CN108610567A - A kind of Polystyrene resin and its application process in wallpaper - Google Patents
A kind of Polystyrene resin and its application process in wallpaper Download PDFInfo
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- CN108610567A CN108610567A CN201611188212.2A CN201611188212A CN108610567A CN 108610567 A CN108610567 A CN 108610567A CN 201611188212 A CN201611188212 A CN 201611188212A CN 108610567 A CN108610567 A CN 108610567A
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- polystyrene
- polystyrene resin
- titanium dioxide
- tea powder
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- 229920005990 polystyrene resin Polymers 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 14
- 230000008569 process Effects 0.000 title claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 31
- 241001122767 Theaceae Species 0.000 claims abstract description 30
- 239000004793 Polystyrene Substances 0.000 claims abstract description 22
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920002223 polystyrene Polymers 0.000 claims abstract description 22
- -1 polyethylene Polymers 0.000 claims abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004698 Polyethylene Substances 0.000 claims abstract description 17
- 229920000573 polyethylene Polymers 0.000 claims abstract description 17
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 15
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 14
- 239000005011 phenolic resin Substances 0.000 claims abstract description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 239000011265 semifinished product Substances 0.000 claims description 12
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000007822 coupling agent Substances 0.000 claims 1
- 238000010304 firing Methods 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
- 239000003063 flame retardant Substances 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- 230000006872 improvement Effects 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 125000001340 2-chloroethyl group Chemical class [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229920001890 Novodur Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Architecture (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of technical field of polymer materials, a kind of Polystyrene resin is provided, the defect that solves existing polystyrene resin easy firing, can not degrade, while a kind of application process of the Polystyrene resin in wallpaper being provided, include each raw material of following parts by weight：100 parts of polystyrene, 20~30 parts of tea powder, 10~15 parts of nano-titanium dioxide, 5~8 parts of silane coupling agent, 30~40 parts of absolute ethyl alcohol, 30~40 parts of dichloroethanes, 80~100 parts of phenolic resin, 10~15 parts of polyethylene wax；The preparation method of the tea powder is：Tealeaves to be discarded was steeped in collection, dries, pulverizes, and crossed 50~100 mesh sieve to get to tea powder.
Description
Technical field
The present invention relates to a kind of technical field of polymer materials more particularly to a kind of Polystyrene resin and its in wall
Application process in paper.
Background technology
Polystyrene resin is due to excellent processing performance and mechanical property, in printer, duplicator, computer etc.
Office equipment shell field or field of household appliances are widely used.However due to it is not degradable there are easy firing,
Application in wallpaper wallpaper field is few.In order to improve its inflammable performance, fire retardant is added in generally use and auxiliary agent realizes resistance
Fuel efficiency fruit, fire-retardant assistance agent in actual use belong to inorganic combustion inhibitor field, and dosage is restricted, if usage amount is excessive
It can influence the shock resistance of styrene.Existing fire retardant includes halogen flame, organic phosphorus flame retardant and inorganic combustion inhibitor,
Wherein halogen flame occupies most of field, especially bromide fire retardant with its excellent cost performance and is hindered since it is efficient
Fuel efficiency rate is widely used in retardant styrenic resin.Although the extensive use of halogen flame, halogen flame contain it is toxic,
The products such as pernicious gas have been paid attention to the harm of human body and environment by various countries.European Union is comprehensive in 1 day July in 2006
It is forbidden to use halogen flame, therefore how to select fire retardant to be improved polystyrene resin and has become art technology
Personnel and researcher's problem encountered.
Furthermore polystyrene itself has plasticity, not degradable.
Invention content
Therefore, for the above content, the present invention provides a kind of Polystyrene resin, solves existing polystyrene tree
Fat easy firing, the defect that can not be degraded, while a kind of application process of the Polystyrene resin in wallpaper being provided.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions：A kind of Polystyrene resin, packet
Include each raw material of following parts by weight：It is 100 parts of polystyrene, 20~30 parts of tea powder, 10~15 parts of nano-titanium dioxide, silane coupled
5~8 parts of agent, 30~40 parts of absolute ethyl alcohol, 30~40 parts of dichloroethanes, 80~100 parts of phenolic resin, polyethylene wax 10~15
Part；The preparation method of the tea powder is：Tealeaves to be discarded was steeped in collection, dries, pulverizes, and crossed 50~100 mesh sieve to get to tea
Powder.
