CN108660485A - A kind of continuous electrolysis purifier - Google Patents
A kind of continuous electrolysis purifier Download PDFInfo
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- CN108660485A CN108660485A CN201810602786.2A CN201810602786A CN108660485A CN 108660485 A CN108660485 A CN 108660485A CN 201810602786 A CN201810602786 A CN 201810602786A CN 108660485 A CN108660485 A CN 108660485A
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- Prior art keywords
- lifting
- stove
- rotation
- discharging
- stripping
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 47
- 230000007246 mechanism Effects 0.000 claims abstract description 61
- 238000007599 discharging Methods 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 42
- 238000010438 heat treatment Methods 0.000 claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 claims description 49
- 239000002184 metal Substances 0.000 claims description 49
- 238000013519 translation Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000000498 cooling water Substances 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 7
- 230000005611 electricity Effects 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 33
- 230000008569 process Effects 0.000 abstract description 16
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 230000008021 deposition Effects 0.000 abstract description 6
- 238000007670 refining Methods 0.000 abstract description 6
- 230000007704 transition Effects 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 description 11
- 230000006870 function Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000008018 melting Effects 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 238000013461 design Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000003028 elevating effect Effects 0.000 description 6
- 239000011257 shell material Substances 0.000 description 6
- 229910052770 Uranium Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 230000036647 reaction Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000003140 Panax quinquefolius Nutrition 0.000 description 2
- 240000005373 Panax quinquefolius Species 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000374 eutectic mixture Substances 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- 239000003500 flue dust Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- -1 uranium ion Chemical class 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 150000000703 Cerium Chemical class 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052767 actinium Inorganic materials 0.000 description 1
- QQINRWTZWGJFDB-UHFFFAOYSA-N actinium atom Chemical compound [Ac] QQINRWTZWGJFDB-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002915 spent fuel radioactive waste Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003671 uranium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/06—Operating or servicing
- C25C7/08—Separating of deposited metals from the cathode
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
A kind of continuous electrolysis purifier, including the cathode rotation and lifting bar, the discharging stove and heating furnace that are vertically arranged, it is characterised in that：The lower part suit of discharging stove is in heating furnace, the stove lower lumen that discharges is equipped with electrolysis unit, cathode rotation and lifting bar lower part passes through discharging stove to enter electrolysis unit, and the top side for the stove that discharges is equipped with the rotary lifting mechanism for driving cathode rotation and lifting bar vertical lifting or rotation；The middle part side of discharging stove, which is equipped with, translates splicing switching mechanism and deposit mechanism for stripping, and the side of discharging stove and heating furnace connects vacuum device simultaneously.The present invention is according to electrolytic refining process flow setting electrolysis zone, deposition material stripping area, material receiving area, material transition range, using the tactic pattern of the convertible mechanical disk splicing of horizontal extension, discharging, reduce electrical components in vacuum reaction room, electrical service life is extended, the replacement of rapid wear electric elements is convenient for.
Description
Technical field
A kind of continuous electrolysis purifier, belongs to electrorefining technical field.
Background technology
Anode is cast with the crude metal that high temperature reduction obtains when electrolysis, electrolyte is done with the salting liquid containing metal to be made,
The impurity that control certain potentials keep dissolution potential more positive than refined metals remains in anode or is deposited in the earth of positive pole（Wherein often contain
There is noble metal）, it is separated and recovered with other methods, and dissolution potential is than the impurity then pass into solution that refined metals are born, not in cathode
Upper precipitation, to the high pure metal that can be refined on cathode, using the metal of electrorefining have copper, gold, silver, platinum, nickel,
Iron, lead, antimony, tin, bismuth etc. make anode by the electrolysis of electrolyte solution by crude metal, and simple metal makees cathode, contain the metal
The solution of ion makees electrolyte, and metal is from anodic solution, the impurity in cathode deposition, crude metal, and inactive impurity is insoluble
Solution, becomes the earth of positive pole and sinks in bottom of electrolytic tank, although active impurity in anodic solution, cannot in cathode deposition, so
The very high metal of purity can be obtained by electrolysis cathode, the referred to as electrorefining of metal, electrorefining is usually used in non-ferrous metal
Refining, such as blister copper, thick silver, the refining of thick nickel etc..
Ripe reprocessing/waste material adjusts the fuse salt method of radioactive nucleus fuel there are two types of in the world,
Method-RIAR the methods of Dimitrovgrad SSC exploitations use high temperature (1000K) eutectic salt mixture as the molten of fuel
Electrolyte system is also made in agent, and in Russia's system, solvent is the eutectic mixture of NaCl/KCl or CsCl/KCl, should
Method chemical oxidizing agent (chlorine and oxygen) forms the high oxidation state compound for dissolving in fuse salt with powdery UO2 fuel reactions
Such as UO2Cl2, uranium compound is reduced to UO2 in cathode, forms skeleton deposit, but use a period of time with
Afterwards, fuse salt has loaded fission product, they not only start to influence the quality of product, but also too many heat is produced in salt
Amount, these fission products are general but simultaneously must non-uniquely be used as the waste material fixed high activity group of the lanthanides of isolation or actinium in the form of being suitble to
Series elements, in the method that U.S. Argonne National Laboratory (ANL) are developed, generally using the LiCl/ of melting
KCl eutectic mixtures, rather than the system containing sodium or cerium salt still use high temperature (773K), and the method is by inflow current with oxygen
Change uranium anode and form uranium ion in molten salt electrolyte to handle spent nuclear fuel, uranium is reduced in cathode, is deposited as metal
Uranium, unfortunately batch process is recycled since uranium is collected in the storage of device bottom in order to remove storage ANL methods
Product, just necessary interrupt processing process, in addition, machinery is intensive when the method operates, including uses for wiping turning for cathode product off
Dynamic anode encounters problems often since machinery blocks.
