CN108640583A - A kind of air entrained concrete straw building block and preparation method thereof - Google Patents

A kind of air entrained concrete straw building block and preparation method thereof Download PDF

Info

Publication number
CN108640583A
CN108640583A CN201810664774.2A CN201810664774A CN108640583A CN 108640583 A CN108640583 A CN 108640583A CN 201810664774 A CN201810664774 A CN 201810664774A CN 108640583 A CN108640583 A CN 108640583A
Authority
CN
China
Prior art keywords
parts
stalk
building block
entrained concrete
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810664774.2A
Other languages
Chinese (zh)
Inventor
刘家坤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen City Zhen Huijian Concrete Co
Original Assignee
Shenzhen City Zhen Huijian Concrete Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen City Zhen Huijian Concrete Co filed Critical Shenzhen City Zhen Huijian Concrete Co
Priority to CN201810664774.2A priority Critical patent/CN108640583A/en
Publication of CN108640583A publication Critical patent/CN108640583A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a kind of air entrained concrete straw building blocks and preparation method thereof, belong to building material technical field, it is therefore an objective to solve the problems, such as that air-entrained concrete building block easily leads to wall crazing in use.The technical solution adopted is that:A kind of air entrained concrete straw building block, is made of the raw material of following parts by weight:30~40 parts of 65~80 parts of flyash, 30~45 parts of cement, 38~48 parts of building waste, 48~60 parts of stalk, 0.2~0.8 part of aluminium powder, 4~6.5 parts of epoxychloropropane, 24~33 parts of gypsum, 2~3.5 parts of water-reducing agent and water.The present invention have the advantages that air entrained concrete straw building block drying shrinkage value is small, wall is built up with mortar after it is not easy to crack.

