CN108641521A - A kind of anti-aging nano modification exterior wall latex paint and preparation method thereof - Google Patents
A kind of anti-aging nano modification exterior wall latex paint and preparation method thereof Download PDFInfo
- Publication number
- CN108641521A CN108641521A CN201810604810.6A CN201810604810A CN108641521A CN 108641521 A CN108641521 A CN 108641521A CN 201810604810 A CN201810604810 A CN 201810604810A CN 108641521 A CN108641521 A CN 108641521A
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- exterior wall
- latex paint
- wall latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anti-aging nano modification exterior wall latex paints and preparation method thereof, and each component substance component by weight is calculated as in exterior wall latex paint：30 50 parts of nano-silicon oxide modified acrylic resin, 79 parts of titanium dioxide, 68 parts of SILICA FUME, 10 18 parts of titanium dioxide, 13 parts of aluminum stearate, 13 parts of dimethyl silicone polymer, 48 parts of emulsifier, 0.5 1 parts of levelling agent, 14 18 parts of epoxy resin latex, 12 parts of UV resistant agent, 35 parts of hydroxypropyl methyl cellulose.The present invention is modified acrylic resin using nano silicon oxide, tridimensional network can be formed using nano silicon dioxide, reticular structure can be formed when coating is dried, the stabilization of UV resistant agent and pigments system is maintained, ultraviolet light is reduced to the aging action of pigment, the color permanency of coating can be kept, in addition, nano silicon dioxide has extremely strong ultraviolet and infrared external reflection characteristic, and shielding action can be formed to coating by being added in coating, achieve the purpose that anti-ultraviolet ageing and heat ageing.
Description
Technical field
The invention belongs to wall finiss technical fields, and in particular to a kind of anti-aging nano modification exterior wall latex paint and its preparation
Method.
Background technology
Emulsion paint is, using water as decentralized medium, pigment, filler and auxiliary agent to be added, through one using synthetic resin emulsion as base-material
Determine coating made of technical process, be one of the main decoration materials for being used for metope in house decoration, finishing accounts for phase on basis
When ratio.
Such as application No. is the patents of CN201510473227.2, and it discloses a kind of novel water-tight corrosion-proof anti-aging property is good
Interiro wall latex paint, which is characterized in that be made of the raw material of following parts by weight：VAE lotions 20-24, fatty acid methyl ester 3-
5, vinyl acetate 6-8, antifoaming agent F-111-1-2, fatty alcohol polyoxyethylene ether ammonium sulfate 1.5-2, sodium bentonite 5-8, receive
Rice calcium carbonate 13-16, micaceous iron oxide 2-4, polyvinyl alcohol 3-5, sodium benzoate 1.5-2, water 90-100, mixed plant slurry 7-
9；Foregoing invention selects the raw material with waterproof, anti-corrosion function, coordinates micaceous iron oxide, strong adhesive force that it is old can to slow down paint film
Change；Mixed plant slurry is added, the volatile quantity of organic compound can be reduced, improve index with fresh air, and safety and environmental protection is nontoxic,
It is corrosion-resistant, antibacterial, antiviral, healthy and safe indoor environment can be provided for people；Foregoing invention is widely used in therapeutic machine
The places such as structure, school.
But there is following defect in said program in use：Exterior wall latex paint is using process exposure range larger, and
The phenomenon that being contacted for a long time with ultraviolet light, causing metope paint solution accelerated ageing, jaundice is presented, influences lacquer painting quality.
Invention content
The purpose of the present invention is to provide a kind of anti-aging nano modification exterior wall latex paints and preparation method thereof, in solution
State the problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions：A kind of anti-aging nano modification exterior wall latex paint, respectively
Component materials component by weight is calculated as：Nano-silicon oxide modified acrylic resin 30-50 parts, 7-9 parts of titanium dioxide, SILICA FUME 6-
8 parts, 10-18 parts of titanium dioxide, 1-3 parts of aluminum stearate, 1-3 parts of dimethyl silicone polymer, 4-8 parts of emulsifier, levelling agent 0.5-1
Part, 14-18 parts of epoxy resin latex, 1-2 parts of UV resistant agent, 3-5 parts of hydroxypropyl methyl cellulose.