In fields such as aerospace, navigation, infrared and photoelectricity, high pure metal is widely used.And the electrolysis essence of high pure metal
Smelting method discloses in Chinese patent 92112474.0《The stripping means of electrode metal and implement this method in electrorefining
Equipment》, Chinese patent 00108703.2 discloses《Dress for removing the deposit generated in electrorefining or electrolytic deposition
It sets》It is disclosed with Chinese patent 02105301.X《Detach the electrolytic smelting method of metal》, but the metal that these methods are refined is remote
Far from requirement of the modern technologies to high pure metal is met, currently, the similar devices used both at home and abroad are not only complicated, price
Height, operation are loaded down with trivial details, and Refining degree is relatively low, and the fault of construction of existing equipment itself, makes to can not achieve in its technique in addition
Continuous electrorefining.
Invention content
The technical problem to be solved by the present invention is to：Overcome the deficiencies of the prior art and provide a kind of realization continuous electrolysis essence
Refining, device structure design are more rationally, technological process is succinctly easy, the continuous electrolysis period is longer, easily worn part replacement operation is simpler
Single continuous electrolysis purifier.
The technical solution adopted by the present invention to solve the technical problems is：A kind of continuous electrolysis purifier, including it is upper solid
Fixed platform, the cathode rotation and lifting bar being vertically arranged, discharging stove and heating furnace, it is characterised in that：It is fixedly mounted out in upper fixed platform
Expect stove and heating furnace, in heating furnace, discharging stove lower lumen is equipped with electrolysis unit to the lower part suit for the stove that discharges, and cathode rotation rises
The lower part of drop bar passes through discharging stove to enter electrolysis unit, and discharging furnace roof portion is stretched out on the top of cathode rotation and lifting bar, and discharge stove
Top side is equipped with the rotary lifting mechanism for driving cathode rotation and lifting bar vertical lifting or rotation；The middle part side of discharging stove is set
There are the translation splicing switching mechanism being laterally arranged and deposit mechanism for stripping, translation splicing switching mechanism one end to pass through material fetching mechanism
The side of connection discharging stove, discharging stove and heating furnace connects vacuum device simultaneously.
The present invention will be electrolysed, deposit is removed and the processes such as feeding form integrated structure type, and discharge stove and heating
The main furnace body structure that stove is formed includes four melting electrolysis zone, electrolytic deposition material stripping area, material receiving area, material transition range functions
The connection combination of vacuum passage had not only may be implemented in region, four functional areas, but also can independently separate, using horizontal retractable machine
The tactic pattern of the splicing of tool disk, discharging so that electrical components are less in vacuum reaction room, effectively extend and electrically use the longevity
Life, and convenient for the replacement of rapid wear electric elements.
According to the flow process of electrorefining, the functions such as material melting of the invention, electrorefining, deposit stripping are vertical
Structure arranges that material transfer is horizontally disposed, forms Trinitarian continuous electrolysis ergasia in this way, both ensure that this technique
The work characteristics of procedure, serialization, and working space has been saved, the operating environment of a relative close type is formed, through long
Phase is it is demonstrated experimentally that the continuous electrolysis purifier of the present invention can be on the basis of stabilization, Effec-tive Function, it is ensured that device structure designs
More rationally, technological process more it is succinct it is easy, the continuous electrolysis period is longer, easily worn part replacement operation is simpler.
The discharging stove includes that the upper furnace body, intermediate furnace body and lower furnace body, intermediate furnace body side of upper and lower connection setting connect
Connect material fetching mechanism, gate valve be equipped between material fetching mechanism and intermediate furnace body, so as to operating environment and discharging environment open and every
From.The hoe scaler of the deposit mechanism for stripping horizontally extends into intermediate furnace body, the shifting of the translation splicing switching mechanism
Moved end may pass through material fetching mechanism and be horizontally entered into intermediate furnace body with gate valve.
The electrolysis unit includes the inside and outside anode canister and barrel being set with, and the top surface of anode canister is equipped with gap, allows the moon
Pole rotation and lifting bar lower lift plate passes through.Cathode rotation and lifting bar lower part is correspondingly provided with sealing locating device, is further true
Fused salt crucible can be smoothly put by protecting anode canister（Barrel）It is interior, back taper ring is designed in anode canister bottom, in anode canister and fused salt
When micro- dislocation occurs for crucible, anode canister may be implemented to suffer from one's own actions middle function.
