CN108587509A - Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof - Google Patents
Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof Download PDFInfo
- Publication number
- CN108587509A CN108587509A CN201810387226.XA CN201810387226A CN108587509A CN 108587509 A CN108587509 A CN 108587509A CN 201810387226 A CN201810387226 A CN 201810387226A CN 108587509 A CN108587509 A CN 108587509A
- Authority
- CN
- China
- Prior art keywords
- bituminous
- rubber
- self
- waterproof coil
- adhesive waterproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
- C09J7/243—Ethylene or propylene polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of novel non-bituminous base adhesive waterproof coil and preparation method thereof, including main body base material, the non-bituminous self-adhesion sizing material and the isolation film that are overlying on main body base material, the non-bituminous self-adhesion sizing material comprise the following raw materials by weight percent：C5/C9 copolymer resins 10 ~ 25%, polyisobutene 3 ~ 14%, naphthenic rubber oil 10 ~ 25%, SIS rubber 3 ~ 12%, butadiene-styrene rubber 4 ~ 14%, filler 15 ~ 35%, pigment 0.5 ~ 2.5%, auxiliary agent 4 ~ 6%.Compared with prior art, the peel strength of novel non-bituminous base adhesive waterproof coil disclosed in this invention is high, and is not easily separate between main body base material and non-bituminous self-adhesion sizing material.
Description
Technical field
The present invention relates to field of waterproof materials, and in particular to the novel non-bituminous base adhesive waterproof coil of one kind and its preparation side
Method.
Background technology
Adhesive waterproof coil is not required to brush in base in construction without heating, the self-adhesive coiled material of especially wet application
Base treatment agent, construction safety is environmentally friendly, is developed in recent years than a kind of faster waterproof roll.Now answer in the market
Adhesive waterproof coil is broadly divided into asphaltic base adhesive waterproof coil and non-bituminous base adhesive waterproof coil.Asphaltic base self-adhesion is anti-
Caking property is poor under cryogenic for water coiled material；And the weatherability and water resistance of general non-bituminous base waterproof roll are poor, together
When there is also polymer base material and adhesive polymer glue can be easily separated phenomenon, in coiled material, peeling is brighter after heat ageing
It is aobvious.
Application No. is 201610462603.2 Chinese invention patents to pass through the side of addition polar resin in macromolecular sheet material
Method improves the peel strength of non-bituminous polymer membranes, changes specifically by low density polyethylene (LDPE), maleic anhydride grafting
Property polyethylene, by the precipitated calcium carbonate of silane coupling agent surface treatment, ultra-violet absorber, primary antioxidant, auxiliary anti-oxidant, hard
Macromolecular sheet material, then the melting extrusion SIS pressure-sensitive hot melt adhesives on macromolecular sheet material are arrived in the raw materials such as resin acid and iron white powder basis, most
After be covered with protective layer, so obtain non-bituminous polymer membranes.Raising of the program for the peel strength of waterproof roll
Mainly by improving polar resin --- modified by maleic acid anhydride graft polyethylene, raw material and processing cost are higher.
Invention content
To overcome existing technological deficiency, the present invention provides a kind of main body base materials (polymer base material) and non-bituminous self-adhesion
The novel non-bituminous base adhesive waterproof coil and preparation method thereof that sizing material is not easily separate.
To achieve the purpose of the present invention, it is achieved using following technical scheme：
A kind of novel non-bituminous base adhesive waterproof coil, including main body base material, the non-bituminous self-adhesion that is overlying on main body base material
Sizing material and isolation film, the non-bituminous self-adhesion sizing material comprise the following raw materials by weight percent：C5/C9 copolymer resins 10~
25%, polyisobutene 3~14%, naphthenic rubber oil 10~25%, SIS rubber 3~12%, butadiene-styrene rubber 4~14%, filler
15~35%, pigment 0.5~2.5%, auxiliary agent 4~6%.
Further, the non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/C9 copolymer resins 15
~22%, polyisobutene 5~12%, naphthenic rubber oil 15~22%, SIS rubber 5~10%, butadiene-styrene rubber 5~10%, fill out
Material 20~30%, pigment 1~2%, auxiliary agent 3~5%.
