CN108641181A - A kind of toughening type master batch and preparation method thereof - Google Patents
A kind of toughening type master batch and preparation method thereof Download PDFInfo
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- CN108641181A CN108641181A CN201810462934.5A CN201810462934A CN108641181A CN 108641181 A CN108641181 A CN 108641181A CN 201810462934 A CN201810462934 A CN 201810462934A CN 108641181 A CN108641181 A CN 108641181A
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
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Abstract
The invention discloses a kind of toughening type master batches and preparation method thereof, including 60 80 parts of vector resin, 58 parts of toughener, 0 30 parts of pigment, 0.5 2.5 parts of dispersant, 0.05 0.15 parts of antioxidant, 0.1 0.3 parts of antiseptic, 0.05 0.1 parts of osmanthus essential oil；Preparation method is：1）Toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil mixing；2）Vector resin is put into together with scattered toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil in mixer, and plasticizing is kneaded；3）By the material extruding pelletization being kneaded, cooling, drying.The present invention uses the vector resin of high pressure polyethylene and random polypropylene as toughening type master batch, has preferable compatibility；The toughness for enhancing master batch by the way that toughener is added improves master batch quality；By the way that osmanthus essential oil is added in the manufacturing process of master batch, make master batch that there is the smell of faint scent, fresh air, environmental protection；Preparation method of the present invention is simple and convenient to operate simultaneously, it is easy to accomplish industrial production.
Description
Technical field
The present invention relates to a kind of high molecular materials more particularly to a kind of toughening type master batch and preparation method thereof.
Background technology
The primary raw material resin of plastic products comes from oil, however the resource of world oil is limited, over time
Can be increasingly deficienter, therefore, resourceful, cheap inorganic powder is added in resin, is the developing direction of Plastics Industry
One of.Inorganic powder filled modified plastics have more than 30 years history in China, with the increase of inorganic powder kind, processing technology
The development of progressive, filling-modified theory and people are to the diversified demand of resin, and inorganic powder filling is from merely
It saves resin raw material, reduce cost, develop into the important means of exploitation new type functional material, be new material sustainable development
Innovative point and power source.
Currently, it is that filler parent granule is added in resin to be filled modified most common method to resin.So-called filling
Master batch refers to, for operational convenience, required various auxiliary agents, filler being carried with a small amount of during plastics forming
Body resin first carries out prepared by mixed milling grain or powder.For high molecular material, toughness and rigidity are two kinds mutual
Therefore contradictory build-in attribute in plastic processes, how under the premise of reducing cost, while taking into account resinous wood
The toughness and rigidity of material products are the maximum research topics for filling master batch and being modified field.
However, above-mentioned improvement does not study the loading of filler parent granule, substantially, since inorganic particulate is high pole
The water-insoluble of property, surface energy is higher, and polymer is mostly apolar substance, and surface energy is low, the two poor compatibility, so inorganic
Particle difficulties in dispersion in high polymer molten, the lack of homogeneity of dispersion is weak with matrix resin effect, thus can lead to system performance
Deterioration, such as occur film breakage, fracture of wire, mold filling deficiency in machine-shaping, especially product impact property declines very much, is to cause
The limited major reason of resin modified effect.Therefore, improve the fillibility to toughening type filler parent granule and matrix resin, it is possible to
Obtain modified effect more preferably filler parent granule.
Invention content
The purpose of the present invention is to solve the disadvantages that toughness in the prior art is inadequate, and a kind of toughening type master batch proposed
And preparation method thereof.
To achieve the goals above, present invention employs following technical solutions：
A kind of toughening type master batch is designed, is made of the raw material of following weight proportion：60-80 parts of vector resin, 5-8 parts of toughener,
0-30 parts of pigment, 0.5-2.5 parts of dispersant, 0.05-0.15 parts of antioxidant, 0.1-0.3 parts of antiseptic, osmanthus essential oil 0.05-0.1
Part.
Preferably, it with mass ratio is 1 that vector resin, which is high pressure polyethylene, random polypropylene,：3 mixture.
Preferably, toughener is one in ethylene-vinyl acetate copolymer, acrylonitrile-butadiene-styrene copolymer
Kind is a variety of.