Sealing locating device includes lifting plate, positioning protrusion and the metal protection screen being arranged in the top of lifting plate, is promoted
Plate is the radial ringed polylith rectangle or fanning strip for being distributed on cathode rotation and lifting bar lower part, is at least laid with three pieces of promotions
Plate is equipped with positioning protrusion at the top of every piece of lifting plate, corresponding, in the radial ringed uniformly distributed polylith square of anode canister upper flange
Shape or fanning strip, are at least laid with three blocks of plates, and every block of plate has the circular hole for coordinating snapping with lifting plate positioning protrusion, works as promotion
When plate drops to anode canister upper flange lower part, cathode rotation and lifting bar drives lifting plate by dynamic rotation certain angle, and it is fixed to make
Position protrusion is mapped with the circular hole on the upper flange plate of anode canister, and cathode rotation and lifting bar is driven by lifting gear and promoted
Plate raises up anode canister, as a result, during the entire process of lifting plate is promoted and declined with anode canister, anode canister and lifting plate
Between any dislocation will not all occur, ensure that concentricity；To prevent the volatilization of salt in electrolytic process to inboard wall of furnace body and furnace body
Circular metal protecting screen is arranged on anode canister top in the enrichment of the gate valve of side, and metal protection screen is equipped with and is superposed up and down
Multilayer, outer diameter and material tube inner wall are that small―gap suture coordinates, and flue dust in electrorefining processes is isolated and volatilizees, setting metal protection screen
Second function be heat-insulated, metal protection screen can effectively obstruct the heat of fused salt, make the temperature of guide rod the upper half
Degree can be effectively reduced, while the metal screen of outer layer also can effectively scatter and disappear the heat on guide rod, to drop
Low middle and upper part guide rod temperature.
The cathode rotation and lifting bar is the metal enclosed tube body of inner hollow setting, the circulation cooling of metal tube cavity
The top both sides of water, metal tube are respectively equipped with inlet and outlet, and water inlet connects cooling water, water outlet by cooling water pipe
Pass through piping connection suction pump, cathode rotation and lifting bar lower thread connection electrode bar.
Cathode rotation and lifting bar is electrification, when being electrolysed in order to prevent in heating furnace as the cathode rod in cell reaction
Temperature it is excessively high the material of cathode rotation and lifting bar and connected seal assembly are damaged, inside cathode rotation and lifting bar
Logical cooling water, inlet and outlet are all disposed within the top of cathode rotation and lifting bar, intake from side, other side water outlet, from
And achieve the effect that cooling.
The rotary lifting mechanism includes lifting cylinder, lifting support and electric rotating machine, and lifting support is parallel to be vertically arranged between
The side of cathode rotation and lifting bar, lifting support one side are equipped with vertically arranged lifting sliding slot, are equipped on the outside of lifting sliding slot
The lifting sliding rail of protrusion, cathode rotation and lifting bar side is slidably mounted on by lifting slider on lifting sliding rail；Cathode rotation rises
The electric rotating machine equipped with its rotation of drive at the top of bar is dropped, lifting drive mechanism, the lifting slider inside are equipped in lifting support
It is fixedly connected with lifting drive mechanism output end.
The translation splicing switching mechanism includes splicing groove, upset motor, sliding support and translation motor, and splicing groove is
The shell of top surface opening, splicing groove side connect upset motor output end by horizontally disposed splicing bar, make splicing groove can be with
It is rotated around splicing bar axle center, upset motor bottom in sliding support by being slidably mounted in splicing groove translating rails, splicing groove
Translating rails are secured transverse in fixed platform, and the connection of sliding support side drives the translation motor of its translation, makes splicing groove
It can be along sliding support transverse shifting.
Two groups of sliding supports are set in upper fixed platform, parallel connection splicing bar, splicing bar one end are designed on sliding support
Splicing groove is set, and the other end is connect with the translation motor of the flexible transmission outside feeding stove or cylinder system, is only tied in feeding stove
Structure original paper, action execute original paper all outside vacuum reaction chamber, greatly ensure that service life and the simple operation of equipment
Property.
For the deposit mechanism for stripping at least provided with symmetrical two groups, every group includes hoe scaler, connecting rod, stripping push-and-pull
Motor and stripping sliding rail, hoe scaler are arranged for rectangular slab, and the inner face contacted with the cathode rotation and lifting bar is equipped with same arc
The arc groove of degree, two groups of hoe scalers simultaneously Contact cathod rotation and lifting bar when in its border be combined into complete annular contact surface,
The outer end face of hoe scaler connects connecting rod, and connecting rod connects stripping push-and-pull motor by push rod, and hoe scaler can be accurately arranged in motor
The amount of feeding, speed and displacement, it is more steady when removing deposit in this way.
The stripping sliding rail being laterally arranged is equipped with outside the hoe scaler, stripping sliding rail is the shell for being internally provided with rectangular enclosure
Body, stripping sliding rail inner end are fixedly mounted on discharging stove, and stripping sliding rail outer end is equipped with seal assembly, and seal form is wavy metal
The seal of tube or sealing ring sealing.
