CN108610735A - A kind of heat dissipation ink and its construction technology - Google Patents
A kind of heat dissipation ink and its construction technology Download PDFInfo
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- CN108610735A CN108610735A CN201810246970.8A CN201810246970A CN108610735A CN 108610735 A CN108610735 A CN 108610735A CN 201810246970 A CN201810246970 A CN 201810246970A CN 108610735 A CN108610735 A CN 108610735A
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- Prior art keywords
- heat dissipation
- ink
- construction technology
- pigment
- resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/28—Printing on other surfaces than ordinary paper on metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/34—Printing on other surfaces than ordinary paper on glass or ceramic surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0058—Digital printing on surfaces other than ordinary paper on metals and oxidised metal surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/007—Digital printing on surfaces other than ordinary paper on glass, ceramic, tiles, concrete, stones, etc.
Abstract
The invention discloses a kind of heat dissipation ink and its construction technology, component matches by mass percentage is:Carbon nanotube 1% 5%, nano-graphene 10% 45%, Nanometer Copper 10% 20%, resin 30% 79%, pigment 8 28%;A kind of construction technology of heat dissipation ink, includes the following steps:Carbon nanotube, nano-graphene, pigment and Nanometer Copper are added first into thermosetting resin or light-cured resin, are diluted after the completion of allotment by the way that diluent is added;Ink is stirred clockwise by dispersion machine or blender;Using supersonic wave cleaning machine to being cleaned by the surface of painting material, to processing is dried by the surface of painting material.The present invention reduces artificial attaching process, everyone prints after radiating ink in 5000PCS by printing, roller the artificial fitting of cooling fin now daily(It scrapes)It applies or spraying calculates daily in 8 12 ten thousand PCS, greatly improve the efficiency, and reduce production cost, solve existing ink and construction technology low production efficiency, lead to the problem that production cost is high.
Description
Technical field
The present invention relates to technical field of ink, specially a kind of heat dissipation ink and its construction technology.
Background technology
Traditional artificial fitting graphite flake, machine cover(It is multiple)It closes, be die cut the modes such as graphite flake, covered with machine in fitting(It is multiple)
It closes, the technique of cross cutting graphite flake, intermediate there are adhesive medias to be combined with by the object that need to be radiated, among these techniques
Have gap or adhesive media, so as to cause lead/heat dissipation performance has a greatly reduced quality, and the wave of waste of manpower resource and graphite sheet material
Expense is all increase at double.
It covers(It is multiple)It carries out direct shape by die-cutting after conjunction graphite flake to be manually bonded on material or after cross cutting, shape by die-cutting
Surrounding must have the rim charge of 1-2mm to waste when graphite flake, be manually bonded every person/day and arrive 5000PCS finished products by 12H calculating 4000,
The larger production capacity of artificial usage amount is relatively low, and cost of labor increases stamping factory or needs the cost of graphite flake enterprise, and country is to people
The demand of power resource is big, and the situation of enterprise's " recruiting everyday " is formed so as to cause human resources deficiency.
In conclusion existing ink and construction technology low production efficiency, cause production cost high, for this purpose, it is proposed that
A kind of gravure printing ink and its construction technology.
Invention content
The purpose of the present invention is to provide a kind of heat dissipation ink and its construction technologies, to solve to propose in above-mentioned background technology
The problem of.
To achieve the above object, the present invention provides the following technical solutions:A kind of heat dissipation ink, component is by mass percentage
Proportioning is:Carbon nanotube 1%-5%, nano-graphene 10%-45%, Nanometer Copper 10%-20%, resin 30%-79%, pigment
8-28%.
Preferably, the pigment includes inorganic pigment and organic pigment, and wherein inorganic pigment includes carbon black, barba hispanica, zinc chrome
Huang, titanium dioxide, lithopone, metallic pigments(Bronze, silver powder)Deng organic pigment includes everbright fast yellow, permanent red, benzidine yellow, phthalein
It is cyanines indigo plant, phthalocyanine green, lithol red, bronze red, fuchsin, peacock blue, sun-proof pink etc..
