CN108570208A - A kind of low smell ABS composite material and preparation method thereof - Google Patents
A kind of low smell ABS composite material and preparation method thereof Download PDFInfo
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- CN108570208A CN108570208A CN201810441563.2A CN201810441563A CN108570208A CN 108570208 A CN108570208 A CN 108570208A CN 201810441563 A CN201810441563 A CN 201810441563A CN 108570208 A CN108570208 A CN 108570208A
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- abs
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of low smell ABS composite materials and preparation method thereof.The present invention is using ABS as base-material, heat-proof modifier, ABS high glue powders, odor adsorption agent, small molecule eliminating smell agent, acid absorbent, antioxidant, lubricant is added, it is good to obtain a kind of low smell, mechanical performance and heat resistance, the simple ABS composite material of processing technology；Preparation method is that various raw materials are placed into melting extrusion in double screw extruder and be granulated through being mixed in homogenizer.The ABS composite material production cost is low, and market prospects are good, can be used for automobile and field of household appliances, such as inner and outer decorative parts of automobile and refrigerator, small household appliances.
Description
Technical field
The present invention relates to modified ABS fields, more particularly to a kind of low smell ABS composite material and preparation method thereof.
Background technology
Requirement of the automobile market to ABS at present is higher and higher, and the material standard of many medium-sized and small enterprises automobile factorys has reached
The standard of internationally renowned brand automobile factory.General ABS in the market cannot generally meet the needs of automobile vendor, especially not
Can meet the needs of automobile vendor's smell.
The material of automobile ABS generally requires to consider heatproof, toughness, and after heat-proof modifier and toughener is added, often
Smell is caused to become worse.For example heat-proof modifier and height is added between 3.5~4.0 in the oder levels of common ABS in the market
Smell is generally at 4~4.5 grades or so after rubber powder.
US6297307 discloses a kind of epoxy resin and oxide improve ABS smell method.But this mixture
Influence of the addition to the mechanical property especially impact property of material it is very big.
The ABS material of low smell, has been respectively adopted Kiselgel A and hydrophobicity disclosed in CN1730542 and CN1730543
Molecular sieve is as eliminating smell agent.But the smell source of modified ABS is various, first, ABS resin matrix is worked as in polymerization process
It is middle to remain some substances (such as emulsifier) with irritant peculiar smell；Secondly, modified ABS material was granulated in melting extrusion
There may be some odorous thermal cracking small molecules in journey；Again, the other ingredients added such as heat-proof modifier, toughening
Agent, stabilizer etc. also bring along certain smell problems.And single eliminating smell agent used by above-mentioned patent often exist it is larger
Limitation.
It is a discovery of the invention that adding odor adsorption agent, small molecule eliminating smell agent, acid absorbent in ABS, made using the collaboration of three
With, it can significantly improve the oder levels of ABS, and on other performances substantially without influence.
Invention content
The object of the present invention is to provide a kind of ABS materials of low smell, have collaboration more particularly to by addition
The smell remover of function of odor removal, to prepare a kind of ABS material of low smell.
In order to achieve the above object, the technical solution adopted in the present invention is a kind of low smell ABS composite material, parts by weights
Number meter, each group distribution ratio are as follows：
The ABS is emulsion polymer or bulk polymer, styrene-content 30~65% in ABS, acrylonitrile content 20
~35%, butadiene content 10~50%；Styrene-content 15~30% in the ABS high glue powders, acrylonitrile content 5~
20%, butadiene content 50~70%.
The heat-proof modifier is N-phenylmaleimide type heat-resisting ABS resin, and preferably the trade mark is Japanese electric apparatus chemistry
MS-NIP.
The odor adsorption agent is molecular sieve.Small molecule eliminating smell agent small-molecule substance volatile when being processing, than
Such as water, the small molecule that when production decomposes when can process ABS is taken out of, and oneself itself it is tasteless.The acid absorbent is oxidation
Object, such as magnesia, silica, zinc oxide.
The primary antioxidant selects four [β-(3,5- di-tert-butyl 4- hydroxy phenyls) propionic acid] pentaerythritol esters, the preferably trade mark
For the Irganox 1010 of Ciba production；Auxiliary anti-oxidant selects three (2,4- di-tert-butylphenol) phosphite esters, the preferably trade mark
For the Irganox 168 of Ciba production；Lubricant selection connects ethylene bis stearamide (EBS).
A kind of preparation method of low smell ABS composite material of the present invention, with following steps：
(1) by weight percentage, by ABS 70~100%, heat-proof modifier 2~40%, ABS high glue powders 2~30%,
Odor adsorption agent 0.1~2%, small molecule eliminating smell agent 0.05~0.2%, acid absorbent 0.05-0.5%, antioxidant 1010 0.1~
1%, 0.1~1% accurate weighing of irgasfos 168 0.1~1% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing；Wherein extruder barrel temperature 180~230
DEG C, 250~350 revs/min of screw speed.
