CN108610003A - The manufacture craft of sky blue Nixing pottery - Google Patents

The manufacture craft of sky blue Nixing pottery Download PDF

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Publication number
CN108610003A
CN108610003A CN201810523765.1A CN201810523765A CN108610003A CN 108610003 A CN108610003 A CN 108610003A CN 201810523765 A CN201810523765 A CN 201810523765A CN 108610003 A CN108610003 A CN 108610003A
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green body
temperature
sky blue
per hour
raised
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CN108610003B (en
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孙继旋
李第钊
张科研
胡铠镇
鲁敏
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Guangxi Xinyi Technology Co.,Ltd.
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Qinzhou University
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/14Colouring matters
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/22Grog products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/442Carbonates

Abstract

The invention discloses the manufacture crafts of sky blue Nixing pottery, include the following steps:1) blank will be prepared;2) sky blue colorant is made in the raw material of following parts by weight:5~10 parts of neodymia, 0.5~1 part of calcium bicarbonate, 1~3 part of the emerging clinker of mud;3) blank forming;4) body drying;5) green body is decorated with sky blue colorant;6) green body decorated is sent into kiln and will be fired, temperature is first raised to 80~120 DEG C with 20~30 DEG C of the speed of heating up per hour, keeps the temperature 20~28 hours;Temperature is raised to 550~700 DEG C with 60~80 DEG C of the speed of heating up per hour again;Then temperature is raised to 1160~1200 DEG C with 40~60 DEG C of the speed of heating up per hour, keeps the temperature 1~2h, stop heating, it is cooling after kiln discharge to get to sky blue Nixing pottery.The present invention decorates Nixing pottery with sky blue colorant, has pure color uniform, fires non-discolouring advantage.