Preferably, the Ph values of the nano-silicon oxide modified acrylic resin are 7.5-8, and the UV resistant agent is adjacent hydroxyl
Any one in yl benzoic acid phenyl ester, benzotriazole and phosphite ester.
Preferably, the levelling agent is one in alkyl-modified organosiloxane or polyether polyester azo polyether polyeste
Kind.
Preferably, the emulsifier is in aliphatic amine polyoxyethylene ether, polyethylene glycol, condensation compound of alkyl phenol and epoxy ethane
Any one.
Meanwhile the invention also discloses a kind of preparation method of anti-aging nano modification exterior wall latex paint, specifically include as
Lower operating procedure：
S1：It weighs nano silicon oxide to be dissolved in the emulsion acrylic resin of 10-20 times of quality, and total emulsion volume 2- is added
4% silane coupling agent stirs evenly, while being heated to above-mentioned mixed system using water-bath, and bath temperature is 80-90 DEG C,
It is mixed later by ultrasonic mixer, mixing finishes standing heat preservation 3-5 hours, is carried out later by 1000 mesh filter screens
Filtrate is collected in filter, and cooling obtains nano-silicon oxide modified acrylic resin, spare；
S2：Weigh titanium dioxide, SILICA FUME, titanium dioxide, aluminum stearate, epoxy resin latex, hydroxypropyl methyl cellulose
It is added into grinder and is ground, collect the slurry after grinding, it is spare；
S3：Slurry, dimethyl silicone polymer, emulsifier, levelling agent in nano-silicon oxide modified acrylic resin, S2 and
UV resistant agent, which is added, is diluted mixing into container, and decentralized processing is carried out to the mixed liquor of above-mentioned substance using homogenizer,
After dispersion anti-aging nano modification exterior wall latex paint is filtered to obtain using 2000 mesh filtering steel wire.
Preferably, the working frequency of ultrasonic mixer is 10-20MHz, processing time 20-30 point in the step S1
Clock.
Preferably, the step S1 is added dropwise triethanolamine and adjusts acid-base value to nano-silicon oxide modified acrylic resin.
Preferably, homogenization pressure is 25-30MPa in the step S3, and jitter time is 10-20 minutes.
The technique effect and advantage of the present invention：
The present invention is modified acrylic resin using nano silicon oxide, and three-dimensional can be formed using nano silicon dioxide
Reticular structure possesses huge specific surface area, and reticular structure can be formed when coating is dried, and maintains UV resistant agent and pigment body
The stabilization of system reduces ultraviolet light to the aging action of pigment, the color permanency of coating can be kept, in addition, nanometer titanium dioxide
Silicon has extremely strong ultraviolet and infrared external reflection characteristic, and shielding action can be formed to coating by being added in coating, and it is old to reach uvioresistant
Change the purpose with heat ageing.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of anti-aging nano modification exterior wall latex paint, each component substance component by weight are calculated as：It is nano-silicon oxide modified
30 parts of acrylic resin, 7 parts of titanium dioxide, 6 parts of SILICA FUME, 10 parts of titanium dioxide, 1 part of aluminum stearate, dimethyl silicone polymer 1
Part, 4 parts of emulsifier, 0.5 part of levelling agent, 14 parts of epoxy resin latex, 1 part of UV resistant agent, 3 parts of hydroxypropyl methyl cellulose.
The Ph values of the nano-silicon oxide modified acrylic resin are 7.5, and the UV resistant agent is septichen phenyl ester.It is described
Levelling agent is alkyl-modified organosiloxane.The emulsifier is aliphatic amine polyoxyethylene ether.