Preferably, the resin uses thermosetting resin or light-cured resin, also need after the completion of ink formulation addition diluent into
Row dilution.
A kind of construction technology of heat dissipation ink, includes the following steps:
(1)Carbon nanotube, nano-graphene, pigment and Nanometer Copper are added first into thermosetting resin or light-cured resin, have been allocated
It is diluted at rear by the way that diluent is added;
(2)Ink is stirred clockwise by dispersion machine or blender;
(3)Using supersonic wave cleaning machine to by painting material(Metal, plastics, ceramics, construction material etc.)Surface cleaned;
(4)To by painting material(Metal, plastics, ceramics, construction material etc.)Surface processing is dried;
(5)To carrying out silk-screen by screen printer by painting material, or roller coating is carried out by coating roller and doctor knife coater, or passes through flush coater
It is sprayed;
(6)Hot setting is carried out to the material that spraying is completed using high-temperature baking equipment, or uses UV machine light curing apparatus pair
The material that spraying is completed carries out UV photocurings;
(7)Cooling and packing processes are carried out to the finished product after solidification using air blower or fan.
Preferably, the step(3)Using the wiping of the cleaning agents such as electric oil, nitrogen hydrogen, alcohol or cleaning showers when middle cleaning.
Preferably, the step(5)In when passing through silk-screen printing, pass through scraper pressure and adjust management and control thickness(Web plate mesh number
It is required that 120 to 300 mesh), when roller coating, pressure management and control thickness is adjusted by pressure roll, when spraying, it is thick to pass through atmospheric pressure adjustment
Degree.
Preferably, the step(6)In when passing through hot setting, 80 degree to 300 degree of temperature requirement, baking time requires 30
Second, when by UV photocurings, UV energy requirements 800um to 1800um, light application time required 3 to 5 seconds to 300 seconds.
Compared with prior art, the beneficial effects of the invention are as follows:Synthesis heat dissipation ink/painting in terms of the cost of raw material of the present invention
After material, than original graphite flake or other heat dissipation cost reductions 30% or more;Do not have to manually be bonded again after being molded finished product,
Avoid the waste of cost of labor;The efficiency of molding factory is improved, original technique is(It is filled by suitable):The laminating cross cutting cooling fins of a, b moulds
It is cut into type, c is manually bonded(Equipment is bonded), d full inspections, it is existing to be:A ink painting/coating is full-automatic by the allotment of this technical solution, b
Printing, roller(It scrapes)Painting or spraying heat radiation coating, c assembly line lights consolidate or thermosetting, the automatic finished product full inspection rewindings of d, reduce artificial patch
Conjunction technique, everyone prints after radiating ink in 5000PCS by printing, roller the artificial fitting of cooling fin now daily(It scrapes)It applies or sprays
It applies and calculates daily in ten thousand PCS of 8-12, greatly improve the efficiency, and reduce production cost, solve existing ink and construction
Production efficiency is low, leads to the problem that production cost is high.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention provides a kind of technical solution:
A kind of heat dissipation ink, component matches by mass percentage is:Carbon nanotube 1%-5%, nano-graphene 10%-
45%, Nanometer Copper 10%-20%, resin 30%-79%, pigment 8-28%.
A kind of construction technology of heat dissipation ink, includes the following steps:
(1)Carbon nanotube, nano-graphene, pigment and Nanometer Copper are added first into thermosetting resin or light-cured resin, have been allocated
It is diluted at rear by the way that diluent is added;
(2)Ink is stirred clockwise by dispersion machine or blender;
(3)Using supersonic wave cleaning machine to by painting material(Metal, plastics, ceramics, construction material etc.)Surface cleaned;
(4)To by painting material(Metal, plastics, ceramics, construction material etc.)Surface processing is dried;
(5)To carrying out silk-screen by screen printer by painting material, or roller coating is carried out by coating roller and doctor knife coater, or passes through flush coater
It is sprayed;
(6)Hot setting is carried out to the material that spraying is completed using high-temperature baking equipment, or uses UV machine light curing apparatus pair
The material that spraying is completed carries out UV photocurings;
(7)Cooling and packing processes are carried out to the finished product after solidification using air blower or fan.
