CN108589014A - A kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric - Google Patents
A kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric Download PDFInfo
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- CN108589014A CN108589014A CN201810229754.2A CN201810229754A CN108589014A CN 108589014 A CN108589014 A CN 108589014A CN 201810229754 A CN201810229754 A CN 201810229754A CN 108589014 A CN108589014 A CN 108589014A
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- graphene
- eyelet fabric
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- yarn
- containing antibacterial
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- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 72
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000004744 fabric Substances 0.000 title claims abstract description 40
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 30
- 239000004952 Polyamide Substances 0.000 claims abstract description 27
- 229920002647 polyamide Polymers 0.000 claims abstract description 27
- 229920002334 Spandex Polymers 0.000 claims abstract description 23
- 239000004759 spandex Substances 0.000 claims abstract description 23
- 229920004933 Terylene® Polymers 0.000 claims abstract description 22
- 238000009941 weaving Methods 0.000 claims abstract description 17
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims abstract description 16
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 229920000742 Cotton Polymers 0.000 claims abstract description 12
- 229920000728 polyester Polymers 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- 239000004677 Nylon Substances 0.000 claims description 11
- 229920001778 nylon Polymers 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 9
- 239000010931 gold Substances 0.000 claims description 9
- 229910052737 gold Inorganic materials 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 229920004934 Dacron® Polymers 0.000 claims description 8
- 230000001413 cellular effect Effects 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 239000008131 herbal destillate Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims 1
- 238000009954 braiding Methods 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 7
- 238000011084 recovery Methods 0.000 abstract description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005457 optimization Methods 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 210000003423 ankle Anatomy 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/10—Open-work fabrics
- D04B21/12—Open-work fabrics characterised by thread material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
- D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
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- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Woven Fabrics (AREA)
- Knitting Of Fabric (AREA)
Abstract
The invention discloses a kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric, the vamp eyelet fabric is formed by following yarn weaving：Using ultra-high molecular weight polyethylene/terylene, one or more of the short fiber yarns such as mixed yarn graphene polyamide, cotton, polyester-cotton blend, terylene or terylene, graphene polyamide filaments, Lycra fiber；Vamp eyelet fabric after weaving obtains finished product by appropriate decatize and setting.Preparation process of the present invention is simple, can mass produce, vamp eyelet fabric product have the characteristics that antibacterial and deodouring, elastic force, it is wear-resisting it is resistance to cut, quality is fine and close, soft, preferably size recovery and gas permeability, have a good application prospect.
Description
Technical field
The present invention relates to the production methods of antibacterial shoe face eyelet fabric, and in particular to a kind of graphene-containing antibacterial shoe face eyelet fabric
Preparation method.
Background technology
China is world's footwear production and big export country, occupies the half of world's shoes industry total output.Domestic external survey
It has been shown that, the consumption of sport footwear have been over the 40% of footwear total amount.Eyelet fabric is applied to shoes more and more widely
It is more universal especially on sport footwear in material manufacture.The quality of sport footwear footwear material directly influences the function of shoes, therefore for
The quality requirement fastness of footwear material, durability and good washing property, gas permeability, antibacterial deodourizing, it is desired in thickness and hardness
Deng to provide good comfort.
Eyelet fabric is primarily used to upper of a shoe, flap, at ankle, also insole.As required, two surfaces of fabric can be with
It is designed to the structure of closely knit either one side closely knit face mesh.It is mainly woven on the market using 100% terylene or nylon
In order to obtain better elasticity, antibacterial and deodouring performance, elasticity, antimicrobial yarn can be added.Sport footwear made of so that has more
Good snugness of fit, to improve the function of shoes.Make up the deficiency of traditional full fabric performance.The high added value of product will be rapid
As the new sales growth point of enterprise.
