyst purifying apparatus 3 work, gas is supplied to from the air feed interface 62 in air-dispersing item 6 by air supply source, And sprayed from ventilating part, gas and the water formation of ejection are shoved, and to 4 upper flow of the shell, to promote double catalyst net The flowing of water body in 3 is set in makeup.
The set-up mode of water body flow has in the above-mentioned double catalyst purifying apparatus 3 of the gas-powered being discharged using air-dispersing item 6 Following advantages:
(1) by controlling the airflow direction and air velocity of the gas that air-dispersing item 6 is discharged, to following for the water body in shell 4 Ring generates mechanical booster action, and the double 3 interior purified waters containing disinfecting substance of catalyst purifying apparatus of promotion are fast with extraneous water body Speed cycle exchanges;
(2) the air-dispersing item 6 is integrally placed in double catalyst purifying apparatus 3, can make the internal structure of double catalyst purifying apparatus 3 It is more compact, to reduce double 3 occupied spaces of catalyst purifying apparatus, convenient for the installation and removal of double catalyst purifying apparatus 3;
(3) gas-powered water body flow is utilized, compared to other power sources, required number of components is less, and power consumption is less, effect Rate higher can effectively reduce the production cost and operating cost of double catalyst purifying apparatus 3.
The UV lamp 61 is set to the downside of the ventilating part of the air-dispersing item 6 along the length direction of air-dispersing item 6.
The UV lamp 61 is arranged below the ventilating part and is had the following advantages:
(1) this setup is avoided that the water body that 4 lower part of shell is flowed into from the water passage is directly arranged by ventilating part The air mass ejection gone out causes the time that water body is irradiated by UV lamp 61 too short to 4 upper flow of shell, the disinfecting substance of generation compared with It is few;
(2) since UV lamp 61 can carry out disinfection to water body sterilization, and catalysis oxidation can be carried out to the pollutant in water body, This setup can ensure that from the water body that the water passage flows into the shell 4 to flow again after UV lamp 61 fully irradiation To 4 top of the shell, to reduce the water body recycled between extraneous and double catalyst purifying apparatus 3 pollutant content.
The ventilating part includes the air-dispersing slot 60 being arranged along the length direction of air-dispersing item 6, and is filled in the air-dispersing slot Gas exhausting stone 64 in 60;The opening direction pair catalyst catalytic domains 53 of the air-dispersing slot 60;The air-dispersing item 6 is located at air-dispersing slot 60 Opening downside is equipped with UV lamp slot 600, and the UV lamp 61 is mounted in the UV lamp slot 600.
It is had the following advantages filled with gas exhausting stone 64 on the air-dispersing slot 60:
(1) air mass being discharged from the air-dispersing slot 60 can be dispersed into uniform minute bubbles by gas exhausting stone 64, and a large amount of stingy The generation of bubble is conducive to the dispersion of water body, is conducive to the catalytic decomposition efficiency of double catalyst purifying apparatus 3 after water body is fully dispersed It improves, and then increases the content of disinfecting substance in water body;
(2) by using the minute bubbles feature slower compared to the big air mass rate of climb, extend water body and filled in double catalytic controls The flowing time in 3 is set, the time of contact of water body and cathode plate 52, anode plate 51, ultraviolet light is on the one hand extended, to increase On the other hand the content of disinfecting substance in water body can reduce cycle speed of the water body between extraneous and double catalyst purifying apparatus 3 Degree makes the water body containing disinfecting substance be come into full contact with extraneous fruit and vegetable food, promotes cleaning effect of the present invention to fruit and vegetable food.
The area of Sole anode plate 51 is 3500-5000mm2, the area of single cathode plate 52 is 4000-5500mm2, individually The area of anode plate 51 is less than the area of single cathode plate 52.
Under standard atmospheric pressure and temperature condition, the standard electrode EMF of oxygen evolution reaction is 1.23V on anode plate 51, but by The electronics transfer of multiple steps is all involved in the chemical reaction on cathode plate 52 and anode plate 51, and each electronic transfer process Activation energy (kinetics energy barrier) will be introduced, the superposition of multiple activation energy can cause the virtual voltage of electrolysis to be much larger than 1.23V, and many factors such as the patency of ion-transfer rate, electrical conductance, blibbing and reaction entropy also result in needed for electrolysis Virtual voltage increase;The voltage applied than standard electrode EMF in electrochemical field is referred to as overpotential more;Due to hydrogen Ion (H+) purification when required overpotential it is relatively small, when the area of cathode plate 52 is more than the area of anode plate 51, it is cloudy from The side reaction that son generates on anode plate 51 is to hydroxide ion (OH-) oxidation reaction be affected, and cation is in the moon The side reaction generated on pole plate 52 is to hydrogen ion (H+) influence it is opposite want small, contribute to hydrogen ion (H in water body in this way+) increasing Add, to improve cleaning capacity of the water body to organic pollution.