Description

The manufacture craft of sky blue Nixing pottery
Technical field
The invention belongs to the production methods of Nixing pottery, and in particular to a kind of manufacture craft of sky blue Nixing pottery.
Background technology
The preparation process of traditional Qiezhou Nixing pottery includes mainly following steps:1) blank is prepared:Blank is by clay material Material is made, and it is raw material to select the distinctive eastern mud in Qiezhou and western mud.The east mud is the Jiang Yidong that admires for crossing Qiezhou urban district The soil in domain, is mostly stored in low lying areas, and the soil compact substance is soft, is mild-clay, and color is yellow-white, contains micro quartz Sand.Western mud is then the soil for crossing region to the west of the river of admiring in Qiezhou urban district, and based on hillside, which is compact block on storage ground Shape is a kind of higher purple mudstone of iron-holder, face containing a small amount of K2O, Na2O, CaO, MgO, Fe2O3, TiO2, SiO2, MnO2 Color is aubergine, and superficial layer has a small amount of irony to disseminate, and is hard paste, plasticity and the more eastern mud of associativity are poor.To the east of mud 40~ 60%, the weight percent mixing of western mud 60~40%, blank method is prepared through Nixing pottery that is existing, generally using:Such as may be used Blank is made in modeling method and slip casting method;2) it is molded:The green body of various types is made of blank;3) repaired biscuit:Green body is modified, with Reach design requirement;4) body drying:Green body is dried, green body moisture is made to be discharged;For example, by using indoor seasoning method, air-dry Method, suning method or other existing, feasible drying means;5) green body is decorated:Nixing pottery neither adds any in the production process Pigment, not glazing, also not on green body with any coloured material drawing colour and pattern, only relying on the transmutation occurred once in a while makes mud Unpredictable and control color is presented in emerging pottery, and decorates green body using artistic carving.The artistic carving is i.e. with sharp Steel knife carves out word and pattern on green body, generally uses flat carving technique and embossing technology.Flat carving is the mud wet in half top dry-up It is carried out on base, piercing, sculpture, the skill and technique such as inlays at wired quarter.Embossment is carried out in absolutely dry green body, there is high relief, bas-relief etc. Skill and technique.For can more distinct prominent decorative pattern, can also fill out white clay on the pattern carved, it is fired after white clay show slightly light Yellow and the same warm tones of pottery color, it is remote to see the benefits of pottery is painted in gold, the overall style of Nixing pottery device can be promoted.6) it fires: The green body loading of kiln decorated is fired;In order to reach higher firing rate and improve transmutation rate, the maximum temperature control that green body is fired For system at 1100~1200 DEG C, the firing time is 10 hours, and fired rear kiln discharge is Nixing pottery device.Nixing pottery green body be to the east of mud It being made with two kinds of china clay materials of western mud, non-refractory, firing temperature is more than 1200 DEG C, and billet surface will appear crackle or breakage, It is serious or even occur blank deformation and caving in.Neodymia belongs to high temperature decorating colour, could stablize at a high temperature of 1300 DEG C or more Color development, if when with this decorative ornament Nixing pottery green body, there is neodymia and the inconsistent problem of Nixing pottery green body firing temperature.
Invention content
The technical problem to be solved in the present invention is to provide a kind of manufacture craft of sky blue Nixing pottery, this method can solve Nixing pottery and the inconsistent problem of sky blue colorant firing temperature, the sky blue Nixing pottery pure color of firing are uniform.
Technical solution provided by the invention is the manufacture craft of sky blue Nixing pottery, it is characterised in that:Include the following steps:
1) 4~6 parts by weight of eastern mud, 4~6 parts by weight of western mud are mixed and made into blank;
2) sky blue colorant is made in the raw material of following parts by weight:5~10 parts of neodymia, 0.5~1 part of calcium bicarbonate, mud are emerging 1~3 part of clinker;
3) blank is made to the green body of various types;
4) by body drying;
5) green body is decorated with sky blue colorant;
6) green body decorated is sent into kiln and will be fired, first with 20~30 DEG C of the speed of heating up per hour by temperature 80~120 DEG C are raised to, keeps the temperature 20~28 hours;Temperature is raised to 550~700 with 60~80 DEG C of the speed of heating up per hour again ℃;Then temperature is raised to 1160~1200 DEG C with 40~60 DEG C of the speed of heating up per hour, keeps the temperature 1~2h, stops heating, it is cold But kiln discharge is to get to sky blue Nixing pottery after.
The parts by weight group of sky blue colorant becomes:7 parts of neodymia, 0.8 part of calcium bicarbonate, 1.5 parts of the emerging clinker of mud.
The preparation method of the Nixing pottery clinker is as follows:
1) pug is prepared:It is most laggard by the eastern mud of select and western mud through weathering, according to the ratio goal, press filtration, vacuum pugging Row is aging to obtain pug;
2) green body is made:Green body is made in pug;
3) body drying:It is 3~8% that green body, which is put into interior and is dried to green body humidity,;
4) green body is fired:Dry green body is put into kiln, heating rate is to increase 60~80 DEG C per hour, is raised to 180~220 DEG C, and at such a temperature, persistently fire 2~4 hours;Then heating rate is to heat up 80~100 DEG C per hour, directly To being raised to 500~600 DEG C, and at such a temperature, persistently fire 2~3 hours;After natural cooling, the green body being fired into is taken out, Complete the firing of green body;
5) Nixing pottery clinker is obtained after being ground the green body after cooking.
In the step 3) of clinker preparation process, the humidity of green body is 5% after drying.
In the step 4) of clinker preparation process, dry green body is put into kiln, heating rate is to heat up per hour 70 DEG C, 200 DEG C are raised to, and at such a temperature, persistently fired 3 hours;Then heating rate is to heat up 90 DEG C per hour, until rising To 550 DEG C, and at such a temperature, persistently fire 2.5 hours.
The present invention decorates Nixing pottery with sky blue colorant, has pure color uniform, fires non-discolouring advantage.
Specific implementation mode
The present invention is further elaborated for following specific examples, but not as a limitation of the invention.
Embodiment 1