Hoe scaler uses split opposite structure, hoe scaler cutter head to be connect with stripping rod, and cutter head structure part is designed with
Semi arch blade is convenient for scraper, and design, which is oriented to, on intermediate furnace body wall removes sliding rail, has been that straight-line guidance is made to stripping rod one
With, second is that this stripping sliding rail is also the supporting surface of stripping rod stress in stripping process simultaneously, the straight line folding of hoe scaler（Namely into
It moves back）Support with power is all realized in rectangle slideway.
The material fetching mechanism is the feeding stove for being fixed on side in the middle part of discharging stove, is equipped with material taking mouth on the downside of feeding stove, takes
Material mouth is equipped with gate valve, plays the role of automatic sliding door.
The bottom of the heating furnace is equipped with liftable heating furnace cradle.
Heating furnace uses resistive cartridge stove for heater, resistance furnace preliminary design 10kW, heated vaccum case enter resistance furnace into
Heat is conducted to material by shell and realizes that melting, this heating process mode have been subjected to continuous electrolysis refining and test by row heat exchange
Card, effect is ideal, meets temperature control needs.
The lifting action of heating furnace cradle executes adds the structure that leading screw adds optical axis to be oriented to for decelerating motor, universal in conjunction with self-locking
Wheel realizes two combinative movements of lifting and translation of heater.
Compared with prior art, advantageous effect possessed by the present invention is：
The present invention will be electrolysed, deposit is removed and the processes such as feeding form integrated structure type, and discharge stove and heating furnace shape
At main furnace body structure include four melting electrolysis zone, electrolytic deposition material stripping area, material receiving area, material transition range functional areas
The connection combination of vacuum passage had not only may be implemented in domain, four functional areas, but also can independently separate, using horizontal retractable machinery
The tactic pattern of disk splicing, discharging so that electrical components are lacked in vacuum reaction room, effectively extend electrical service life,
And the replacement convenient for rapid wear electric elements.
According to the flow process of electrorefining, the functions such as material melting of the invention, electrorefining, deposit stripping are vertical
Structure arranges that material transfer is horizontally disposed, forms Trinitarian continuous electrolysis ergasia in this way, both ensure that this technique
The work characteristics of procedure, serialization, and working space has been saved, the operating environment of a relative close type is formed, through long
Phase is it is demonstrated experimentally that the continuous electrolysis purifier of the present invention can be on the basis of stabilization, Effec-tive Function, it is ensured that device structure designs
More rationally, technological process more it is succinct it is easy, the continuous electrolysis period is longer, easily worn part replacement operation is simpler.
Description of the drawings
Fig. 1 is continuous electrolysis purifier front view schematic diagram；
Fig. 2 is continuous electrolysis purifier side view schematic diagram；
Fig. 3 is continuous electrolysis purifier top view illustration；
Fig. 4 is deposit mechanism for stripping structural schematic diagram；
Fig. 5 is rotary lifting mechanism structural schematic diagram；
Fig. 6 is translation splicing switching mechanism structural schematic diagram；
Fig. 7 is the part A close-up schematic view of Fig. 1；
Fig. 8 is the part B close-up schematic view of Fig. 1；
Fig. 9 is cathode rotation and lifting bar and lifting drive mechanism installation relation schematic diagram.
Wherein, 1, upper bracket, 101, leading screw, 102, leading screw rotary electric machine, 2, cathode rotation and lifting bar, 201, lifting plate,
202, positioning protrusion, 203, metal protection screen, 204, electrode stem, 205, water inlet, 206, water outlet, 3, upper furnace body, 301, on
Bell, 4, intermediate furnace body, 5, lower furnace body, 6, barrel, 7, anode canister, 8, heating furnace, 9, heating furnace cradle, 10, feeding stove,
1001, discharging door, 11, translation splicing switching mechanism, 1101, splicing groove, 1102, splicing bar, 1103, upset motor, 1104,
Sliding support, 1105, translation motor, 1106, splicing groove translating rails, 12, lower part fixed platform, 13, deposit mechanism for stripping,
1301, hoe scaler, 1302, connecting rod, 1303, push rod, 1304, stripping push-and-pull motor, 1305, stripping sliding rail, 14, evacuator
Structure, 1401, vacuum tube, 1402, vacuum pump, 15, upper fixed platform, 16, rotary lifting mechanism, 1601, lifting cylinder, 1602,
Lifting support, 1603, lifting sliding rail, 1604, lifting sliding slot, 1605, lifting slider, 1606, electric rotating machine, 17, gate valve.
Specific implementation mode
Fig. 1 ~ 9 are highly preferred embodiment of the present invention, and 1 ~ 9 the present invention will be further described below in conjunction with the accompanying drawings.