4 front side of the shell is equipped with shell nozzle 40, and the shell nozzle 40 is the water passage;After the shell 4 Side wall is equipped with the connecting terminal 56 being connect with electrode unit, and this setup can ensure that anode plate 51 and cathode plate 52 and institute It states 4 rear wall of shell to fit closely, avoids water body from flowing away from 4 rear wall of the shell and anode plate 51,52 gap of cathode plate, subtract The water body for participating in catalysis reaction is lacked;The outer cover 7 for covering the connecting terminal 56 is equipped on the outside of the rear wall, by described outer Cover 7 covers connecting terminal 56, is avoided that connecting terminal 56 is exposed, on the one hand improves the aesthetics of the present invention, on the other hand can The safety for improving the present invention avoids user from touching connecting terminal 56, causes safety accident.
40 outside of the shell nozzle is equipped with sealing ring 41, by the way that sealing ring 41 is arranged, it is ensured that double catalytic control dresses 3 are set to be tightly connected with external equipment.
It is set there are two reinforcing rib 45 on the side wall of the shell nozzle 40 relatively of the shell 4, the reinforcing rib 45 is used for Reinforce the intensity of the shell 4, the position that anode plate 51, cathode plate 52 correspond to described two reinforcing ribs 45 is equipped with groove 57, leads to It crosses pole plate mounting groove 42 and reinforcing rib 45 coordinates, anode plate 51,52 accurate contraposition of cathode plate is made to be mounted in the shell 4.
Further include filter mechanism (not shown), the filter mechanism is arranged in the water passage;The filtering Mechanism includes filter screen, and the filter screen upper and lower part is provided with filter opening, and guide part is formed in the middle part of the filter screen.
By the way that the filter mechanism is arranged, it is avoided that the pollutant remained in water body after cleaning fruit and vegetable food is brought into In double catalyst purifying apparatus 3, normal operation and the catalytic efficiency of double catalyst purifying apparatus 3 are influenced;In addition, due to the filter screen The guide part at middle part is closed state, can play guiding role to the water body in double catalyst purifying apparatus 3, makes water body from double catalyst 3 lower part Xiang Shuan catalyst purifying apparatus of purifier, 3 top directed flow, on the one hand anti-water-stop body reflux, improves double catalytic controls On the other hand the working efficiency of device 3 makes the time of contact of water body and water catalyst device, photocatalyst device longer, improve water and touch The catalytic efficiency of medium/device, photocatalyst device.
Specifically, the aperture of the filter opening is not more than 2.5 μm, so as to effectively filter the pollutant in water body.
4 outside of the shell is equipped with several installation feet 43, and double catalyst purifying apparatus 3 are arranged by the installation foot 43 In 1 outside of the sink;The installation foot 43 is equipped with strip mounting hole 44, easy to produce by the way that strip mounting hole 44 is arranged The installation site of personnel's adjustment pair catalyst purifying apparatus 3.
Embodiment two
Referring to Fig. 8, the difference between this embodiment and the first embodiment lies in:It is additionally provided with nothing on double catalyst purifying apparatus 3 Pipe water pump (not shown).No pipe water pump and air-dispersing item 6 collectively promote water body and the external world in double catalyst purifying apparatus 3 Water body swap.
The no pipe water pump is arranged in the purify cavity 400, and the no pipe water pump is equipped with towards the water passage Inlet and outlet.
400 middle part of the purify cavity is equipped with water pump mounting groove 93, and the no pipe water pump is arranged in the water pump mounting groove 93 On.
Water body in the shell 4 enters the no pipe water pump by the water inlet, and the no pipe water pump passes through described Water outlet exports water body to outside the shell 4.
The no pipe water pump is integrally placed in the shell 4, is avoided external connection power device and pipeline of the present invention, is reduced The loss of water pump power pumps out efficiency to improve, energy saving, and avoids the purified water containing disinfecting substance by outside The pollution at water source.
Scheme as an improvement of this embodiment, double catalyst purifying apparatus 3 can be only arranged without pipe water pump (in figure not Show), double catalyst purifying apparatus 3 are swapped by the water body of water body and the external world inside the driving of no pipe water pump.
Embodiment three
Referring to Fig. 9 to Figure 10, the difference between this embodiment and the first embodiment lies in:The filter mechanism 8 includes strainer 81, with And the flip-arm 83 in 81 both sides of the filter screen is set.
83 upper end of the flip-arm and 4 upper articulation of the shell, 83 lower end of the flip-arm are cut with scissors with the filter screen 81 It connects, the alternative lid of the filter screen 81 is located on the shell nozzle 40.The filter screen 81 is lifted off the shell by user Opening 40, you can filter screen 81 is cleaned, so that it is guaranteed that the filter effect of filter screen 81.