Invention content
Goal of the invention：In order to solve the deficiencies in the prior art, the present invention provides a kind of graphene-containing antibacterial shoe veil eyes
The preparation method of cloth, product have that good elastic force, quality be fine and close, soft, preferably size recovery and gas permeability, pole
The earth improves antibacterial, the deodorization that footwear uses, and extends the service life of product, and improve product uses valence
Value, meets consumption demand, to improve added value of product, the market competitiveness is extremely strong, is that existing product preferably substitutes production
Product.
Technical solution：The preparation method of a kind of graphene-containing antibacterial shoe face eyelet fabric, using ultra-high molecular weight polyethylene/wash
The short fiber yarns such as synthetic fibre mixed yarn, graphene polyamide, cotton, polyester-cotton blend, terylene or terylene, graphene polyamide filaments, Lycra are fine
One or more of dimension is weaved, and the vamp eyelet fabric after weaving obtains finished product by the decatize and setting of appropriateness, obtains
Finished product is the cellular fabric of several mesh composition, and product specification is：Vertical close 30-40 rows/5cm, grammes per square metre 80-100g/m2。
As an optimization：Warp thread is poly- for 90/10,70/30,65/35,50/50,30S/2-50 S/2 super high molecular weights of blending ratio
Ethylene/blend polyester yarn or 50-75D100% polyester DTYs, one kind in 100% nylon of 70D-120D/2.
As an optimization：Weft yarn is 30S/2-50 S/2 graphene polyamide filaments, graphene in graphene Fypro
Content is 0.5-1% or 30S/2-50 S/2 graphenes polyamide/Lycra mixed yarn, graphene in graphene Fypro
Content is 0.5-1%, Lycra blending ratio 5-8%.
As an optimization：Bundled yarn is 50-180D100% polyester DTYs, 70D-120D/2100% nylon DTY.
As an optimization：Warping process in the weaving process, using DSN21/30 type warping machine section warpings, warping room
20 ± 4 DEG C, humidity 60-70%, tension in Warping 0.5-0.8g/dex of temperature, speed of beaming 200-600m/min.
As an optimization：The weaving is woven using ultrahigh speed double-needle bed raschel tricot machine, and technique is GB 1:1- 0- 0-
0/1- 2- 2- 2//completely wear ultra-high molecular weight polyethylene/dacron blended yarn；GB 2:2- 3- 3- 3/1- 0- 0- 0//full
Wear graphene polyamide/Lycra mixed yarn；GB 3:1- 2- 2- 3/2- 1- 1- 0//completely wear 100% polyester DTY；GB 4:
0- 0- 1- 3/3- 3- 2- 0//completely wear 100% terylene, DTY intervals are 5~9mm.
As an optimization：The braided fabric is immersed in 2-6% gold redrock nano-titanium dioxides/1-4% graphene hydrosols
5-10 minutes, titanium dioxide average diameter grain was in 20-30nm, and with roll roll compacting, pick-up 100-120%, 140-160 DEG C dries,
102 DEG C of decatizes, 150-160 DEG C of finished product of shaping to obtain.
Advantageous effect：Present invention process is simple, it can be achieved that mass automatic production, the antibacterial shoe face eyelet fabric have good
Quality, soft feel, preferably size recovery and the gas permeability of good elastic force, densification, significantly improve footwear
Antibacterial, the deodorization used, wear-resisting resistance to the advantages of cutting.It solves the problems, such as full fiber product antibacterial and deodouring, significantly improves
The comfort of product, meets the consumer demands such as outdoor sports crowd.
Long acting antibiotic, the performance that eliminates the unusual smell are by graphene Fypro and gold redrock nano-titanium dioxide/stone in the present invention
The black alkene hydrosol provides.Good elastic force, the preferably performances such as size recovery are provided by Lycra fiber in the present invention.The present invention
In the wear-resisting resistance to ultra-high molecular weight polyethylene/blend polyester yarn of cutting provide.Gas permeability wet guilding is mainly compiled by design in the present invention
The mesh knitted provides.