Preferably, pigment is the mixture of organic pigment and inorganic pigment, and organic dyestuff is phthalocyanine blue, phthalocyanine green, consolidates forever
It is one or more in Huang, permanent violet, azophloxine；Inorganic pigment is in cadmium red, cadmium yellow, titanium dioxide, iron oxide red, iron oxide yellow
It is one or more.
Preferably, dispersant is polyethylene low-molecular-weight wax or stearate；Antioxidant is 2,6- three-level butyl -4- methyl
Phenol, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) seasons penta
Four alcohol esters are with mass ratio for 0.8：1-2：2 mixture；Antiseptic zirconium phosphate nano carrying silver antimicrobials.
Preferably, antioxidant 2,6- three-level butyl -4- methylphenols, bis- (3,5- three-level butyl -4- hydroxy phenyls) sulphur
Ether, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) pentaerythritol esters are with mass ratio for 0.8：1：2 mixture.
The present invention also provides a kind of preparation methods of toughening type master batch, include the following steps：
1）Toughener, pigment, dispersant, antioxidant, antiseptic, the osmanthus essential oil for weighing formulation weight part are added Multidirectional motion and mix
Mixed at high speed, incorporation time 5-10min are carried out in conjunction machine；
2）Weigh the vector resin and scattered toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil of formula ratio
It puts into mixer, is plasticized with mixer mixing at 250-280 DEG C together, mixing time 30-35min；
3）By the material being kneaded using extruder at 210-220 DEG C extruding pelletization, cooling, drying to get toughening type master batch.
Preferably, extrusion uses double screw extruder.
A kind of toughening type master batch proposed by the present invention and preparation method thereof, advantageous effect is：The present invention is poly- using high pressure
The vector resin of ethylene and random polypropylene as toughening type master batch has preferable compatibility；Antioxidant and antiseptic are added,
Service life to master batch in the present invention and safety during use have higher protectiveness；By the way that toughener enhancing is added
The toughness of master batch improves master batch quality；By the way that osmanthus essential oil is added in the manufacturing process of master batch, make master batch that there is the gas of faint scent
Taste, fresh air, environmental protection；Preparation method of the present invention is simple and convenient to operate simultaneously, it is easy to accomplish industrial production.
Specific implementation mode
It is clearly and completely described below in conjunction with the technical solution in the embodiment of the present invention, it is clear that described reality
It is only a part of the embodiment of the present invention to apply example, instead of all the embodiments.
Embodiment 1
A kind of toughening type master batch, is made of the raw material of following weight proportion：60 parts of vector resin, 5 parts of toughener, dispersant 0.5
Part, 0.05 part of antioxidant, 0.1 part of antiseptic, 0.05 part of osmanthus essential oil.
Wherein, it with mass ratio is 1 that vector resin, which is high pressure polyethylene, random polypropylene,：3 mixture.
Wherein, toughener is ethylene-vinyl acetate copolymer.
Wherein dispersant is polyethylene low-molecular-weight wax or stearate；Antioxidant is 2,6- three-level butyl -4- methylbenzenes
Phenol, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) Ji Wusi
Alcohol ester is with mass ratio for 0.8：1：2 mixture；Antiseptic zirconium phosphate nano carrying silver antimicrobials.
A kind of preparation method of toughening type master batch, includes the following steps：
1）Toughener, pigment, dispersant, antioxidant, antiseptic, the osmanthus essential oil for weighing formulation weight part are added Multidirectional motion and mix
Mixed at high speed, incorporation time 5min are carried out in conjunction machine；
2）Weigh the vector resin and scattered toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil of formula ratio
It puts into mixer, is plasticized with mixer mixing at 250 DEG C together, mixing time 30min；
3）By the material being kneaded, using double screw extruder, extruding pelletization, cooling, drying at 210 DEG C are female to get toughening type
Grain.
Embodiment 2
A kind of toughening type master batch, is made of the raw material of following weight proportion：80 parts of vector resin, 8 parts of toughener, 30 parts of pigment,
2.5 parts of dispersant, 0.15 part of antioxidant, 0.3 part of antiseptic, 0.1 part of osmanthus essential oil.