The hinged place that the cathode plate 52,51 lower part of anode plate correspond to the flip-arm 83 and the filter screen 81 is equipped with and keeps away Empty dog-ear 58.
Compared with prior art, double catalyst food purification equipments of the present embodiment one to embodiment three have below beneficial to effect Fruit:
(1) present invention generates hydroxyl radical free radical by decomposing water body, and hydroxyl radical free radical has extremely strong acquisition electronics With organic matter (such as agriculture residual, hormone) oxidation reaction can occur for ability, by oxidation operation at harmless substance, such as oxygen Gas, carbon dioxide, water, mineral salt etc., therefore the present invention is safe, cleaning effect is reliable and stable, can fully meet daily life The cleaning and disinfection of middle fruit and vegetable food, vessel;
(2) band curvature can be occurred after being irradiated by light due to water body, and water body is decomposed reaction (H after powered up20 =H++0H-), the present invention by the way that water catalyst device and photocatalyst device is arranged, realize electro-catalysis and it is light-catalysed be combined, make water Body quickly generates hydroxyl radical free radical under electro-catalysis and light-catalysed collective effect, to make the hydroxyl radical free radical in water body in finger Number increases, and then improves cleaning effect of the present invention to fruit and vegetable food and vessel;
(3) present invention improves the efficiency that double catalyst purifying apparatus 3 generate hydroxyl radical free radical by the way that photocatalyst device is arranged, therefore It is shorter with the time that existing food cleaning device reaches needed for identical cleaning effect, to save electric energy and water resource, drop The cleaning fruit and vegetable food of low user, the cost of vessel;
(4) structure of the invention is compact, makes full use of the internal structure of shell 4, effectively reduces double catalyst purifying apparatus 3 and occupies Space, convenient for user installation use.
Example IV
Referring to Figure 11 to Figure 12, it is a further object to provide a kind of using above-mentioned double catalyst purifying apparatus 3 Double catalyst food purification equipments comprising sink 1, water filling device 2 and double catalyst purifying apparatus 3;1 upper opening of the sink, Bottom is equipped with discharge outlet (not shown);The setting of the water filling device 2 is in 1 upper end of the sink, for into the sink 1 Water filling;The side-wall outer side in the sink 1 is arranged in double catalyst purifying apparatus 3, and the side wall of sink 1 was equipped with the mouth of a river 11, The mouth of a river 11 of crossing is connected to water passage.
Specifically, there are two the sink 1 is set, double catalyst purifying apparatus 3 are arranged on right side sink 1, left side water Slot 1 is used to carry out general clear water flushing to vessel, food materials for user;1 upper end of the sink extends to form horizontal flat outward Platform 10, the water filling device 2 are arranged on the levelling bench 10, and the water filling device 2 is Universal faucet, the water filling dress Setting 2 can carry out adding water to any sink 1.
Further include feeder (not shown), the feeder is arranged on the sink 1, the feeder It is connected to the air feed interface 62, the feeder is used to supply to the air-dispersing item 6.
Further include control device, the control device includes control panel 91 and control box 92, and the control box 92 is arranged On the levelling bench 10, the setting of the control panel 91 is arranged in 92 upper end of the control box, the feeder in institute It states in control box 92, double catalyst purifying apparatus 3 are electrically connected with the control box 92, and the control box 92 is described for controlling The running of double catalyst purifying apparatus 3.
Further include pH sensor (not shown)s, the pH sensors are equipped at least two, are separately positioned on the sun Pole plate 51,52 outside of cathode plate, the pH value for detecting anode region 54 and cathodic region 55, the pH sensors are filled with the control Electrical connection is set, the display on the control device can show the pH numerical value that pH sensors are measured.When the pH numerical value of anode region 54 When less than 5, the water body in sink 1 can meet the needs of sterilization;When the pH numerical value in cathodic region 55 is more than 9, the water body in sink 1 Can meet the needs of organics removal, this setup quickly judges the clarification time of sink 1 convenient for user, so as to shorten net Change the time and saves electric energy.
Preferably, the filter mechanism 8 includes filter screen 81, and the filter screen 81 can be integrally formed with the sink 1, this Kind set-up mode can reduce the production cost of double catalyst food purification equipments, or, the filter screen 81 can be seperated with the sink 1 Setting, to reduce the assembling difficulty for reducing double catalyst food purification equipments.
Compared with prior art, double catalyst food purification equipments of the invention, by double catalyst purifying apparatus 3 by sink 1 Interior water decomposition generates a large amount of disinfecting substances, to thoroughly be cleaned to fruit and vegetable food, has energy conservation and environmental protection, easy to use Advantage.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula is changed and is changed.Therefore, the invention is not limited in specific implementation modes disclosed and described above, to the present invention's Some modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, although being used in this specification Some specific terms, these terms are merely for convenience of description, does not limit the present invention in any way.

