CN108609860A - A kind of new shape environmental protection low-reflection glass and its processing technology - Google Patents
A kind of new shape environmental protection low-reflection glass and its processing technology Download PDFInfo
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- CN108609860A CN108609860A CN201810398927.3A CN201810398927A CN108609860A CN 108609860 A CN108609860 A CN 108609860A CN 201810398927 A CN201810398927 A CN 201810398927A CN 108609860 A CN108609860 A CN 108609860A
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- glass
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
- C03C2217/732—Anti-reflective coatings with specific characteristics made of a single layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/77—Coatings having a rough surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/13—Deposition methods from melts
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of new shape low-reflection glass and its processing technology, the glass body surface is equipped with one layer of aqueous, environmental protective ground glass powder ink mixed layer, and processing technology is：1) white glass particle or stained glass particle are chosen and wears into 200~600 mesh powders, be then placed in crystalline ceramics glaze, diluent stirs evenly that be mixed to form mixture A spare；2) first low temperature is used to preheat mixture A, on preheated mixture A setting plate glass one sides surface, thickness is 50 μm -200 μm；3) and then heat plate glass, the mixture A on surface of plate glass is directly molten to be sticked to on surface of plate glass under high temperature action, forms low-reflection glass.Realize the opaque polychrome mat glass effect of clear beautiful light transmission, aesthetic effect is changeable persistently, and light-weight, impact resistance solves processing technology problem of environmental pollution, while processing technology is simple, is more advantageous to industrialized production.
Description
Technical field
The present invention relates to a kind of glass working arts field, one kind of especially a kind of alternative strong acid etching process is low anti-
Penetrate the preparation of glass.
Background technology
In building decoration engineering, in daily life application, much need not full through occasion will use frosting glass
Glass (i.e. low-reflection glass), such as wall, furred ceiling, dining table, screen, mirror drawing, entry, partition, ground, railing, shower house, glass
Tea table ....Mat glass is organically combined together indoor with external landscape by artistic decoration, its crystalistic sense makes
People place oneself in the midst of indoor and are seemingly communicated with the external world, and the opaque effect of light transmission has effectively expanded spatial depth and height.Greatly
Spatial decoration class is improved greatly, and in the manufacture craft of mat glass, wherein it is opaque to corrode the light transmission to be formed using strong acid
Frosting technique is a kind of technique being most widely used.
Frosting handles specific practice：Ordinary plate glass is processed into through strong acid corrosion/machinery/sandblasting/hand lapping
Even hair side, then obscured glass is placed in strong acid frosting slot, by acid-proof pump, glass frosting liquid is sufficiently stirred (by fluoride.Sulphur
Acid and hydrochloric acid form by a certain percentage), frosting liquor at this moment is drenched to glass uniformly continuous, (should be properly added when weather is colder dense
Sulfuric acid), several minutes of rear frostings can be completed, but this traditional method is handled glass by strong acid liquid, waste liquid,
Exhaust gas injures greatly environment, operating personnel, and present environmental requirement has not allowed with this technique productions.
In addition, the present inventor is applying for a kind of low-reflection glass and its processing technology (number of patent application before
2017113601700) it is, to replace metal ion welding on glass body surface by heating using high temperature waterborne glass ink layer
On, the ground glass that can form low reflection can be completed after processing, but during actual processing, metal ion and glass surface sodium
The time is long when ion exchange, and some metal ions are difficult to exchange, that is, is difficult to oxidation and reaches exchange effect, such as chromium, need
Give-and-take conditions temperature is high, and the time is long, directly affects the coloration and fine definition of color sometimes.For clearly colored frosting glass
Glass, it more difficult to which, in realization, technique is more complex.
Invention content
In view of the problems of the existing technology the present invention, provides a kind of by the way that one layer of aqueous, environmental protective ground glass powder oil is arranged
Black mixed layer is on glass body surface, after the completion of processing technology, realizes the opaque mat glass effect of clear beautiful light transmission,
Aesthetic effect is changeable persistently, and light-weight, impact resistance solves processing technology problem of environmental pollution, while processing technology is simple, more
Be conducive to industrialized production.
To solve the above-mentioned problems, the technical solution adopted in the present invention is：
A kind of new shape environmental protection low-reflection glass, including glass body, it is characterised in that：The glass body surface is equipped with one
Layer aqueous, environmental protective ground glass powder ink mixed layer.
The aqueous, environmental protective ground glass powder ink mixed layer is by heating welding on glass body surface.
The aqueous, environmental protective ground glass ink film thickness is 50 μm -200 μm.