Meanwhile the invention also discloses a kind of preparation method of anti-aging nano modification exterior wall latex paint, specifically include as
Lower operating procedure：
S1：It weighs nano silicon oxide to be dissolved in the emulsion acrylic resin of 10 times of quality, and total emulsion volume 2% is added
Silane coupling agent stirs evenly, and triethanolamine is added dropwise and adjusts acid-base value to nano-silicon oxide modified acrylic resin, uses simultaneously
Above-mentioned mixed system is heated in water-bath, and bath temperature is 80 DEG C, is mixed later by ultrasonic mixer, ultrasonic wave
The working frequency of mixer is 10MHz, and 20 minutes processing times, mixing finishes standing heat preservation 3 hours, filtered later by 1000 mesh
Net is filtered, and collects filtrate, cooling obtains nano-silicon oxide modified acrylic resin, spare；
S2：Weigh titanium dioxide, SILICA FUME, titanium dioxide, aluminum stearate, epoxy resin latex, hydroxypropyl methyl cellulose
It is added into grinder and is ground, collect the slurry after grinding, it is spare；
S3：Slurry, dimethyl silicone polymer, emulsifier, levelling agent in nano-silicon oxide modified acrylic resin, S2 and
UV resistant agent, which is added, is diluted mixing into container, and decentralized processing is carried out to the mixed liquor of above-mentioned substance using homogenizer,
Homogenization pressure is 25MPa, and jitter time is 10 minutes, is filtered anti-ageing using 2000 mesh filtering steel wire after dispersion
Change nano modification exterior wall latex paint.
Embodiment 2
A kind of anti-aging nano modification exterior wall latex paint, each component substance component by weight are calculated as：It is nano-silicon oxide modified
40 parts of acrylic resin, 8 parts of titanium dioxide, 7 parts of SILICA FUME, 14 parts of titanium dioxide, 2 parts of aluminum stearate, dimethyl silicone polymer 2
Part, 6 parts of emulsifier, 0.7 part of levelling agent, 16 parts of epoxy resin latex, 1 part of UV resistant agent, 4 parts of hydroxypropyl methyl cellulose.
The Ph values of the nano-silicon oxide modified acrylic resin are 7.8, and the UV resistant agent is benzotriazole and phosphite ester.
The levelling agent is polyether polyester azo polyether polyeste.The emulsifier is polyethylene glycol.
Meanwhile the invention also discloses a kind of preparation method of anti-aging nano modification exterior wall latex paint, specifically include as
Lower operating procedure：
S1：It weighs nano silicon oxide to be dissolved in the emulsion acrylic resin of 15 times of quality, and total emulsion volume 3% is added
Silane coupling agent stirs evenly, and triethanolamine is added dropwise and adjusts acid-base value to nano-silicon oxide modified acrylic resin, uses simultaneously
Above-mentioned mixed system is heated in water-bath, and bath temperature is 85 DEG C, is mixed later by ultrasonic mixer, ultrasonic wave
The working frequency of mixer is 15MHz, and 25 minutes processing times, mixing finishes standing heat preservation 4 hours, filtered later by 1000 mesh
Net is filtered, and collects filtrate, cooling obtains nano-silicon oxide modified acrylic resin, spare；
S2：Weigh titanium dioxide, SILICA FUME, titanium dioxide, aluminum stearate, epoxy resin latex, hydroxypropyl methyl cellulose
It is added into grinder and is ground, collect the slurry after grinding, it is spare；
S3：Slurry, dimethyl silicone polymer, emulsifier, levelling agent in nano-silicon oxide modified acrylic resin, S2 and
UV resistant agent, which is added, is diluted mixing into container, and decentralized processing is carried out to the mixed liquor of above-mentioned substance using homogenizer,
Homogenization pressure is 27MPa, and jitter time is 15 minutes, is filtered anti-ageing using 2000 mesh filtering steel wire after dispersion
Change nano modification exterior wall latex paint.