Embodiment one:
A kind of heat dissipation ink, component matches by mass percentage is:Carbon nanotube 1%-5%, nano-graphene 10%-
45%, Nanometer Copper 10%-20%, resin 30%-79%, pigment 8-28%.
Construction method:Carbon nanotube, nano-graphene, pigment and nanometer are added first into thermosetting resin or light-cured resin
Copper is diluted after the completion of allotment by the way that diluent is added;Then ink is stirred clockwise by dispersion machine or blender
It mixes;Then use supersonic wave cleaning machine to by painting material(Metal, plastics, ceramics, construction material etc.)Surface cleaned;So
Afterwards to by painting material(Metal, plastics, ceramics, construction material etc.)Surface processing is dried;Then to being passed through by painting material
Screen printer carries out silk-screen, or carries out roller coating by coating roller and doctor knife coater, or is sprayed by flush coater;Then high temperature is used
Roasting plant to spraying complete material carry out hot setting, or using UV machine light curing apparatus to spraying complete material into
Row UV photocurings;Finally air blower or fan is used to carry out cooling and packing processes to the finished product after solidification.
Embodiment two:
A kind of heat dissipation ink, component matches by mass percentage is:Carbon nanotube 1%-5%, nano-graphene 10%-
45%, Nanometer Copper 10%-20%, resin 30%-79%, pigment 8-28%.
Construction method:Carbon nanotube, nano-graphene, pigment and nanometer are added first into thermosetting resin or light-cured resin
Copper is diluted after the completion of allotment by the way that diluent is added;Then ink is stirred clockwise by dispersion machine or blender
It mixes;Then use supersonic wave cleaning machine to by painting material(Metal, plastics, ceramics, construction material etc.)Surface cleaned, clearly
Using the wiping of the cleaning agents such as electric oil, nitrogen hydrogen, alcohol or cleaning showers when washing;Then to by painting material(Metal, ceramics, is built plastics
Build material etc.)Surface processing is dried;Then to carrying out silk-screen by screen printer by painting material, or by coating roller and scraping
Painting machine carries out roller coating, or is sprayed by flush coater, and when passing through silk-screen printing, management and control thickness is adjusted by scraper pressure(Net
Plate mesh number requires 120 to 300 mesh), when roller coating, pressure management and control thickness is adjusted by pressure roll, when spraying, passes through atmospheric pressure tune
Whole thickness;Then it uses high-temperature baking equipment to carry out hot setting to the material that spraying is completed, or is set using the solidification of UV machine light
The standby material completed to spraying carries out UV photocurings;Finally air blower or fan is used to cool down and wrap the finished product after solidification
Dress processing.
Embodiment three:
A kind of heat dissipation ink, component matches by mass percentage is:Carbon nanotube 1%-10%, nano-graphene 10%-
60%, resin 30%-89%, pigment 8-28%.