A further improvement is that：Each raw material including following parts by weight：100 parts of polystyrene, tea powder 25~30 part, nanometer
13~15 parts of titanium dioxide, 6~8 parts of silane coupling agent, 35~40 parts of absolute ethyl alcohol, 35~40 parts of dichloroethanes, phenolic resin
90~100 parts, 13~15 parts of polyethylene wax.
A further improvement is that：Each raw material including following parts by weight；100 parts of polystyrene, 29 parts of tea powder, nano-silica
Change 11 parts of titanium, 5 parts of silane coupling agent, 35 parts of absolute ethyl alcohol, 31 parts of dichloroethanes, 89 parts of phenolic resin, 15 parts of polyethylene wax.
A further improvement is that：The preparation method of the Polystyrene resin is, first by absolute ethyl alcohol and nanometer two
Titanium oxide mixing, stirring, silane coupling agent is added after ultrasonic wave disperses, and is continued after disperseing 30~60min using ultrasonic wave, 60
DEG C water bath with thermostatic control handles 1~1.5h, then dries, obtains modified nano-titanium dioxide, then will smash it through 50~100 mesh sieve
Polystyrene mix with modified nano-titanium dioxide, melt, extrusion obtains semi-finished product；Then semi-finished product are dissolved in two
In chloroethanes, tea powder, phenolic resin, polyethylene wax are added after dissolving, 1~1.5h is disperseed using ultrasonic wave.
A kind of application process of Polystyrene resin in wallpaper, including using above-mentioned Polystyrene resin as
Raw material are applied in wallpaper.
A further improvement is that：Using non-woven fabrics or non-woven paper as bottom, the Polystyrene resin is coated in
On bottom.
By using preceding solution, the beneficial effects of the invention are as follows：The Polystyrene resin of the present invention, including
Each raw material of following parts by weight：100 parts of polystyrene, 20~30 parts of tea powder, 10~15 parts of nano-titanium dioxide, silane coupling agent
5~8 parts, 30~40 parts of absolute ethyl alcohol, 30~40 parts of dichloroethanes, 80~100 parts of phenolic resin, 10~15 parts of polyethylene wax；
Tea powder be collected from the daily tealeaves drunk of people dry, pulverize, being sieved obtains, and fully recycles waste, pass through
Nano-titanium dioxide is modified, and then polystyrene is modified, the preparation process of modified nano-titanium dioxide is：
Absolute ethyl alcohol is mixed with nano-titanium dioxide first, is stirred, silane coupling agent is added after ultrasonic wave disperses, is continued using ultrasound
After wavelength-division dissipates 30~60min, 60 DEG C of waters bath with thermostatic control handle 1~1.5h, are then dried to get to modified nanometer titanium dioxide
Titanium；Polystyrene mixes with modified nano-titanium dioxide after pulverizing and sieving, melts, squeeze out after, obtained semi-finished product
It can be changed, there is readily degradable energy, then semi-finished product are dissolved in dichloroethanes, tea powder, phenolic aldehyde tree are added after dissolving
Fat, polyethylene wax disperse 1~1.5h using ultrasonic wave, are further processed by above-mentioned, obtained Polystyrene resin tool
There is nonflammable characteristic.The Polystyrene resin of the present invention has nonflammable, degradable excellent by modified
Point, applies it in wallpaper, and obtained wallpaper has nonflammable, degradable performance.
Specific implementation mode
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and the realization process for reaching technique effect can fully understand and implement.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person indicates on the first appearance.
Embodiment one
A kind of Polystyrene resin includes each raw material of following parts by weight：100 parts of polystyrene, is received 20 parts of tea powder
10 parts of titanium dioxide of rice, 5 parts of silane coupling agent, 30 parts of absolute ethyl alcohol, 30 parts of dichloroethanes, 80 parts of phenolic resin, polyethylene wax
10 parts；The preparation method of the tea powder is：Tealeaves to be discarded was steeped in collection, dries, pulverizes, and crossed 500 mesh sieve to get to tea
Powder.