A kind of processing technology such as above-mentioned new shape environmental protection low-reflection glass includes the following steps：
1) it chooses white glass particle or stained glass particle is spare, white glass particle or stained glass particle are worn into 200
~600 mesh powders are then placed in crystalline ceramics glaze, diluent stirs evenly that be mixed to form mixture A spare；
2), first low temperature is used to preheat mixture A, one flat plate glass body is then selected, on surface of plate glass
Required figure web plate is got ready according to necessary requirement, and on preheated mixture A setting plate glass one sides surface, thickness is
50μm—200μm；
3) and then heat plate glass, the mixture A on surface of plate glass is directly molten under high temperature action
It is sticked to on surface of plate glass, forms one layer of aqueous, environmental protective ground glass powder ink mixed layer (2) on surface of plate glass, i.e.,
Form low-reflection glass.
Three kinds of objects of powder, crystalline ceramics glaze, diluent of white glass particle or stained glass particle described in step 1
Material presses 2：1：2 weight ratio uniformly mixes.
High temperature waterborne glass ink is arranged using printing, silk-screen, spray, painting or leaching mode in flat glass table in walking poly- 2
Face, preheating temperature are 50 DEG C~100 DEG C (preheating reaches good mixing, and color is made to obtain efficient balance).
At 500~600 DEG C, warm-up time is 8~12 minutes for warm temperature control in step 3.
The glass body surface one side, two-sided, list is double simultaneously, single side is local, two-sided partially over aqueous, environmental protective frosted
Powdered glass printing ink mixed layer is by heating welding in glass body.
The beneficial effects of the invention are as follows：1, by under the mixture high temperature action of glass powder and crystalline ceramics glaze, firmly
Ground glassivation surface, generates low reflection, and the reflectivity of light is reduced to 1% hereinafter, Clear ＆ Transparent good visual effect by 8%,
Since using glass powder and crystalline ceramics glaze, multiple colors low-reflection glass, while technique processing technology can be produced into
It is simpler, environmentally friendly, prevent original strong acid pollution treatment process, the processing technology time is long, and processing technology requires simpler
It is single.
2, the low-reflection glass structure after processing still is former piece, can carry out secondary operation, tempering, hot bending again.
3, the low-reflection glass intensity after processing increases, and product can bear the processing of further requirement, can high temperature, bendable
Song, can in particular be used for wall, furred ceiling, dining table, mirror drawing, screen, entry, partition, ground, railing, shower house, glass tea table,
Solves the limitation that simple glass causes fitting-up to use.
The present invention has a wide range of application, is simple for process, is environmentally friendly, is safe, resistance to decoration, and aesthetic effect is changeable persistently, suitable for it is indoor,
Outdoor decoration, and manufacture craft is simpler, it is of low cost, it is easier to realize industrialized production, solve mat glass and cause to add
The limitation that work processing, fitting-up use.
Description of the drawings：
Fig. 1 is the glass structure schematic diagram of the present invention.
It is identified as in figure：1 glass body, 2 aqueous, environmental protective ground glass powder ink mixed layers.
Specific implementation mode
The present invention is described in further details below by embodiment, these embodiments are only used for illustrating the present invention, and
It does not limit the scope of the invention.
A kind of new shape environmental protection low-reflection glass, including glass body 1, it is characterised in that：1 surface of the glass body is equipped with
One layer of aqueous, environmental protective ground glass powder ink mixed layer 2.
The aqueous, environmental protective ground glass powder ink mixed layer 2 is the institute by heating welding on 1 surface of glass body
The aqueous, environmental protective ground glass ink film thickness stated is 50 μm -200 μm.
A kind of processing technology such as above-mentioned new shape environmental protection low-reflection glass includes the following steps：
1) it chooses white glass particle or stained glass particle is spare, white glass particle or stained glass particle are worn into 200
~600 mesh powders are then placed in crystalline ceramics glaze, diluent stirs evenly that be mixed to form mixture A spare；
Crystalline ceramics glaze is existing product, mainly with quartz, potassium, albite, talcum, dolomite, silica and three
Crystalline ceramics glaze based on Al 2 O
Diluent is existing product, mainly the diluent based on acetone, butanone, cyclopentanone, methylisobutylketone.
2), first low temperature is used to preheat mixture A, one flat plate glass body is then selected, on surface of plate glass
Required figure web plate is got ready according to necessary requirement, and on preheated mixture A setting plate glass one sides surface, thickness is
50μm—200μm；
3) and then heat plate glass, the mixture A on surface of plate glass is directly molten under high temperature action
It is sticked to on surface of plate glass, forms one layer of aqueous, environmental protective ground glass powder ink mixed layer 2, i.e. shape on surface of plate glass
At low-reflection glass.
