CN108623864A - The dipping method and gloves of a kind of emgloves dipping emulsion and gloves - Google Patents
The dipping method and gloves of a kind of emgloves dipping emulsion and gloves Download PDFInfo
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- CN108623864A CN108623864A CN201810494313.5A CN201810494313A CN108623864A CN 108623864 A CN108623864 A CN 108623864A CN 201810494313 A CN201810494313 A CN 201810494313A CN 108623864 A CN108623864 A CN 108623864A
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- emgloves
- dipping
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- emulsion
- gloves
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of emgloves dipping emulsion and the dipping method and gloves of gloves, the emgloves dipping emulsion is calculated in parts by weight, including：3~15 parts of polyurethane, 5~50 parts of acrylic acid, 35~92 parts of butyronitrile；The method includes emulsion gloves ceramic mould to be impregnated in coagulator, take out, 110 DEG C of dry 10min；It is impregnated in natural milk gelatin, takes out again, dry 15min, dipping thickness is the one third of finished product gloves thickness；Then the emgloves dipping emulsion is prepared, emgloves green body is impregnated in the emgloves dipping emulsion, dipping thickness is 2/3rds of finished product gloves thickness, takes out levelling, 120 DEG C of dry 30min；Demoulding, obtains finished product；There is the dipping emulsion coating that the emgloves includes genuine milk glue-line, is wrapped on genuine milk glue-line excellent anti-adhesion performance, its wearability to improve 30% with general emgloves on the market compared with, anti-punctures property raising 50%, yellowing resistance raising 60%.
Description
Technical field
The present invention relates to appliances for labor protection and its dipping technique field, more particularly to a kind of emgloves dipping emulsion and gloves
Dipping method and gloves.
Background technology
Gloves are a kind of common appliances for labor protection, are a kind of protective articles of important hand, in industrial and agricultural production, doctor
It suffers from and is widely applied in treatment, daily life.Natural rubber gloves are relatively more viscous, are easily sticked to together if do not dealt with, no
Only be not easy to separate between gloves and gloves, use when also bad de- wear；To solve this problem, more commonly used at present to do
Method is anti-sticking to increase cunning in the powder of the lubricating actions such as glove interior surface viscous maize starch or talcum powder, however these powder are stained with
On hand can be uncomfortable, or even cause skin allergy, in this special dimension of electronics industry using also restrained；Another is often
Method is chlorination, although eliminate the puzzlement of powder, the gloves that are handled through superchlorination are permanent to turn to be yellow, the drawing of gloves
Intensity, elasticity etc. are stretched also due to chlorination reaction reduces the ageing resistance of sizing material and drastically declines, and pin hole are also often occurred and are asked
Topic, and chloridization process not only to health generate harm, can also electroetching production line metal parts.
As it can be seen that the prior art could be improved and improve.
Invention content
Place in view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of emgloves dipping emulsion and
The dipping method and gloves of gloves, it is intended to solve in the prior art emgloves inner wall be easy bond, wearability, anti-puncture property and
Yellowing resistance is not high enough, is not suitable with corrosivity and the problem of the bigger occasion of frictional property uses.
In order to achieve the above object, this invention takes following technical schemes：
A kind of emgloves dipping emulsion, is calculated in parts by weight, including：
3~15 parts of polyurethane,
5~50 parts of acrylic acid,
35~92 parts of butyronitrile.
The emgloves dipping emulsion, is calculated in parts by weight, including：
5~12 parts of polyurethane,
20~45 parts of acrylic acid,
40~70 parts of butyronitrile.
The emgloves dipping emulsion, is calculated in parts by weight, including：
8 parts of polyurethane,
30 parts of acrylic acid,
62 parts of butyronitrile.
In the emgloves dipping emulsion, the solid content of the emgloves dipping emulsion is 40%~
55%。
In the emgloves dipping emulsion, the solid content of the emgloves dipping emulsion is 45%.
In the emgloves dipping emulsion, the viscosity of the emgloves dipping emulsion is 900~1100cps.
