CN108611878A - 一种sls/sla复合材料的染色方法 - Google Patents

一种sls/sla复合材料的染色方法 Download PDF

Info

Publication number
CN108611878A
CN108611878A CN201810425949.4A CN201810425949A CN108611878A CN 108611878 A CN108611878 A CN 108611878A CN 201810425949 A CN201810425949 A CN 201810425949A CN 108611878 A CN108611878 A CN 108611878A
Authority
CN
China
Prior art keywords
sls
sla
composite materials
bath
dressing liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810425949.4A
Other languages
English (en)
Inventor
陈锋
叶军祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Sapp Polytron Technologies Inc
Original Assignee
Wuhan Sapp Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Sapp Polytron Technologies Inc filed Critical Wuhan Sapp Polytron Technologies Inc
Priority to CN201810425949.4A priority Critical patent/CN108611878A/zh
Publication of CN108611878A publication Critical patent/CN108611878A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/56—Condensation products or precondensation products prepared with aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/422—Hydrazides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
    • D06M13/453—Phosphates or phosphites containing nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/06—After-treatment with organic compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Fireproofing Substances (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及一种SLS/SLA复合材料的染色方法，包括S1、采用第一浴整理液对SLS/SLA复合材料进行浸泡处理；S2、将经过所述第一浴整理液处理后的SLS/SLA复合材料采用第二浴整理液进行浸泡处理；S3、将经过所述第二浴整理液处理后的SLS/SLA复合材料置于频率＞200kHz的超声波声场中的含有染色浴液中染色至少1min，染色温度为55～75℃；S4、将经过染色浴液处理后的SLS/SLA复合材料用2450MHz的微波辐照至少1min；S5、将经过微波辐照后的SLS/SLA复合材料采用第三浴整理液进行浸泡处理；S6、将经过所述第三浴整理液处理后的SLS/SLA复合材料烘干，完成染色。本发明染色后的SLS/SLA复合材料具有较好的阻燃效果，并且力学性能与染色之前一样。

