CN108586840A - A kind of high intensity, low deformation are easy to rubber composition with metal adhesive - Google Patents
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive Download PDFInfo
- Publication number
- CN108586840A CN108586840A CN201810457116.6A CN201810457116A CN108586840A CN 108586840 A CN108586840 A CN 108586840A CN 201810457116 A CN201810457116 A CN 201810457116A CN 108586840 A CN108586840 A CN 108586840A
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- parts
- easy
- rubber composition
- high intensity
- metal adhesive
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L17/00—Compositions of reclaimed rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, are related to a kind of rubber composition, have following group to be in parts by weight grouped as：100 parts of rubber；1 ~ 3 part of mineral reserve filler；1.5 ~ 2.5 parts of organic active agent；4.5 ~ 6 parts of inorganic active agent；1.5 ~ 3 parts of dispersant；1.5 ~ 2.5 parts of naphthylamine antioxidant；3 parts of plasticizer；30 ~ 45 parts of reinforcing agent；1.0 ~ 1.5 parts of thiazole accelerator；2 ~ 2.5 parts of vulcanizing agent.Present invention discover that made injecting glue machine support rubber composition raw material is cheap and easy to get, product has the characteristics of high intensity, low deformation, energy and metal adhesive, temperature tolerance is good, can be combined well with glue-injection machine in assembly and use, assembly and use in more conducively producing.
Description
Technical field
The present invention relates to a kind of rubber compositions, more particularly to a kind of high intensity, low deformation, are easy to and metal adhesive
Rubber composition.
Background technology
The adhesive property of rubber mechanical property itself and metal cannot meet the needs of rubber product, high-strength for having required
Degree, low compression set are easy to the injecting glue machine support with metal adhesive, to overcome the intensity in reclaimed rubber insufficient, compression
Permanent deformation is big, is not easy to and metal adhesive, this is difficult to meet.Therefore, a kind of high intensity, low deformation, be easy to viscous with metal
The research of the injecting glue machine support rubber composition connect has very profound significance.
Glue-injection machine timbering material main component is natural rubber and reclaimed rubber, and because of its intensity height, good air-tightness is prevented
Aqueous, plasticity, insulating properties, it is cheap and easy to get and be widely adopted.But it is low because its injecting glue machine support requires that high intensity must be carried
Compression set is easy to the function with metal adhesive, is the metal frame because institute's stress is larger in the environment that glue-injection machine works
It needs to be connected with rubber composition between frame, more tacit complexed metal frame being properly positioned in the bracket, to ensure glue-injection machine
Trouble free service.
Invention content
The purpose of the present invention is to provide a kind of high intensity, low deformation, it is easy to rubber composition with metal adhesive, this hair
Bright base rubber used is natural rubber（SCR5）And reclaimed rubber（T-NF1）, vulcanizing system used is sulfur cross-linking body
System, obtained rubber composition properties can be up to state standards and intensity is high, deformation is low, be easy to and metal adhesive.
The purpose of the present invention is what is be achieved through the following technical solutions：
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the composition rubber is SCR5 natural rubbers
With the composition of T-NF1 reclaimed rubbers；It is grouped as by the group of following parts by weight meter：
100 parts of rubber；1 ~ 3 part of mineral reserve filler；1.5 ~ 2.5 parts of organic active agent；4.5 ~ 6 parts of inorganic active agent；Dispersant 1.5 ~ 3
Part；1.5 ~ 2.5 parts of naphthylamine antioxidant；3 parts of plasticizer；30 ~ 45 parts of reinforcing agent；1.0 ~ 1.5 parts of thiazole accelerator；Vulcanizing agent
2 ~ 2.5 parts.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the mineral reserve filler is oxidation
Iron oxide red.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the organic active agent is hard
Resin acid.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the inorganic active agent is oxygen
Change zinc.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the dispersant is dispersant
RDP-100。
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the naphthylamine antioxidant is
N- phenyl-1-naphthylamines（Antioxidant A）With N- phenyl-2-naphthylamines（Antioxidant D）Composition.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the plasticizer is adjacent benzene two
Formic acid dibutyl ester（DOP）.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the reinforcing agent is carbon black.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the thiazole accelerator is
2-steryl benzothiazole（Captax）With 2,2'- dithio-bis-benzothiazoles（Altax）Composition.