With reference to attached drawing 1 ~ 9：A kind of continuous electrolysis purifier, including upper fixed platform 15, the cathode rotation and lifting that is vertically arranged
Bar 2, discharge stove and heating furnace 8, and discharging stove is fixedly mounted in upper fixed platform 15 and heating furnace 8, the lower part for the stove that discharges are sleeved on
In heating furnace 8, discharging stove lower lumen is equipped with electrolysis unit, and the lower part of cathode rotation and lifting bar 2 passes through discharging stove to enter electrolysis
Discharging furnace roof portion is stretched out on the top of device, cathode rotation and lifting bar 2, and the top side for the stove that discharges, which is equipped with, drives cathode rotation and lifting
2 vertical lifting of bar or the rotary lifting mechanism 16 of rotation；The middle part side of discharging stove is equipped with the translation splicing overturning being laterally arranged
Mechanism 11 and deposit mechanism for stripping 13,11 one end of translation splicing switching mechanism connect discharging stove by material fetching mechanism, and discharge stove
Vacuum device 14 is connected with the side of heating furnace 8 simultaneously.
A upper fixed platform 15 can be also arranged in the outside of discharging stove, and upper bracket 1 is arranged at 15 top of upper fixed platform, on
Holder 1 includes the leading screw rotary electric machine 102 that the multigroup upper bracket leading screw 101 being vertically arranged is connected with 101 one end of upper bracket leading screw, upper stove
The top of body 3 is equipped with can be by the upper bell 301 of the rotation oscilaltion of upper bracket leading screw 101, four angles point of upper bell 301
Multigroup upper bracket leading screw 101 is not connected by ball-screw bearing, 301 middle part of upper bell, which is equipped with, allows cathode rotation and lifting bar 2
The through-hole passed through.
Discharging stove includes the upper furnace body 3, intermediate furnace body 4 and lower furnace body 5 of upper and lower connection setting, the connection of 4 side of intermediate furnace body
Material fetching mechanism is equipped with gate valve 17, the hoe scaler of the deposit mechanism for stripping 13 between material fetching mechanism and intermediate furnace body 4
1301 horizontally extend into intermediate furnace body 4, and the mobile terminal of the translation splicing switching mechanism 11 may pass through material fetching mechanism and plate
Valve 17 horizontally enters into intermediate furnace body 4.
With reference to attached drawing 8 and 9：Electrolysis unit includes the inside and outside anode canister 7 being set with and barrel 6, and the top surface of anode canister 7, which is equipped with, to hold
Perhaps the strip hole that 2 lower part of cathode rotation and lifting bar passes through, 2 lower part of cathode rotation and lifting bar are correspondingly provided with sealing locating device, sun
The top surface of pole cylinder 7 is equipped with gap, and 2 lower lift plate 201 of cathode rotation and lifting bar is allowed to pass through.The cathode rotation and lifting bar being vertically arranged
2 inside are hollow metal enclosed tube body, and metal tube cavity circulation cooling water, the top both sides of metal tube are respectively equipped with water inlet
205 and water outlet 206, water inlet 205 connects cooling water by cooling water pipe, and water outlet 206 passes through piping connection suction pump, cloudy
2 lower thread connection electrode bar 204 of pole rotation and lifting bar；Sealing locating device include lifting plate 201, positioning protrusion 202 and
The metal protection screen 203 of the top setting of lifting plate 201, lifting plate 201 are radial ringed be distributed under cathode rotation and lifting bar 2
The plurality of plates in portion is at least laid with three pieces of lifting plates 201, and the top of every piece of lifting plate 201 is equipped with positioning protrusion 202, with
Corresponding, the corresponding position on the upper flange plate of anode canister 7, the circular hole for coordinating snapping with positioning protrusion 202 is equipped with, when carrying
When lift slab 201 drops to anode flange frame bottom, cathode rotation and lifting bar 2 drives lifting plate 201 to pass through the certain angle of dynamic rotation
Degree, makes positioning protrusion 202 be mapped with the circular hole on the upper flange plate of anode canister 7, and cathode rotation and lifting bar 2 is filled by lifting
It sets and drives lifting plate 201, anode canister 7 is raised up, promote the whole process declined with anode canister 7 in lifting plate 201 as a result,
In, any dislocation will not all occur between anode canister 7 and lifting plate 201, ensure that concentricity；To prevent salt in electrolytic process
The enrichment volatilized to the gate valve of inboard wall of furnace body and furnace body side, on 7 top of anode canister, setting metal protection screen 203, metal is anti-
Shield screen 203 is equipped with the multilayer being superposed up and down, and outer diameter coordinates for small―gap suture with material tube inner wall, is isolated in electrorefining processes
Flue dust volatilizees, and second function of setting metal protection screen 203 is heat-insulated, and metal protection screen 203 can be effectively by fused salt
Heat is obstructed, and the temperature of guide rod the upper half is allow to be effectively reduced, while the metal screen of outer layer also can be effective
Heat on guide rod is scattered and disappeared, to reduce middle and upper part guide rod temperature.With reference to attached drawing 5：Rotary lifting mechanism 16 includes rising
Oil cylinder 1601, lifting support 1602 and electric rotating machine 1606 drop, and lifting support 1602 is parallel to be vertically arranged between cathode rotation and lifting bar 2
Side, 1602 one side of lifting support are equipped with vertically arranged lifting sliding slot 1604, and 1604 outside of lifting sliding slot is equipped with protrusion
Lifting sliding rail 1603,2 side of cathode rotation and lifting bar is slidably mounted on by lifting slider 1605 on lifting sliding rail 1603；It is cloudy
Rotation and lifting bar 2 top in pole is equipped with the electric rotating machine 1606 for driving its rotation, and lifting drive mechanism is equipped in lifting support 1602,
1605 inside of lifting slider is fixedly connected with lifting drive mechanism output end.