In the emgloves dipping emulsion, the viscosity of the emgloves dipping emulsion is 1000cps.
A kind of dipping method of emgloves, includes the following steps：
S001. emulsion gloves ceramic mould is impregnated in coagulator, is taken out, 110 DEG C of dry 10min；
S002. the emgloves green body after dipping coagulator in step S001 is impregnated in natural milk gelatin, is taken out, it is dry
15min, dipping thickness are the one third of finished product gloves thickness；
S003. the emgloves dipping emulsion described in claim any one of 1-7 is prepared, by step S002 treated latexes
Gloves green body is impregnated in the emgloves dipping emulsion, and dipping thickness is 2/3rds of finished product gloves thickness, takes out stream
It is flat, 120 DEG C of dry 30min；Demoulding, obtains finished product.
A kind of emgloves of emgloves dipping emulsion dipping, including genuine milk glue-line and it is wrapped in genuine milk glue-line
On dipping emulsion coating.
Advantageous effect：
The present invention provides a kind of emgloves dipping emulsion and the dipping method and gloves of gloves, the emgloves has excellent
Good anti-adhesion performance, the gloves after dipping emulsion dipping, which are used for a long time inner wall all, to be bonded together, and are free of
The substance of the lubricities such as cornstarch or talcum powder, avoids powder from dropping out, influences work；It is the wearability of the gloves, anti-stab
Wearing property, yellowing resistance are apparently higher than existing emgloves on the market, and wearability improves 30%, and anti-puncture property improves 50%,
Yellowing resistance improves 60%, substantially increases the service life of the gloves.
Description of the drawings
Fig. 1 is the process flow chart of the dipping method of the emgloves provided by the invention.
Specific implementation mode
The present invention provides the dipping method and gloves of a kind of emgloves dipping emulsion and gloves, to make the mesh of the present invention
, technical solution and effect it is clearer, clear, the present invention is described in more detail for the embodiment that develops simultaneously referring to the drawings.
It should be appreciated that described herein, specific examples are only used to explain the present invention, is not intended to limit the present invention.
The present invention provides a kind of emgloves dipping emulsion, calculates in parts by weight, including：
3~15 parts of polyurethane,
5~50 parts of acrylic acid,
35~92 parts of butyronitrile.
Said components synthesize the emgloves dipping emulsion under certain conditions according to the proportioning,
With good mobility and levelability, to impregnate the emgloves after the lotion and on the market general emgloves into
The test of row wearability, anti-puncture property and yellowing resistance, the wearability for impregnating the latex after the lotion are significantly improved, than
General emgloves improves 30% on the market, and anti-puncture property improves 50%, and yellowing resistance improves 60%, effectively improves latex hand
The service life of set has widened its use occasion, and has had good grease proofness, and emgloves can keep dry and comfortable, be not required to
To be suitble to the use of the special dimensions such as electronics industry by greasing substances such as cornstarch or talcum powder.
The emgloves dipping emulsion can also be polymerized by following two combinations, the first scheme, including：
5%~50% polyurethane, 50%~95% butyronitrile；Second scheme, including：10%~70% butyronitrile, 30%~90% acrylic acid；The present invention
A kind of preferred scheme is provided, the emgloves after emgloves dipping emulsion dipping is in wearability, anti-puncture
All reach best level on property and yellowing resistance.
Preferably, the emgloves dipping emulsion, is calculated in parts by weight, including：
5~12 parts of polyurethane,
20~45 parts of acrylic acid,
40~70 parts of butyronitrile；
The advantages of proportioning of the ingredient is preferred scheme, this proportioning lower emgloves dipping emulsion more protrudes.
It is highly preferred that the emgloves dipping emulsion, is calculated in parts by weight, including：
8 parts of polyurethane,
30 parts of acrylic acid,
62 parts of butyronitrile；
The emgloves dipping emulsion reaches best state after being synthesized under mentioned component and proportioning, soaks
The emgloves obtained after stain reaches best level in terms of wearability, anti-puncture property and yellowing resistance.