Further, the non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/C9 copolymer resins 17
~20%, polyisobutene 7~10%, naphthenic rubber oil 17~21%, SIS rubber 7~9%, butadiene-styrene rubber 7~9%, filler
25~27%, pigment 1.3~1.7%, auxiliary agent 3.5~4.5%.
Currently, the base material in the market without tire base pitch or non-bituminous base volume material polymer membranes is mostly high-density polyethylene
Alkene film, but it is density polyethylene film with high heat resistance, dimensional stability, all poor with self-adhesion sizing material caking property.To solve the problems, such as this,
The main body reinforcing material of novel non-bituminous base self-adhesive coiled material provided by the present invention uses roll with strong crossed laminated film.Preferably, it selects
Roll with strong crossed laminated film can be assigned so highly dense with the cross-laminated composite membrane of the oblique 45° angle of density polyethylene film with high
Spend the fine dimensional stability of polyethylene film and tearing toughness.
In order to further enhance the attachment between roll with strong crossed laminated film and non-bituminous self-adhesion sizing material, cross-laminated multiple
Close film carry out sided corona treatment, using high-frequency high voltage cross-laminated composite membrane surface corona (high-frequency ac voltage
Up to 5000~15000V/m2) and generate low temperature plasma, so that film surface is generated functional group reactions and polymer is made to hand over
Connection, surface are roughening so that increasing the adhesive ability on surface.
Further, it is 90~110 DEG C that the C5/C9 copolymerized petroleum resins, which are softening points,.Current non-bituminous base is anti-
The self-adhesion compound layer of water coiled material uses C5 hydrogenation resins or C9 resins mostly.Although however C5 hydrogenation resins make in hot melt adhesive industry
With universal, but due to higher price so that the hot melt adhesive cost of production is more expensive, in this way relative to common self-adhesive coiled material sizing material cost
Upper no advantage；And use C9 resin costs relatively low, but since C9 resins have the double bond structures such as the isoprene of high level,
So that self-adhesion compound layer heat ageing and UV resistance reduce.Therefore, in summary factor, the present invention select C5/C9 to be copolymerized stone
Oleoresin.Preferably, the C5/C9 copolymerized petroleum resins select coloration to add hydrogen C5/C9 copolymerized petroleum resins less than No. 5.This
Non-bituminous base is that can be coloured to other colors from sizing, and color of resin is too deep, bad to be coloured to thin shade.Coloration is to sizing material
Matter does not influence.
The polyisobutene is the polyisobutene (PIB) of molecular weight 1000~5000 or so.The PIB of the segment molecule amount has
Relatively good heat-resisting, oxytolerant, weather-proof, UV resistant, acidproof and alkali resistance.
It is so that non-bituminous self-adhesion sizing material shows excellent, described SIS rubber in terms of low temperature flexibility and adhesive property
SIS rubber of the isoprene content 80% or more.
To further increase the viscosity of self-adhesion sizing material, the butadiene-styrene rubber is that glue content is 80% or more, moisture
Butylbenzene solid powder rubber less than 0.5%.
The filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more.
The auxiliary agent is organo montmorillonite.To increase the thermal stability of system, the organo montmorillonite is using receiving base
Montmorillonite.
Further, red-brown powder iron oxide red may be used in the pigment, plays material coloration.
The preparation method of the non-bituminous base self-adhesion sizing material is specially：
Further, the preparation method of the non-bituminous base self-adhesion sizing material is specially：
S1：The naphthenic rubber oil and polyisobutene of formula rate are added to the first reaction kettle, is then turned on stirring, heats up
To 150 DEG C；
S2：After temperature rise is dissolved completely to 160 DEG C and C5/C9 copolymer resins, SIS rubber and butadiene-styrene rubber is added,
Continue to be warming up to 178~182 DEG C, then whip modified 2.5h at this temperature；
S3：The modified materials of step S2 are transferred in high shear grinding dispersion machine, high shear grinding dispersion machine is passed through
Enter the second reaction kettle after 40~50min of grinding distribution, pigment, filler and auxiliary agent are added in the second reaction kettle, 160~
Non-bituminous base self-adhesion sizing material is obtained after stirring 40~60min at 165 DEG C.