Gold redrock nano-titanium dioxide/graphene hydrosol high degree of dispersion, homogenization and stabilisation, has in the present invention
Big specific surface area, the electrically charged hydroxyl of strong chemical bonding adsorptivity.With good film forming, film forming is smooth, by force
Degree is big.Offer greatly improves water-fastness, the performances such as wear-resisting, antibacterial.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, so that the technology of this field
Personnel can be better understood from advantages and features of the invention, to make apparent boundary to protection scope of the present invention
It is fixed.Embodiment described in the invention is only a part of the embodiment of the present invention, instead of all the embodiments, based on the present invention
In embodiment, the every other implementation that those of ordinary skill in the art are obtained without making creative work
Example, shall fall within the protection scope of the present invention.
Specific embodiment 1
A kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric, using ultra-high molecular weight polyethylene/dacron blended yarn,
One kind in the short fiber yarns such as graphene polyamide, cotton, polyester-cotton blend, terylene or terylene, graphene polyamide filaments, Lycra fiber
Or it is several weaved, the vamp eyelet fabric after weaving by appropriateness decatize and setting obtain finished product, obtain finished product be it is several
The cellular fabric of a mesh composition, product specification are：Vertical close 30 rows/5cm, grammes per square metre 80g/m2。
Warp thread is blending ratio 90/10,70/30,65/35,50/50,30S/2-50S/2 ultra-high molecular weight polyethylene/terylene
Scribbled or 50D100% polyester DTYs, one kind in 100% nylon of 70D/2.
Weft yarn is 30S/2 graphene polyamide filaments, and graphene content is 0.5% in graphene Fypro, or
30S/2 graphenes polyamide/Lycra mixed yarn, graphene content is 0.5% in graphene Fypro, Lycra blending ratio
5%.
Bundled yarn is 50D100% polyester DTYs, 100% nylon DTY of 70D/2.
Warping process in the weaving process, using DSN21/30 type warping machine section warpings, 16 DEG C of the temperature of warping room,
Humidity 60%, tension in Warping 0.5g/dex, speed of beaming 200m/min.
The weaving is woven using ultrahigh speed double-needle bed raschel tricot machine, and technique is GB 1:1- 0- 0- 0/1- 2-
2- 2//completely wear ultra-high molecular weight polyethylene/dacron blended yarn；GB 2:2- 3- 3- 3/1- 0- 0- 0//completely wear graphene
Polyamide/Lycra mixed yarn；GB 3:1- 2- 2- 3/2- 1- 1- 0//completely wear 100% polyester DTY；GB 4:0- 0- 1-
3/3- 3- 2- 0//completely wear 100% terylene, DTY intervals are 5mm.
The braided fabric is immersed in the graphene hydrosol of 2% gold redrock nano-titanium dioxide/1% 5 minutes, titanium dioxide
Average diameter grain is in 20nm, with roll roll compacting, pick-up 100%, 140 DEG C of drying, 102 DEG C of decatizes, 150 DEG C of finished products of shaping to obtain.
Specific embodiment 2
A kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric, using ultra-high molecular weight polyethylene/dacron blended yarn,
One kind in the short fiber yarns such as graphene polyamide, cotton, polyester-cotton blend, terylene or terylene, graphene polyamide filaments, Lycra fiber
Or it is several weaved, the vamp eyelet fabric after weaving by appropriateness decatize and setting obtain finished product, obtain finished product be it is several
The cellular fabric of a mesh composition, product specification are：Vertical close 40 rows/5cm, grammes per square metre 100g/m2。
Warp thread is blending ratio 90/10,70/30,65/35,50/50,30S/2-50S/2 ultra-high molecular weight polyethylene/terylene
Scribbled or 75D100% polyester DTYs, one kind in 100% nylon of 120D/2.
Weft yarn is 50S/2 graphene polyamide filaments, and graphene content is 1% or 50S/2 in graphene Fypro
Graphene polyamide/Lycra mixed yarn, graphene content is 1% in graphene Fypro, Lycra blending ratio 8%.
Bundled yarn is 180D100% polyester DTYs, 100% nylon DTY of 120D/2.