Three kinds of objects of powder, crystalline ceramics glaze, diluent of white glass particle or stained glass particle described in step 1
Material presses 2：1：2 weight ratio uniformly mixes.
High temperature waterborne glass ink is arranged using printing, silk-screen, spray, painting or leaching mode in flat glass table in walking poly- 2
Face.
At 500~600 DEG C, warm-up time is 8~12 minutes for warm temperature control in step 3.
The glass body surface one side, two-sided, list is double simultaneously, single side is local, two-sided partially over aqueous, environmental protective frosted
Powdered glass printing ink mixed layer 2 is by heating welding in glass body 1.
Embodiment 1
1, it chooses stained glass particle and wears into 600 mesh powders, when attrition process, be crushed, ball milling, float and wash, drying,
Powder is beaten, compounding process eventually forms particulate powders, is then placed in crystalline ceramics glaze, diluent is stirred evenly and is mixed to form
Mixture A is spare, and three kinds of materials of powder, crystalline ceramics glaze, diluent of stained glass particle press 2：1：2 weight ratio is mixed
It closes, then preheats 100 DEG C of spare formation mixture B；
2, one flat plate glass is chosen, required figure web plate is got ready in surface of plate glass, with 400 mesh silk printing screens in tablet
Glass one side prints B100 μm of last layer mixture, is then heated at high temperature, 600 degree, 12 minutes continuous times, glass powder
With under the mixture high temperature action of crystalline ceramics glaze, a kind of silk-screen of reflectivity 0.9 is made in firmly glassivation surface
Low reflection coloured glass.
Embodiment 2
1, it chooses stained glass particle and wears into 400 mesh powders, be then placed in crystalline ceramics glaze, diluent stirring mixes
It closes, three kinds of materials of powder, crystalline ceramics glaze, diluent of stained glass particle press 2：1：2 weight ratio uniformly mixes, and is formed
Mixture A is spare, then preheats 80 DEG C of spare formation mixture B；
2, one flat plate glass is chosen, required figure web plate is got ready in surface of plate glass, with roller printing machine in plate glass
60 μm of surface roll last layer mixture B, is then heated at high temperature, 550 degree, 10 minutes continuous times temperature, glass powder with
Under the mixture high temperature action of crystalline ceramics glaze, firmly glassivation surface, the roll marks that a kind of reflectivity 0.6 is made is low anti-
Penetrate glass.
Embodiment 3
1, it chooses stained glass particle and wears into 200 mesh powders, be then placed in crystalline ceramics glaze, diluent stirring mixes
It closes, three kinds of materials of powder, crystalline ceramics glaze, diluent of stained glass particle press 2：1：2 weight ratio uniformly mixes, and is formed
Mixture A is spare, then preheats 90 DEG C of spare formation mixture B；
2, one flat plate glass is chosen, required figure web plate is got ready in surface of plate glass, with spray gun in flat glass table
B50 μm of last layer glass mixture is sprayed in face, is then heated at high temperature, 500 degree of temperature, 8 minutes continuous times, glass powder and
Under the mixture high temperature action of crystalline ceramics glaze, a kind of low reflection glass of reflectivity 0.3 is made in firmly glassivation surface
Glass.
Claims (8)
1. a kind of new shape environmental protection low-reflection glass, including glass body (1), it is characterised in that：Glass body (1) surface is set
There is one layer of aqueous, environmental protective ground glass powder ink mixed layer (2).
2. a kind of new shape environmental protection low-reflection glass according to claim 1, it is characterised in that：The aqueous, environmental protective frosted
Powdered glass printing ink mixed layer (2) is by heating welding on glass body (1) surface.
3. a kind of new shape environmental protection low-reflection glass according to claim 1, it is characterised in that：The aqueous, environmental protective frosted
Glass ink layer thickness is 50 μm -200 μm.
4. a kind of processing technology of new shape environmental protection low-reflection glass as described in claim 1 includes the following steps：
1) it chooses white glass particle or stained glass particle is spare, white glass particle or stained glass particle are worn into 200~600
Mesh powder is then placed in crystalline ceramics glaze, diluent is uniformly mixed that form mixture A spare；
2), first low temperature is used to preheat mixture A, then selects one flat plate glass body, the basis on surface of plate glass
Necessary requirement gets required figure web plate ready, and on preheated mixture A setting plate glass one sides surface, thickness is 50 μ
m—200μm；
3) and then heat plate glass, the mixture A on surface of plate glass is directly molten to be sticked under high temperature action
With on surface of plate glass, one layer of aqueous, environmental protective ground glass powder ink mixed layer (2) is formed on surface of plate glass, that is, is formed
Low-reflection glass.