A kind of preparation method of above-mentioned novel non-bituminous base adhesive waterproof coil, specifically includes following steps：
(1) roller press briquetting：The non-bituminous base self-adhesion sizing material prepared is added in online gluing reaction kettle, two pairs of rollers are adjusted
Spacing and baffle distance, after cross-level press mold and isolation film are put in two to roller surface respectively, blowing extrusion forming is rolled up
Material；
(2) cooling and shaping：The coiled material of two pairs of rollers extrusion forming enters back into after being sprayed water in sink, controls the temperature of bosh
Degree makes it quickly be fully cooled sizing between 20~23 DEG C；
(3) dry：Coiled material dries up the water of coiled material surface after bosh cools down, with wind turbine, then with spongy layer handle
The remaining water of coiled material surface blots, and finally hot wind unit is used to dry；
(4) it flattens：After coiled material drying, carry out carrying out flattening processing to coiled material by multiple rollers；
(5) it winds：Automatic coiling machine is wanted to be wound；
(6) it packs：It is packed with thermal shrinking package machine.
In preparation method provided by the present invention, improvement is specially：
1) forming temperature in production process is controlled
Currently, most of manufacturer when producing such coiled material, in order to improve production effect, reduces material viscosity, at
Type temperature can control between 165 DEG C~175 DEG C, and moulding process temperature drops in the preparation method of coiled material provided by the present invention
As low as 160~165 DEG C, temperature is no more than 165 DEG C.Low temperature moulding makes the main body density polyethylene film with high of enhancing from high temperature
Moment scalds film, while having no effect on the property and quality of coiled material.
2) in production process cooling water setting and requirement
Itself there is higher temperature, common recirculated cooling water to carry out cooling and shaping after coiled material roller press briquetting.If cooling
Water is without refrigeration, and the temperature of cooling water can be continuously improved, to substantially reduce the cooling effect of coiled material.It is provided by the present invention
Novel non-bituminous base self-adhesive coiled material recirculated cooling water need to carry out cooling and shaping, cooling water temperature control after cryocooled to coiled material
System is between 20~23 DEG C.
Further, for the tension force of production process, since many producers are to promote production effect and production capacity, production
Speed leads to overtension in 40~50m/min, be easy to cause coiled material deformation surface itself and gauffer occurs.It is provided by the present invention
Non-bituminous base volume material reduce production speed in production process, speed controls between 25~30m/min, and it is whole to reduce production line
Tension allows and produces the not wrinkled pleat of coiled material, does not interfere with subsequent construction overlap joint so that the overlap joint more closely knit gapless of effect.
The present invention provides a kind of novel non-bituminous base adhesive waterproof coils and preparation method thereof, compared with prior art,
It has the advantages that：
1, the density polyethylene film with high that the present invention uses is that oblique 45° angle is cross-laminated as enhancing matrix, the tear-proof of film
Intensity higher, while film is handled by high-pressure electrostatic, greatly strengthens the cohesive force of film and non-bituminous base self-adhesion sizing material.
2, in the formula design of non-bituminous base self-adhesion sizing material provided by the present invention, for PIB and C5/C9 copolymer resins
Selection can ensure coiled material in water-fast, heat-proof aging, corrosion-resistant, UV resistant performance is more excellent；Simultaneously in formula designs
The butadiene-styrene rubber of the SIS and high-glue content that also use high-isoprene content can ensure that coiled material has stronger cohesive force.
3, line speed is controlled in process of production, reduces production tension, can so that coiled material is outer in process of production
It sees more smooth；Roller press briquetting temperature is controlled in process of production, and production process is avoided to occur scalding film phenomenon and high temperature to film
Damage；The water temperature of cooling water is controlled in process of production so that the cooling effect of coiled material is more preferable, the moment sizing of advantageous coiled material,
Advantageously to coil thickness control.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, embodiment of the present invention is made below further
It explains in detail.