Preferably, the solid content of the emgloves dipping emulsion is 40%~55%.
It is highly preferred that the solid content of the emgloves dipping emulsion is 45%；The solid content of lotion is to it
All there is influence in mechanical property, hot property and microstructure after dipping film forming；Applicant proves through a large number of experiments,
The solid content of the emgloves dipping emulsion is 40%~55%, when especially 45%, the emgloves dipping emulsion dipping at
Tensile strength after film is best, and elongation at break is minimum, and the centralized particle diameter of lotion, and film is smooth, good in thermal property.
Preferably, the viscosity of the emgloves dipping emulsion is 900~1100cps.
It is highly preferred that the viscosity of the emgloves dipping emulsion is 1000cps；The size of emulsion viscosity stablizes it
Property, the performances such as mobility and levelability all exist and influence, under normal circumstances, the big emulsion intercalation method of viscosity is preferable, but flows
Dynamic property and levelling effect are relatively poor；The small stability of emulsion of viscosity is poor, and mobility and levelling effect are preferable；The latex hand
The viscosity for covering dipping emulsion is 900~1100cps, and when specifically for 1000cps, stability, mobility and levelling effect reach
One best balance, which is the emgloves after lotion dipping, has optimal physicochemical property.
Referring to Fig. 1, a kind of dipping method of emgloves, includes the following steps：
S001. emulsion gloves ceramic mould is impregnated in coagulator, is taken out, 110 DEG C of dry 10min；
S002. the emgloves green body after dipping coagulator in step S001 is impregnated in natural milk gelatin, is taken out, it is dry
15min, dipping thickness are the one third of finished product gloves thickness；
S003. the emgloves dipping emulsion described in claim any one of 1-7 is prepared, by step S002 treated latexes
Gloves green body is impregnated in the emgloves dipping emulsion, and dipping thickness is 2/3rds of finished product gloves thickness, takes out stream
It is flat, 120 DEG C of dry 30min；Demoulding, obtains finished product.
Strict temperature control is wanted in dipping process, ensures that lotion has good mobility, and it is heated rear more preferable to be immersed article
Ground is combined with dipping emulsion, but temperature is too high to be easy to make the volatile component in dipping emulsion to evaporate, and may be sent out
Life further polymerize and changes its physicochemical property, influences the performance of product after dipping；When setting leaching coagulator in dipping process
Temperature is 110 DEG C, and temperature is 120 DEG C when soaking emgloves dipping emulsion, is according to coagulator and emgloves dipping breast
What the performance of liquid determined, it will not both change the performance of dipping emulsion, so that the mobility of dipping emulsion is in optimum state, very well
Ground is combined with immersed article, so as to get the physicochemical property of emgloves reach best state.
A kind of emgloves of emgloves dipping emulsion dipping, including genuine milk glue-line and it is wrapped in genuine milk glue-line
On dipping emulsion coating.
Embodiment 1
The emgloves dipping emulsion, is calculated in parts by weight, including：
3 parts of polyurethane,
38 parts of acrylic acid,
78 parts of butyronitrile.
The preparation method of above-mentioned emgloves dipping emulsion, including：Emulsion gloves ceramic mould is impregnated in coagulator,
It takes out, 110 DEG C of dry 10min；
The emgloves green body after dipping coagulator is impregnated in natural milk gelatin again, is taken out, dry 15min impregnates thickness
For the one third of finished product gloves thickness；
The emgloves dipping emulsion is prepared, the emgloves green body after dipping natural milk gelatin is impregnated in the latex hand
It covers in dipping emulsion, dipping thickness is 2/3rds of finished product gloves thickness, takes out levelling, 120 DEG C of dry 30min；Demoulding, obtains
Finished product.
Embodiment 2
The emgloves dipping emulsion, is calculated in parts by weight, including：
15 parts of polyurethane,
5 parts of acrylic acid,
47 parts of butyronitrile.