Description

A kind of air entrained concrete straw building block and preparation method thereof
Technical field
The present invention relates to building material technical field more particularly to a kind of air entrained concrete straw building block and its preparation sides Method.
Background technology
Air-entrained concrete building block is light porous one kind, insulation, the good New Building Materials of fire protecting performance, is used The components such as waste and industry byproduct and cement, lime, sandstone, foaming agent etc. mix, and by dispensing, stir, pour, conserve Etc. technical process be made, have many advantages, such as that environmental protection, sound-absorbing effect are good, gradually substitute traditional solid clay brick and obtain extensive Application.
In the application process of air-entrained concrete building block, due to the characteristic and part construction factor of material itself, wall is caused The problems such as cracking after body construction, hollowing, leakage.Since air-entrained concrete building block itself is a kind of high dispersive porous structure Construction material, porosity reaches 70%~80%, and air hole structure relative distribution is independent, is the small structure of the big mouth of thorax, has and inhale Water is more, surface watering is not easy to irrigate, absorb water after moisture evaporation is slow and drying shrinkage value is big feature, this results in air entrained concrete In the construction process, building block directly absorbs moisture from mortar for building block, and the position part dehydration for making mortar be contacted with building block easily goes out Situations such as bonding force between existing desiccation layering, mortar and building block declines, porous media is uneven, dry on building block section in addition Dry shrinkage value is big, is also easy to produce shrinkage stress, and then lead to wall crazing.
In the prior art, the Chinese patent that publication No. is CN106242433A discloses a kind of for air-entrained concrete building block The water conservation anticracking grout on surface, including cement, granular polystyrene, gypsum, powdered whiting, calcium hydroxide, cellulose ether, wooden fibre Dimension, latex powder and polypropylene fibre, by improving the water-retaining property and cementitiousness of mortar, reaching prevents building block from being made because of water absorption rate height It is fast at mortar dehydration and crack and the case where strength reduction occurs.But this is just needed using specific mortar and building block coordinative construction, It makes troubles for construction.
Invention content
The purpose of the present invention is to provide a kind of air entrained concrete straw building blocks, have drying shrinkage value small, not easy to crack The advantages of.
The present invention above-mentioned purpose technical scheme is that:
A kind of air entrained concrete straw building block, is made of the raw material of following parts by weight:65~80 parts of flyash, cement 30~45 Part, 38~48 parts of building waste, 48~60 parts of stalk, 0.2~0.8 part of aluminium powder, 4~6.5 parts of epoxychloropropane, gypsum 24~33 30~40 parts of part, 2~3.5 parts of water-reducing agent and water.
Further, it is made of the raw material of following parts by weight:70~75 parts of flyash, 32~40 parts of cement, building waste 40 ~45 parts, 50~58 parts of stalk, 0.3~0.5 part of aluminium powder, 5~6 parts of epoxychloropropane, 26~30 parts of gypsum, water-reducing agent 2.5~3 32~36 parts of part and water.
Implement above-mentioned technical proposal, using cement as cementitious material, using gypsum as aggregate, using aluminium powder as foaming agent, blending with The ingredients such as flyash and building waste make slurry stabilization be unlikely to deform, and addition stalk and epoxychloropropane in building block formula With other auxiliary agents, make air-entrained concrete building block in forming process, by the action-reaction of epoxychloropropane and stalk, in aerating Grid system is formed in the hole of concrete segment, i.e., the cellulose family ingredient in stalk is formed under the action of epoxychloropropane Water soluble polymer with cross-linked network thus changes the hole that the big mouth of thorax is small in existing air-entrained concrete building block Structure contributes to the water absorption rate for reducing air-entrained concrete building block.Meanwhile the water soluble polymer that stalk is constituted with epoxychloropropane In contain hydroxyl, can with hydrone formed hydrogen bond, have good water-absorbing-retaining performance, help to improve air-entrained concrete building block Water-taking efficiency, and to the structure for support of air-entrained concrete building block act on, improve the big situation of its drying shrinkage value.
Further, the mass ratio of the stalk and epoxychloropropane is 9.8:1.
Implement above-mentioned technical proposal and is conducive to cellulose family ingredient and the epoxy in stalk in the proportioning of the mass ratio Chloropropane reacts.
Further, the building waste includes dregs, concrete block, stone and brick;The average grain of the building waste Diameter is 0.2~0.4mm.
Implement above-mentioned technical proposal, building waste refers to unit in charge of construction or individual to all kinds of buildings, structures, pipe network etc. The waste built, be laid with or removed, generated in reparative processes, the raw material as air-entrained concrete building block carry out again it It utilizes, advantageously reduces building waste pollution on the environment.
Further, the water-reducing agent is one or both of sulfamate water reducer or polycarboxylate water-reducer.