A kind of high intensity, low deformation are easy to rubber composition with metal adhesive, and the vulcanizing agent is sulphur.
Advantages of the present invention is with effect：
1. the matrix used rubber of the present invention is natural rubber（SCR5）And reclaimed rubber（T-NF1）Composition, with its complex
Intensity is high after forming rubber composition, and compression set is small, is easy to and metal adhesive, and reclaimed rubber is cheap and easy to get, fully
It realizes waste utilization, has critically important economic benefit and social benefit to energy saving.
The present invention is applied to after forming injecting glue machine support rubber composition with its complex, and intensity is high, compression set
It is small, it is easy to and metal adhesive, metal framework being properly positioned in the bracket in more tacit cooperation glue-injection machine, and reclaimed rubber valence
It is honest and clean to be easy to get, it fully realizes waste utilization, has critically important economic benefit and social benefit to energy saving.
Specific implementation mode
The following describes the present invention in detail with reference to examples.
Embodiment 1：
The present invention is applied to after forming injecting glue machine support rubber composition with its complex, and intensity is high, and compression set is small, easily
In with metal adhesive, metal framework being properly positioned in the bracket, injecting glue machine support rubber group in more tacit cooperation glue-injection machine
Object is closed, is grouped as by following group in parts by weight, is shown in Table 1：
Table 1：
Preparation method is as follows：
A. open mill roll spacing is adjusted to 1mm, first by thin logical 3 ~ 5 packet rollers of natural rubber, adds thin logical 3 ~ 5 packet rollers of reclaimed rubber.
B. zinc oxide, stearic acid, dispersant RDP-100, iron oxide red, antioxidant A, antioxidant D, accelerating agent are sequentially added
M and altax sequentially add carbon black N550 and N330 using beating after triangle bag method is kneaded uniformly, DOP are added, using beating
Triangle bag method is kneaded uniform rear addition sulphur, and uniformly rear bottom sheet is kneaded using triangle bag method is beaten；
C. after rubber compound is placed 24 hours, t is measured with vulcameter10、t90；
D. rubber compound is placed on 145 DEG C × 10Mpa vulcanizing presses and is vulcanized, then survey its performance.
The performance indicator of embodiment 1 is shown in Table 5.
Embodiment 2：
The present invention is applied to after forming injecting glue machine support rubber composition with its complex, and intensity is high, and compression set is small, easily
In with metal adhesive, metal framework being properly positioned in the bracket, injecting glue machine support rubber group in more tacit cooperation glue-injection machine
Object is closed, is grouped as by following group in parts by weight, is shown in Table 2：
Table 2：
The preparation method is the same as that of Example 1.The performance indicator of embodiment 2 is shown in Table 5.
Embodiment 3：
The present invention is applied to after forming injecting glue machine support rubber composition with its complex, and intensity is high, and compression set is small, easily
In with metal adhesive, metal framework being properly positioned in the bracket, injecting glue machine support rubber group in more tacit cooperation glue-injection machine
Object is closed, is grouped as by following group in parts by weight, is shown in Table 3：
Table 3：
The preparation method is the same as that of Example 1.The performance indicator of embodiment 3 is shown in Table 5.
Embodiment 4：
The present invention is applied to after forming injecting glue machine support rubber composition with its complex, and intensity is high, and compression set is small, easily
In with metal adhesive, metal framework being properly positioned in the bracket, injecting glue machine support rubber group in more tacit cooperation glue-injection machine
Object is closed, is grouped as by following group in parts by weight, is shown in Table 4.
Table 4：
The preparation method is the same as that of Example 1.The performance indicator of embodiment 4 is shown in Table 5.