The preparation method of above-mentioned emgloves dipping emulsion, including：Emulsion gloves ceramic mould is impregnated in coagulator,
It takes out, 110 DEG C of dry 10min；
The emgloves green body after dipping coagulator is impregnated in natural milk gelatin again, is taken out, dry 15min impregnates thickness
For the one third of finished product gloves thickness；
The emgloves dipping emulsion is prepared, the emgloves green body after dipping natural milk gelatin is impregnated in the latex hand
It covers in dipping emulsion, dipping thickness is 2/3rds of finished product gloves thickness, takes out levelling, 120 DEG C of dry 30min；Demoulding, obtains
Finished product.
Embodiment 3
The emgloves dipping emulsion, is calculated in parts by weight, including：
8 parts of polyurethane,
30 parts of acrylic acid,
62 parts of butyronitrile.
The preparation method of above-mentioned emgloves dipping emulsion, including：Emulsion gloves ceramic mould is impregnated in coagulator,
It takes out, 110 DEG C of dry 10min；
The emgloves green body after dipping coagulator is impregnated in natural milk gelatin again, is taken out, dry 15min impregnates thickness
For the one third of finished product gloves thickness；
The emgloves dipping emulsion is prepared, the emgloves green body after dipping natural milk gelatin is impregnated in the latex hand
It covers in dipping emulsion, dipping thickness is 2/3rds of finished product gloves thickness, takes out levelling, 120 DEG C of dry 30min；Demoulding, obtains
Finished product.
Embodiment 4
The emgloves dipping emulsion, is calculated in parts by weight, including：
12 parts of polyurethane,
50 parts of acrylic acid,
35 parts of butyronitrile.
The preparation method of above-mentioned emgloves dipping emulsion, including：Emulsion gloves ceramic mould is impregnated in coagulator,
It takes out, 110 DEG C of dry 10min；
The emgloves green body after dipping coagulator is impregnated in natural milk gelatin again, is taken out, dry 15min impregnates thickness
For the one third of finished product gloves thickness；
The emgloves dipping emulsion is prepared, the emgloves green body after dipping natural milk gelatin is impregnated in the latex hand
It covers in dipping emulsion, dipping thickness is 2/3rds of finished product gloves thickness, takes out levelling, 120 DEG C of dry 30min；Demoulding, obtains
Finished product.
Embodiment 5
The emgloves dipping emulsion, is calculated in parts by weight, including：
5 parts of polyurethane,
21 parts of acrylic acid,
92 parts of butyronitrile.
The preparation method of above-mentioned emgloves dipping emulsion, including：Emulsion gloves ceramic mould is impregnated in coagulator,
It takes out, 110 DEG C of dry 10min；
The emgloves green body after dipping coagulator is impregnated in natural milk gelatin again, is taken out, dry 15min impregnates thickness
For the one third of finished product gloves thickness；
The emgloves dipping emulsion is prepared, the emgloves green body after dipping natural milk gelatin is impregnated in the latex hand
It covers in dipping emulsion, dipping thickness is 2/3rds of finished product gloves thickness, takes out levelling, 120 DEG C of dry 30min；Demoulding, obtains
Finished product.
Emgloves finished product prepared by above-described embodiment 1~5 carries out wearability with general emgloves on the market, prevents
The test of puncture property, yellowing resistance, the above-mentioned performance of emgloves prepared by Examples 1 to 5 are greatly better than on the market one
As emgloves, wherein wearability improves 30%, and anti-punctures property improves 50%, and yellowing resistance raising 60% greatly increases
The service life of emgloves；The emgloves is dry and comfortable, does not after-tack, and need not add the powder of lubricity, is suitble to electricity
The special dimensions such as sub- industry use.
It, can according to the technique and scheme of the present invention and its hair it is understood that for those of ordinary skills
Bright design is subject to equivalent substitution or change, and all these changes or replacement should all belong to the guarantor of appended claims of the invention
Protect range.
Claims (9)
1. a kind of emgloves dipping emulsion, which is characterized in that the emgloves dipping emulsion is calculated in parts by weight, packet
It includes：
3~15 parts of polyurethane,
5~50 parts of acrylic acid,
35~92 parts of butyronitrile.