Implement above-mentioned technical proposal, Water-reducing Admixtures To Cements particle has peptizaiton, can improve its workability, reduces unit and uses Water.
Further, the stalk obtains by the following method:Stalk is crushed to the graininess that grain size is 2~5mm, uses hydrogen The mixed solution of sodium oxide molybdena and thiocarbamide impregnates stalk particle, impregnates 80~110min, spare;In mixed solution, sodium hydroxide A concentration of 1~3wt%, a concentration of 1~2wt% of thiocarbamide.
Implement above-mentioned technical proposal, handles stalk particle with the mixed solution of sodium hydroxide and thiocarbamide, be conducive in stalk The ingredients such as lignocellulosic, lignin separation, in order in the preparation process of air entrained concrete straw building block, Neng Gouyu Epoxychloropropane comes into full contact with.Meanwhile under the solvent action of stalk particle surface remaining, may advantageously facilitate in stalk correlation at Divide and has an effect with epoxychloropropane.
Further, the solid-liquid mass ratio of the graininess stalk and mixed solution is 12~15:1.
It is a further object to provide a kind of methods preparing air entrained concrete straw building block, including following step Suddenly:
Step 1 mixes flyash, building waste, gypsum and water according to mass ratio, and mixture I is obtained after stirring evenly.
Cement, water-reducing agent and aluminium powder are added into mixture I, mixture II is obtained after stirring evenly for step 2.
Stalk and epoxychloropropane are added into mixture II, mixture III is obtained after stirring evenly for step 3.
Mixture III is poured into mould by step 4, by precuring, demoulding, it is steam-cured after strengthened concrete straw building block.
Implement above-mentioned technical proposal, first by admixture and water add after mixing cementitious material cement and water-reducing agent, Foaming agent makes concrete slurry gradually shape and generates hole by stirring, and stalk and epoxychloropropane is then added, is allowed to Grid system is formed in the hole of concrete slurry, changes the small air-entrained concrete building block pore structure of the big mouth of thorax, and then improve Air-entrained concrete building block water suction is more, is not easy the problem irrigated, drying shrinkage value is big.
Further, the stalk obtains by the following method:Stalk is crushed to the graininess that grain size is 2~5mm, uses hydrogen The mixed solution of sodium oxide molybdena and thiocarbamide impregnates stalk particle, impregnates 80~110min, spare;In mixed solution, sodium hydroxide A concentration of 1~3wt%, a concentration of 1~2wt% of thiocarbamide.
Implement above-mentioned technical proposal, handles stalk particle with the mixed solution of sodium hydroxide and thiocarbamide, be conducive in stalk The ingredients such as lignocellulosic, lignin separation, in order in the preparation process of air entrained concrete straw building block, Neng Gouyu Epoxychloropropane comes into full contact with.Meanwhile under the solvent action of stalk particle surface remaining, may advantageously facilitate in stalk correlation at Divide and has an effect with epoxychloropropane.
Further, the solid-liquid mass ratio of the graininess stalk and mixed solution is 12~15:1.
In conclusion the invention has the advantages that:
By the way that stalk and epoxychloropropane are added in the formula of air-entrained concrete building block, it is allowed to be molded in air-entrained concrete building block Cross-linked network is formed in the process, is interspersed in the hole of air-entrained concrete building block, and it is small thus to change the big mouth of hole thorax Structure, and play a supportive role to pore structure, advantageously reduce the water absorption and drying shrinkage value of air-entrained concrete building block, into And absorption of the air-entrained concrete building block to moisture in mortar in work progress is reduced, it is also allowed to the contraction that is not easy after completing to construct and becomes Shape, air entrained concrete straw building block provided by the invention in this way can be used cooperatively with ordinary mortar and be not easy to deform upon cracking.
Specific implementation mode
The technical solution of the embodiment of the present invention will be described below.
Embodiment one
A kind of air entrained concrete straw building block, is made of the raw material of following weight:The flyash of 78kg, the cement of 36kg, The building waste of 45.6kg, the stalk of 57.6kg, the aluminium powder of 0.24kg, the epoxychloropropane of 4.8kg, 28.8kg gypsum, The sulfamate water reducer of 2.4kg and the water of 36kg.The building waste that the present embodiment uses includes dregs, concrete block, stone Block and brick, and the average grain diameter of building waste is 0.3mm.
The air entrained concrete straw building block of the present embodiment is prepared according to the following steps:
Step 1 obtains mixture I by flyash, building waste, gypsum and water according to above-mentioned mass mixing after stirring evenly.
Cement, water-reducing agent and aluminium powder are added into mixture I, mixture II is obtained after stirring evenly for step 2.
Stalk and epoxychloropropane are added into mixture II, mixture III is obtained after stirring evenly for step 3.
Mixture III is poured into mould by step 4, by precuring, demoulding, it is steam-cured after strengthened concrete straw building block. Wherein, precuring environment is 38 ± 2 DEG C, time 80min;Steam-cured environment is 180 ± 1 DEG C, pressure 1.3MPa, and the time is 11.5h。