The preparation method of the Polystyrene resin is first to mix absolute ethyl alcohol with nano-titanium dioxide, stir,
Silane coupling agent is added after ultrasonic wave disperses, continues using after ultrasonic wave dispersion 30min, 60 DEG C of waters bath with thermostatic control handle 1h, connect
Drying, modified nano-titanium dioxide is obtained, then the nanometer titanium dioxide that the polystyrene of 50 mesh sieve will be smashed it through and be modified
Titanium mixes, and melts, and squeezes out, obtains semi-finished product；Then semi-finished product are dissolved in dichloroethanes, tea powder, phenolic aldehyde is added after dissolving
Resin, polyethylene wax disperse 1h using ultrasonic wave.
A kind of application process of Polystyrene resin in wallpaper includes making above-mentioned Polystyrene resin
It is applied in wallpaper for raw material, specifically using non-woven fabrics as bottom, the Polystyrene resin is coated in bottom
On.
Embodiment two
A kind of Polystyrene resin includes each raw material of following parts by weight；100 parts of polystyrene, is received 29 parts of tea powder
11 parts of titanium dioxide of rice, 5 parts of silane coupling agent, 35 parts of absolute ethyl alcohol, 31 parts of dichloroethanes, 89 parts of phenolic resin, polyethylene wax
15 parts；The preparation method of the tea powder is：Tealeaves to be discarded was steeped in collection, dries, pulverizes, and crossed 50 mesh sieve to get to tea powder.
The preparation method of the Polystyrene resin is first to mix absolute ethyl alcohol with nano-titanium dioxide, stir,
Silane coupling agent is added after ultrasonic wave disperses, continues using after ultrasonic wave dispersion 40min, 60 DEG C of waters bath with thermostatic control handle 1.2h,
Then it dries, obtains modified nano-titanium dioxide, then the nano-silica that the polystyrene of 80 mesh sieve will be smashed it through and be modified
Change titanium mixing, melt, squeezes out, obtain semi-finished product；Then semi-finished product are dissolved in dichloroethanes, tea powder, phenol is added after dissolving
Urea formaldehyde, polyethylene wax disperse 1.2h using ultrasonic wave.
A kind of application process of Polystyrene resin in wallpaper includes making above-mentioned Polystyrene resin
It is applied in wallpaper for raw material, specifically using non-woven fabrics as bottom, the Polystyrene resin is coated in bottom
On.
Embodiment three
A kind of Polystyrene resin includes each raw material of following parts by weight：100 parts of polystyrene, is received 30 parts of tea powder
15 parts of titanium dioxide of rice, 8 parts of silane coupling agent, 40 parts of absolute ethyl alcohol, 40 parts of dichloroethanes, 100 parts of phenolic resin, polyethylene wax
15 parts；The preparation method of the tea powder is：Tealeaves to be discarded was steeped in collection, dries, pulverizes, and sieved with 100 mesh sieve to get to tea
Powder.
The preparation method of the Polystyrene resin is first to mix absolute ethyl alcohol with nano-titanium dioxide, stir,
Silane coupling agent is added after ultrasonic wave disperses, continues using after ultrasonic wave dispersion 60min, 60 DEG C of waters bath with thermostatic control handle 1.5h,
Then it dries, obtains modified nano-titanium dioxide, then the nano-silica that the polystyrene of 100 mesh sieve will be smashed it through and be modified
Change titanium mixing, melt, squeezes out, obtain semi-finished product；Then semi-finished product are dissolved in dichloroethanes, tea powder, phenol is added after dissolving
Urea formaldehyde, polyethylene wax disperse 1.5h using ultrasonic wave.
A kind of application process of Polystyrene resin in wallpaper includes making above-mentioned Polystyrene resin
It is applied in wallpaper for raw material, specifically using non-woven fabrics as bottom, the Polystyrene resin is coated in bottom
On.
Wherein, in the present invention, each raw material component of the Polystyrene resin can be real in following parameter area
The existing purpose of the present invention：100 parts of polystyrene, 20~30 parts of tea powder, 10~15 parts of nano-titanium dioxide, silane coupling agent 5~8
Part, 30~40 parts of absolute ethyl alcohol, 30~40 parts of dichloroethanes, 80~100 parts of phenolic resin, 10~15 parts of polyethylene wax.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and is not limited to those disclosed embodiments.
