CN108676128A - The method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid - Google Patents
The method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid Download PDFInfo
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- CN108676128A CN108676128A CN201810482404.7A CN201810482404A CN108676128A CN 108676128 A CN108676128 A CN 108676128A CN 201810482404 A CN201810482404 A CN 201810482404A CN 108676128 A CN108676128 A CN 108676128A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2688—Copolymers containing at least three different monomers
- C04B24/2694—Copolymers containing at least three different monomers containing polyether side chains
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
- C08F228/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/40—Redox systems
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
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Abstract
The present invention relates to prepare polycarboxylate water-reducer technical field, and in particular to the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid, its step are as follows:It is first put into methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride, hydrogen peroxide and appropriate amount of deionized water as bottom material in reaction kettle, stirring heats up to after being completely dissolved;Solution A and solution B is added dropwise simultaneously after bottom material dissolving, after completion of dropwise addition, continues to be stirred to react;The pH value for adjusting mixed solution again, obtains polycarboxylate water-reducer, then with amino resins waste liquid is compound according to a certain percentage can be prepared by;Cationic functional monomer metering system phthalein oxy-ethyl-trimethyl salmiac has been introduced in the present invention, can be formed certain complex compound, can be improved the compactness of structure itself;The amino resins waste liquid containing methanol being added in the present invention can prevent concrete from freezing, to not influence the compression strength of concrete, density and durability.
Description
Technical field
The present invention relates to prepare polycarboxylate water-reducer technical field, and in particular to prepares anti-freeze type using amino resins waste liquid
The method of high-performance polycarboxylic acids water reducing agent.
Background technology
The vast northern area weather in China is usually colder, and winter is up to the 4-6 months, is influenced on concrete engineering construction
It is very big.When the temperature increases, hydration is accelerated, and gain in strength is also very fast;And when temperature is reduced to 0 DEG C, it is present in coagulation
Some starts to freeze for water in soil, gradually becomes solid phase from liquid phase.At this moment participating in the water of cement aquation reduces, because
This, hydration slows down, and gain in strength is accordingly relatively slow.Temperature continues to decline, when the water being present in concrete becomes ice completely,
When namely becoming solid phase from liquid phase completely, cement aquation stops substantially, and intensity just no longer increases at this time, in order to ensure mixed
The quality and progress of solidifying soil construction, most economical effective method are to use antifreezing agent.Concrete antifreezer experienced villaumite type, chlorine
Salt hinders rust type, without the high alkaline of chlorine, no chlorine and low alkali type several stages.At present mixing plant using antifreezing component be nitrite, villaumite,
Urea, ammonium hydroxide etc..Not only alkali content is high in the diminishing component of these antifreezing agents, but also contains remaining formaldehyde, and environment-friendly type is poor,
In addition water-reducing rate is not also high, to the bad adaptability of cement, sand material, it is difficult to meet the requirement of current high performance concrete, it is antifreeze
Chloride ion content, sulphates content in component is very high, is unfavorable for improving the compactness and durability of concrete.Small molecule alcohol
It is a kind of relatively good antifreezing agent, but volume is higher, whole water-reducing agent higher price, produces in amino resin waste water containing big
Methanol and butanol are measured, usually all regards wastewater treatment, the waste of resource can be caused.
Invention content
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention is by using redox system, causes free radical polymerization, on configuration with
There are a great differences to shorten the induction period of aquation to change the heat evolution velocity of cement for the water-reducing agent of the prior art so that
Aquation accelerated period, arrives quickly;Cationic functional monomer metering system phthalein oxy-ethyl-trimethyl salmiac has been introduced in the present invention
(DMC), certain complex compound can be formed, so as to inhibit the formation of aquation early stage loose structure, the close of structure itself can be improved
Solidity;The amino resins waste liquid containing methanol being added in the present invention can prevent concrete from freezing, to not influence concrete
Compression strength, density and durability.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:
The method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid, includes the following steps:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 6-7 above-mentioned mixed solution to be adjusted pH value with reagent, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Preferential, polycarboxylate water-reducer is made by the raw material of following parts by weight in the step c:Methacrylic polyoxy second
290-340 parts of alkene ether, 70-120 parts of metering system phthalein oxy-ethyl-trimethyl salmiac, 2-4 parts of 27.5% hydrogen peroxide, methyl
1.5-3 parts of 2-4 parts of sodium allylsulfonate, 30-40 parts of acrylic acid, 5-10 parts of maleic anhydride and potassium peroxydisulfate.
