CN108659605A - A kind of preparation method and applications of ink anti-pollution modifying agent - Google Patents
A kind of preparation method and applications of ink anti-pollution modifying agent Download PDFInfo
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- CN108659605A CN108659605A CN201810547209.8A CN201810547209A CN108659605A CN 108659605 A CN108659605 A CN 108659605A CN 201810547209 A CN201810547209 A CN 201810547209A CN 108659605 A CN108659605 A CN 108659605A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Life Sciences & Earth Sciences (AREA)
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- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of preparation method and applications of ink anti-pollution modifying agent, extract is prepared into through a series of processing using the bast of anti-pollution type plant silk cotton tree and Chinese parasol tree tree, and it is introduced into the poly- polypeptide solution of biodegradable sill, processing is modified using non-thermal plasma trap, improves the binding ability of the two；The bast of pollution-resistant plant has higher stain resistance, can effectively improve the anti-pollution and soil pick-up ability of whole ink, and in conjunction with the carrier of poly- polypeptide, when further increasing its application and the biocompatibility of ink has following advantages compared with prior art：Water-based ink after processing not only has splendid antifouling property, and anti-pollution persistence is good, uses raw material is most of to have environmentally friendly low-carbon for natural environmental-protective plant extract, is free of noxious material, safe advantage.
Description
Technical field
The present invention relates to the preparation method of the preparation method of ink addition agent more particularly to a kind of ink anti-pollution modifying agent and its
Using.
Background technology
With the rapid development of Chinese national economy, the prosperity of press-packaging industry has driven the manufacturing fast short-term training of ink
It is long so that China emerges rapidly between the nearest more than ten years becomes one of world's ink manufacture big country, at present country's ink industry
Scale is just maintained sustained and rapid growth with 10% or more speed.
Ink mainly has the types such as solvent ink, water-based ink, UV ink, ink for screen printing, offset ink；Wherein aqueous oil
Ink has preferable anti-sticking greasy property and waterproof antifouling property；But the water-based ink that domestic production at present goes out exists simultaneously
The problem that the feature of environmental protection is not strong or even some are below standard, the in addition insufficient supply of high-grade ink.
Existing anti-pollution ink major part is improved from formula, how to be carried out one to existing ink finished product and is changed
Property agent simple addition handle and improve its stain resistance, it will have a broader market prospects.
Invention content
Goal of the invention：In order to solve the problems of prior art, the present invention provides a kind of ink anti-pollution modifying agent
Preparation method and applications；Treated, and ink not only has excellent antifouling property, its own is free of harmful chemicals
Matter has environmentally friendly low-carbon, the harmless advantage of health.
Technical solution：In order to achieve the above objectives, the present invention uses following technical scheme：A kind of system of ink anti-pollution modifying agent
Preparation Method includes the following steps：
(1) select silk cotton tree, Chinese parasol tree tree bast co-grinding to 60 mesh, the water of 20-30 times of quality of addition first carries out
Once boiling processing is added highly basic, hydrogen peroxide and sodium citrate and carries out degumming process, and boiling temperature is 180 DEG C, digestion time
For 30-40min；
(2) boiling, which finishes, is placed on 200W processing 2-3min in microwave heating appts；It takes out and is added totally after being disposed
The sodium acetate of product 1/10th, progress is secondary boiled, and boiling temperature is 120 DEG C, digestion time 10-20min；It is added after the completion
The eighth polyalcohol of total volume, be heated to 120 DEG C maintain 2h after be added and filter to get filtrate；Vacuum distillation drying obtains component A；
(3) component A is added in poly- polypeptide solution, adding proportion obtains mixture, mixture for the 20% of solution quality
It is placed in low-temperature plasma device and takes the method for radiating progress successively of dual wavelength two temperature, short wave ultraviolet is first used at -5 DEG C
It is radiated, radiated time keeps 10min；It is then warming up to 5 DEG C to be radiated using ultraviolet B radiation, radiated time is
15min is up to ink anti-pollution modifying agent finished product.
More preferably, the mass ratio of silk cotton tree and Chinese parasol tree tree is 3 in step (1):2.
More preferably, highly basic described in step (1) is sodium hydroxide and potassium hydroxide quality ratio is 1:1 mixture.
More preferably, the addition of step (1) described highly basic is 1g/L；The addition of hydrogen peroxide is 3g/L；Citric acid
The addition of sodium is 2g/L.
More preferably, polyalcohol described in step (2) is glycerine.
More preferably, step (3) intermediate waves ultraviolet wavelength is 260nm.
More preferably, ultraviolet B radiation wavelength is 320nm in step (3).