Embodiment 3
A kind of anti-aging nano modification exterior wall latex paint, each component substance component by weight are calculated as：It is nano-silicon oxide modified
50 parts of acrylic resin, 9 parts of titanium dioxide, 8 parts of SILICA FUME, 18 parts of titanium dioxide, 3 parts of aluminum stearate, dimethyl silicone polymer 3
Part, 8 parts of emulsifier, 1 part of levelling agent, 18 parts of epoxy resin latex, 2 parts of UV resistant agent, 5 parts of hydroxypropyl methyl cellulose.Institute
The Ph values for stating nano-silicon oxide modified acrylic resin are 8, and the UV resistant agent is phosphite ester.The levelling agent is alkyl
Azo polyether polyeste.The emulsifier is condensation compound of alkyl phenol and epoxy ethane.
Meanwhile the invention also discloses a kind of preparation method of anti-aging nano modification exterior wall latex paint, specifically include as
Lower operating procedure：
S1：It weighs nano silicon oxide to be dissolved in the emulsion acrylic resin of 20 times of quality, and total emulsion volume 4% is added
Silane coupling agent stirs evenly, and triethanolamine is added dropwise and adjusts acid-base value to nano-silicon oxide modified acrylic resin, uses simultaneously
Above-mentioned mixed system is heated in water-bath, and bath temperature is 90 DEG C, is mixed later by ultrasonic mixer, ultrasonic wave
The working frequency of mixer is 20MHz, and 30 minutes processing times, mixing finishes standing heat preservation 5 hours, filtered later by 1000 mesh
Net is filtered, and collects filtrate, cooling obtains nano-silicon oxide modified acrylic resin, spare；
S2：Weigh titanium dioxide, SILICA FUME, titanium dioxide, aluminum stearate, epoxy resin latex, hydroxypropyl methyl cellulose
It is added into grinder and is ground, collect the slurry after grinding, it is spare；
S3：Slurry, dimethyl silicone polymer, emulsifier, levelling agent in nano-silicon oxide modified acrylic resin, S2 and
UV resistant agent, which is added, is diluted mixing into container, and decentralized processing is carried out to the mixed liquor of above-mentioned substance using homogenizer,
Homogenization pressure is 30MPa, and jitter time is 20 minutes, is filtered anti-ageing using 2000 mesh filtering steel wire after dispersion
Change nano modification exterior wall latex paint.
The present invention is modified acrylic resin using nano silicon oxide, and three-dimensional can be formed using nano silicon dioxide
Reticular structure possesses huge specific surface area, and reticular structure can be formed when coating is dried, and maintains UV resistant agent and pigment body
The stabilization of system reduces aging action of the ultraviolet light to pigment, while improving the suspension of pigment, and the color of coating can be kept permanent
It is constant, in addition, nano silicon dioxide has extremely strong ultraviolet and infrared external reflection characteristic, it is added in coating that coating can be formed and shields
The effect of covering, achievees the purpose that anti-ultraviolet ageing and heat ageing.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (8)
1. a kind of anti-aging nano modification exterior wall latex paint, which is characterized in that each component substance component by weight is calculated as：Nano oxygen
SiClx is 30-50 parts acrylic resin modified, 7-9 parts of titanium dioxide, 6-8 parts of SILICA FUME, 10-18 parts of titanium dioxide, aluminum stearate 1-3
Part, 1-3 parts of dimethyl silicone polymer, 4-8 parts of emulsifier, 0.5-1 parts of levelling agent, 14-18 parts of epoxy resin latex, uvioresistant
1-2 parts of agent, 3-5 parts of hydroxypropyl methyl cellulose.
2. a kind of anti-aging nano modification exterior wall latex paint according to claim 1, it is characterised in that：It is described nano oxidized
The Ph values of fluorine-silicon modified acrylic resin are 7.5-8, and the UV resistant agent is septichen phenyl ester, benzotriazole and Asia
Any one in phosphate.
3. a kind of anti-aging nano modification exterior wall latex paint according to claim 1, it is characterised in that：The levelling agent is
One kind in alkyl-modified organosiloxane or polyether polyester azo polyether polyeste.
4. a kind of anti-aging nano modification exterior wall latex paint according to claim 1, it is characterised in that：The emulsifier is
Any one in aliphatic amine polyoxyethylene ether, polyethylene glycol, condensation compound of alkyl phenol and epoxy ethane.