Preferential, polycarboxylate water-reducer is made by the raw material of following parts by weight in the step c:Methacrylic polyoxy second
300-340 parts of alkene ether, 80-120 parts of metering system phthalein oxy-ethyl-trimethyl salmiac, 3-4 parts of 27.5% hydrogen peroxide, methyl-prop
2-3 parts of 3-4 parts of alkene sodium sulfonate, 30-38 parts of acrylic acid, 5-9 parts of maleic anhydride and potassium peroxydisulfate.
Preferential, polycarboxylate water-reducer is made by the raw material of following parts by weight in the step c:Methacrylic polyoxy second
320 parts of alkene ether, 100 parts of metering system phthalein oxy-ethyl-trimethyl salmiac, 3 parts of 27.5% hydrogen peroxide, methylpropene sodium sulfonate
2 parts of 3 parts, 35 parts of acrylic acid, 8 parts of maleic anhydride and potassium peroxydisulfate.
Preferential, reagent is diethanol amine in the step c.
Preferential, the deionized water quality is 1.3-2.4 times of each raw material gross mass.
Preferential, the molecular weight of the methyl allyl polyoxyethylene ether is 3000-5000.
(3) advantageous effect
1, the present invention is by using redox system, causes free radical polymerization, the water-reducing agent on configuration with the prior art
There are a great difference, its molecular characterization is:Side chain is long, and backbone length is shorter, and side chain lengths are much larger than
Backbone length, the distance between side chain and side chain are also bigger, and poly- shuttle acid water-reducing agent molecular configuration is in integrally inverted T shaped, to change
The heat evolution velocity for having become cement shortens the induction period of aquation so that aquation accelerated period arrives quickly;Also change poly- shuttle simultaneously
Sour water-reducing agent promotes the early hydration of tricalcium silicate (C3S) and tricalcium aluminate (C3A) in the absorption situation of cement particle surface,
It generates more multipair early strength and develops strong hydrated product.
2, cationic functional monomer metering system phthalein oxy-ethyl-trimethyl salmiac (DMC), meeting have been introduced in the present invention
Certain complex compound is formed, tricalcium aluminate (C3A) and tetra calcium aluminoferrite (C4AF) rate of dissolution can be accelerated, promotes the objects such as entringite
The generation of matter can improve the compactness of structure itself so as to inhibit the formation of aquation early stage loose structure.
3, the amino resins waste liquid containing methanol being added in the present invention can prevent concrete from freezing, and increase its internal liquid
Phase reduces solid phase, accelerates the hydration of cement, to not influence the compression strength of concrete, density and durability.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, shall fall within the protection scope of the present invention.
Embodiment 1:
The method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid, steps are as follows:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 6 above-mentioned mixed solution reagent to be adjusted pH value, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Polycarboxylate water-reducer is made by the raw material of following parts by weight in step c:
Embodiment 2:
The method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid, steps are as follows:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 6.5 above-mentioned mixed solution reagent to be adjusted pH value, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Polycarboxylate water-reducer is made by the raw material of following parts by weight in step c:
Embodiment 3:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 7 above-mentioned mixed solution reagent to be adjusted pH value, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Polycarboxylate water-reducer is made by the raw material of following parts by weight in step c:
Embodiment 4:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 6.5 above-mentioned mixed solution reagent to be adjusted pH value, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Polycarboxylate water-reducer is made by the raw material of following parts by weight in step c:
Embodiment 5:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 6 above-mentioned mixed solution reagent to be adjusted pH value, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Polycarboxylate water-reducer is made by the raw material of following parts by weight in step c:
Embodiment 6:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride,
27.5% hydrogen peroxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50
℃;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by persulfuric acid
It is for use that potassium and deionized water be hybridly prepared into solution B, and solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, molten
Liquid A is added dropwise to complete through 2h, and solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 7 above-mentioned mixed solution reagent to be adjusted pH value, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 it is compound can be obtained it is antifreeze
Type high-performance polycarboxylic acids water reducing agent.