1) pug is prepared:By the eastern mud of select and western mud through weathering, by weight 6:4 proportioning goal, press filtration, vacuum are practiced Mud finally carries out aging obtaining pug;
2) green body is made:Green body is made in pug;
3) body drying:It is 3% that green body, which is put into interior and is dried to green body humidity,;
4) green body is fired:Dry green body is put into kiln, heating rate is to increase 60 DEG C per hour, is raised to 180 DEG C, and at such a temperature, persistently fire 2 hours;Then heating rate is 80 DEG C of heating per hour, until 500 DEG C are raised to, and At this temperature, it persistently fires 2 hours;After natural cooling, the green body being fired into is taken out, the firing of green body is completed;
5) Nixing pottery clinker is obtained after being ground the green body after cooking;
6) eastern mud 4kg, western mud 6kg are mixed and made into blank;
7) sky blue colorant is made in the raw material of following parts by weight:The emerging clinker 1kg of neodymia 5kg, calcium bicarbonate 0.5kg, mud;
8) blank of step 6) is made to the green body of various types;
9) by body drying;
10) green body is decorated with sky blue colorant;
11) green body decorated is sent into kiln and will be fired, first with 20 DEG C of the speed of heating up per hour by temperature liter To 80 DEG C, 20 hours are kept the temperature;Temperature is raised to 550 DEG C with 60 DEG C of the speed of heating up per hour again;Then to heat up 40 per hour DEG C speed temperature is raised to 1160 DEG C, keep the temperature 1h, stop heating, it is cooling after kiln discharge to get to sky blue Nixing pottery.Blank is sent out It is colour-stable, pure color.
Embodiment 2
1) pug is prepared:By the eastern mud of select and western mud through weathering, by weight 6:4 proportioning goal, press filtration, vacuum are practiced Mud finally carries out aging obtaining pug;
2) green body is made:Green body is made in pug;
3) body drying:It is 8% that green body, which is put into interior and is dried to green body humidity,;
4) green body is fired:Dry green body is put into kiln, heating rate is to increase 80 DEG C per hour, is raised to 220 DEG C, and at such a temperature, persistently fire 4 hours;Then heating rate is 100 DEG C of heating per hour, until 600 DEG C are raised to, and At such a temperature, it persistently fires 3 hours;After natural cooling, the green body being fired into is taken out, the firing of green body is completed;
5) Nixing pottery clinker is obtained after being ground the green body after cooking;
6) eastern mud 6kg, western mud 6kg are mixed and made into blank;
7) sky blue colorant is made in the raw material of following parts by weight:The emerging clinker 3kg of neodymia 10kg, calcium bicarbonate 1kg, mud;
8) blank of step 6) is made to the green body of various types;
9) by body drying;
10) green body is decorated with sky blue colorant;
11) green body decorated is sent into kiln and will be fired, first with 30 DEG C of the speed of heating up per hour by temperature liter To 120 DEG C, 28 hours are kept the temperature;Temperature is raised to 700 DEG C with 80 DEG C of the speed of heating up per hour again;Then to heat up 60 per hour DEG C speed temperature is raised to 1200 DEG C, keep the temperature 2h, stop heating, it is cooling after kiln discharge to get to sky blue Nixing pottery.Blank is sent out It is colour-stable, pure color.
Embodiment 3
1) pug is prepared:By the eastern mud of select and western mud through weathering, by weight 6:4 proportioning goal, press filtration, vacuum are practiced Mud finally carries out aging obtaining pug;
2) green body is made:Green body is made in pug;
3) body drying:It is 5% that green body, which is put into interior and is dried to green body humidity,;
4) green body is fired:Dry green body is put into kiln, heating rate is to heat up 70 DEG C per hour, is raised to 200 DEG C, and at such a temperature, persistently fire 3 hours;Then heating rate is 90 DEG C of heating per hour, until 550 DEG C are raised to, and At this temperature, it persistently fires 2.5 hours;After natural cooling, the green body being fired into is taken out, the firing of green body is completed;
5) Nixing pottery clinker is obtained after being ground the green body after cooking;
6) eastern mud 6kg, western mud 4kg are mixed and made into blank;
7) sky blue colorant is made in the raw material of following parts by weight:Neodymia 7kg, calcium bicarbonate 0.8kg, the emerging clinker of mud 1.5kg;
8) blank of step 6) is made to the green body of various types;
9) by body drying;
10) green body is decorated with sky blue colorant;
11) green body decorated is sent into kiln and will be fired, first with 25 DEG C of the speed of heating up per hour by temperature liter To 100 DEG C, 24 hours are kept the temperature;Temperature is raised to 650 DEG C with 70 DEG C of the speed of heating up per hour again;Then to heat up 50 per hour DEG C speed temperature is raised to 1180 DEG C, keep the temperature 1.5h, stop heating, it is cooling after kiln discharge to get to sky blue Nixing pottery.Blank Color development is stablized, pure color.
Embodiment 4
1) pug is prepared:By the eastern mud of select and western mud through weathering, by weight 6:4 proportioning goals, press filtration, vacuum are practiced Mud finally carries out aging obtaining pug;
2) green body is made:Green body is made in pug;
3) body drying:It is 3% that green body, which is put into interior and is dried to green body humidity,;
4) green body is fired:Dry green body is put into kiln, heating rate is to increase 80 DEG C per hour, is raised to 180 DEG C, and at such a temperature, persistently fire 4 hours;Then heating rate is 80 DEG C of heating per hour, until 600 DEG C are raised to, and At this temperature, it persistently fires 2 hours;After natural cooling, the green body being fired into is taken out, the firing of green body is completed;
5) Nixing pottery clinker is obtained after being ground the green body after cooking;
6) eastern mud 6kg, western mud 4kg are mixed and made into blank;
7) sky blue colorant is made in the raw material of following parts by weight:Neodymia 10kg, calcium bicarbonate 0.5kg, the emerging clinker of mud 3kg;
8) blank of step 6) is made to the green body of various types;
9) by body drying;
10) green body is decorated with sky blue colorant;
11) green body decorated is sent into kiln and will be fired, first with 20 DEG C of the speed of heating up per hour by temperature liter To 120 DEG C, 20 hours are kept the temperature;Temperature is raised to 550 DEG C with 80 DEG C of the speed of heating up per hour again;Then to heat up 60 per hour DEG C speed temperature is raised to 1160 DEG C, keep the temperature 2h, stop heating, it is cooling after kiln discharge to get to sky blue Nixing pottery.Blank is sent out It is colour-stable, pure color.