Wherein, it with mass ratio is 1 that vector resin, which is high pressure polyethylene, random polypropylene,：3 mixture.
Wherein, toughener is acrylonitrile-butadiene-styrene copolymer.
Wherein, pigment is the mixture of organic pigment and inorganic pigment, and organic dyestuff is phthalocyanine blue, phthalocyanine green；Inorganic face
Material is cadmium red, cadmium yellow.
Wherein dispersant is polyethylene low-molecular-weight wax or stearate；Antioxidant is 2,6- three-level butyl -4- methylbenzenes
Phenol, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) Ji Wusi
Alcohol ester is with mass ratio for 0.8：2：2 mixture；Antiseptic zirconium phosphate nano carrying silver antimicrobials.
A kind of preparation method of toughening type master batch, includes the following steps：
1）Toughener, pigment, dispersant, antioxidant, antiseptic, the osmanthus essential oil for weighing formulation weight part are added Multidirectional motion and mix
Mixed at high speed, incorporation time 10min are carried out in conjunction machine；
2）Weigh the vector resin and scattered toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil of formula ratio
It puts into mixer, is plasticized with mixer mixing at 280 DEG C together, mixing time 35min；
3）By the material being kneaded, using double screw extruder, extruding pelletization, cooling, drying at 220 DEG C are female to get toughening type
Grain.
Embodiment 3
A kind of toughening type master batch, is made of the raw material of following weight proportion：70 parts of vector resin, 7 parts of toughener, 15 parts of pigment,
2 parts of dispersant, 1 part of antioxidant, 0.2 part of antiseptic, 0.09 part of osmanthus essential oil.
Wherein, it with mass ratio is 1 that vector resin, which is high pressure polyethylene, random polypropylene,：3 mixture.
Wherein, toughener is ethylene-vinyl acetate copolymer.
Wherein, pigment is the mixture of organic pigment and inorganic pigment, and organic dyestuff is azophloxine；Inorganic pigment is cadmium
It is red.
Wherein dispersant is polyethylene low-molecular-weight wax or stearate；Antioxidant is 2,6- three-level butyl -4- methylbenzenes
Phenol, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) Ji Wusi
Alcohol ester is with mass ratio for 0.8：1.2：2 mixture；Antiseptic zirconium phosphate nano carrying silver antimicrobials.
A kind of preparation method of toughening type master batch, includes the following steps：
1）Toughener, pigment, dispersant, antioxidant, antiseptic, the osmanthus essential oil for weighing formulation weight part are added Multidirectional motion and mix
Mixed at high speed, incorporation time 10min are carried out in conjunction machine；
2）Weigh the vector resin and scattered toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil of formula ratio
It puts into mixer, is plasticized with mixer mixing at 250 DEG C together, mixing time 35min；
3）By the material being kneaded, using double screw extruder, extruding pelletization, cooling, drying at 210 DEG C are female to get toughening type
Grain.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of toughening type master batch, it is characterised in that：It is made of the raw material of following weight proportion：60-80 parts of vector resin, toughening
5-8 parts of agent, 0-30 parts of pigment, 0.5-2.5 parts of dispersant, 0.05-0.15 parts of antioxidant, 0.1-0.3 parts of antiseptic, osmanthus essential oil
0.05-0.1 parts.
2. a kind of toughening type master batch according to claim 1, it is characterised in that：The vector resin be high pressure polyethylene,
Random polypropylene is with mass ratio for 1：3 mixture.
3. a kind of toughening type master batch according to claim 1, it is characterised in that：The toughener is ethene-vinyl acetate
It is one or more in ester copolymer, acrylonitrile-butadiene-styrene copolymer.
4. a kind of toughening type master batch according to claim 1, it is characterised in that：The pigment is organic pigment and inorganic face
The mixture of material, the organic dyestuff are one or more in phthalocyanine blue, phthalocyanine green, permanent yellow, permanent violet, azophloxine；Institute
It is one or more in cadmium red, cadmium yellow, titanium dioxide, iron oxide red, iron oxide yellow to state inorganic pigment.