Polycarboxylate water-reducer is made by the raw material of following parts by weight in step c:
The present invention selects common polycarboxylate water-reducer to be added in concrete mix as an aqueous solution, and (its volume is water
The 1.8% of mud weight) as control group, product made from embodiment 1-6 is added in concrete mix as an aqueous solution
(its volume is the 1.8% of cement weight) obtains properties data such as 1 institute of table under the same conditions as experimental group
Show:
Table 1
As shown in Table 1, the product of the 1-6 of the embodiment of the present invention is being added to concrete mix as an aqueous solution
Shi Junneng shortens the induction period of aquation, hence it is evident that the early hydration for improving cement improves the early strength of concrete, while also can
Stomatal parameters and compactness, the improvement of the product of the present embodiment 6 inside improvement maturing are the most apparent.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
Invention is explained in detail, it will be understood by those of ordinary skill in the art that:It still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features;And these modification or
It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.
Claims (7)
1. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid, which is characterized in that including following
Step:
A, first by methyl allyl polyoxyethylene ether, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, maleic anhydride, 27.5% mistake
Hydrogen oxide and appropriate amount of deionized water are put into as bottom material in reaction kettle, are stirred to being completely dissolved, temperature is adjusted to 50 DEG C;
B, be hybridly prepared into solution A by acrylic acid, methylpropene sodium sulfonate and deionized water for use, by potassium peroxydisulfate and goes
It is for use that ionized water be hybridly prepared into solution B, solution A and solution B is added dropwise simultaneously after bottom material dissolving in step a, solution A is through 2h
It is added dropwise to complete, solution B is added dropwise to complete through 2.5h, after solution B completion of dropwise addition, continues to be stirred to react 50min;
C, it is 6-7 above-mentioned mixed solution to be adjusted pH value with reagent, continues to stir 30min to get polycarboxylate water-reducer;
D, take in step c polycarboxylate water-reducer and amino resins waste liquid according to mass ratio 1:2.5 compound can be obtained anti-freeze type height
Performance polycarboxylate water-reducer.
2. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid as described in claim 1,
It is characterized in that, polycarboxylate water-reducer is made by the raw material of following parts by weight in the step c:Methyl allyl polyoxyethylene ether
290-340 parts, 70-120 parts of MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, 2-4 parts of 27.5% hydrogen peroxide, metering system sulphur
1.5-3 parts of sour sodium 2-4 parts, 30-40 parts of acrylic acid, 5-10 parts of maleic anhydride and potassium peroxydisulfate.
3. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid as described in claim 1,
It is characterized in that, polycarboxylate water-reducer is made by the raw material of following parts by weight in the step c:Methyl allyl polyoxyethylene ether
300-340 parts, 80-120 parts of metering system phthalein oxy-ethyl-trimethyl salmiac, 3-4 parts of 27.5% hydrogen peroxide, metering system sulphur
2-3 parts of sour sodium 3-4 parts, 30-38 parts of acrylic acid, 5-9 parts of maleic anhydride and potassium peroxydisulfate.
4. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid as described in claim 1,
It is characterized in that, polycarboxylate water-reducer is made by the raw material of following parts by weight in the step c:Methyl allyl polyoxyethylene ether
320 parts, 100 parts of metering system phthalein oxy-ethyl-trimethyl salmiac, 3 parts of 27.5% hydrogen peroxide, 3 parts of methylpropene sodium sulfonate,
2 parts of 35 parts of acrylic acid, 8 parts of maleic anhydride and potassium peroxydisulfate.
5. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid as described in claim 1,
It is characterized in that:Reagent is diethanol amine in the step c.
6. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid as described in claim 1,
It is characterized in that:The deionized water quality is 1.3-2.4 times of each raw material gross mass.
7. the method for preparing anti-freeze type high-performance polycarboxylic acids water reducing agent using amino resins waste liquid as described in claim 1,
It is characterized in that:The molecular weight of the methyl allyl polyoxyethylene ether is 3000-5000.
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