Wherein, the stalk that the present embodiment uses obtains by the following method:Stalk is crushed to that average grain diameter is 3mm It is granular, impregnate stalk particle, the solid-liquid mass ratio of graininess stalk and mixed solution with the mixed solution of sodium hydroxide and thiocarbamide It is 12:1,110min is impregnated, it is spare.In mixed solution, a concentration of 1wt% of sodium hydroxide, a concentration of 1wt% of thiocarbamide.
Embodiment two
The present embodiment and the difference of embodiment one essentially consist in:It is made of the raw material of following weight:Flyash, the 48kg of 105kg Cement, the building waste of 60kg, the stalk of 45kg, the aluminium powder of 0.45kg, the epoxychloropropane of 7.5kg, 39kg gypsum, The polycarboxylate water-reducer of 3.75kg and the water of 48kg.
Wherein, the stalk that the present embodiment uses obtains by the following method:Stalk is crushed to that average grain diameter is 4mm It is granular, impregnate stalk particle, the solid-liquid mass ratio of graininess stalk and mixed solution with the mixed solution of sodium hydroxide and thiocarbamide It is 14:1,100min is impregnated, it is spare.In mixed solution, a concentration of 2wt% of sodium hydroxide, a concentration of 2wt% of thiocarbamide.
Embodiment three
The present embodiment and the difference of embodiment one essentially consist in:It is made of the raw material of following weight:The flyash of 80.3kg, The cement of 39.6kg, the building waste of 47.3kg, the stalk of 59.4kg, the aluminium powder of 0.44kg, 6.05kg epoxychloropropane, The water of the gypsum of 30.8kg, the sulfamate water reducer of 2kg, the polycarboxylate water-reducer of 1.08kg and 37.4kg.
Wherein, the stalk that the present embodiment uses obtains by the following method:Stalk is crushed to that average grain diameter is 5mm It is granular, impregnate stalk particle, the solid-liquid mass ratio of graininess stalk and mixed solution with the mixed solution of sodium hydroxide and thiocarbamide It is 15:1,80min is impregnated, it is spare.In mixed solution, a concentration of 3wt% of sodium hydroxide, a concentration of 2wt% of thiocarbamide.
Example IV
The present embodiment and the difference of embodiment one essentially consist in:It is made of the raw material of following weight:The flyash of 60kg, 32kg Cement, the building waste of 36kg, the stalk of 46.4kg, the aluminium powder of 0.4kg, the epoxychloropropane of 4.8kg, 24kg gypsum, The water of the sulfamate water reducer of 0.8kg, the polycarboxylate water-reducer of 1.6kg and 28.8kg.
Wherein, the stalk that the present embodiment uses obtains by the following method:Stalk is crushed to that average grain diameter is 4mm It is granular, impregnate stalk particle, the solid-liquid mass ratio of graininess stalk and mixed solution with the mixed solution of sodium hydroxide and thiocarbamide It is 13:1,90min is impregnated, it is spare.In mixed solution, a concentration of 2.5wt% of sodium hydroxide, a concentration of 2wt% of thiocarbamide.
Embodiment five
The present embodiment and the difference of embodiment one essentially consist in:It is made of the raw material of following weight:The flyash of 60kg, The cement of 33.75kg, the building waste of 36kg, the stalk of 45kg, the aluminium powder of 0.6kg, 4.88kg epoxychloropropane, The water of the gypsum of 24.75kg, the sulfamate water reducer of 1.13kg, the polycarboxylate water-reducer of 1.5kg and 30kg.
Wherein, the stalk that the present embodiment uses obtains by the following method:Stalk is crushed to that average grain diameter is 3mm It is granular, impregnate stalk particle, the solid-liquid mass ratio of graininess stalk and mixed solution with the mixed solution of sodium hydroxide and thiocarbamide It is 12:1,105min is impregnated, it is spare.In mixed solution, a concentration of 1.5wt% of sodium hydroxide, a concentration of 1wt% of thiocarbamide.
Comparative example one
The difference of this comparative example and embodiment three essentially consists in:Stalk is not contained in the component prescription of this comparative example.
Comparative example two
The difference of this comparative example and embodiment three essentially consists in:Epoxychloropropane is not contained in the component prescription of this comparative example.
Comparative example three
The difference of this comparative example and embodiment three essentially consists in:Stalk and epoxy chloropropionate are not contained in the component prescription of this comparative example Alkane.
Product testing
According to the standard of GB/T11968-2006 to the dry close of the air entrained concrete straw building block product of each embodiment and comparative example Degree and drying shrinkage value are detected, and testing result is as shown in table 1.
The testing result of 1 each embodiment and comparative example product of table
Dry density (kg/m3) Drying shrinkage value (mm/m)
Embodiment one 296 0.09
Embodiment two 287 0.08
Embodiment three 293 0.06
Example IV 285 0.10
Embodiment five 287 0.11
Comparative example one 462 0.53
Comparative example two 332 0.35
Comparative example three 481 0.56
By table 1 as it can be seen that the dry density and drying shrinkage value of air entrained concrete straw building block prepared by various embodiments of the present invention It is superior to not add the comparative example product of stalk or epoxychloropropane, while adding stalk and epoxychloropropane to air entrained concrete The performance of building block has positive impact;The product correlated performance of comparative example two is better than comparative example one and comparative example three, that is, adds stalk There is promotion to the dry density and drying shrinkage value of air-entrained concrete building block.Wherein, the drying shrinkage value of embodiment three is minimum, can See that the mass ratio of stalk and epoxychloropropane is 9.8:The air-entrained concrete building block of 1 proportioning production, drying shrinkage value aspect Best performance.

