CN108641269A - A kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys and preparation method thereof - Google Patents
A kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys and preparation method thereof Download PDFInfo
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- CN108641269A CN108641269A CN201810262978.3A CN201810262978A CN108641269A CN 108641269 A CN108641269 A CN 108641269A CN 201810262978 A CN201810262978 A CN 201810262978A CN 108641269 A CN108641269 A CN 108641269A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention discloses a kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys and preparation method thereof, which is grouped as by the group of following mass parts：ABS resin：50~70 parts；Polyketone resin：10~25 parts；Bromine antimony fire retardant：10~20 parts；Ultra-violet absorber：0.4~0.8 part；Compatilizer：1~5 part；Toughener：2~8 parts；Antioxidant：0.2~0.5 part；Processing aid：0.3~0.5 part；Toner：3~5 parts.Preparation method is as follows：It is uniformly mixed homogenizer is added after each raw material drying, then material is transferred to double screw extruder, squeezed out, is cooling, being granulated, is dry.The ABS/POK alloys of the present invention have excellent solvent resistance, flame retardant property, uvioresistant performance and comprehensive mechanical property, and preparation process is simple, are easy to carry out large-scale industrial production.
Description
Technical field
The present invention relates to a kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys and preparation method thereof.
Background technology
ABS resin is the terpolymer of acrylonitrile, butadiene and styrene, and it is molten that acrylonitrile assigns its good chemically-resistant
Agent performance, butadiene assign its excellent shock resistance, and styrene assigns its good processing performance so that ABS is used extensively
In fields such as automobile, household electrical appliances, electronics.However, the continuous improvement with people's demand with the development of science and technology, ABS show with
Lower deficiency：1) since ABS main chains contain carbon-carbon double bond, so its is fast light, oxidative aging energy is poor；2) ABS belongs to easy fuel wood
Material；3) solvent resistance of modified ABS is poor, easily deforms, opens if product is immersed in for a long time inside chemical reagent
It splits.Therefore, it is necessary to be modified to ABS.CN 101638503A disclose a kind of environment-friendly composite flame retardant weatherproof ABS composition and
Preparation method improves the flame retardant property of ABS by adding brominated flame-retardant and antimony oxide, is inhaled by adding ultraviolet light
Receive agent improves fast light, the oxidative aging energy of ABS to a certain extent, although the ABS composition middle-ultraviolet lamp absorbents add
Dosage is very big, but the practical improvement to the fast light of product, oxidative aging energy is extremely limited, and can not improve its product and exist
Deformation, cracking phenomena in chemical solvent environment.
Invention content
It is an object of the invention to disclose a kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys and preparation method thereof.
The technical solution used in the present invention is：
A kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys, are grouped as by the group of following mass parts：
ABS resin：50~70 parts；
Polyketone resin：10~25 parts；
Bromine antimony fire retardant：10~20 parts；
Ultra-violet absorber：0.4~0.8 part；
Compatilizer：1~5 part；
Toughener：2~8 parts；
Antioxidant：0.2~0.5 part；
Processing aid：0.3~0.5 part；
Toner：3~5 parts.
The ABS resin is acrylnitrile-butadiene-styrene copolymer, and melt index is 15~40g/
10min, 220 DEG C/10kg.
The polyketone resin be ethylene-propylene-carbon monoxide multipolymer, melt index be 40~120g/10min, 240
℃/2.16kg。
The bromine antimony fire retardant is by decabromodiphenylethane, three (tribromophenoxy) triazines, brominated Polystyrene, brominated
At least one of oxygen resin compounds to obtain with antimony oxide.
The ultra-violet absorber is by least three kinds of compoundings in UV-326, UV-531, UV-3364, UV-P, UV-770
It obtains.
The compatilizer is ABS grafted maleic anhydrides, styrene-acrylonitrile-glycidyl methacrylate copolymerization
At least one of object.
The toughener is methyl methacrylate-butadiene-styrene terpolymer, in ABS high glue powders extremely
Few one kind.
The antioxidant is compounded to obtain by Hinered phenols antioxidant and phosphite ester kind antioxidant.
The processing aid is at least one of silicone master batch, zinc stearate, ethylene bis stearic acid amide.