Claims (6)
1. a kind of Polystyrene resin, which is characterized in that each raw material including following parts by weight：100 parts of polystyrene, tea
20~30 parts of powder, 10~15 parts of nano-titanium dioxide, 5~8 parts of silane coupling agent, 30~40 parts of absolute ethyl alcohol, dichloroethanes 30
~40 parts, 80~100 parts of phenolic resin, 10~15 parts of polyethylene wax；The preparation method of the tea powder is：Collection was steeped to be discarded
Tealeaves, dry, pulverize, cross 50~100 mesh sieve to get to tea powder.
2. a kind of Polystyrene resin according to claim 1, it is characterised in that：Each original including following parts by weight
Material：100 parts of polystyrene, 25~30 parts of tea powder, 13~15 parts of nano-titanium dioxide, 6~8 parts of silane coupling agent, absolute ethyl alcohol
35~40 parts, 35~40 parts of dichloroethanes, 90~100 parts of phenolic resin, 13~15 parts of polyethylene wax.
3. a kind of Polystyrene resin according to claim 1, it is characterised in that：Each original including following parts by weight
Material；100 parts of polystyrene, 29 parts of tea powder, 11 parts of nano-titanium dioxide, 5 parts of silane coupling agent, 35 parts of absolute ethyl alcohol, two chloroethenes
31 parts of alkane, 89 parts of phenolic resin, 15 parts of polyethylene wax.
4. a kind of Polystyrene resin according to claim 1 or 2 or 3, it is characterised in that：The polystyrene changes
The preparation method of property resin is first to mix absolute ethyl alcohol with nano-titanium dioxide, stir, and silane is added after ultrasonic wave disperses
Coupling agent continues after disperseing 30~60min using ultrasonic wave, and 60 DEG C of waters bath with thermostatic control handle 1~1.5h, then dry, are changed
Property nano-titanium dioxide, then the polystyrene of 50~100 mesh sieve will be smashed it through and modified nano-titanium dioxide mixes, it is molten
Melt, squeezes out, obtain semi-finished product；Then semi-finished product are dissolved in dichloroethanes, tea powder, phenolic resin, poly- second is added after dissolving
Alkene wax disperses 1~1.5h using ultrasonic wave.
5. a kind of application process of Polystyrene resin in wallpaper, it is characterised in that：Including will be described in claim 4
Polystyrene resin is applied to as raw material in wallpaper.
6. a kind of application process of the Polystyrene resin according to claim 5 in wallpaper, it is characterised in that：With
The Polystyrene resin is coated on bottom by non-woven fabrics or non-woven paper as bottom.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611188212.2A CN108610567A (en) | 2016-12-20 | 2016-12-20 | A kind of Polystyrene resin and its application process in wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611188212.2A CN108610567A (en) | 2016-12-20 | 2016-12-20 | A kind of Polystyrene resin and its application process in wallpaper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108610567A true CN108610567A (en) | 2018-10-02 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611188212.2A Pending CN108610567A (en) | 2016-12-20 | 2016-12-20 | A kind of Polystyrene resin and its application process in wallpaper |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101377069A (en) * | 2008-10-07 | 2009-03-04 | 河南红旗渠建设集团有限公司 | Conditioning deodorization antibiotic mildew-proof wallpaper |
| CN102153820A (en) * | 2011-03-22 | 2011-08-17 | 天津工业大学 | Preparation method of flame retarding styrene polymer composite material |
| CN103483669A (en) * | 2013-10-10 | 2014-01-01 | 苏州市湘园特种精细化工有限公司 | Antibiotic nanometer flame-retardant plastic and preparation method thereof |
| CN105199258A (en) * | 2015-08-17 | 2015-12-30 | 林炳灿 | Non-woven cloth wallpaper |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101377069A (en) * | 2008-10-07 | 2009-03-04 | 河南红旗渠建设集团有限公司 | Conditioning deodorization antibiotic mildew-proof wallpaper |
| CN102153820A (en) * | 2011-03-22 | 2011-08-17 | 天津工业大学 | Preparation method of flame retarding styrene polymer composite material |
| CN103483669A (en) * | 2013-10-10 | 2014-01-01 | 苏州市湘园特种精细化工有限公司 | Antibiotic nanometer flame-retardant plastic and preparation method thereof |
| CN105199258A (en) * | 2015-08-17 | 2015-12-30 | 林炳灿 | Non-woven cloth wallpaper |
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