5. a kind of preparation method of anti-aging nano modification exterior wall latex paint, which is characterized in that specifically include following operating procedure：
S1：It weighs nano silicon oxide to be dissolved in the emulsion acrylic resin of 10-20 times of quality, and total emulsion volume 2-4% is added
Silane coupling agent stir evenly, while above-mentioned mixed system is heated using water-bath, bath temperature is 80-90 DEG C, it
It is mixed afterwards by ultrasonic mixer, mixing finishes standing heat preservation 3-5 hours, is carried out later by 1000 mesh filter screens
Filtrate is collected in filter, and cooling obtains nano-silicon oxide modified acrylic resin, spare；
S2：Titanium dioxide, SILICA FUME, titanium dioxide, aluminum stearate, epoxy resin latex, hydroxypropyl methyl cellulose is weighed to be added
To being ground in grinder, the slurry after grinding is collected, it is spare；
S3：Slurry, dimethyl silicone polymer, emulsifier, levelling agent in nano-silicon oxide modified acrylic resin, S2 and anti-purple
Outside line agent, which is added, is diluted mixing into container, and decentralized processing, dispersion are carried out to the mixed liquor of above-mentioned substance using homogenizer
After using 2000 mesh filtering steel wire be filtered to obtain anti-aging nano modification exterior wall latex paint.
6. a kind of preparation method of anti-aging nano modification exterior wall latex paint according to claim 5, it is characterised in that：Institute
The working frequency for stating ultrasonic mixer in step S1 is 10-20MHz, processing time 20-30 minute.
7. a kind of preparation method of anti-aging nano modification exterior wall latex paint according to claim 5, it is characterised in that：Institute
It states step S1 and triethanolamine is added dropwise to nano-silicon oxide modified acrylic resin adjustment acid-base value.
8. a kind of preparation method of anti-aging nano modification exterior wall latex paint according to claim 5, it is characterised in that：Institute
It is 25-30MPa to state homogenization pressure in step S3, and jitter time is 10-20 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810604810.6A CN108641521A (en) | 2018-06-13 | 2018-06-13 | A kind of anti-aging nano modification exterior wall latex paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810604810.6A CN108641521A (en) | 2018-06-13 | 2018-06-13 | A kind of anti-aging nano modification exterior wall latex paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108641521A true CN108641521A (en) | 2018-10-12 |
Family
ID=63752249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810604810.6A Pending CN108641521A (en) | 2018-06-13 | 2018-06-13 | A kind of anti-aging nano modification exterior wall latex paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108641521A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705691A (en) * | 2019-01-22 | 2019-05-03 | 段小宁 | A kind of preparation method of fast, waterproof the aqueous, environmental protective paint of film forming |
| CN111073366A (en) * | 2019-12-31 | 2020-04-28 | 南京红枫环保材料有限公司 | Exterior wall latex paint with heat insulation function and preparation method and application thereof |
| CN116285632A (en) * | 2023-05-22 | 2023-06-23 | 佛山市三水联美化工有限公司 | Tensile and ultraviolet-resistant resin coating and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101096400A (en) * | 2006-06-30 | 2008-01-02 | 天津市振东涂料有限公司 | Synthesizing method for confecting inner-outer wall coating water-proof stain-resistant latex |
| CN101412892A (en) * | 2007-10-19 | 2009-04-22 | 芜湖力特尔涂料制造有限公司 | Composite self-cleaning exterior wall nano-emulsion paint and preparation thereof |
| CN101575472A (en) * | 2009-06-04 | 2009-11-11 | 无锡市艺博涂料有限公司 | Anti-cracking stain-resistant exterior wall latex paint and preparation method thereof |
| CN106519845A (en) * | 2016-11-17 | 2017-03-22 | 重庆文理学院 | Preparation method of anti-ageing external wall nano-paint |
-
2018