Claims (10)

1. a kind of air entrained concrete straw building block, which is characterized in that be made of the raw material of following parts by weight:Flyash 65~80 Part, 30~45 parts of cement, 38~48 parts of building waste, 48~60 parts of stalk, 0.2~0.8 part of aluminium powder, epoxychloropropane 4~6.5 Part, 24~33 parts of gypsum, 2~3.5 parts of water-reducing agent and 30~40 parts of water.
2. a kind of air entrained concrete straw building block according to claim 1, which is characterized in that by the raw material of following parts by weight Composition:70~75 parts of flyash, 32~40 parts of cement, 40~45 parts of building waste, 50~58 parts of stalk, aluminium powder 0.3~0.5 Part, 5~6 parts of epoxychloropropane, 26~30 parts of gypsum, 2.5~3 parts of water-reducing agent and 32~36 parts of water.
3. a kind of air entrained concrete straw building block according to claim 1, which is characterized in that the stalk and epoxy chloropropionate The mass ratio of alkane is 9.8:1.
4. a kind of air entrained concrete straw building block according to claim 1, which is characterized in that the building waste includes slag Soil, concrete block, stone and brick;The average grain diameter of the building waste is 0.2~0.4mm.
5. a kind of air entrained concrete straw building block according to claim 1, which is characterized in that the water-reducing agent is amino sulphur One or both of hydrochlorate water-reducing agent or polycarboxylate water-reducer.
6. a kind of air entrained concrete straw building block according to claim 1, which is characterized in that the stalk is according to following sides Method obtains:Stalk is crushed to the graininess that grain size is 2~5mm, impregnates stalk with the mixed solution of sodium hydroxide and thiocarbamide Grain impregnates 80~110min, spare;In mixed solution, a concentration of 1~3wt% of sodium hydroxide, thiocarbamide a concentration of 1~ 2wt%。
7. a kind of air entrained concrete straw building block according to claim 6, which is characterized in that the graininess stalk with it is mixed The solid-liquid mass ratio for closing solution is 12~15:1.
8. a kind of preparation method of air entrained concrete straw building block as claimed in any of claims 1 to 7 in one of claims, feature exist In including the following steps:
Step 1 mixes flyash, building waste, gypsum and water according to mass ratio, and mixture I is obtained after stirring evenly;
Cement, water-reducing agent and aluminium powder are added into mixture I, mixture II is obtained after stirring evenly for step 2;
Stalk and epoxychloropropane are added into mixture II, mixture III is obtained after stirring evenly for step 3;
Mixture III is poured into mould by step 4, by precuring, demoulding, it is steam-cured after strengthened concrete straw building block.
9. a kind of preparation method of air entrained concrete straw building block according to claim 8, which is characterized in that the stalk It obtains by the following method:Stalk is crushed to the graininess that grain size is 2~5mm, with the mixed solution of sodium hydroxide and thiocarbamide Stalk particle is impregnated, 80~110min is impregnated, it is spare;In mixed solution, a concentration of 1~3wt% of sodium hydroxide, thiocarbamide it is dense Degree is 1~2wt%.
10. a kind of preparation method of air entrained concrete straw building block according to claim 9, which is characterized in that described The solid-liquid mass ratio of granular stalk and mixed solution is 12~15:1.
CN201810664774.2A 2018-06-25 2018-06-25 A kind of air entrained concrete straw building block and preparation method thereof Pending CN108640583A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810664774.2A CN108640583A (en) 2018-06-25 2018-06-25 A kind of air entrained concrete straw building block and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810664774.2A CN108640583A (en) 2018-06-25 2018-06-25 A kind of air entrained concrete straw building block and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108640583A true CN108640583A (en) 2018-10-12

Family

ID=63753606

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810664774.2A Pending CN108640583A (en) 2018-06-25 2018-06-25 A kind of air entrained concrete straw building block and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108640583A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109678424A (en) * 2019-01-14 2019-04-26 青岛天利兴达新型建材有限公司 A kind of autoclave aerated concrete building block and preparation method thereof
CN109734386A (en) * 2018-12-27 2019-05-10 广州华隆建筑材料有限公司 A kind of engineering brick of environment-friendly type and preparation method thereof
CN110835241A (en) * 2018-08-16 2020-02-25 安徽四建控股集团有限公司 Building waste treatment method and preparation process for producing autoclaved fly ash bricks by using building waste
CN115259887A (en) * 2022-08-11 2022-11-01 启东海中港建材有限公司 High-strength aerated renewable concrete