5. a kind of toughening type master batch according to claim 1, it is characterised in that：The dispersant is polyethylene low-molecular-weight wax
Or stearate；The antioxidant is 2,6- three-level butyl -4- methylphenols, bis- (3,5- three-level butyl -4- hydroxy phenyls)
Thioether, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) pentaerythritol esters are with mass ratio for 0.8：1-2：2 mixing
Object；The antiseptic zirconium phosphate nano carrying silver antimicrobials.
6. a kind of toughening type master batch according to claim 5, it is characterised in that：The antioxidant is 2,6- three-levels butyl-
4- methylphenols, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β-(3,5- three-level butyl -4- hydroxy phenyls) third
Acid) pentaerythritol ester with mass ratio be 0.8：1：2 mixture.
7. the preparation method of toughening type master batch described in a kind of claim 1, it is characterised in that：Include the following steps：
1）Toughener, pigment, dispersant, antioxidant, antiseptic, the osmanthus essential oil for weighing formulation weight part are added Multidirectional motion and mix
Mixed at high speed, incorporation time 5-10min are carried out in conjunction machine；
2）Weigh the vector resin and scattered toughener, pigment, dispersant, antioxidant, antiseptic, osmanthus essential oil of formula ratio
It puts into mixer, is plasticized with mixer mixing at 250-280 DEG C together, mixing time 30-35min；
3）By the material being kneaded using extruder at 210-220 DEG C extruding pelletization, cooling, drying to get toughening type master batch.
8. preparation method according to claim 7, it is characterised in that：The extrusion uses double screw extruder.
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| CN201810462934.5A CN108641181A (en) | 2018-05-15 | 2018-05-15 | A kind of toughening type master batch and preparation method thereof |
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| CN201810462934.5A CN108641181A (en) | 2018-05-15 | 2018-05-15 | A kind of toughening type master batch and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504077A (en) * | 2018-11-15 | 2019-03-22 | 杭州如墨科技有限公司 | A kind of preparation method of high concentration plastic master batch |
| CN110565186A (en) * | 2019-09-16 | 2019-12-13 | 苏州宝丽迪材料科技股份有限公司 | preparation method of high-concentration colored antibacterial master batch |
| CN114835963A (en) * | 2022-03-28 | 2022-08-02 | 无锡国豪新材料科技有限公司 | Environment-friendly pre-dispersed master batch preparation process capable of realizing automatic continuous production |
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| CN104910485A (en) * | 2015-05-29 | 2015-09-16 | 苏州博利迈新材料科技有限公司 | Environment-friendly antibacterial anti-ultraviolet-radiation plastic master batch and preparation method thereof |
| CN105330962A (en) * | 2015-11-17 | 2016-02-17 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of super-tough antibacterial masterbatch with high concentration |
| CN105462146A (en) * | 2016-01-14 | 2016-04-06 | 安徽联科水基材料科技有限公司 | Multifunctional masterbatch |
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2018
- 2018-05-15 CN CN201810462934.5A patent/CN108641181A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104910485A (en) * | 2015-05-29 | 2015-09-16 | 苏州博利迈新材料科技有限公司 | Environment-friendly antibacterial anti-ultraviolet-radiation plastic master batch and preparation method thereof |
| CN105330962A (en) * | 2015-11-17 | 2016-02-17 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of super-tough antibacterial masterbatch with high concentration |
| CN105462146A (en) * | 2016-01-14 | 2016-04-06 | 安徽联科水基材料科技有限公司 | Multifunctional masterbatch |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504077A (en) * | 2018-11-15 | 2019-03-22 | 杭州如墨科技有限公司 | A kind of preparation method of high concentration plastic master batch |
| CN110565186A (en) * | 2019-09-16 | 2019-12-13 | 苏州宝丽迪材料科技股份有限公司 | preparation method of high-concentration colored antibacterial master batch |
| CN114835963A (en) * | 2022-03-28 | 2022-08-02 | 无锡国豪新材料科技有限公司 | Environment-friendly pre-dispersed master batch preparation process capable of realizing automatic continuous production |
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Application publication date: 20181012 |