Embodiment 1
It present embodiments provides a kind of novel non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/
C9 copolymer resins 10%, polyisobutene 14%, naphthenic rubber oil 25%, SIS rubber 12%, butadiene-styrene rubber 14%, filler
16.5%, pigment 2.5%, auxiliary agent 6%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film, and plasma surface treatment is carried out to cross-level press mold, intersected with improving
Adhesive ability between laminated film and non-bituminous self-adhesion sizing material.
The preparation method of above-mentioned non-bituminous base self-adhesion sizing material is specially：
S1：The naphthenic rubber oil and polyisobutene of formula rate are added to the first reaction kettle, is then turned on stirring, heats up
To 150 DEG C；
S2：After temperature rise is dissolved completely to 160 DEG C and C5/C9 copolymer resins, SIS rubber and butadiene-styrene rubber is added,
Continue to be warming up to 178~182 DEG C, then whip modified 2.5h at this temperature；
S3：The modified materials of step S2 are transferred in high shear grinding dispersion machine, high shear grinding dispersion machine is passed through
Enter the second reaction kettle after 40~50min of grinding distribution, pigment, filler and auxiliary agent are added in the second reaction kettle, 160~
Non-bituminous base self-adhesion sizing material is obtained after stirring 40~60min at 165 DEG C.
A kind of preparation method of above-mentioned novel non-bituminous base adhesive waterproof coil, specifically includes following steps：
(1) roller press briquetting：The non-bituminous base self-adhesion sizing material prepared is added in online gluing reaction kettle, two pairs of rollers are adjusted
Spacing and baffle distance, after cross-level press mold and isolation film are put in two to roller surface respectively, blowing extrusion forming is rolled up
Material；
(2) cooling and shaping：The coiled material of two pairs of rollers extrusion forming enters back into after being sprayed water in sink, controls the temperature of bosh
Degree makes it quickly be fully cooled sizing between 20~23 DEG C；
(3) dry：Coiled material dries up the water of coiled material surface after bosh cools down, with wind turbine, then with spongy layer handle
The remaining water of coiled material surface blots, and finally hot wind unit is used to dry；
(4) it flattens：After coiled material drying, carry out carrying out flattening processing to coiled material by multiple rollers；
(5) it winds：Automatic coiling machine is wanted to be wound；
(6) it packs：It is packed with thermal shrinking package machine.
Embodiment 2
It present embodiments provides a kind of novel non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/
C9 copolymer resins 25%, polyisobutene 3%, naphthenic rubber oil 25%, SIS rubber 3%, butadiene-styrene rubber 4%, filler 35%,
Pigment 0.5%, auxiliary agent 4.5%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film, and plasma surface treatment is carried out to cross-level press mold, intersected with improving
Adhesive ability between laminated film and non-bituminous self-adhesion sizing material.
Wherein, the preparation method of non-bituminous base self-adhesion sizing material and coiled material is with reference to embodiment 1.
Embodiment 3
It present embodiments provides a kind of novel non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/
C9 copolymer resins 15%, polyisobutene 12%, naphthenic rubber oil 22%, SIS rubber 6%, butadiene-styrene rubber 10%, filler
28%, pigment 2%, auxiliary agent 5%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film, and plasma surface treatment is carried out to cross-level press mold, intersected with improving
Adhesive ability between laminated film and non-bituminous self-adhesion sizing material.
Wherein, the preparation method of non-bituminous base self-adhesion sizing material and coiled material is with reference to embodiment 1.
Embodiment 4
It present embodiments provides a kind of novel non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/
C9 copolymer resins 22%, polyisobutene 8%, naphthenic rubber oil 18%, SIS rubber 10%, butadiene-styrene rubber 8%, filler 30%,
Pigment 1%, auxiliary agent 3%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film, and plasma surface treatment is carried out to cross-level press mold, intersected with improving
Adhesive ability between laminated film and non-bituminous self-adhesion sizing material.
Wherein, the preparation method of non-bituminous base self-adhesion sizing material and coiled material is with reference to embodiment 1.