The invention also discloses the application of ink anti-pollution modifying agent prepared by above-mentioned preparation method, specific adding proportion is water
The 3% of property ink quality；It is added in three times, first time addition is the half of total amount, and 65 DEG C are heated to after stirring evenly
Second of addition is carried out after maintaining 20min, addition is the half of surplus, and 85 DEG C of heat preservation 15min are warming up to after mixing uniformly
The printing ink modifier of surplus is added afterwards, room temperature is down to after 105 DEG C of heat preservation 10min are warming up to after stirring evenly to obtain the final product.
Advantageous effect：A kind of preparation method and applications of ink anti-pollution modifying agent provided by the present invention；With existing skill
Art is compared, and has following advantages：Water-based ink after processing not only has splendid antifouling property, and anti-pollution persistence
It is good, it uses raw material is most of to have environmentally friendly low-carbon for natural environmental-protective plant extract, is free of noxious material, safe advantage.
Specific implementation mode
With reference to specific embodiment, invention is further explained：
Embodiment 1：
A kind of preparation method of ink anti-pollution modifying agent, includes the following steps：
(1) select mass ratio for 3:20 times of quality are added in 2 silk cotton tree, the bast co-grinding of Chinese parasol tree tree to 60 mesh
Water, first carry out once boiling processing, highly basic be added, hydrogen peroxide and sodium citrate carry out degumming process, boiling temperature 180
DEG C, digestion time 30min；The highly basic is sodium hydroxide and potassium hydroxide quality ratio is 1:1 mixture；The highly basic
Addition is 1g/L；The addition of hydrogen peroxide is 3g/L；The addition of sodium citrate is 2g/L；
(2) boiling, which finishes, is placed on 200W processing 2min in microwave heating appts；It is taken out after being disposed and total volume is added
/ 10th sodium acetate, progress is secondary boiled, and boiling temperature is 120 DEG C, digestion time 10min；It is added after the completion overall
The eighth glycerine of product is heated to 120 DEG C and maintains to be added after 2h to filter to get filtrate；Vacuum distillation drying obtains component A；
(3) component A is added in poly- polypeptide solution, adding proportion obtains mixture, mixture for the 20% of solution quality
It is placed in low-temperature plasma device and takes the method for radiating progress successively of dual wavelength two temperature, first at -5 DEG C using the short of 260nm
Wave ultraviolet light is radiated, and radiated time keeps 10min；It is then warming up to 5 DEG C of ultraviolet B radiations using 320nm and carries out spoke
It penetrates, radiated time is 15min up to ink anti-pollution modifying agent finished product.
The invention also discloses the application of ink anti-pollution modifying agent prepared by above-mentioned preparation method, specific adding proportion is water
The 3% of property ink quality；It is added in three times, first time addition is the half of total amount, and 65 DEG C are heated to after stirring evenly
Second of addition is carried out after maintaining 20min, addition is the half of surplus, and 85 DEG C of heat preservation 15min are warming up to after mixing uniformly
The printing ink modifier of surplus is added afterwards, room temperature is down to after 105 DEG C of heat preservation 10min are warming up to after stirring evenly to obtain the final product.
Embodiment 2：
A kind of preparation method of ink anti-pollution modifying agent, includes the following steps：
(1) select mass ratio for 3:30 times of quality are added in 2 silk cotton tree, the bast co-grinding of Chinese parasol tree tree to 60 mesh
Water, first carry out once boiling processing, highly basic be added, hydrogen peroxide and sodium citrate carry out degumming process, boiling temperature 180
DEG C, digestion time 40min；The highly basic is sodium hydroxide and potassium hydroxide quality ratio is 1:1 mixture；The highly basic
Addition is 1g/L；The addition of hydrogen peroxide is 3g/L；The addition of sodium citrate is 2g/L；
(2) boiling, which finishes, is placed on 200W processing 3min in microwave heating appts；It is taken out after being disposed and total volume is added
/ 10th sodium acetate, progress is secondary boiled, and boiling temperature is 120 DEG C, digestion time 20min；It is added after the completion overall
The eighth glycerine of product is heated to 120 DEG C and maintains to be added after 2h to filter to get filtrate；Vacuum distillation drying obtains component A；
(3) component A is added in poly- polypeptide solution, adding proportion obtains mixture, mixture for the 20% of solution quality
It is placed in low-temperature plasma device and takes the method for radiating progress successively of dual wavelength two temperature, first at -5 DEG C using the short of 260nm
Wave ultraviolet light is radiated, and radiated time keeps 10min；It is then warming up to 5 DEG C of ultraviolet B radiations using 320nm and carries out spoke
It penetrates, radiated time is 15min up to ink anti-pollution modifying agent finished product.
The invention also discloses the application of ink anti-pollution modifying agent prepared by above-mentioned preparation method, specific adding proportion is water
The 3% of property ink quality；It is added in three times, first time addition is the half of total amount, and 65 DEG C are heated to after stirring evenly
Second of addition is carried out after maintaining 20min, addition is the half of surplus, and 85 DEG C of heat preservation 15min are warming up to after mixing uniformly
The printing ink modifier of surplus is added afterwards, room temperature is down to after 105 DEG C of heat preservation 10min are warming up to after stirring evenly to obtain the final product.