Compared with prior art, the beneficial effects of the invention are as follows：
1, the molecular sieve odor adsorption agent that the present invention is added can adsorb the peculiar smell generated in ABS synthesis, granulation；
Acid absorbent can neutralize remaining emulsifier etc. in ABS productions；Small molecule eliminating smell agent promotes small molecule through vacuum port in processing
Discharge, to improve the oder levels of material.
2, the present invention in be added odor adsorption agent, small molecule eliminating smell agent, acid absorbent, three synergistic effect, can be substantially
Degree improves the oder levels of ABS, on other performances substantially without influence.
3, heat-proof modifier and toughener high glue powder are added in the present invention, to improve the temperature tolerance and toughness of material, with
Adapt to the needs of automobile market.
4, ABS composite material simple production process prepared by the present invention, at low cost, market prospects are good, can be used for automobile
And field of household appliances, such as inner and outer decorative parts of automobile and refrigerator, small household appliances.
Specific implementation mode
The present invention is further explained in the light of specific embodiments.In material used, odor adsorption agent choice of powder
Shape molecular sieve.Small molecule eliminating smell agent select distilled water, sour adsorbent selective oxidation zinc, antioxidant select Ciba 1010,
168, lubricant is the EBS of Malaysian Palm Corp.'s production.
Embodiment one
(1) by weight percentage, by ABS 82.8%, heat-proof modifier 10%, high glue powder 5%, molecular sieve 1%, water
0.05%, zinc oxide 0.5%, 0.3% accurate weighing of antioxidant 1010 0.2%, irgasfos 168 0.2% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing.Wherein extruder barrel temperature 200~230
DEG C, 300 revs/min of screw speed.
Embodiment two
(1) by weight percentage, by ABS 82.8%, heat-proof modifier 10%, high glue powder 5%, molecular sieve 1%, water
0.1%, zinc oxide 0.5%, 0.3% accurate weighing of antioxidant 1010 0.2%, irgasfos 168 0.2% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing.Wherein extruder barrel temperature 200~230
DEG C, 300 revs/min of screw speed.
Embodiment three
(1) by weight percentage, by ABS 82.8%, heat-proof modifier 10%, high glue powder 5%, molecular sieve 1%, water
0.2%, zinc oxide 0.5%, 0.3% accurate weighing of antioxidant 1010 0.2%, irgasfos 168 0.2% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing.Wherein extruder barrel temperature 200~230
DEG C, 300 revs/min of screw speed.
Comparative example one
(1) by weight percentage, by ABS 82.8%, heat-proof modifier 10%, high glue powder 5%, molecular sieve 1%, oxygen
Change zinc 0.5%, 0.3% accurate weighing of antioxidant 1010 0.2%, irgasfos 168 0.2% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing.Wherein extruder barrel temperature 200~230
DEG C, 300 revs/min of screw speed.
Comparative example two
(1) by weight percentage, by ABS 82.3%, heat-proof modifier 10%, high glue powder 5%, water 0.1%, oxidation
Zinc 0.5%, 0.3% accurate weighing of antioxidant 1010 0.2%, irgasfos 168 0.2% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing.Wherein extruder barrel temperature 200~230
DEG C, 300 revs/min of screw speed.
Comparative example three
(1) by weight percentage, by ABS 82.6%, heat-proof modifier 10%, high glue powder 5%, molecular sieve 1%, water
0.2%, 0.3% accurate weighing of antioxidant 1010 0.2%, irgasfos 168 0.2% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, twin-screw extrusion then is added in mixed material
Machine is got product through double screw extruder melting extrusion postcooling, drying, pelletizing.Wherein extruder barrel temperature 200~230
DEG C, 300 revs/min of screw speed.
As stated above by embodiment and comparative example gained particle 3~6h of drying in 90 DEG C of baking oven, then will dry
Good particle injects sample preparation on injection machine.Die temperance control is injection moulded at 35~45 DEG C.
Bending property test is carried out by GB/T9341-2008, and specimen size is 80 × 10 × 4mm, rate of bending 2mm/
Min, span 64mm；Test equipment is the XWW-20A type electronic universal testers of Chengde Jinjian Testing Instrument Co., Ltd.；
Notched Chalpy impact intensity is executed by GB/T1843-2008, and specimen size is 80 × 10 × 4mm, pendulum energy
5.5J, test equipment are the XC-22D radial-boom impact testers of Chengde Jinjian Testing Instrument Co., Ltd.；
Load deformation temperature is executed by testing standard GB/T1634.2-2004, and test equipment is that Chengde gold builds detector
The XRW-300M thermal deformation vicat softening point temperature analyzers of device Co., Ltd.
Oder levels test is executed by PV3900.
The formula and performance of embodiment one to three and comparative example one to three are relatively shown in Table 1.