Construction method:Carbon nanotube, nano-graphene, pigment and nanometer are added first into thermosetting resin or light-cured resin
Copper is diluted after the completion of allotment by the way that diluent is added;Then ink is stirred clockwise by dispersion machine or blender
It mixes;Then use supersonic wave cleaning machine to by painting material(Metal, plastics, ceramics, construction material etc.)Surface cleaned, clearly
Using the wiping of the cleaning agents such as electric oil, nitrogen hydrogen, alcohol or cleaning showers when washing;Then to by painting material(Metal, ceramics, is built plastics
Build material etc.)Surface processing is dried;Then to carrying out silk-screen by screen printer by painting material, or by coating roller and scraping
Painting machine carries out roller coating, or is sprayed by flush coater, and when passing through silk-screen printing, management and control thickness is adjusted by scraper pressure(Net
Plate mesh number requires 120 to 300 mesh), when roller coating, pressure management and control thickness is adjusted by pressure roll, when spraying, passes through atmospheric pressure tune
Whole thickness;Then it uses high-temperature baking equipment to carry out hot setting to the material that spraying is completed, or is set using the solidification of UV machine light
The standby material completed to spraying carries out UV photocurings, and when passing through hot setting, 80 degree to 300 degree of temperature requirement, baking time is wanted
It asks 30 seconds to 300 seconds, when by UV photocurings, UV energy requirements 800um to 1800um, light application time requires 3 to 5 seconds;Finally
Cooling and packing processes are carried out to the finished product after solidification using air blower or fan.
In the present invention, carbon nanotube has good heat transfer property, has very big draw ratio, thus it is along length
The heat exchange performance in direction is very high, and the heat exchange performance of its opposite vertical direction is relatively low, by being suitably orientated, carbon nanotube
The heat conducting material of high anisotropy can be synthesized, in addition, carbon nanotube has higher thermal conductivity, as long as in the composite
Micro carbon nanotube is adulterated, the thermal conductivity of material will be likely to be obtained prodigious improvement.
The lattice structure that graphene is stablized makes carbon atom that there is outstanding electric conductivity, the electronics in graphene to be moved in track
When dynamic, it will not be scattered due to lattice defect or introducing foreign atom, since interatomic force is very strong, at normal temperatures,
Even if surrounding carbon atom telescopes very small if the interference that electronics in graphene is subject to, the structure of graphene is highly stable, interior
Connection between the carbon atom in portion is very flexible, when applying external force in graphene, carbon atom face meeting flexural deformation so that carbon atom
It need not be rearranged to adapt to external force, to which holding structure is stablized, the lattice structure of this stabilization makes graphene with outstanding
Thermal conductivity.
The heat dissipation performance of copper is inherently just outstanding, so the heat dissipation performance of copper is one of the three big standards for weighing quality,
Thermal resistance value and thermal expansion value are quite to be higher than other machine objects;
Resin impact resistance, chemicals-resistant, good fluidity and heat-resisting material are main to rise for fixing graphene and carbon nanotube
Link effect plays molding and conjugation after hardening.
In terms of the cost of raw material of the present invention after synthesis heat dissipation ink/coating, dropped than original graphite flake or other heat dissipation costs
Low 30% or more;Do not have to manually be bonded again after being molded finished product, avoids the waste of cost of labor;Improve molding factory
Efficiency, original technique are(It is filled by suitable):The laminating cross cutting cooling fins of a, b shape by die-cutting, c are manually bonded(Equipment is bonded), d full inspections,
It is existing to be:A ink painting/coating is allocated by this technical solution, b automatically prints, roller(It scrapes)Apply or spray heat radiation coating, c flowing water
Linear light is solid or thermosetting, the automatic finished product full inspection rewindings of d, reduces artificial attaching process, cooling fin manually fitting daily everyone
5000PCS presses printing, roller after printing heat dissipation ink now(It scrapes)It applies or spraying calculates daily in ten thousand PCS of 8-12, substantially increase
Efficiency, and production cost is reduced, it solves existing ink and construction technology low production efficiency, causes production cost is high to ask
Topic.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (7)
1. a kind of heat dissipation ink, it is characterised in that:Its component matches by mass percentage:Carbon nanotube 1%-5%, nanometer stone
Black alkene 10%-45%, Nanometer Copper 10%-20%, resin 30%-79%, pigment 8-28%.
2. a kind of heat dissipation ink according to claim 1, it is characterised in that:The pigment includes inorganic pigment and organic face
Material, wherein inorganic pigment includes carbon black, barba hispanica, zinc yellow, titanium dioxide, lithopone, metallic pigments(Bronze, silver powder)Deng organic
Pigment includes everbright fast yellow, permanent red, benzidine yellow, phthalocyanine blue, phthalocyanine green, lithol red, bronze red, fuchsin, peacock blue, sun-proof
It is pink etc..