Claims (5)

1. the manufacture craft of sky blue Nixing pottery, it is characterised in that:Include the following steps:
1) 4~6 parts by weight of eastern mud, 4~6 parts by weight of western mud are mixed and made into blank;
2) sky blue colorant is made in the raw material of following parts by weight:The emerging clinker of 5~10 parts of neodymia, 0.5~1 part of calcium bicarbonate, mud 1 ~3 parts;
3) blank is made to the green body of various types;
4) by body drying;
5) green body is decorated with sky blue colorant;
6) green body decorated is sent into kiln and will be fired, be first raised to temperature with 20~30 DEG C of the speed of heating up per hour 80~120 DEG C, keep the temperature 20~28 hours;Temperature is raised to 550~700 DEG C with 60~80 DEG C of the speed of heating up per hour again;It connects It and temperature is raised to 1160~1200 DEG C with 40~60 DEG C of the speed of heating up per hour, keep the temperature 1~2h, stop heating, after cooling Kiln discharge is to get to sky blue Nixing pottery.
2. the manufacture craft of sky blue Nixing pottery according to claim 1, it is characterised in that:The parts by weight group of sky blue colorant Become:7 parts of neodymia, 0.8 part of calcium bicarbonate, 1.5 parts of the emerging clinker of mud.
3. the manufacture craft of sky blue Nixing pottery according to claim 1 or 2, it is characterised in that:The Nixing pottery clinker Preparation method it is as follows:
1) pug is prepared:By the eastern mud of select and western mud through weathering, according to the ratio goal, press filtration, vacuum pugging, finally carry out old Corruption obtains pug;
2) green body is made:Green body is made in pug;
3) body drying:It is 3~8% that green body, which is put into interior and is dried to green body humidity,;
4) green body is fired:Dry green body is put into kiln, heating rate is to increase 60~80 DEG C per hour, is raised to 180 ~220 DEG C, and at such a temperature, persistently fire 2~4 hours;Then heating rate is to heat up 80~100 DEG C per hour, up to 500~600 DEG C are raised to, and at such a temperature, persistently fired 2~3 hours;After natural cooling, the green body being fired into is taken out, it is complete At the firing of green body;
5) Nixing pottery clinker is obtained after being ground the green body after cooking.
4. the manufacture craft of sky blue Nixing pottery according to claim 3, it is characterised in that:In step 3), base after drying The humidity of body is 5%.
5. the manufacture craft of sky blue Nixing pottery according to claim 3, it is characterised in that:In step 4), dry Green body is put into kiln, and heating rate is to heat up 70 DEG C per hour, is raised to 200 DEG C, and at such a temperature, and it is small persistently to fire 3 When;Then heating rate is to heat up 90 DEG C per hour, until being raised to 550 DEG C, and at such a temperature, is persistently fired 2.5 hours.
CN201810523765.1A 2018-05-28 2018-05-28 Manufacturing process of sky blue nixing pottery Active CN108610003B (en)