Embodiment 5
It present embodiments provides a kind of novel non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/
C9 copolymer resins 20%, polyisobutene 10%, naphthenic rubber oil 21%, SIS rubber 9%, butadiene-styrene rubber 9%, filler 26%,
Pigment 1.5%, auxiliary agent 4.5%.
Wherein, it is 90~110 DEG C that C5/C9 copolymerized petroleum resins, which are softening points, and coloration adds hydrogen C5/C9 copolymerization less than No. 5
Petropols；Polyisobutene is the polyisobutene of molecular weight 1000~5000 or so；SIS rubber is isoprene content 80%
Above SIS rubber；Butadiene-styrene rubber is that glue content is 80% or more, and moisture is less than 0.5% butylbenzene solid powder rubber；
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；Auxiliary agent is organo montmorillonite.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film, and plasma surface treatment is carried out to cross-level press mold, intersected with improving
Adhesive ability between laminated film and non-bituminous self-adhesion sizing material.
Wherein, the preparation method of non-bituminous base self-adhesion sizing material and coiled material is with reference to embodiment 1.
Comparative example 1
It is compared with embodiment 1, the roll with strong crossed laminated film as main body base material is without corona treatment.
Comparative example 2
This comparative example 2 provides a kind of plain asphalt base adhesive waterproof coil, including main body base material, is overlying on main body base material
Pitch self-adhesion sizing material and isolation film.The asphaltic base self-adhesion sizing material comprises the following raw materials by weight percent：Pitch
45%, base oil 10%, SBS 7%, butadiene-styrene rubber 4%, thickening Petropols 5%, rubber powder：7%, filler 22%.
Wherein, main body base material uses polyethylene composite film.Preferably, the composite membrane of the double-layer polyethylene of selection.
Comparative example 3
This comparative example 3 provides a kind of common non-bituminous base adhesive waterproof coil, including main body base material, is overlying on main body base material
On non-bituminous self-adhesion sizing material and isolation film.The asphaltic base self-adhesion sizing material comprises the following raw materials by weight percent：Carbon 5
Hydrogenation resin 30%, naphthenic oil 20%, SIS 20%, filler material 28%, auxiliary agent 2%.
Wherein, main body base material uses roll with strong crossed laminated film.Preferably, the roll with strong crossed laminated film of selection is to use high density
The cross-laminated composite membrane of the oblique 45° angle of polyethylene film.
Performance test
By GB/T23457-2009 and GB/T35467-2017 acceptance of the bid alignment requests, novel non-drip is provided to Examples 1 to 5
Green base waterproof roll is tested with the peel strength of cement mortar at different conditions with common adhesive waterproof coil, specific to survey
Test result is as shown in table 1.
Table 1
According to the data of table 1 it is found that the peel strength for the novel non-bituminous base waterproof roll that Examples 1 to 5 is provided is high
In asphaltic base waterproof roll and common non-bituminous base waterproof roll, especially pass through heat ageing, salt treatment, alkali process, immersion
30 days and it is 30 days exposed after peel strength.
The above embodiment is merely an example for clearly illustrating the present invention, and is not the embodiment party to the present invention
The restriction of formula.For those of ordinary skill in the art, other differences can also be made on the basis of the above description
The variation or variation of form.There is no necessity and possibility to exhaust all the enbodiments.All spirit and original in the present invention
All any modification, equivalent and improvement made by within then etc., should all be included in the scope of protection of the claims of the present invention.
Claims (10)
1. a kind of novel non-bituminous base adhesive waterproof coil, including main body base material, the non-bituminous self-adhesive that is overlying on main body base material
Material and isolation film, which is characterized in that the non-bituminous self-adhesion sizing material comprises the following raw materials by weight percent：C5/C9 is total
Poly resin 10 ~ 25%, polyisobutene 2 ~ 14%, naphthenic rubber oil 10 ~ 25%, SIS rubber 2 ~ 12%, butadiene-styrene rubber 3 ~ 14%, filler
15 ~ 35%, pigment 0.5 ~ 2.5%, auxiliary agent 4 ~ 6%.