Claims (10)

1. pair catalyst purifying apparatus, it is characterised in that:Including shell, water catalyst device and photocatalyst device;
Purify cavity is equipped in the shell, the water catalyst device and photocatalyst device are mounted in the purify cavity, the shell Body is equipped with the water passage of connection purify cavity;
The water catalyst device includes electrode unit, and electrode unit is alternately arranged by several vertically arranged anode plate and cathode plate It constitutes, forms double catalyst catalytic domains between anode plate and adjacent cathode plate, water catalyst device can be catalyzed double catalyst after being powered The water body in area carries out electro-catalysis;
The photocatalyst device is used to carry out photocatalysis to the water body of double catalyst catalytic domains after being powered.
2. double catalyst purifying apparatus according to claim 1, it is characterised in that:The photocatalyst device includes UV lamp, institute UV lamp setting is stated at purify cavity lower part, the UV lamp work to double catalyst catalytic domain irradiating ultraviolet lights.
3. double catalyst purifying apparatus according to claim 2, it is characterised in that:The photocatalyst device further includes air-dispersing Item, air-dispersing item are equipped with the ventilating part that can be ventilated to double catalyst catalytic domains, and air-dispersing one end is equipped with the gas supply being connected to ventilating part and connects Mouthful, air feed interface with air supply source for connecting;
The UV lamp is set to along the length direction of air-dispersing item on the air-dispersing item.
4. double catalyst purifying apparatus according to claim 3, it is characterised in that:Length direction of the UV lamp along air-dispersing item Set on the downside of the ventilating part of the air-dispersing item.
5. double catalyst purifying apparatus according to claim 4, it is characterised in that:The ventilating part includes the length along air-dispersing item The air-dispersing slot of direction setting is spent, and the gas exhausting stone being filled in the air-dispersing slot;
The double catalyst catalytic domains of opening direction of the air-dispersing slot;
The air-dispersing item, which is located on the downside of the opening of air-dispersing slot, is equipped with UV lamp slot, and the UV lamp is mounted in the UV lamp slot.
6. double catalyst purifying apparatus according to claim 2 or 3, it is characterised in that:The photocatalyst device further includes nothing Pipe water pump, the no pipe water pump are arranged in the purify cavity, the no pipe water pump be equipped with towards the water passage into The mouth of a river and water outlet.
7. double catalyst purifying apparatus according to claim 1, it is characterised in that:The area of Sole anode plate is 3500- 5000mm2, the area of single cathode plate is 4000-5500mm2, and the area of Sole anode plate is less than the face of single cathode plate Product.
8. double catalyst purifying apparatus according to claim 1, it is characterised in that:Shell nozzle is equipped on front side of the shell, The shell nozzle is the water passage;
The shell rear wall is equipped with the connecting terminal being connect with electrode unit, is equipped with described in covering and connects on the outside of the rear wall The outer cover of line terminals.
9. double catalyst purifying apparatus according to claim 1, it is characterised in that:Further include filter mechanism, the filter Structure is arranged in the water passage;
The filter mechanism includes filter screen, and the filter screen upper and lower part is provided with filter opening, is formed in the middle part of the filter screen Guide part.
10. pair catalyst food purification equipment, including sink and purifier, it is characterised in that:The purifier is wanted for right Ask the double catalyst purifying apparatus of 1 to 9 any one of them, the purifier that the side-wall outer side in the sink is set, sink Side wall was equipped with the mouth of a river, and the mouth of a river of crossing is connected to water passage.
CN201810731656.9A 2018-07-05 2018-07-05 Double-catalyst purifying device and double-catalyst food purifying equipment Active CN108689456B (en)

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CN110250402A (en) * 2019-01-28 2019-09-20 广东美集世智能科技有限公司 A kind of processing unit for going agriculture residual for food materials
CN110507227A (en) * 2019-09-10 2019-11-29 浙江翔鹰中央厨房设备有限公司 A kind of beet washer with water catalyst
CN110593364A (en) * 2019-10-25 2019-12-20 佛山市顺德区悍高五金制品有限公司 Food purifying equipment

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CN110250402A (en) * 2019-01-28 2019-09-20 广东美集世智能科技有限公司 A kind of processing unit for going agriculture residual for food materials
CN110507227A (en) * 2019-09-10 2019-11-29 浙江翔鹰中央厨房设备有限公司 A kind of beet washer with water catalyst
CN110593364A (en) * 2019-10-25 2019-12-20 佛山市顺德区悍高五金制品有限公司 Food purifying equipment

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