Warping process in the weaving process, using DSN21/30 type warping machine section warpings, 24 DEG C of the temperature of warping room,
Humidity 70%, tension in Warping 0.8g/dex, speed of beaming 600m/min.
The weaving is woven using ultrahigh speed double-needle bed raschel tricot machine, and technique is GB 1:1- 0- 0- 0/1- 2-
2- 2//completely wear ultra-high molecular weight polyethylene/dacron blended yarn；GB 2:2- 3- 3- 3/1- 0- 0- 0//completely wear graphene
Polyamide/Lycra mixed yarn；GB 3:1- 2- 2- 3/2- 1- 1- 0//completely wear 100% polyester DTY；GB 4:0- 0- 1-
3/3- 3- 2- 0//completely wear 100% terylene, DTY intervals are 9mm.
The braided fabric is immersed in the graphene hydrosol of 6% gold redrock nano-titanium dioxide/4% 10 minutes, titanium dioxide
Titanium average diameter grain is in 30nm, with roll roll compacting, pick-up 120%, 160 DEG C of drying, 102 DEG C of decatizes, 160 DEG C of finished products of shaping to obtain.
Specific embodiment 3
A kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric, using ultra-high molecular weight polyethylene/dacron blended yarn,
One kind in the short fiber yarns such as graphene polyamide, cotton, polyester-cotton blend, terylene or terylene, graphene polyamide filaments, Lycra fiber
Or it is several weaved, the vamp eyelet fabric after weaving by appropriateness decatize and setting obtain finished product, obtain finished product be it is several
The cellular fabric of a mesh composition, product specification are：Vertical close 36 rows/5cm, grammes per square metre 90g/m2。
Warp thread is 90/10,70/30,65/35,50/50,30S/2-50 S/2 ultra-high molecular weight polyethylenes of blending ratio/terylene
Scribbled or 65D100% polyester DTYs, one kind in 100% nylon of 90D/2.
Weft yarn is 40S/2 graphene polyamide filaments, and graphene content is 0.8% in graphene Fypro, or
40S/2 graphenes polyamide/Lycra mixed yarn, graphene content is 0.7% in graphene Fypro, Lycra blending ratio
6%.
Bundled yarn is 120D100% polyester DTYs, 100% nylon DTY of 90D/2.
Warping process in the weaving process, using DSN21/30 type warping machine section warpings, 20 DEG C of the temperature of warping room,
Humidity 66%, tension in Warping 0.6g/dex, speed of beaming 400m/min.
The weaving is woven using ultrahigh speed double-needle bed raschel tricot machine, and technique is GB 1:1- 0- 0- 0/1- 2-
2- 2//completely wear ultra-high molecular weight polyethylene/dacron blended yarn；GB 2:2- 3- 3- 3/1- 0- 0- 0//completely wear graphene
Polyamide/Lycra mixed yarn；GB 3:1- 2- 2- 3/2- 1- 1- 0//completely wear 100% polyester DTY；GB 4:0- 0- 1-
3/3- 3- 2- 0//completely wear 100% terylene, DTY intervals are 7mm.
The braided fabric is immersed in the graphene hydrosol of 4% gold redrock nano-titanium dioxide/2% 8 minutes, titanium dioxide
Average diameter grain is in 26nm, with roll roll compacting, pick-up 110%, 150 DEG C of drying, 102 DEG C of decatizes, 154 DEG C of finished products of shaping to obtain.
Present invention process is simple, it can be achieved that mass automatic production, the antibacterial shoe face eyelet fabric have good elastic force,
Fine and close quality, soft feel, preferably size recovery and gas permeability, significantly improve footwear use it is anti-
Bacterium, deodorization, wear-resisting resistance to the advantages of cutting.It solves the problems, such as full fiber product antibacterial and deodouring, significantly improves product
Comfort meets the consumer demands such as outdoor sports crowd.