Embodiment 3：
A kind of preparation method of ink anti-pollution modifying agent, includes the following steps：
(1) select mass ratio for 3:25 times of quality are added in 2 silk cotton tree, the bast co-grinding of Chinese parasol tree tree to 60 mesh
Water, first carry out once boiling processing, highly basic be added, hydrogen peroxide and sodium citrate carry out degumming process, boiling temperature 180
DEG C, digestion time 36min；The highly basic is sodium hydroxide and potassium hydroxide quality ratio is 1:1 mixture；The highly basic
Addition is 1g/L；The addition of hydrogen peroxide is 3g/L；The addition of sodium citrate is 2g/L；
(2) boiling, which finishes, is placed on 200W processing 2min in microwave heating appts；It is taken out after being disposed and total volume is added
/ 10th sodium acetate, progress is secondary boiled, and boiling temperature is 120 DEG C, digestion time 15min；It is added after the completion overall
The eighth glycerine of product is heated to 120 DEG C and maintains to be added after 2h to filter to get filtrate；Vacuum distillation drying obtains component A；
(3) component A is added in poly- polypeptide solution, adding proportion obtains mixture, mixture for the 20% of solution quality
It is placed in low-temperature plasma device and takes the method for radiating progress successively of dual wavelength two temperature, first at -5 DEG C using the short of 260nm
Wave ultraviolet light is radiated, and radiated time keeps 10min；It is then warming up to 5 DEG C of ultraviolet B radiations using 320nm and carries out spoke
It penetrates, radiated time is 15min up to ink anti-pollution modifying agent finished product.
The invention also discloses the application of ink anti-pollution modifying agent prepared by above-mentioned preparation method, specific adding proportion is water
The 3% of property ink quality；It is added in three times, first time addition is the half of total amount, and 65 DEG C are heated to after stirring evenly
Second of addition is carried out after maintaining 20min, addition is the half of surplus, and 85 DEG C of heat preservation 15min are warming up to after mixing uniformly
The printing ink modifier of surplus is added afterwards, room temperature is down to after 105 DEG C of heat preservation 10min are warming up to after stirring evenly to obtain the final product.
Using test：
Comparative example：Commercially available water-based ink.
Ink anti-pollution modifying agent prepared by embodiment 1, embodiment 2, embodiment 3 is applied in commercially available water-based ink,
It is prepared into paint film according to spray coating method respectively together with comparative example, to the appearance of paint film, volatile organic compounds, transparency, light
Damp degree, adhesive force, tinting strength, tinting power, stain resistance are measured.
Wherein：
Volatile organic compounds is measured with reference to the method for GB/T23986-2009；
Glossiness is detected using tri- angle type vancometers of MN268, and crevice projection angle is 60 °；
Adhesive force is detected using cross-hatching；
Tinctorial yield is detected with reference to the method for GB/T14624.2-2008, and test condition temperature is 25 ± 1 DEG C, relatively wet
Degree is 65 ± 5%；Calculation formula S=B/A × 100% of tinting strength, tinting power percentage, wherein S are tinctorial yield percentage, and A rushes for standard specimen
Light white ink dosage, B are that sample waters down chalk dosage；
Transparency is detected by the way of expert opinion；
Stain resistance test method is as follows：
A4 paper is coverd on one piece of plank, then by paint film brush on A4 paper, with free ink pen, oil pen in paint film after dry
On write see whether can erase test stain resistance；The then new mopping film on writing, whether observation writing is complete after dry
Covering；
Test result is as follows：
1 ink performance test comparison of table
A kind of ink prepared by the preparation method of ink anti-pollution modifying agent of the present invention is can be seen that from the test data of table 1
Anti-pollution modifying agent is applied in commercially available water-based ink and goes after being modified processing, and stain resistance significantly improves, while volatility has
Machine compounds content is low, Environmental Safety, and glossiness, adhesive force, tinctorial yield and transparency are better than untreated aqueous oil
Ink.
It should be pointed out that the above specific implementation mode is only illustrative of the invention and is not intended to limit the scope of the invention,
After having read the present invention, those skilled in the art fall within appended by the application the modification of the various equivalent forms of the present invention and weigh
Profit requires limited range.