Table 5：
Claims (10)
1. a kind of high intensity, low deformation are easy to rubber composition with metal adhesive, which is characterized in that the composition rubber
For the composition of SCR5 natural rubbers and T-NF1 reclaimed rubbers；It is grouped as by the group of following parts by weight meter：
100 parts of rubber；1 ~ 3 part of mineral reserve filler；1.5 ~ 2.5 parts of organic active agent；4.5 ~ 6 parts of inorganic active agent；Dispersant 1.5 ~ 3
Part；1.5 ~ 2.5 parts of naphthylamine antioxidant；3 parts of plasticizer；30 ~ 45 parts of reinforcing agent；1.0 ~ 1.5 parts of thiazole accelerator；Vulcanizing agent
2 ~ 2.5 parts.
2. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the mineral reserve filler is iron oxide red.
3. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the organic active agent is stearic acid.
4. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the inorganic active agent is zinc oxide.
5. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the dispersant is dispersant RDP-100.
6. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the naphthylamine antioxidant is N- phenyl-1-naphthylamines（Antioxidant A）With N- phenyl-2-naphthylamines（Antioxidant D）Combination
Object.
7. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the plasticizer is o-phthalic acid dibutyl ester（DOP）.
8. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the reinforcing agent is carbon black.
9. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the thiazole accelerator is 2-steryl benzothiazole（Captax）With 2,2'- dithio-bis-benzothiazoles（Promote
Agent DM）Composition.
10. a kind of high intensity according to claim 1, low deformation are easy to rubber composition with metal adhesive, feature
It is, the vulcanizing agent is sulphur.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810457116.6A CN108586840B (en) | 2018-05-14 | 2018-05-14 | High-strength low-deformation rubber composition easy to bond with metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810457116.6A CN108586840B (en) | 2018-05-14 | 2018-05-14 | High-strength low-deformation rubber composition easy to bond with metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108586840A true CN108586840A (en) | 2018-09-28 |
| CN108586840B CN108586840B (en) | 2020-08-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810457116.6A Active CN108586840B (en) | 2018-05-14 | 2018-05-14 | High-strength low-deformation rubber composition easy to bond with metal |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040135287A1 (en) * | 2003-01-14 | 2004-07-15 | Delphi Technologies Inc. | Method of forming a molded powertrain mount assembly |
| CN101575427A (en) * | 2008-11-17 | 2009-11-11 | 四川轮胎橡胶（集团）股份有限公司 | Sizing material of steel wire clip glue |
| CN102775651A (en) * | 2012-08-16 | 2012-11-14 | 中橡集团曙光橡胶工业研究设计院 | Sponge tire sponge rubber material containing butyl reclaimed rubber |
| CN104497377A (en) * | 2014-12-07 | 2015-04-08 | 青岛万盈橡胶科技有限公司 | Disc filling adhesive formula and production process thereof |
-
2018
- 2018-05-14 CN CN201810457116.6A patent/CN108586840B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040135287A1 (en) * | 2003-01-14 | 2004-07-15 | Delphi Technologies Inc. | Method of forming a molded powertrain mount assembly |
| CN101575427A (en) * | 2008-11-17 | 2009-11-11 | 四川轮胎橡胶（集团）股份有限公司 | Sizing material of steel wire clip glue |
| CN102775651A (en) * | 2012-08-16 | 2012-11-14 | 中橡集团曙光橡胶工业研究设计院 | Sponge tire sponge rubber material containing butyl reclaimed rubber |
| CN104497377A (en) * | 2014-12-07 | 2015-04-08 | 青岛万盈橡胶科技有限公司 | Disc filling adhesive formula and production process thereof |
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| Publication number | Publication date |
|---|---|
| CN108586840B (en) | 2020-08-07 |
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Effective date of registration: 20230629 Address after: No. 91-1 Tonggang Road, Dalian Economic and Technological Development Zone, Liaoning Province, 116600 Patentee after: DALIAN YIDA PRECISION RUBBER PRODUCTS CO.,LTD. Address before: 110142 No. 11 economic and Technological Development Zone, Liaoning, Shenyang Patentee before: SHENYANG University OF CHEMICAL TECHNOLOGY |