Specifically, lifting drive mechanism can be the lifting cylinder 1601 that 1602 top of lifting support is vertically arranged, lifting cylinder
1601 output end is mounted on 1602 inner cavity of lifting support, and 1605 inside of lifting slider is fixedly connected with the output of lifting cylinder 1601
End, alternatively, lifting drive mechanism is alternatively the drive mechanism of lifting motor and elevating screw, lifting motor is vertically arranged between lifting support
1602 top, the output end of lifting motor, which stretches into 1602 inner cavity of lifting support and connects, is vertically arranged between 1602 inner cavity of lifting support
Elevating screw, 1605 inside of lifting slider are fixedly connected on elevating screw.
With reference to attached drawing 6：It includes splicing groove 1101, upset motor 1103, sliding support 1104 to translate splicing switching mechanism 11
With translation motor 1105, splicing groove 1101 is the shell of top surface opening, and 1101 side of splicing groove passes through horizontally disposed splicing bar
1102 connection 1103 output ends of upset motor, 1103 bottom of upset motor in sliding support 1104 by being slidably mounted on splicing groove
In translating rails 1106, splicing groove translating rails 1106 are secured transverse in fixed platform 15, and 1104 side of sliding support connects
Tape splicing moves the translation motor 1105 of its translation.
With reference to attached drawing 4：For deposit mechanism for stripping 13 at least provided with symmetrical two groups, every group includes hoe scaler 1301, company
Bar 1302, stripping push-and-pull motor 1304 and stripping sliding rail 1305, hoe scaler 1301 is arranged for rectangular slab, with cathode rotation and lifting bar
The inner faces of 2 contacts are equipped with the arc groove with radian, two groups of hoe scalers 1301 simultaneously Contact cathod rotation and lifting bar 2 when
Its border is combined into complete annular contact surface；The outer end face of hoe scaler 1301 connects connecting rod 1302, and connecting rod 1302 passes through push rod
1303 connection stripping push-and-pull motors 1304,1301 outside of hoe scaler is equipped with the stripping sliding rail 1305 being laterally arranged, removes sliding rail
1305 be the shell for being internally provided with rectangular enclosure, and 1305 inner end of stripping sliding rail is fixedly mounted on discharging stove, removes sliding rail 1305
Outer end is equipped with seal assembly.
Material fetching mechanism is the feeding stove 10 for being fixed on side in the middle part of discharging stove, and 10 side of feeding stove is equipped with material taking mouth, feeding
Mouth is equipped with discharging door 1001, and the bottom of heating furnace 8 is equipped with liftable heating furnace cradle 9.
The present invention is at work：Vacuum requirement≤5Pa is configured by level-one unit contruction pump, main furnace body chamber（That is intermediate furnace
Body 4）With splicing transfer chamber（Feeding stove 10）Share a set of vacuum system, when operation among furnace body 4 and 10 two, feeding stove it is true
Plenum chamber realizes partition or unicom by high vacuum gate valve 17, and one DC output power of DC electrolysis system configuration, output is directly
Galvanic electricity presses 0-2V, maximum output DC current 80A, a pole to be imported by the cathode rotation and lifting bar 2 that top is arranged, cathode rotation
Elevating lever 2 is connected through a screw thread with electrode stem 204, so that electrode stem 204 charges, and another pole is connected on barrel 6.
First, cathode rotation and lifting bar 2 declines under the drive of lifting cylinder 1601 and lifting slider 1605 so that cathode
The lower part of rotation and lifting bar 2 is stretched into barrel 6, meanwhile, lifting plate 201 is fastened with anode canister 7, under cathode rotation and lifting bar 2
The electrode stem 204 in portion is powered, and 204 top of electrode stem is mutual with external screw thread and the internal thread of the lower part of cathode rotation and lifting bar 2
Cooperation is tightened.Meanwhile being heated by heating furnace 8, heating furnace 8 uses resistive cartridge stove for heater, resistance furnace preliminary design 10kW, under
It is vacuumized in furnace body 5, the vaccum case lower furnace body 5 that is heated carries out heat exchange in heating furnace 8, and heat is conducted to object by shell
Material realizes melting.