Claims (8)
1. a kind of preparation method of ink anti-pollution modifying agent, it is characterised in that include the following steps：
(1) select silk cotton tree, Chinese parasol tree tree bast co-grinding to 60 mesh, the water of 20-30 times of quality is added, first carries out once
Boiling is handled, and highly basic, hydrogen peroxide and sodium citrate is added and carries out degumming process, boiling temperature is 180 DEG C, and digestion time is
30-40min；
(2) boiling, which finishes, is placed on 200W processing 2-3min in microwave heating appts；It is taken out after being disposed and total volume ten is added
/ mono- sodium acetate, progress is secondary boiled, and boiling temperature is 120 DEG C, digestion time 10-20min；It is added after the completion overall
The eighth polyalcohol of product is heated to 120 DEG C and maintains to be added after 2h to filter to get filtrate；Vacuum distillation drying obtains component A；
(3) component A is added in poly- polypeptide solution, adding proportion obtains mixture for the 20% of solution quality, and mixture is placed in
Dual wavelength two temperature is taken in low-temperature plasma device, and method of radiating carries out successively, is first carried out using short wave ultraviolet at -5 DEG C
Radiation, radiated time keep 10min；It is then warming up to 5 DEG C to be radiated using ultraviolet B radiation, radiated time is for 15min
Obtain ink anti-pollution modifying agent finished product.
2. a kind of preparation method of ink anti-pollution modifying agent according to claim 1, it is characterised in that：It is wooden in step (1)
The mass ratio of cotton plant and Chinese parasol tree tree is 3:2.
3. a kind of preparation method of ink anti-pollution modifying agent according to claim 1, it is characterised in that：Institute in step (1)
State that highly basic is sodium hydroxide and potassium hydroxide quality ratio is 1:1 mixture.
4. a kind of preparation method of ink anti-pollution modifying agent according to claim 1, it is characterised in that：Step (1) is described
The addition of highly basic is 1g/L；The addition of hydrogen peroxide is 3g/L；The addition of sodium citrate is 2g/L.
5. a kind of preparation method of ink anti-pollution modifying agent according to claim 1, it is characterised in that：Institute in step (2)
It is glycerine to state polyalcohol.
6. a kind of preparation method of ink anti-pollution modifying agent according to claim 1, it is characterised in that：It is short in step (3)
Wave ultraviolet wavelength is 260nm.
7. a kind of preparation method of ink anti-pollution modifying agent according to claim 1, it is characterised in that：In in step (3)
Wave ultraviolet wavelength is 320nm.
8. a kind of application of ink anti-pollution modifying agent prepared by preparation method described in claim 1, it is characterised in that addition ratio
Example is the 3% of water-based ink quality；It is added in three times, first time addition is the half of total amount, is heated after stirring evenly
Second of addition is carried out after maintaining 20min to 65 DEG C, addition is the half of surplus, and 85 DEG C of heat preservations are warming up to after mixing uniformly
The printing ink modifier of surplus is added after 15min, room temperature is down to after 105 DEG C of heat preservation 10min are warming up to after stirring evenly to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810547209.8A CN108659605A (en) | 2018-05-31 | 2018-05-31 | A kind of preparation method and applications of ink anti-pollution modifying agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810547209.8A CN108659605A (en) | 2018-05-31 | 2018-05-31 | A kind of preparation method and applications of ink anti-pollution modifying agent |
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| Publication Number | Publication Date |
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| CN108659605A true CN108659605A (en) | 2018-10-16 |
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| CN201810547209.8A Withdrawn CN108659605A (en) | 2018-05-31 | 2018-05-31 | A kind of preparation method and applications of ink anti-pollution modifying agent |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104147645A (en) * | 2014-05-19 | 2014-11-19 | 上海大学 | Injectable porous microcarrier material for in-vivo tissue regeneration and reconstruction and preparation method thereof |
| CN106566679A (en) * | 2015-10-12 | 2017-04-19 | 重庆市巴南区特宇机械制造厂(普通合伙) | Antifouling agent for automobile interior leather accessories |
| CN106956336A (en) * | 2017-04-06 | 2017-07-18 | 霍邱县淮美奇工艺品有限公司 | A kind of method of wicker microwave dip dyeing |
| CN107400404A (en) * | 2017-08-08 | 2017-11-28 | 方政 | A kind of environment-friendlyink ink auxiliary agent and its preparation technology |
-
2018
- 2018-05-31 CN CN201810547209.8A patent/CN108659605A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104147645A (en) * | 2014-05-19 | 2014-11-19 | 上海大学 | Injectable porous microcarrier material for in-vivo tissue regeneration and reconstruction and preparation method thereof |
| CN106566679A (en) * | 2015-10-12 | 2017-04-19 | 重庆市巴南区特宇机械制造厂(普通合伙) | Antifouling agent for automobile interior leather accessories |
| CN106956336A (en) * | 2017-04-06 | 2017-07-18 | 霍邱县淮美奇工艺品有限公司 | A kind of method of wicker microwave dip dyeing |
| CN107400404A (en) * | 2017-08-08 | 2017-11-28 | 方政 | A kind of environment-friendlyink ink auxiliary agent and its preparation technology |
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Application publication date: 20181016 |
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