The preparation method of above-mentioned solvent resistant weather-resistance flame-retardant ABS/POK alloys, includes the following steps：It will add after each raw material drying
Enter homogenizer to be uniformly mixed, then material is transferred to double screw extruder, squeezes out, is cooling, being granulated, is dry, obtaining solvent resistant
Weather-resistance flame-retardant ABS/POK alloys.
The beneficial effects of the invention are as follows：The present invention ABS/POK alloys have excellent solvent resistance, flame retardant property,
Uvioresistant performance and comprehensive mechanical property, preparation process is simple, is easy to carry out large-scale industrial production.
1) it is added with polyketone resin in ABS/POK alloys of the invention, the solvent resistant of ABS/POK alloys can be significantly improved
Performance；
2) it is added with compatilizer in ABS/POK alloys of the invention, the compatibility of ABS and POK can be increased so that ABS/
POK alloys have excellent comprehensive mechanical property；
3) it is added with bromine antimony fire retardant in ABS/POK alloys of the invention, by carrying out bromo- antimony compounding, even if additive amount
Very little can also obtain excellent flame retardant property；
4) it is added with ultra-violet absorber in ABS/POK alloys of the invention, is compounded by UV-326, UV-P and UV-770
It arrives, there is synergy between three, the uvioresistant performance of ABS/POK alloys can be substantially improved.
Specific implementation mode
A kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys, are grouped as by the group of following mass parts：
ABS resin：50~70 parts；
Polyketone resin：10~25 parts；
Bromine antimony fire retardant：10~20 parts；
Ultra-violet absorber：0.4~0.8 part；
Compatilizer：1~5 part；
Toughener：2~8 parts；
Antioxidant：0.2~0.5 part；
Processing aid：0.3~0.5 part；
Toner：3~5 parts.
Preferably, the ABS resin be acrylnitrile-butadiene-styrene copolymer, melt index be 15~
40g/10min, 220 DEG C/10kg.
Preferably, the polyketone resin (POK) be ethylene-propylene-carbon monoxide multipolymer, melt index be 40~
120g/10min, 240 DEG C/2.16kg.
Preferably, the bromine antimony fire retardant is by decabromodiphenylethane, three (tribromophenoxy) triazines, brominated polyphenylene second
At least one of alkene, brominated epoxy resin compound to obtain with antimony oxide.
Preferably, the ultra-violet absorber is by least 3 in UV-326, UV-531, UV-3364, UV-P, UV-770
Kind compounding obtains.
It is further preferred that the ultra-violet absorber is compounded to obtain by UV-326, UV-P and UV-770.
Preferably, the compatilizer is ABS grafted maleic anhydrides, styrene-acrylonitrile-methyl propenoic acid glycidyl
At least one of ester copolymer.
Preferably, the toughener is methyl methacrylate-butadiene-styrene terpolymer (MBS), ABS
At least one of high glue powder.
Preferably, the antioxidant is compounded to obtain by Hinered phenols antioxidant and phosphite ester kind antioxidant.
Preferably, the processing aid be silicone master batch, zinc stearate, in ethylene bis stearic acid amide (EBS) extremely
Few one kind.
Preferably, the toner is titanium dioxide.
The preparation method of above-mentioned solvent resistant weather-resistance flame-retardant ABS/POK alloys, includes the following steps：It will add after each raw material drying
Enter homogenizer to be uniformly mixed, then material is transferred to double screw extruder, squeezes out, is cooling, being granulated, is dry, obtaining solvent resistant
Weather-resistance flame-retardant ABS/POK alloys.
Preferably, the preparation method of above-mentioned solvent resistant weather-resistance flame-retardant ABS/POK alloys, includes the following steps：By each raw material
Homogenizer, adjustment homogenizer rotating speed to 400~800r/min, stirring is added after dry 1~2h at 80~100 DEG C
6~10min, then material is transferred to double screw extruder, the temperature in each area of double screw extruder is set as 150~230 DEG C, feeding
Rotating speed is 12~24r/min, engine speed is 220~600r/min, squeezes out, is cooling, being granulated, is dry, it is weather-proof to obtain solvent resistant
Flame-proof ABS/POK alloys.
The present invention is made further explanation and description with reference to specific embodiment.