Description

一种SLS/SLA复合材料的染色方法
技术领域
本发明涉及一种染色领域，尤其涉及一种SLS/SLA复合材料的染色方 法。
背景技术
3D打印的材料主要是尼龙(SLS)/光敏树脂(SLA)复合材料。采用 现有技术染色后，其形状会发生肉眼可见的变化。并且，SLS/SLA复合材 料材料的防火性能较低，不适合用在高温环境下。
发明内容
本发明的目的是针对上述现状，提供一种不影响染色后的力学性能同 时具有较好耐火性能的SLS/SLA复合材料的染色方法。
本发明采用的技术方案：一种SLS/SLA复合材料的染色方法，包括：
S1、采用第一浴整理液对SLS/SLA复合材料进行浸泡处理，所述第一 浴整理液包括至少一种含磷化合物、至少一种含氮化合物、至少一种氧化 剂；
S2、将经过所述第一浴整理液处理后的SLS/SLA复合材料采用第二浴 整理液进行浸泡处理，所述第二浴整理液包括至少一种含磷化合物、至少 一种含氮化合物和至少一种交联剂；
S3、将经过所述第二浴整理液处理后的SLS/SLA复合材料置于频率＞ 200kHz的超声波声场中的含有染色浴液中染色至少1min，染色温度为 55～75℃；
S4、将经过所述染色浴液处理后的SLS/SLA复合材料用2450MHz的 微波辐照至少1min；
S5、将经过微波辐照后的SLS/SLA复合材料采用第三浴整理液进行浸 泡处理，所述第三浴整理液至少包括一种氧化剂、至少一种甲醛捕集剂；
S6、将经过所述第三浴整理液处理后的SLS/SLA复合材料烘干，完成 染色。
进一步，所述步骤S1、S2之后均包括加热烘干和焙烘，其中加热烘干 温度为95～100℃，焙烘温度为160～165℃。
进一步，所述第一浴整理液的pH值范围为3.0～4.0，所述第二浴整理 液的pH值范围为2.0～5.0。
进一步，所述第一浴整理液中，所述含磷化合物选自四羟甲基磷盐、 四羟甲基磷盐与氨的预缩物、四羟甲基磷盐与尿素的初缩体、N-羟甲基-3- (二甲氧基膦酰基)丙酰胺、阻燃剂DM-3070、环状磷酸酯中的一种或几 种；所述含氮化合物选自氨基甲酰肼、尿素、N-羟甲基丙烯酰胺的一种或 几种；所述的氧化剂选自间硝基苯磺酸钠、间硝基对甲苯磺酸钠、过碳酸 钠中的一种或几种。
进一步，所述第二浴整理液中，所述含磷化合物选自四羟甲基磷盐、 四羟甲基磷盐与氨的预缩物、四羟甲基磷盐与尿素的初缩体、N-羟甲基-3- (二甲氧基膦酰基)丙酰胺、阻燃剂DM-3070、环状磷酸酯中的一种或几 种；所述含氮化合物选自氨基甲酰肼、尿素、N-羟甲基丙烯酰胺的一种或 几种；所述交联剂选自醚化2D树脂、三羟甲基三聚氰胺树脂、六羟甲基三 聚氰胺树脂的一种或几种。
进一步，所述步骤S3中，将经过所述第二浴整理液处理后的SLS/SLA 复合材料置于频率200～300kHz的超声波声场，且超声波强度为 1～5W/cm2。
进一步，所述步骤S4中，微波辐射强度为0.1～3W/cm3，微波辐照时 间为1～3min。
进一步，所述步骤S4中，所述染色浴液包括苯酚200份，甲醛148～ 152份，催化剂2～10份，无机纳米材料0.1～0.7份，色素炭黑6～8份， 分散剂0.1份，润滑剂0.1～0.15份，消泡剂0.01份，乳化剂0.1～0.2份， 偶联剂0.2份。
进一步，所述步骤S5中，所述氧化剂选自双氧水、过碳酸钠、过硫酸 钠中的一种或几种；所述甲醛捕集剂选自尿素、乙烯脲、碳酰肼、吡咯、 咪唑、己二酸二酰肼中的一种或几种。
本发明的效果是：具有较好的阻燃效果，并且外观保持较好。
具体实施方式
以下对本发明的原理和特征进行描述，所举实例只用于解释本发明， 并非用于限定本发明的范围。
实施例1
第一浴整理液为：四羟甲基磷盐与尿素的初缩体(THPC-U)308g/L，N- 羟甲基-3-(二甲氧基膦酰基)丙酰胺(PyrovatexCP)62g/L，阻燃剂DM- 3070107g/L，环状磷酸酯33g/L，N-羟甲基丙烯酰胺31g/L，尿素88g/L， 聚硅氧烷乳液30g/L，硝基对甲苯磺酸钠55g/L。
采用第一浴整理液浸泡SLS/SLA复合材料十分钟，浸泡温度为40℃。
然后进行烘干，烘干温度为95℃，再进行焙烘，焙烘温度为160℃。
第二浴整理液为：四羟甲基磷盐与氨的预缩物(THPN)234g/L，阻燃剂 DM-307092g/L、环状磷酸酯(即双环亚磷酸酯与膦酸酯缩合物)45g/L，氨基 甲酰肼20g/L、尿素55g/L，自醚化2D树脂30g/L。
采用第二浴整理液再次浸泡SLS/SLA复合材料十分钟，浸泡温度为 40℃。
然后进行烘干，烘干温度为95℃，再进行焙烘，焙烘温度为160℃。
将经过第二浴整理液处理后的SLS/SLA复合材料置于频率200kHz的 超声波声场中的含有染色浴液中染色1min，超声波强度为1W/cm2，染色 温度为55℃；染色浴液包括苯酚200份，甲醛148份，催化剂2份，无机 纳米材料0.1份，色素炭黑6份，分散剂0.1份，润滑剂0.1份，消泡剂 0.01份，乳化剂0.1份，偶联剂0.2份。
再用2450MHz的微波辐照1min，微波辐射强度为0.1W/cm3。
第三浴整理液：30％过硫酸钠60g/L，咪唑20g/L，乙烯脲30g/L，双 油基咪唑啉季铵盐20g/L。通过浸轧的方式将第三浴整理液整理到经第二浴 整理后的棉/尼龙混纺织物上，而后100℃烘干，150℃焙烘1分钟。完成染 色。
实施例2
第一浴整理液为：四羟甲基磷盐与氨的预缩物(THPN)315g/L，四羟甲 基磷盐(THPC)55g/L，阻燃剂DM-307090g/L，环状磷酸酯20g/L，N-羟甲 基丙烯酰胺25g/L，尿素62g/L，聚硅氧烷乳液30g/L，硝基对甲苯磺酸钠 50g/L。。
采用第一浴整理液浸泡SLS/SLA复合材料十五分钟，浸泡温度为 50℃。
然后进行烘干，烘干温度为100℃，再进行焙烘，焙烘温度为165℃。
第二浴整理液为：四羟甲基磷盐与尿素的初缩体(THPS-U)245g/L，阻 燃剂DM-307085g/L、N-羟甲基-3-(二甲氧基膦酰基)丙酰胺(Pyrovatex CP)30g/L、环状磷酸酯(即双环亚磷酸酯与膦酸酯缩合物)30g/L，氨基甲酰 肼25g/L、尿素40g/L，自醚化2D树脂30g/L。
采用第二浴整理液再次浸泡SLS/SLA复合材料十五分钟，浸泡温度为 50℃。
然后进行烘干，烘干温度为100℃，再进行焙烘，焙烘温度为165℃。
将经过第二浴整理液处理后的SLS/SLA复合材料置于频率300kHz的 超声波声场中的含有染色浴液中染色1min，超声波强度为5W/cm2，染色 温度为55℃；染色浴液包括苯酚200份，甲醛148份，催化剂2份，无机 纳米材料0.1份，色素炭黑6份，分散剂0.1份，润滑剂0.1份，消泡剂 0.01份，乳化剂0.1份，偶联剂0.2份。
随后用2450MHz的微波辐照3min，微波辐射强度为3W/cm3。
第三浴整理液：30％双氧水68g/L，尿素25g/L，乙烯脲35g/L，氧化 聚乙烯蜡乳液30g/L。通过浸轧的方式将第三浴整理液整理到经第二浴整 理后的棉/尼龙混纺织物上，而后100℃烘干，150℃焙烘1分钟。完成染 色。
通过实验得到，实施例1最终处理后的SLS/SLA复合材料，遇火不发 生膨胀，经过酒精灯火焰垂直燃烧20min后产生火苗，且火苗在9s内自熄 灭；经染色后长度改变幅度为0.31％，宽度改变幅度为0.16％，高度改变幅 度为0.24％。
实施例2最终处理后的SLS/SLA复合材料，遇火不发生膨胀，经过酒 精灯火焰垂直燃烧18min后产生火苗，且火苗在6s内自熄灭；经染色后长 度改变幅度为0.35％，宽度改变幅度为0.2％，高度改变幅度为0.30％。
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发 明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在 本发明的保护范围之内。