3. a kind of heat dissipation ink according to claim 1, it is characterised in that:The resin uses thermosetting resin or light Gu Shu
Fat, ink formulation also need addition diluent to be diluted after the completion.
4. a kind of construction technology of heat dissipation ink, it is characterised in that:Include the following steps:
(1)Carbon nanotube, nano-graphene, pigment and Nanometer Copper are added first into thermosetting resin or light-cured resin, have been allocated
It is diluted at rear by the way that diluent is added;
(2)Ink is stirred clockwise by dispersion machine or blender;
(3)Using supersonic wave cleaning machine to by painting material(Metal, plastics, ceramics, construction material etc.)Surface cleaned;
(4)To by painting material(Metal, plastics, ceramics, construction material etc.)Surface processing is dried;
(5)To carrying out silk-screen by screen printer by painting material, or roller coating is carried out by coating roller and doctor knife coater, or passes through flush coater
It is sprayed;
(6)Hot setting is carried out to the material that spraying is completed using high-temperature baking equipment, or uses UV machine light curing apparatus pair
The material that spraying is completed carries out UV photocurings;
(7)Cooling and packing processes are carried out to the finished product after solidification using air blower or fan.
5. a kind of construction technology of heat dissipation ink according to claim 4, it is characterised in that:The step(3)Middle cleaning
Cleaning agents wiping or the cleaning showers such as Shi Caiyong electricity oil, nitrogen hydrogen, alcohol.
6. a kind of construction technology of heat dissipation ink according to claim 4, it is characterised in that:The step(5)In pass through
When silk-screen printing, management and control thickness is adjusted by scraper pressure(Web plate mesh number requires 120 to 300 mesh), when roller coating, pass through pressure roll
Pressure management and control thickness is adjusted, when spraying, thickness is adjusted by atmospheric pressure.
7. a kind of construction technology of heat dissipation ink according to claim 4, it is characterised in that:The step(6)In pass through
When hot setting, 80 degree to 300 degree of temperature requirement, baking time requires 30 seconds to 300 seconds, when by UV photocurings, UV energy
It is required that 800um to 1800um, light application time requires 3 to 5 seconds.
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Cited By (5)
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CN109839692A (en) * | 2019-01-28 | 2019-06-04 | 凤阳硅谷智能有限公司 | A kind of heat dissipation glass light guide plate and preparation method thereof |
CN113604105A (en) * | 2021-07-20 | 2021-11-05 | 佛山安亿纳米材料有限公司 | High-heat-dissipation ink and preparation method thereof |
CN114161653A (en) * | 2021-11-18 | 2022-03-11 | 锦翰印刷(深圳)有限公司 | Printing injection molding process based on UV laminating adhesive |
CN115851031A (en) * | 2022-12-23 | 2023-03-28 | 深圳稀导技术有限公司 | Heat-dissipation printing ink |
CN116457426A (en) * | 2020-10-13 | 2023-07-18 | 峡谷先进材料股份有限公司 | Curable carbon nanotube ink and transparent conductive film produced using the same |
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CN116457426A (en) * | 2020-10-13 | 2023-07-18 | 峡谷先进材料股份有限公司 | Curable carbon nanotube ink and transparent conductive film produced using the same |
CN113604105A (en) * | 2021-07-20 | 2021-11-05 | 佛山安亿纳米材料有限公司 | High-heat-dissipation ink and preparation method thereof |
CN114161653A (en) * | 2021-11-18 | 2022-03-11 | 锦翰印刷(深圳)有限公司 | Printing injection molding process based on UV laminating adhesive |
CN114161653B (en) * | 2021-11-18 | 2024-04-02 | 锦翰印刷(深圳)有限公司 | Printing injection molding process based on UV laminating adhesive |
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