Examples 1 to 3 and comparative example 1~2：
The raw material composition of ABS/POK alloys prepared by Examples 1 to 3 and comparative example 1~2 is as shown in table 1, preparation method
It is as follows：Homogenizer, adjustment homogenizer rotating speed to 600r/min, stirring is added in each raw material at 85 DEG C after dry 2h
10min, then material is transferred to double screw extruder, set the temperature of 11 warm areas of double screw extruder as 150 DEG C, 230 DEG C,
230 DEG C, 230 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 225 DEG C, 230 DEG C, 230 DEG C, feeding rotating speed be 15r/min, host
Rotating speed is 350r/min, squeezes out, is cooling, being granulated, is dry, obtaining ABS/POK alloys.
ABS/POK alloys are kneaded, are granulated, injection moulding, standard testing batten is obtained, is tested for the property, test knot
Fruit is as shown in table 2.
The raw material of the ABS/POK alloys of 1 Examples 1 to 3 of table and comparative example 1~2 forms table
| Raw material (mass parts) | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| ABS resin | 70 | 58 | 50 | 76.7 | 60.7 |
| Polyketone resin | 10 | 15 | 20 | — | 10 |
| Three (tribromophenoxy) triazines | 8 | 11 | 14.5 | 13 | 13 |
| Decabromodiphenylethane | — | — | — | 2 | 2 |
| Antimony oxide | 2 | 2 | 2 | 2 | 2 |
| UV-531 | 0.2 | — | — | — | — |
| UV-326 | 0.2 | 0.3 | — | — | — |
| UV-3346 | 0.1 | — | 0.2 | — | — |
| UV-P | — | 0.3 | 0.2 | — | 0.8 |
| UV-770 | — | 0.1 | 0.4 | 0.8 | — |
| Compatilizer SAG-002 | 1 | 2.5 | 4.2 | — | — |
| ABS high glue powders | 3 | 7 | 5 | — | 6 |
| Antioxidant B215 | 0.2 | 0.3 | 0.2 | 0.2 | 0.2 |
| EBS | 0.3 | 0.5 | 0.3 | 0.3 | 0.3 |
| Titanium dioxide | 5 | 3 | 3 | 5 | 5 |
Note：
ABS resin：8391, Shanghai Gaoqiao petrochemical industry limited liability company；
Polyketone resin：M330A, Xiaoxing Co., Ltd. of South Korea；
Three (tribromophenoxy) triazines：RDT-8；
Decabromodiphenylethane：RDT-3, Shouguang chemical inc Wei Dong；
Antimony oxide：Guangxi day Xingxin Material Co limited liability company；
Ultra-violet absorber：UV-326、UV-531、UV-3364、UV-P、UV-770；
ABS high glue powders：HR181, Korea Gumho Petrochemical Co., Ltd.；
Compatilizer：SAG-002,400~850g/mol of epoxide equivalent, the limited public affairs of raising molecule new material science and technology of Nantong day
Department；Antioxidant：Irganox B215 (the synergistic mixture of Irganox 1010 and Irganox 168), BASF；
EBS：Japanese Kao；
Toner：Titanium dioxide, R105, Dupont Co., Ltd.
The performance test data of the ABS/POK alloys of 2 Examples 1 to 3 of table and comparative example 1~2
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications,
Equivalent substitute mode is should be, is included within the scope of the present invention.
Claims (10)
1. a kind of solvent resistant weather-resistance flame-retardant ABS/POK alloys, it is characterised in that：It is grouped as by the group of following mass parts：
ABS resin：50~70 parts；
Polyketone resin：10~25 parts；
Bromine antimony fire retardant：10~20 parts；
Ultra-violet absorber：0.4~0.8 part；
Compatilizer：1~5 part；
Toughener：2~8 parts；
Antioxidant：0.2~0.5 part；
Processing aid：0.3~0.5 part；
Toner：3~5 parts.
2. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The ABS resin is
Acrylnitrile-butadiene-styrene copolymer, melt index be 15~40g/10min, 220 DEG C/10kg.
3. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The polyketone resin
For ethylene-propylene-carbon monoxide multipolymer, melt index is 40~120g/10min, 240 DEG C/2.16kg.
4. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The bromine antimony is fire-retardant
Agent is by least one of decabromodiphenylethane, three (tribromophenoxy) triazines, brominated Polystyrene, brominated epoxy resin and three
Two antimony are aoxidized to compound to obtain.
5. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The ultraviolet light is inhaled
Agent is received to be obtained by least three kinds of compoundings in UV-326, UV-531, UV-3364, UV-P, UV-770.
6. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The compatilizer is
At least one of ABS grafted maleic anhydrides, styrene-acrylonitrile-glycidyl methacrylate copolymer.
7. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The toughener is
At least one of methyl methacrylate-butadiene-styrene terpolymer, ABS high glue powders.
8. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The antioxidant by
Hinered phenols antioxidant and phosphite ester kind antioxidant compound to obtain.
9. solvent resistant weather-resistance flame-retardant ABS/POK alloys according to claim 1, it is characterised in that：The processing aid
For at least one of silicone master batch, zinc stearate, ethylene bis stearic acid amide.
10. the preparation method of the solvent resistant weather-resistance flame-retardant ABS/POK alloys described in any one of claim 1~9, feature
It is：Include the following steps：It is uniformly mixed homogenizer is added after each raw material drying, then material is transferred to twin-screw extrusion
Machine squeezes out, is cooling, being granulated, is dry, obtaining solvent resistant weather-resistance flame-retardant ABS/POK alloys.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627671A (en) * | 2018-11-27 | 2019-04-16 | 金发科技股份有限公司 | A kind of ABS composite material |
| CN109666256A (en) * | 2018-11-15 | 2019-04-23 | 广州敬信高聚物科技有限公司 | A kind of halogen-free flame-retardant thermoplastic elastomer composition and its preparation method and application |
| CN109825027A (en) * | 2019-02-28 | 2019-05-31 | 威海联桥新材料科技股份有限公司 | A kind of ABS/POK alloy exempts from sprayed on material and preparation method thereof |
| CN110343382A (en) * | 2019-07-23 | 2019-10-18 | 金发科技股份有限公司 | A kind of high-performance flame-resistant ABS composite material and preparation method |
| CN110372988A (en) * | 2019-07-23 | 2019-10-25 | 金发科技股份有限公司 | A kind of ABS/POK composite material and preparation method |
| CN112226060A (en) * | 2020-09-18 | 2021-01-15 | 金发科技股份有限公司 | Polycarbonate alloy composition and preparation method and application thereof |
| CN112266568A (en) * | 2020-10-19 | 2021-01-26 | 武汉金发科技有限公司 | High-shrinkage ABS resin composition and preparation method thereof |
| WO2021012187A1 (en) * | 2019-07-23 | 2021-01-28 | 金发科技股份有限公司 | High-performance flame retardant abs composite material and preparation method therefor |
| CN115403921A (en) * | 2022-09-16 | 2022-11-29 | 上海金发科技发展有限公司 | Solvent-resistant high-modulus PA/ABS alloy material and preparation method and application thereof |
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Cited By (12)
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| CN109666256A (en) * | 2018-11-15 | 2019-04-23 | 广州敬信高聚物科技有限公司 | A kind of halogen-free flame-retardant thermoplastic elastomer composition and its preparation method and application |
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| CN109825027A (en) * | 2019-02-28 | 2019-05-31 | 威海联桥新材料科技股份有限公司 | A kind of ABS/POK alloy exempts from sprayed on material and preparation method thereof |
| CN109825027B (en) * | 2019-02-28 | 2021-11-16 | 威海联桥新材料科技股份有限公司 | ABS/POK alloy spraying-free material and preparation method thereof |
| CN110343382A (en) * | 2019-07-23 | 2019-10-18 | 金发科技股份有限公司 | A kind of high-performance flame-resistant ABS composite material and preparation method |
| CN110372988A (en) * | 2019-07-23 | 2019-10-25 | 金发科技股份有限公司 | A kind of ABS/POK composite material and preparation method |
| WO2021012187A1 (en) * | 2019-07-23 | 2021-01-28 | 金发科技股份有限公司 | High-performance flame retardant abs composite material and preparation method therefor |
| CN112226060A (en) * | 2020-09-18 | 2021-01-15 | 金发科技股份有限公司 | Polycarbonate alloy composition and preparation method and application thereof |
| CN112266568A (en) * | 2020-10-19 | 2021-01-26 | 武汉金发科技有限公司 | High-shrinkage ABS resin composition and preparation method thereof |
| CN115403921A (en) * | 2022-09-16 | 2022-11-29 | 上海金发科技发展有限公司 | Solvent-resistant high-modulus PA/ABS alloy material and preparation method and application thereof |
| CN115403921B (en) * | 2022-09-16 | 2023-12-22 | 上海金发科技发展有限公司 | Solvent-resistant high-modulus PA/ABS alloy material, and preparation method and application thereof |
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