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CN111454042A (en) * 2020-04-10 2020-07-28 瑞丽市点土文化创意设计有限公司 Dai pottery handicraft clay formula and manufacturing process thereof
CN112830764A (en) * 2021-01-22 2021-05-25 广西钦州市钦州湾坭兴陶艺有限责任公司 Manufacturing process of needle tube nixing decoration characteristic nixing pottery

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JP2010275515A (en) * 2009-05-27 2010-12-09 Myongji Univ Industry & Academia Cooperation Foundation Method for manufacturing green color pigment for reduction firing using copper oxide and green color pottery manufactured by the same
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CN104926286A (en) * 2015-05-25 2015-09-23 钦州华安陶艺有限公司 Firing method for Nixing pottery wall hanging
CN104944925A (en) * 2015-06-15 2015-09-30 钦州学院 Preparation process of underglaze red nixing pottery
CN106187317A (en) * 2016-07-05 2016-12-07 佛山欧神诺陶瓷股份有限公司 A kind of high-temperature red rare-earth ceramic colorant and preparation method thereof

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CN101508598A (en) * 2009-03-13 2009-08-19 白皓 Rare earth neodymium red flambe glaze pigment and method of producing the same
JP2010275515A (en) * 2009-05-27 2010-12-09 Myongji Univ Industry & Academia Cooperation Foundation Method for manufacturing green color pigment for reduction firing using copper oxide and green color pottery manufactured by the same
CN102515863A (en) * 2011-12-14 2012-06-27 广东长城集团有限公司 Nd-doped discolour glaze and its preparation method
CN104150870A (en) * 2014-07-31 2014-11-19 钦州市登峰陶艺有限公司 Clay of nixing pottery
CN104671781A (en) * 2015-01-22 2015-06-03 东莞劲胜精密组件股份有限公司 Preparation method of sky-blue zirconia ceramic
CN104926286A (en) * 2015-05-25 2015-09-23 钦州华安陶艺有限公司 Firing method for Nixing pottery wall hanging
CN104944925A (en) * 2015-06-15 2015-09-30 钦州学院 Preparation process of underglaze red nixing pottery
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111454042A (en) * 2020-04-10 2020-07-28 瑞丽市点土文化创意设计有限公司 Dai pottery handicraft clay formula and manufacturing process thereof
CN112830764A (en) * 2021-01-22 2021-05-25 广西钦州市钦州湾坭兴陶艺有限责任公司 Manufacturing process of needle tube nixing decoration characteristic nixing pottery
CN112830764B (en) * 2021-01-22 2022-09-23 广西钦州市钦州湾坭兴陶艺有限责任公司 Manufacturing process of needle tube nixing decoration characteristic nixing pottery

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