5. requiring a kind of processing technology of new shape environmental protection low-reflection glass described in 4 according to power, it is characterised in that：Institute in step 1
Three kinds of materials of powder, crystalline ceramics glaze, diluent of the white glass particle or stained glass particle stated are by 2：1：2 weight ratio
Uniformly mixing.
6. requiring a kind of processing technology of new shape environmental protection low-reflection glass described in 4 according to power, it is characterised in that：Handle in walking poly- 2
High temperature waterborne glass ink is arranged using printing, silk-screen, spray, painting or leaching mode in surface of plate glass.
7. requiring a kind of processing technology of low-reflection glass described in 4 according to power, it is characterised in that：Warm temperature control in step 3
For system at 500~600 DEG C, warm-up time is 8~12 minutes.
8. requiring a kind of processing technology of low-reflection glass described in 1 according to power, it is characterised in that：The glass body surface one
Face, it is two-sided, single double simultaneously, single side part, it is two-sided partially over aqueous, environmental protective ground glass powder ink mixed layer (2) by heating
Welding is in glass body (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810398927.3A CN108609860A (en) | 2018-04-28 | 2018-04-28 | A kind of new shape environmental protection low-reflection glass and its processing technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810398927.3A CN108609860A (en) | 2018-04-28 | 2018-04-28 | A kind of new shape environmental protection low-reflection glass and its processing technology |
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| Publication Number | Publication Date |
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| CN108609860A true CN108609860A (en) | 2018-10-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810398927.3A Pending CN108609860A (en) | 2018-04-28 | 2018-04-28 | A kind of new shape environmental protection low-reflection glass and its processing technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110304835A (en) * | 2018-12-25 | 2019-10-08 | 深圳丽朴显像量子高科技有限公司 | A kind of glass display screen and its preparation process |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60226431A (en) * | 1984-04-25 | 1985-11-11 | Matsushita Electric Works Ltd | Manufacture of frost-tone glass article |
| CN1654391A (en) * | 2004-01-20 | 2005-08-17 | 肖特股份有限公司 | Plane glass ceramic object having at least one dull polishing region and its preparing method |
| CN1872926A (en) * | 2006-05-24 | 2006-12-06 | 朱爱群 | Technique for producing dull polished coating material in environmental protection |
| CN102676053A (en) * | 2012-05-31 | 2012-09-19 | 慈溪市国兴电子有限公司 | Transmitting coating for turning transparent glass into ground glass |
| CN103601370A (en) * | 2013-11-06 | 2014-02-26 | 河北省沙河玻璃技术研究院 | Environment-friendly acid-pollution-free scrub powder, preparation method of scrub powder and preparation method of dull polish glass |
| CN107042712A (en) * | 2017-06-02 | 2017-08-15 | 信利光电股份有限公司 | A kind of processing method of the ground glass of fade effect |
-
2018
- 2018-04-28 CN CN201810398927.3A patent/CN108609860A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60226431A (en) * | 1984-04-25 | 1985-11-11 | Matsushita Electric Works Ltd | Manufacture of frost-tone glass article |
| CN1654391A (en) * | 2004-01-20 | 2005-08-17 | 肖特股份有限公司 | Plane glass ceramic object having at least one dull polishing region and its preparing method |
| CN1872926A (en) * | 2006-05-24 | 2006-12-06 | 朱爱群 | Technique for producing dull polished coating material in environmental protection |
| CN102676053A (en) * | 2012-05-31 | 2012-09-19 | 慈溪市国兴电子有限公司 | Transmitting coating for turning transparent glass into ground glass |
| CN103601370A (en) * | 2013-11-06 | 2014-02-26 | 河北省沙河玻璃技术研究院 | Environment-friendly acid-pollution-free scrub powder, preparation method of scrub powder and preparation method of dull polish glass |
| CN107042712A (en) * | 2017-06-02 | 2017-08-15 | 信利光电股份有限公司 | A kind of processing method of the ground glass of fade effect |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110304835A (en) * | 2018-12-25 | 2019-10-08 | 深圳丽朴显像量子高科技有限公司 | A kind of glass display screen and its preparation process |
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Application publication date: 20181002 |
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