2. novel non-bituminous base adhesive waterproof coil according to claim 1, which is characterized in that the non-bituminous self-adhesive
Material comprises the following raw materials by weight percent：C5/C9 copolymer resins 15 ~ 22%, polyisobutene 5 ~ 12%, naphthenic rubber oil 15
~ 22%, SIS rubber 5 ~ 10%, butadiene-styrene rubber 5 ~ 10%, filler 20 ~ 30%, pigment 1 ~ 2%, auxiliary agent 3 ~ 5%.
3. novel non-bituminous base adhesive waterproof coil according to claim 2, which is characterized in that the non-bituminous self-adhesive
Material comprises the following raw materials by weight percent：C5/C9 copolymer resins 17 ~ 20%, polyisobutene 7 ~ 10%, naphthenic rubber oil 17
~ 21%, SIS rubber 7 ~ 9%, butadiene-styrene rubber 7 ~ 9%, filler 25 ~ 27%, pigment 1.3 ~ 1.7%, auxiliary agent 3.5 ~ 4.5%.
4. according to the novel non-bituminous base adhesive waterproof coil of claim 1 ~ 3 any one of them, which is characterized in that the main body
Base material is roll with strong crossed laminated film.
5. novel non-bituminous base adhesive waterproof coil according to claim 4, which is characterized in that the roll with strong crossed laminated
Film passes through Low Temperature Plasma Treating.
6. according to any one of claim 1 ~ 3 or the novel non-bituminous base adhesive waterproof coil described in 5, which is characterized in that described
C5/C9 copolymerized petroleum resins select softening point be 90 ~ 110 DEG C plus hydrogen C5/C9 copolymerized petroleum resins；And/or it is described poly-
Isobutene is the polyisobutene of molecular weight 1000 ~ 5000；And/or the SIS rubber be isoprene content 80% or more
SIS rubber；And/or it is 80% or more that the butadiene-styrene rubber, which is glue content, moisture is less than 0.5% butylbenzene solid powder rubber
Glue.
7. according to any one of claim 1 ~ 3 or the novel non-bituminous base adhesive waterproof coil described in 5, which is characterized in that described
Filler be calcium carbonate, talcum powder, coarse whiting, fine particle calcium carbonate, calcined kaolin it is one or more；And/or the auxiliary agent is organic
Montmorillonite.
8. according to any one of claim 1 ~ 3 or the novel non-bituminous base adhesive waterproof coil described in 5, which is characterized in that described
The preparation method of non-bituminous base self-adhesion sizing material is specially：
S1：The naphthenic rubber oil and polyisobutene of formula rate are added to the first reaction kettle, is then turned on stirring, is warming up to
150 DEG C of addition C5/C9 copolymer resins；
S2：After temperature rise is dissolved completely to 160 DEG C and C5/C9 copolymer resins, SIS rubber and butadiene-styrene rubber is added, continues
178 ~ 182 DEG C are warming up to, then whip modified 2.5h at this temperature；
S3：The modified materials of step S2 are transferred in high shear grinding dispersion machine, are ground by high shear grinding dispersion machine
Enter the second reaction kettle after disperseing 40 ~ 50min, pigment, filler and auxiliary agent is added in the second reaction kettle, at 160 ~ 165 DEG C
Non-bituminous base self-adhesion sizing material is obtained after 40 ~ 60min of stirring.
9. according to the preparation method of the novel non-bituminous base adhesive waterproof coil described in claim 1 ~ 8, which is characterized in that specific
Include the following steps：
（1）Roller press briquetting：Non-bituminous base self-adhesion sizing material is added in online gluing reaction kettle, adjust two pairs of rollers spacing and baffle away from
From after cross-level press mold and isolation film are put in two to roller surface respectively, blowing extrusion forming obtains coiled material；
（2）Cooling and shaping：The coiled material of two pairs of rollers extrusion forming enters back into after being sprayed water in sink, and the temperature for controlling bosh exists
Between 20 ~ 23 DEG C, it is made quickly to be fully cooled sizing；
（3）It is dry：Coiled material dries up the water of coiled material surface after bosh cools down, with wind turbine, then with spongy layer coiled material
The water of surface residual blots, and finally hot wind unit is used to dry；
（4）Flattening：After coiled material drying, carry out carrying out flattening processing to coiled material by multiple rollers；
（5）Winding：Automatic coiling machine is wanted to be wound；
（6）Packaging：It is packed with thermal shrinking package machine.