Electrode stem 204 is that cathode is negatively charged, and the barrel 6 and lower furnace body 5 that anode canister 7 connects are that anode is positively charged, electrode stem
204 occur cell reaction in anode canister 7, and positive metal atoms ion gathers electrode stem 204, must be electronically generated metal simple-substance,
It is adsorbed onto on electrode stem 204, as metal simple-substance is continuously generated aggregation, the metal simple-substance for being adsorbed onto electrode stem 204 is constantly assembled
Increase, after reaction, drives cathode rotation and lifting bar 2 and lifting plate 201 to rotate by electric rotating machine 1606 so that lifting plate
201 disengagings are fastened and connected with anode canister 7, then are promoted to intermediate furnace body by lifting cylinder 1601 and the drive of lifting slider 1605
4 inner cavities, at this point, the hoe scaler 1301 in 4 both sides of intermediate furnace body is arranged in stripping push-and-pull motor 1304, connecting rod 1302 and push rod
1303, under the cooperation of stripping sliding rail 1305, translate, until two groups of hoe scalers 1301 rotate cathode to cathode rotation and lifting bar 2
Elevating lever 2 clamps, and drives cathode rotation and lifting bar 2 to be lifted up again by lifting cylinder 1601 and lifting slider 1605, leads to
Cross stripping of the realization of hoe scaler 1301 to the deposit on cathode rotation and lifting bar 2；It is removed simultaneously in electrodeposit, material
Connect Sheng and transfer need individually designed system to realize, in material receiving area, horizontal direction increases material and connects Sheng and transfer system, it is intermediate with
Gate valve 17 carries out opening and being isolated for operating environment.
Before cathode rotation and lifting bar 2 is lifted up, gate valve 17 is opened, splicing groove 1101 is in 1104 He of sliding support
Being driven through 10 inner cavity of feeding stove and then entering in intermediate furnace body 4 for translation motor 1105, rests on cathode rotation and lifting bar 2
Underface, when stripping, material is fallen in splicing groove 1101, and stripping terminates, and splicing groove 1101 is retracted into feeding stove 10
Chamber closes gate valve 17, and splicing groove 1101 is parked in the upside of the positions Xia Kou of discharging gate valve 1001, opens discharging gate valve
1001, by rotating mechanism 1103, by quickly 180 ° of the overturning of splicing groove 1101, you can material is taken out, meanwhile, hoe scaler 1301
It is resetted outward under stripping push-and-pull motor 1304, connecting rod 1302 and push rod 1303 and the cooperation for removing sliding rail 1305.
In addition, cathode rotation and lifting bar 2 is as the cathode rod in cell reaction, it is electronegative, when being electrolysed in order to prevent
Temperature in heating furnace is excessively high to damage the material of cathode rotation and lifting bar 2 and connected seal assembly, is rotated in cathode
2 inside of elevating lever leads to cooling water, and water inlet 205 and water outlet 206 are all disposed within the top of cathode rotation and lifting bar 2, from side
Water inlet, other side water outlet are cooling to achieve the effect that.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Embodiment is imitated, but it is every without departing from technical solution of the present invention content, according to the technical essence of the invention to above example institute
Any simple modification, equivalent variations and the remodeling made, still fall within the protection domain of technical solution of the present invention.
Claims (10)
1. a kind of continuous electrolysis purifier, including upper fixed platform（15）, the cathode rotation and lifting bar that is vertically arranged（2）, discharging stove
And heating furnace（8）, it is characterised in that：Upper fixed platform（15）Upper fixed installation discharging stove and heating furnace（8）, the lower part for the stove that discharges
It is sleeved on heating furnace（8）Interior, discharging stove lower lumen is equipped with electrolysis unit, cathode rotation and lifting bar（2）Lower part pass through discharging
Stove enters electrolysis unit, cathode rotation and lifting bar（2）Top stretch out discharging furnace roof portion, the top side for the stove that discharges, which is equipped with, to be driven
Cathode rotation and lifting bar（2）Vertical lifting or the rotary lifting mechanism of rotation（16）；The middle part side of discharging stove, which is equipped with, laterally to be set
The translation splicing switching mechanism set（11）With deposit mechanism for stripping（13）, translate splicing switching mechanism（11）One end passes through feeding
Mechanism connection discharging stove, discharge stove and heating furnace（8）Side simultaneously connect vacuum device（14）.
2. according to claim 1, it is characterised in that：The discharging stove includes the upper furnace body of upper and lower connection setting（3）、
Intermediate furnace body（4）And lower furnace body（5）, intermediate furnace body（4）Side connects material fetching mechanism, material fetching mechanism and intermediate furnace body（4）Between
Equipped with gate valve（17）, the deposit mechanism for stripping（13）Hoe scaler（1301）Horizontally extend into intermediate furnace body（4）It is interior, institute
The translation splicing switching mechanism stated（11）Mobile terminal may pass through material fetching mechanism and gate valve（17）Horizontally enter into intermediate furnace body（4）
It is interior.
3. a kind of continuous electrolysis purifier according to claim 1, it is characterised in that：The electrolysis unit includes interior
The anode canister of outer suit（7）And barrel（6）, anode canister（7）Top surface be equipped with allow cathode rotation and lifting bar（2）What lower part passed through
Strip hole, cathode rotation and lifting bar（2）Lower part is correspondingly provided with sealing locating device.