Claims (9)

1.一种SLS/SLA复合材料的染色方法，其特征在于，包括：
S1、采用第一浴整理液对SLS/SLA复合材料进行浸泡处理，所述第一浴整理液包括至少一种含磷化合物、至少一种含氮化合物、至少一种氧化剂；
S2、将经过所述第一浴整理液处理后的SLS/SLA复合材料采用第二浴整理液进行浸泡处理，所述第二浴整理液包括至少一种含磷化合物、至少一种含氮化合物和至少一种交联剂；
S3、将经过所述第二浴整理液处理后的SLS/SLA复合材料置于频率＞200kHz的超声波声场中的含有染色浴液中染色至少1min，染色温度为55～75℃；
S4、将经过所述染色浴液处理后的SLS/SLA复合材料用2450MHz的微波辐照至少1min；
S5、将经过微波辐照后的SLS/SLA复合材料采用第三浴整理液进行浸泡处理，所述第三浴整理液至少包括一种氧化剂、至少一种甲醛捕集剂；
S6、将经过所述第三浴整理液处理后的SLS/SLA复合材料烘干，完成染色。
2.根据权利要求1所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述步骤S1、S2之后均包括加热烘干和焙烘，其中加热烘干温度为95～100℃，焙烘温度为160～165℃。
3.根据权利要求2所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述第一浴整理液的pH值范围为3.0～4.0，所述第二浴整理液的pH值范围为2.0～5.0。
4.根据权利要求1所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述第一浴整理液中，所述含磷化合物选自四羟甲基磷盐、四羟甲基磷盐与氨的预缩物、四羟甲基磷盐与尿素的初缩体、N-羟甲基-3-(二甲氧基膦酰基)丙酰胺、阻燃剂DM-3070、环状磷酸酯中的一种或几种；所述含氮化合物选自氨基甲酰肼、尿素、N-羟甲基丙烯酰胺的一种或几种；所述的氧化剂选自间硝基苯磺酸钠、间硝基对甲苯磺酸钠、过碳酸钠中的一种或几种。
5.根据权利要求1所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述第二浴整理液中，所述含磷化合物选自四羟甲基磷盐、四羟甲基磷盐与氨的预缩物、四羟甲基磷盐与尿素的初缩体、N-羟甲基-3-(二甲氧基膦酰基)丙酰胺、阻燃剂DM-3070、环状磷酸酯中的一种或几种；所述含氮化合物选自氨基甲酰肼、尿素、N-羟甲基丙烯酰胺的一种或几种；所述交联剂选自醚化2D树脂、三羟甲基三聚氰胺树脂、六羟甲基三聚氰胺树脂的一种或几种。
6.根据权利要求1所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述步骤S3中，将经过所述第二浴整理液处理后的SLS/SLA复合材料置于频率200～300kHz的超声波声场，且超声波强度为1～5W/cm2。
7.根据权利要求1所述的一种SLS/SLA复合材料染色方法，其特征在于，所述步骤S4中，微波辐射强度为0.1～3W/cm3，微波辐照时间为1～3min。
8.根据权利要求7所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述步骤S4中，所述染色浴液包括苯酚200份，甲醛148～152份，催化剂2～10份，无机纳米材料0.1～0.7份，色素炭黑6～8份，分散剂0.1份，润滑剂0.1～0.15份，消泡剂0.01份，乳化剂0.1～0.2份，偶联剂0.2份。
9.根据权利要求1所述的一种SLS/SLA复合材料的染色方法，其特征在于，所述步骤S5中，所述氧化剂选自双氧水、过碳酸钠、过硫酸钠中的一种或几种；所述甲醛捕集剂选自尿素、乙烯脲、碳酰肼、吡咯、咪唑、己二酸二酰肼中的一种或几种。
CN201810425949.4A 2018-05-07 2018-05-07 一种sls/sla复合材料的染色方法 Pending CN108611878A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810425949.4A CN108611878A (zh) 2018-05-07 2018-05-07 一种sls/sla复合材料的染色方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810425949.4A CN108611878A (zh) 2018-05-07 2018-05-07 一种sls/sla复合材料的染色方法