10. the preparation method of novel non-bituminous base adhesive waterproof coil according to claim 9, which is characterized in that waterproof
The speed of production of coiled material is 25 ~ 30 m/min；And/or the roller press briquetting temperature of coiled material is 160 ~ 165 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810387226.XA CN108587509A (en) | 2018-04-26 | 2018-04-26 | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810387226.XA CN108587509A (en) | 2018-04-26 | 2018-04-26 | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108587509A true CN108587509A (en) | 2018-09-28 |
Family
ID=63609772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810387226.XA Pending CN108587509A (en) | 2018-04-26 | 2018-04-26 | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108587509A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111662677A (en) * | 2020-06-02 | 2020-09-15 | 岳阳市科兴防水材料有限公司 | Non-asphalt-based self-adhesive waterproof sizing material, and preparation method and application thereof |
| CN112521875A (en) * | 2020-10-30 | 2021-03-19 | 江西玉龙防水科技有限公司 | Novel non-asphalt-based self-adhesive waterproof coiled material |
| CN112980362A (en) * | 2021-03-02 | 2021-06-18 | 江苏凯伦建材股份有限公司 | Preparation method of self-adhesive waterproof material |
| CN113956811A (en) * | 2021-10-25 | 2022-01-21 | 科顺防水科技股份有限公司 | Non-asphalt-based self-adhesive waterproof roll capable of being exposed and application thereof |
| CN114214013A (en) * | 2021-12-30 | 2022-03-22 | 科顺防水科技股份有限公司 | Non-asphalt self-adhesive polymer waterproof coiled material and preparation method thereof |
| CN114479687A (en) * | 2022-02-25 | 2022-05-13 | 湖北华宇防水材料科技股份有限公司 | Preparation process of double-sided self-adhesive non-asphalt-based waterproof roll |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103074013A (en) * | 2013-02-07 | 2013-05-01 | 宁波申山新材料科技有限公司 | Hot-melt pressure-sensitive adhesive |
| CN104059553A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Preparation method of high-polymer self-adhesive waterproof roll |
| US20150299535A1 (en) * | 2012-07-30 | 2015-10-22 | Bostik Sa | Hot-melt pressure-sensitive adhesive for a reclosable packaging having improved organoleptic properties |
| CN105238347A (en) * | 2015-08-21 | 2016-01-13 | 湖北永阳材料股份有限公司 | Self-adhesive glue, FPF macromolecular self-adhesive waterproof coiled material and manufacturing process therefor |
| CN106893536A (en) * | 2017-03-10 | 2017-06-27 | 新乡市华洋粘合剂有限公司 | A kind of waterproof roll PUR and preparation method thereof |
-
2018
- 2018-04-26 CN CN201810387226.XA patent/CN108587509A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150299535A1 (en) * | 2012-07-30 | 2015-10-22 | Bostik Sa | Hot-melt pressure-sensitive adhesive for a reclosable packaging having improved organoleptic properties |
| CN103074013A (en) * | 2013-02-07 | 2013-05-01 | 宁波申山新材料科技有限公司 | Hot-melt pressure-sensitive adhesive |
| CN104059553A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Preparation method of high-polymer self-adhesive waterproof roll |
| CN105238347A (en) * | 2015-08-21 | 2016-01-13 | 湖北永阳材料股份有限公司 | Self-adhesive glue, FPF macromolecular self-adhesive waterproof coiled material and manufacturing process therefor |
| CN106893536A (en) * | 2017-03-10 | 2017-06-27 | 新乡市华洋粘合剂有限公司 | A kind of waterproof roll PUR and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 化工百科全书》编辑委员会: "《化工百科全书 第4卷 发光材料-氟》", 30 September 1993, 化学工业出版社 * |
| 朱洪法: "《精细化工常用原材料手册》", 31 December 2003, 金盾出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111662677A (en) * | 2020-06-02 | 2020-09-15 | 岳阳市科兴防水材料有限公司 | Non-asphalt-based self-adhesive waterproof sizing material, and preparation method and application thereof |