2. emgloves dipping emulsion according to claim 1, which is characterized in that the emgloves dipping emulsion according to
Listed as parts by weight, including：
5~12 parts of polyurethane,
20~45 parts of acrylic acid,
40~70 parts of butyronitrile.
3. emgloves dipping emulsion according to claim 1, which is characterized in that the emgloves dipping emulsion according to
Listed as parts by weight, including：
8 parts of polyurethane,
30 parts of acrylic acid,
62 parts of butyronitrile.
4. emgloves dipping emulsion according to claim 1, which is characterized in that the emgloves dipping emulsion is consolidated
Content is 40%~55%.
5. emgloves dipping emulsion according to claim 4, which is characterized in that the emgloves dipping emulsion is consolidated
Content is 45%.
6. emgloves dipping emulsion according to claim 1, which is characterized in that the emgloves dipping emulsion glues
Degree is 900~1100cps.
7. emgloves dipping emulsion according to claim 6, which is characterized in that the emgloves dipping emulsion glues
Degree is 1000cps.
8. a kind of dipping method of emgloves, which is characterized in that include the following steps：
S001. emulsion gloves ceramic mould is impregnated in coagulator, is taken out, 110 DEG C of dry 10min；
S002. the emgloves green body after dipping coagulator in step S001 is impregnated in natural milk gelatin, is taken out, it is dry
15min, dipping thickness are the one third of finished product gloves thickness；
S003. the emgloves dipping emulsion described in claim any one of 1-7 is prepared, by step S002 treated latexes
Gloves green body is impregnated in the emgloves dipping emulsion, and dipping thickness is 2/3rds of finished product gloves thickness, takes out stream
It is flat, 120 DEG C of dry 30min；Demoulding, obtains finished product.
9. a kind of emgloves impregnated using the emgloves dipping emulsion as described in claim any one of 1-7, feature
It is, including genuine milk glue-line and the dipping emulsion coating that is wrapped on genuine milk glue-line.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810494313.5A CN108623864A (en) | 2018-05-22 | 2018-05-22 | The dipping method and gloves of a kind of emgloves dipping emulsion and gloves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810494313.5A CN108623864A (en) | 2018-05-22 | 2018-05-22 | The dipping method and gloves of a kind of emgloves dipping emulsion and gloves |
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| Publication Number | Publication Date |
|---|---|
| CN108623864A true CN108623864A (en) | 2018-10-09 |
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|---|---|---|---|
| CN201810494313.5A Pending CN108623864A (en) | 2018-05-22 | 2018-05-22 | The dipping method and gloves of a kind of emgloves dipping emulsion and gloves |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112293820A (en) * | 2019-07-31 | 2021-02-02 | 斯特托手套有限公司 | Medical hand covering |
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| CN106213629A (en) * | 2016-07-22 | 2016-12-14 | 镇江苏惠乳胶制品有限公司 | A kind of preparation method of double-layer rubber glove |
| CN106666879A (en) * | 2017-01-17 | 2017-05-17 | 南通强生安全防护科技股份有限公司 | Production method of butyronitrile superfine foam glove |
| CN107865471A (en) * | 2017-12-01 | 2018-04-03 | 北京瑞京乳胶制品有限公司 | A kind of double-deck emgloves and preparation method thereof |
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2018
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|---|---|---|---|---|
| JP2001081614A (en) * | 1999-09-06 | 2001-03-27 | Dia Gomme Kk | Gloves for working |
| CN103330309A (en) * | 2012-10-23 | 2013-10-02 | 镇江苏惠乳胶制品有限公司 | Multi-layer composite gloves |
| CN106213629A (en) * | 2016-07-22 | 2016-12-14 | 镇江苏惠乳胶制品有限公司 | A kind of preparation method of double-layer rubber glove |
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| CN112293820A (en) * | 2019-07-31 | 2021-02-02 | 斯特托手套有限公司 | Medical hand covering |
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Application publication date: 20181009 |
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