- 2018-06-13 CN CN201810604810.6A patent/CN108641521A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101096400A (en) * | 2006-06-30 | 2008-01-02 | 天津市振东涂料有限公司 | Synthesizing method for confecting inner-outer wall coating water-proof stain-resistant latex |
| CN101412892A (en) * | 2007-10-19 | 2009-04-22 | 芜湖力特尔涂料制造有限公司 | Composite self-cleaning exterior wall nano-emulsion paint and preparation thereof |
| CN101575472A (en) * | 2009-06-04 | 2009-11-11 | 无锡市艺博涂料有限公司 | Anti-cracking stain-resistant exterior wall latex paint and preparation method thereof |
| CN106519845A (en) * | 2016-11-17 | 2017-03-22 | 重庆文理学院 | Preparation method of anti-ageing external wall nano-paint |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705691A (en) * | 2019-01-22 | 2019-05-03 | 段小宁 | A kind of preparation method of fast, waterproof the aqueous, environmental protective paint of film forming |
| CN111073366A (en) * | 2019-12-31 | 2020-04-28 | 南京红枫环保材料有限公司 | Exterior wall latex paint with heat insulation function and preparation method and application thereof |
| CN116285632A (en) * | 2023-05-22 | 2023-06-23 | 佛山市三水联美化工有限公司 | Tensile and ultraviolet-resistant resin coating and preparation method and application thereof |
| CN116285632B (en) * | 2023-05-22 | 2023-08-15 | 佛山市三水联美化工有限公司 | Tensile and ultraviolet-resistant resin coating and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108641521A (en) | A kind of anti-aging nano modification exterior wall latex paint and preparation method thereof | |
| CN105199521A (en) | Hydrophobic silica aerogel modified acrylate emulsion coating | |
| CN105755800B (en) | A kind of heat-reflective coating cloth | |
| CN106256859A (en) | A kind of colorful environmental protection coating material of nanometer high durable and preparation method thereof | |
| CN102850878A (en) | Weather-resistant exterior wall paint and preparation method thereof | |
| CN107325663A (en) | Architectural reflective heat-insulation paint and preparation method thereof | |
| CN102391754A (en) | Double-coated hollow glass microbead heat-insulated coating and preparation method thereof | |
| CN110183878A (en) | A kind of ceramic coating and preparation method thereof with environmental protection self-cleaning antibacterial damage resistant effect | |
| CN108285710A (en) | A kind of color compositions and preparation method thereof and purposes | |
| CN104946058A (en) | Energy-saving type building outer wall coating | |
| CN106366892A (en) | Scratch-resistant outdoor powder paint | |
| CN107057490A (en) | A kind of external wall elastic coating with reflective insulation effect and preparation method thereof | |
| CN104927504A (en) | Building external wall coating | |
| CN109021720A (en) | A kind of building wall water-repellent paint | |
| CN103013259B (en) | Ultraviolet-proof insulating type environment-friendly interior wall paint | |
| CN109897409A (en) | Nanometer environmental protection paint and preparation method thereof | |
| CN107629627A (en) | One kind infiltration hydrophobicity Multifucntional water-repellent paint and preparation method and application | |
| CN107118646B (en) | Energy-saving durable automatically cleaning discoloration exterior wall sealing wax and preparation method thereof | |
| CN106810978A (en) | A kind of comprehensive exterior wall paint special of high durable and preparation method thereof | |
| CN109251597A (en) | A kind of aqueous insulation paint for building and its preparation process | |
| CN105482569A (en) | Water-in-water colorful coating and preparation method thereof | |
| CN109233504A (en) | A kind of surface super hydrophilic type exterior wall anti-pollution paint and preparation method thereof | |
| CN105199522A (en) | Weather-resistant heat-isolation outer wall emulsion paint | |
| CN108467635A (en) | A kind of phenylpropyl alcohol antibacterial inner wall paint and preparation method thereof | |
| CN112063296A (en) | High-hardness fireproof hydrophobic stone-like ceramic coating, and preparation process and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181012 |
|
| RJ01 | Rejection of invention patent application after publication |