Long acting antibiotic, the performance that eliminates the unusual smell are by graphene Fypro and gold redrock nano-titanium dioxide/stone in the present invention
The black alkene hydrosol provides.Good elastic force, the preferably performances such as size recovery are provided by Lycra fiber in the present invention.The present invention
In the wear-resisting resistance to ultra-high molecular weight polyethylene/blend polyester yarn of cutting provide.Gas permeability wet guilding is mainly compiled by design in the present invention
The mesh knitted provides.
Gold redrock nano-titanium dioxide/graphene hydrosol high degree of dispersion, homogenization and stabilisation, has in the present invention
Big specific surface area, the electrically charged hydroxyl of strong chemical bonding adsorptivity.With good film forming, film forming is smooth, by force
Degree is big.Offer greatly improves water-fastness, the performances such as wear-resisting, antibacterial.
Claims (7)
1. a kind of preparation method of graphene-containing antibacterial shoe face eyelet fabric, it is characterised in that：Using ultra-high molecular weight polyethylene/wash
The short fiber yarns such as synthetic fibre mixed yarn, graphene polyamide, cotton, polyester-cotton blend, terylene or terylene, graphene polyamide filaments, Lycra are fine
One or more of dimension is weaved, and the vamp eyelet fabric after weaving obtains finished product by the decatize and setting of appropriateness, obtains
Finished product is the cellular fabric of several mesh composition, and product specification is：Vertical close 30-40 rows/5cm, grammes per square metre 80-100g/m2。
2. the preparation method of graphene-containing antibacterial shoe according to claim 1 face eyelet fabric, it is characterised in that：Warp thread is mixed
Spin ratio 90/10,70/30,65/35,50/50,30S/2-50S/2 ultra-high molecular weight polyethylene/blend polyester yarn or 50-
75D100% polyester DTYs, one kind in 100% nylon of 70D-120D/2.
3. the preparation method of graphene-containing antibacterial shoe according to claim 1 face eyelet fabric, it is characterised in that：Weft yarn is
30S/2-50S/2 graphene polyamide filaments, graphene content is 0.5-1% or 30S/2- in graphene Fypro
50S/2 graphenes polyamide/Lycra mixed yarn, graphene content is 0.5-1%, Lycra blending ratio in graphene Fypro
5-8%.
4. the preparation method of graphene-containing antibacterial shoe according to claim 1 face eyelet fabric, it is characterised in that：Bundled yarn is
50-180D100% polyester DTYs, 100% nylon DTY of 70D-120D/2.
5. the preparation method of graphene-containing antibacterial shoe according to claim 1 face eyelet fabric, it is characterised in that：The weaving
Warping process in technique, using DSN21/30 type warping machine section warpings, 20 ± 4 DEG C, humidity 60-70% of the temperature of warping room,
Tension in Warping 0.5-0.8g/dex, speed of beaming 200-600m/min.
6. the preparation method of graphene-containing antibacterial shoe according to claim 1 face eyelet fabric, it is characterised in that：The weaving
It is woven using ultrahigh speed double-needle bed raschel tricot machine, technique is GB 1:1-0-0-0/1-2-2-2//completely wear super high molecular weight is poly-
Ethylene/dacron blended yarn；GB 2:2-3-3-3/1-0-0-0//completely wear graphene polyamide/Lycra mixed yarn；GB 3:1-2-2-
3/2-1-1-0//completely wear 100% polyester DTY；GB 4:0-0-1-3/3-3-2-0//completely wear 100% terylene, DTY intervals are
5~9mm.
7. the preparation method of graphene-containing antibacterial shoe according to claim 1 face eyelet fabric, it is characterised in that：The braiding
Object is immersed in 2-6% gold redrock nano-titanium dioxides/1-4% graphene hydrosols 5-10 minutes, titanium dioxide average diameter grain
In 20-30nm, with roll roll compacting, pick-up 100-120%, 140-160 DEG C of drying, 102 DEG C of decatizes, 150-160 DEG C is shaped
Finished product.
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