Publications (1)

Publication Number Publication Date
CN108611878A true CN108611878A (zh) 2018-10-02

Family

ID=63662343

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810425949.4A Pending CN108611878A (zh) 2018-05-07 2018-05-07 一种sls/sla复合材料的染色方法

Country Status (1)

Country Link
CN (1) CN108611878A (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613963A (zh) * 2009-07-14 2009-12-30 四川大学 利用超声波和微波辐射的连续化皮革染色方法
CN104611928A (zh) * 2015-01-07 2015-05-13 广东德美精细化工股份有限公司 纯棉或棉混纺织物的阻燃整理方法
CN105153634A (zh) * 2015-10-15 2015-12-16 建瓯市闽欧绝缘材料有限公司 一种酚醛树脂黑色功能母料及其制备方法
CN105200765A (zh) * 2015-09-17 2015-12-30 无锡市长安曙光手套厂 一种纯棉或棉混纺织物及其制备方法
CN105200768A (zh) * 2015-09-01 2015-12-30 广东德美精细化工股份有限公司 棉/尼龙混纺织物耐久防火整理方法及染色方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101613963A (zh) * 2009-07-14 2009-12-30 四川大学 利用超声波和微波辐射的连续化皮革染色方法
CN104611928A (zh) * 2015-01-07 2015-05-13 广东德美精细化工股份有限公司 纯棉或棉混纺织物的阻燃整理方法
CN105200768A (zh) * 2015-09-01 2015-12-30 广东德美精细化工股份有限公司 棉/尼龙混纺织物耐久防火整理方法及染色方法
CN105200765A (zh) * 2015-09-17 2015-12-30 无锡市长安曙光手套厂 一种纯棉或棉混纺织物及其制备方法
CN105153634A (zh) * 2015-10-15 2015-12-16 建瓯市闽欧绝缘材料有限公司 一种酚醛树脂黑色功能母料及其制备方法

Similar Documents

Publication Publication Date Title
CN105200768B (zh) 棉/尼龙混纺织物耐久防火整理方法及染色方法
KR880000926B1 (ko) 직물의 방염가공법
CN108611878A (zh) 一种sls/sla复合材料的染色方法
CN106283661B (zh) 一种棉/尼龙混纺织物的阻燃整理方法
CA1317401C (en) Fusible textile product and method of manufacture
JPH0665861A (ja) セルロース−含有繊維材料のホルムアルデヒドなしでの容易なケア仕上げ
WO2013115402A1 (ja) インク乾燥方法及びインク乾燥装置
CN107858832A (zh) 一种层层自组装阻燃改性纤维织物的方法
GB1048379A (en) Process for treating napped fabrics and products thereof
GB1092793A (en) Phosphorus-containing aminoplasts, process for their preparation and their use
US3958932A (en) Flame-resistant textiles through finishing treatments with vinyl monomer systems
US4292036A (en) Process for imparting flame retardance to textile materials
US3632297A (en) Process for rendering cellulose-containing fabrics durably flame-retardant by wet-curing a melamine resin and a phosphoric acid amide on the fabric
US3936562A (en) Fire retardant fabrics
CN105542099A (zh) 一种纺织用交联树脂的制备方法及其应用
GB754158A (en) An improved process for coating glass fibres with vinyl or allyl silanes
JPH0127187B2 (zh)
CN106378898A (zh) 一种三聚氰胺甲醛树脂微波发泡及后处理装置
JPH0114343B2 (zh)
JPS583065B2 (ja) 難燃性パイル糸およびその製造法
US3425856A (en) Process for producing permanent creases and other desirable properties in textile fabrics
JPH0123587B2 (zh)
JPH041775B2 (zh)
JPS589194B2 (ja) セルロ−ス繊維構造物の難燃処理方法
JPH0470417B2 (zh)

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181002