| CN112521875A (en) * | 2020-10-30 | 2021-03-19 | 江西玉龙防水科技有限公司 | Novel non-asphalt-based self-adhesive waterproof coiled material |
| CN112980362A (en) * | 2021-03-02 | 2021-06-18 | 江苏凯伦建材股份有限公司 | Preparation method of self-adhesive waterproof material |
| CN113956811A (en) * | 2021-10-25 | 2022-01-21 | 科顺防水科技股份有限公司 | Non-asphalt-based self-adhesive waterproof roll capable of being exposed and application thereof |
| CN114214013A (en) * | 2021-12-30 | 2022-03-22 | 科顺防水科技股份有限公司 | Non-asphalt self-adhesive polymer waterproof coiled material and preparation method thereof |
| CN114214013B (en) * | 2021-12-30 | 2022-06-14 | 科顺防水科技股份有限公司 | Non-asphalt self-adhesive polymer waterproof coiled material and preparation method thereof |
| CN114479687A (en) * | 2022-02-25 | 2022-05-13 | 湖北华宇防水材料科技股份有限公司 | Preparation process of double-sided self-adhesive non-asphalt-based waterproof roll |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108587509A (en) | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof | |
| CN108641628A (en) | A kind of waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof | |
| CN105619929B (en) | A kind of both-sided adhesive asphaltic base pet vector wet-laying waterproof roll and its production technology | |
| CN103059763B (en) | Bidirectional stretching polypropylene film for hot binding compounding, and its preparation method | |
| CN102304330B (en) | Clean and environmentally-friendly hot melt adhesive capable of being operated at low temperature as well as preparation method and application thereof | |
| CN1219150A (en) | Two-side coated label facestock | |
| CN105415821B (en) | A kind of novel modified asphalt waterproof roll and preparation method thereof | |
| CN102604553A (en) | Reaction-type high-strength laminated film waterproof roll | |
| CN109263162B (en) | A kind of Biaxially oriented polypropylene precoating ground and its preparation method and application | |
| CN111101658B (en) | Modified asphalt waterproof coiled material and preparation method thereof | |
| CN111662677A (en) | Non-asphalt-based self-adhesive waterproof sizing material, and preparation method and application thereof | |
| CN108724870A (en) | A kind of wet-laid process adhesive waterproof coil and preparation method thereof | |
| CN112794937B (en) | High-molecular polymer emulsion and preparation method thereof, functional coating, film layer and waterproof roll | |
| CN114085646A (en) | Non-curing self-healing self-adhesive waterproof coating, waterproof roll and preparation method thereof | |
| CN108504117A (en) | A kind of wet-laid process adhesive waterproof coil modified pitch sizing material and preparation method thereof | |
| CN109370068A (en) | A kind of low temperature resistant TPO self-adhesive layer and preparation method thereof and low temperature resistant TPO waterproof roll | |
| CN105400377A (en) | Epoxy powder coating with self-repairing function and preparation method thereof | |
| WO2024067580A1 (en) | Composite reinforcing layer having high bonding strength with asphalt mastic, and preparation method therefor | |
| CN109808276B (en) | Reaction type polymer self-adhesion waterproofing membrane | |
| CN112521875A (en) | Novel non-asphalt-based self-adhesive waterproof coiled material | |
| CN115505154B (en) | Functional film and preparation method and application thereof | |
| CN106753012A (en) | A kind of hydrophily antifog film and preparation method thereof | |
| CN113683978B (en) | Self-adhesive SBS waterproof coiled material and preparation method thereof | |
| CN103492515A (en) | Pressure sensitive adhesive composition and pressure sensitive adhesive sheet | |
| CN206406558U (en) | A kind of hydrophily antifog film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180928 |