4. a kind of continuous electrolysis purifier according to claim 1, it is characterised in that：The cathode rotation being vertically arranged rises
Bar drops（2）Inside is hollow metal enclosed tube body, and metal tube cavity circulation cooling water, the top both sides of metal tube are respectively equipped with
Water inlet（205）And water outlet（206）, water inlet（205）Cooling water, water outlet are connected by cooling water pipe（206）Pass through pipe
Road connects suction pump, metal tube lower thread connection electrode bar（204）.
5. a kind of continuous electrolysis purifier according to claim 1, it is characterised in that：The rotary lifting mechanism
（16）Including lifting cylinder（1601）, lifting support（1602）And electric rotating machine（1606）, lifting support（1602）It is parallel to be vertically arranged
In cathode rotation and lifting bar（2）Side, lifting support（1602）One side is equipped with vertically arranged lifting sliding slot（1604）,
Lift sliding slot（1604）Outside is equipped with the lifting sliding rail of protrusion（1603）, cathode rotation and lifting bar（2）Side passes through lifting slider
（1605）It is slidably mounted on lifting sliding rail（1603）On；Cathode rotation and lifting bar（2）Top is equipped with the electric rotating for driving its rotation
Machine（1606）, lifting support（1602）It is interior to be equipped with lifting drive mechanism, the lifting slider（1605）Inside is fixedly connected with lifting
Actuating unit output end.
6. a kind of continuous electrolysis purifier according to claim 1 or 2, it is characterised in that：The translation splicing is turned over
Rotation mechanism（11）Including splicing groove（1101）, upset motor（1103）, sliding support（1104）And translation motor（1105）, splicing
Slot（1101）For the shell of top surface opening, splicing groove（1101）Side passes through horizontally disposed splicing bar（1102）Connection overturning electricity
Machine（1103）Output end, upset motor（1103）Bottom passes through in sliding support（1104）It is slidably mounted on splicing groove translating rails
（1106）It is interior, splicing groove translating rails（1106）It is secured transverse to fixed platform（15）On, sliding support（1104）Side connects
Tape splicing moves the translation motor 1105 of its translation.
7. a kind of continuous electrolysis purifier according to claim 1 or 2, it is characterised in that：The deposit stripping
Mechanism（13）At least provided with symmetrical two groups, every group includes hoe scaler（1301）, connecting rod（1302）, stripping push-and-pull motor
（1304）With stripping sliding rail（1305）, hoe scaler（1301）It is arranged for rectangular slab, with the cathode rotation and lifting bar（2）Contact
Inner face is equipped with the arc groove with radian, two groups of hoe scalers（1301）Contact cathod rotation and lifting bar simultaneously（2）Shi Qi
Border is combined into complete annular contact surface；Hoe scaler（1301）Outer end face connect connecting rod（1302）, connecting rod（1302）By pushing away
Bar（1303）Connection stripping push-and-pull motor（1304）.
8. a kind of continuous electrolysis purifier according to claim 7, it is characterised in that：The hoe scaler（1301）Outside
Portion is equipped with the stripping sliding rail being laterally arranged（1305）, remove sliding rail（1305）To be internally provided with the shell of rectangular enclosure, stripping is slided
Rail（1305）Inner end is fixedly mounted on discharging stove, removes sliding rail（1305）Outer end is equipped with seal assembly.
9. a kind of continuous electrolysis purifier according to claim 1, it is characterised in that：The material fetching mechanism is to fix
The feeding stove of side in the middle part of discharging stove（10）, feeding stove（10）Side is equipped with material taking mouth, and material taking mouth is equipped with discharging door
（1001）.
10. a kind of continuous electrolysis purifier according to claim 1, it is characterised in that：The bottom of the heating furnace 8
Equipped with liftable heating furnace cradle 9.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810602786.2A CN108660485A (en) | 2018-06-12 | 2018-06-12 | A kind of continuous electrolysis purifier |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810602786.2A CN108660485A (en) | 2018-06-12 | 2018-06-12 | A kind of continuous electrolysis purifier |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112030194A (en) * | 2020-09-02 | 2020-12-04 | 李宁 | Molten salt electrolysis device for preparing metal mixed powder |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523847A (en) * | 2017-08-14 | 2017-12-29 | 有研亿金新材料有限公司 | A kind of rotary double-station high pure metal fused salt electrolysis apparatus |
| CN108221005A (en) * | 2018-03-24 | 2018-06-29 | 淄博业齐机械设备有限公司 | A kind of continuous electrolysis purifier |
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2018
- 2018-06-12 CN CN201810602786.2A patent/CN108660485A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523847A (en) * | 2017-08-14 | 2017-12-29 | 有研亿金新材料有限公司 | A kind of rotary double-station high pure metal fused salt electrolysis apparatus |
| CN108221005A (en) * | 2018-03-24 | 2018-06-29 | 淄博业齐机械设备有限公司 | A kind of continuous electrolysis purifier |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112030194A (en) * | 2020-09-02 | 2020-12-04 | 李宁 | Molten salt electrolysis device for preparing metal mixed powder |
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Application publication date: 20181016 |