The formula and performance of 1 embodiment one to three of table and comparative example one to three compare
From example 1~3 and the comparison of comparative example 1~3 as can be seen that while odor adsorption agent, acid absorbent and small molecule is added
The oder levels of eliminating smell agent, material can reach 2.5.Without one in aerating taste adsorbent, acid absorbent or small molecule eliminating smell agent
Kind, can all oder levels be caused to decline.
Low smell ABS composite material production cost prepared by the present invention is low, and market prospects are good, are particularly suitable for automobile
Field, while can also be applied to refrigerator, small household appliances etc..
The above-mentioned description to embodiment is that this hair can be understood and applied for the ease of those skilled in the art
It is bright.Man skilled in the art obviously can easily to these embodiments, various modifications may be made, and General Principle described herein
It is applied in other embodiments without having to go through creative labor.Therefore, the present invention is not limited to the embodiment of this fruit, this fields
Technical staff's announcement according to the present invention, not departing from improvement that scope is made and modification all should be in the protection of the present invention
Within the scope of.
Claims (4)
1. a kind of low smell ABS composite material, which is characterized in that score meter by weight, each group distribution ratio are as follows：
Wherein, the ABS is emulsion polymer or bulk polymer, styrene-content 30~65% in ABS, acrylonitrile content 20
~35%, butadiene content 10~50%；The heat-proof modifier is N-phenylmaleimide type heat-resisting ABS resin；It is described
Styrene-content 15~30% in ABS high glue powders, acrylonitrile content 5~20%, butadiene content 50~70%；The smell is inhaled
Attached dose is molecular sieve；The small molecule eliminating smell agent is water.
2. low smell ABS composite material according to claim 1, it is characterized in that：The acid absorbent refers to magnesia, oxygen
Change at least one of zinc, calcium oxide.
3. low smell ABS composite material according to claim 1, it is characterized in that：The primary antioxidant is four [β-(3,5-
Di-tert-butyl 4- hydroxy phenyls) propionic acid] pentaerythritol ester；The auxiliary anti-oxidant is three (2,4- di-tert-butylphenol) phosphite esters；
The lubricant is ethylene bis stearamide (EBS).
4. the preparation method of automobile ABS composite material according to claim 1 has following steps：
(1) by weight percentage, by ABS 70~100%, heat-proof modifier 2~40%, ABS high glue powders 2~30%, smell
Adsorbent 0.1~2%, small molecule eliminating smell agent 0.05~0.2%, acid absorbent 0.05-0.5%, antioxidant 1010 0.1~1%,
0.1~1% accurate weighing of irgasfos 168 0.1~1% and lubricant；
(2) 1~4min of high-speed mixer for dry mixing is added in above-mentioned material, double screw extruder then is added in mixed material,
It is got product through double screw extruder melting extrusion postcooling, drying, pelletizing；Wherein 180~230 DEG C of extruder barrel temperature,
250~350 revs/min of screw speed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810441563.2A CN108570208A (en) | 2018-05-10 | 2018-05-10 | A kind of low smell ABS composite material and preparation method thereof |
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| CN201810441563.2A CN108570208A (en) | 2018-05-10 | 2018-05-10 | A kind of low smell ABS composite material and preparation method thereof |
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| CN108570208A true CN108570208A (en) | 2018-09-25 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110128777A (en) * | 2019-06-04 | 2019-08-16 | 苏州银禧科技有限公司 | Low smell heat-resistant high impact-resistant ABS material of a kind of dumb light and preparation method thereof |
| CN112480593A (en) * | 2020-11-25 | 2021-03-12 | 北方华锦化学工业股份有限公司 | Heat-resistant low-odor bulk ABS composite material and preparation method thereof |
| CN112724585A (en) * | 2020-11-02 | 2021-04-30 | 上海普利特复合材料股份有限公司 | ABS modified material with low butadiene residual quantity and preparation method thereof |
| CN116574352A (en) * | 2023-06-26 | 2023-08-11 | 深圳市富恒新材料股份有限公司 | High-performance low-precipitation low-odor ABS material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110128777A (en) * | 2019-06-04 | 2019-08-16 | 苏州银禧科技有限公司 | Low smell heat-resistant high impact-resistant ABS material of a kind of dumb light and preparation method thereof |
| CN112724585A (en) * | 2020-11-02 | 2021-04-30 | 上海普利特复合材料股份有限公司 | ABS modified material with low butadiene residual quantity and preparation method thereof |
| CN112480593A (en) * | 2020-11-25 | 2021-03-12 | 北方华锦化学工业股份有限公司 | Heat-resistant low-odor bulk ABS composite material and preparation method thereof |
| CN116574352A (en) * | 2023-06-26 | 2023-08-11 | 深圳市富恒新材料股份有限公司 | High-performance low-precipitation low-odor ABS material and preparation method thereof |
| CN116574352B (en) * | 2023-06-26 | 2023-11-14 | 深圳市富恒新材料股份有限公司 | High-performance low-precipitation low-odor ABS material and preparation method thereof |
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