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1141087A1 (en) * 1982-12-03 1985-02-23 Центральный Научно-Исследовательский Институт Строительных Конструкций Им.В.А.Кучеренко Raw mixture for making heat-insulating construction material
CN101182163A (en) * 2007-11-06 2008-05-21 福州大学 Raw materials formula of enzymatic hydrolysis lignin or its derivative-concrete composite material and preparation method
CN101961645A (en) * 2010-10-14 2011-02-02 华南理工大学 Adsorbing agent for eliminating S4O2<-> in acid mine wastewater and preparation method thereof
CN103396044A (en) * 2013-07-13 2013-11-20 王进 Energy-saving building block compounded with construction waste, straws and foamed concrete

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1141087A1 (en) * 1982-12-03 1985-02-23 Центральный Научно-Исследовательский Институт Строительных Конструкций Им.В.А.Кучеренко Raw mixture for making heat-insulating construction material
CN101182163A (en) * 2007-11-06 2008-05-21 福州大学 Raw materials formula of enzymatic hydrolysis lignin or its derivative-concrete composite material and preparation method
CN101961645A (en) * 2010-10-14 2011-02-02 华南理工大学 Adsorbing agent for eliminating S4O2<-> in acid mine wastewater and preparation method thereof
CN103396044A (en) * 2013-07-13 2013-11-20 王进 Energy-saving building block compounded with construction waste, straws and foamed concrete

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
段久芳: "《天然高分子材料》", 30 September 2016, 华中科技大学出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835241A (en) * 2018-08-16 2020-02-25 安徽四建控股集团有限公司 Building waste treatment method and preparation process for producing autoclaved fly ash bricks by using building waste
CN109734386A (en) * 2018-12-27 2019-05-10 广州华隆建筑材料有限公司 A kind of engineering brick of environment-friendly type and preparation method thereof
CN109678424A (en) * 2019-01-14 2019-04-26 青岛天利兴达新型建材有限公司 A kind of autoclave aerated concrete building block and preparation method thereof
CN115259887A (en) * 2022-08-11 2022-11-01 启东海中港建材有限公司 High-strength aerated renewable concrete

Similar Documents

Publication Publication Date Title
CN108046712B (en) High-strength low-resilience-rate sprayed concrete and construction process thereof
CN108623239B (en) Special mortar for aerated concrete
CN108640583A (en) A kind of air entrained concrete straw building block and preparation method thereof
US6217646B1 (en) Sculptable and breathable wall coating mortar compound
CN105130333B (en) A kind of non-evaporating foster high-strength cement sawdust-board and preparation method thereof
CN108530009A (en) A kind of inner wall of building lightweight plastering gupsum
CN100577601C (en) Dried powder boundary processing agent
CN101130993A (en) Cut-off wall slurry material and wall building technique
CN103771807B (en) A kind of lightweight grain cell concrete heat insulation building block and preparation method thereof
CN108609974A (en) A kind of preparation method of ultra-high performance concrete and prefabricated PC
CN110467407A (en) A kind of C70 mass concrete and its preparation process
CN105733382B (en) A kind of micro-nano reinforced steel bar rust preventing agent and preparation method thereof of autoclaved aerated concrete slab
CN108529940A (en) A kind of foamed concrete thermal insulation board
CN108546072A (en) A kind of resistance to water dispenser dusting brush gypsum material
CN108484211A (en) A kind of preparation method of foamed concrete thermal insulation board
CN107098667A (en) Gypsum base light energy conservation plate and preparation method thereof
CN108585939A (en) A kind of formula and preparation method of Novel foam concrete
CN106946526A (en) A kind of energy saving building material and preparation method thereof
CN106242433A (en) A kind of water conservation anticracking grout for air-entrained concrete building block surface
CN101712545A (en) Inner wall plastering mortar and construction method thereof
JP2009084092A (en) Mortar-based restoring material
CN101698587A (en) Exterior wall plastering mortar and construction method thereof
RU2338724C1 (en) Dry heat-insulating plastered cellular polystyrene construction mixture for coatings, items and structures and method of its preparation
CN108516747A (en) A kind of haydite heat preservation energy-saving building materials and preparation method thereof
CN108726942A (en) A kind of air-mixed concrete pieces and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181012

RJ01 Rejection of invention patent application after publication