CN108559592A - 一种环保切削油及其制备方法和应用 - Google Patents

一种环保切削油及其制备方法和应用 Download PDF

Info

Publication number
CN108559592A
CN108559592A CN201810490976.XA CN201810490976A CN108559592A CN 108559592 A CN108559592 A CN 108559592A CN 201810490976 A CN201810490976 A CN 201810490976A CN 108559592 A CN108559592 A CN 108559592A
Authority
CN
China
Prior art keywords
environmental protection
cutting oil
protection cutting
oil
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810490976.XA
Other languages
English (en)
Inventor
颜炳姜
莫大卓
王勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Huizhuan Tools Co Ltd
Conprofe Technology Group Co Ltd
Original Assignee
Guangzhou Huizhuan Tools Co Ltd
Conprofe Technology Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Huizhuan Tools Co Ltd, Conprofe Technology Group Co Ltd filed Critical Guangzhou Huizhuan Tools Co Ltd
Priority to CN201810490976.XA priority Critical patent/CN108559592A/zh
Publication of CN108559592A publication Critical patent/CN108559592A/zh
Priority to CN201910136672.8A priority patent/CN109852457B/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23Q—DETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
    • B23Q11/00—Accessories fitted to machine tools for keeping tools or parts of the machine in good working condition or for cooling work; Safety devices specially combined with or arranged in, or specially adapted for use in connection with, machine tools
    • B23Q11/10—Arrangements for cooling or lubricating tools or work
    • B23Q11/1038—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality
    • B23Q11/1061—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality using cutting liquids with specially selected composition or state of aggregation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/0215—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C10M2207/2815—Esters of (cyclo)aliphatic monocarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C10M2207/2835—Esters of polyhydroxy compounds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C10M2207/2895—Partial esters containing free hydroxy groups used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种环保切削油及其制备方法和应用。这种环保切削油是由以下质量份的原料组成：合成酯30～50份；脂肪醇20～40份；聚α烯烃20～40份；抗氧剂1～2份；防锈剂1～2份；金属减活剂1～2份。同时也公开了这种环保切削油的制备方法。还公开了一种使用该环保切削油进行金属切削加工的方法。本发明的切削油润滑性能优异，抗氧化性能好，可生物降解，对人体和生态环境无毒无害，符合相关环境指标要求。

Description

一种环保切削油及其制备方法和应用
技术领域
本发明涉及一种环保切削油及其制备方法和应用。
背景技术
在金属的切削加工中，工件与刀具，刀具与切屑之间会产生大量的摩擦并且产生大量热量，为了减少摩擦，提高切削效率，提高工件的精度和降低工件表面的粗糙度，延长刀具使用寿命，通常配合使用切削液或者使用切削油。
随着工件材料超硬化和多样化的发展，金属加工难度越来越高，对切削油性能的要求也日益提高。
传统的切削油生物降解性能差，生态成本高，随着人们环保意识的不断提高，要求切削油除了具备良好的性能外，还必须对环境无污染，对人体无害。
发明内容
本发明的目的在于提供一种环保切削油及其制备方法和应用。
本发明所采取的技术方案是：
一种环保切削油，是由以下质量份的原料组成：
环保切削油中，合成酯为季戊四醇四油酸酯、三羟甲基丙烷油酸酯、新戊二醇油酸酯、硬脂酸异辛酯、油酸异辛酯中的至少一种。
环保切削油中，脂肪醇为碳原子数6～24的脂肪醇。
环保切削油中，聚α烯烃为PAO4。
环保切削油中，抗氧剂为酚类抗氧剂、烷基苯胺类抗氧剂中的至少一种。
环保切削油中，防锈剂为苯并三氮唑、2-巯基苯并噻唑中的至少一种。
环保切削油中，金属减活剂为噻二唑衍生物、***衍生物中的至少一种。
这种环保切削油的制备方法，包括以下步骤：
1)按上述的组成称取原料，将合成酯、脂肪醇和聚α烯烃，混合搅拌，得到基础油；
2)将基础油加热搅拌，加入抗氧剂、防锈剂和金属减活剂，混合搅拌，得到粗油品；
3)将粗油品过滤，得到环保切削油。
制备方法的步骤2)具体为：将基础油加热至60℃～100℃搅拌，加入抗氧剂、防锈剂和金属减活剂，混合搅拌均匀，然后降温至50℃以下，停止搅拌，得到粗油品。
一种金属的切削加工方法，是使用这种环保切削油进行油雾润滑加工。
本发明的有益效果是：
本发明的切削油润滑性能优异，抗氧化性能好，可生物降解，对人体和生态环境无毒无害，符合相关环境指标要求。
本发明的切削油产品对人体和生态环境无毒无害，符合相关环境指标要求，润滑性和氧化稳定性优异，通用性强，适合于大部分材质的金属切削加工，特别适用于半干式和微量润滑加工，主要用于油雾润滑。气液两相的油雾既能起到润滑作用，又能带走大量的热量，还能减少切削液的使用量，降低成本，减少废液排放，有利于环境保护。
具体实施方式
切削油由基础油和添加剂两部分组成，基础油是切削油的主要成分，起到主要润滑作用；添加剂则可改善切削油的使用性能。
一种环保切削油，是由以下质量份的原料组成：
优选的，环保切削油中，合成酯为季戊四醇四油酸酯、三羟甲基丙烷油酸酯、新戊二醇油酸酯、硬脂酸异辛酯、油酸异辛酯中的至少一种；进一步优选的，环保切削油中，合成酯为季戊四醇四油酸酯、三羟甲基丙烷油酸酯、硬脂酸异辛酯、油酸异辛酯以质量比4:3:1:1组成的混合物。
优选的，环保切削油中，脂肪醇为碳原子数6～24的脂肪醇；进一步优选的，环保切削油中，脂肪醇为异辛醇、正癸醇、月桂醇中的至少一种；再进一步优选的，环保切削油中，脂肪醇为异辛醇、正癸醇、月桂醇以质量比4:3:3组成的混合物。
优选的，环保切削油中，聚α烯烃(PAO)为PAO4。
优选的，环保切削油中，抗氧剂为酚类抗氧剂、烷基苯胺类抗氧剂中的至少一种；进一步优选的，环保切削油中，抗氧剂为2,6-二叔丁基对甲酚、液态辛基丁基二苯胺、高分子量酚类抗氧剂中的至少一种。
优选的，环保切削油中，防锈剂为苯并三氮唑、2-巯基苯并噻唑中的至少一种；进一步优选的，环保切削油中，防锈剂为苯并三氮唑和2-巯基苯并噻唑以质量比1:1组成的混合物。
优选的，环保切削油中，金属减活剂为噻二唑衍生物、***衍生物中的至少一种；进一步优选的，环保切削油中，金属减活剂为噻二唑衍生物与***衍生物以质量比1:1组成的混合物。
这种环保切削油的制备方法，包括以下步骤：
1)按上述的组成称取原料，将合成酯、脂肪醇和聚α烯烃，混合搅拌，得到基础油；
2)将基础油加热搅拌，加入抗氧剂、防锈剂和金属减活剂，混合搅拌，得到粗油品；
3)将粗油品过滤，得到环保切削油。
制备方法的步骤2)具体为：将基础油加热至60℃～100℃搅拌，加入抗氧剂、防锈剂和金属减活剂，混合搅拌均匀，然后降温至50℃以下，停止搅拌，得到粗油品。
一种金属的切削加工方法，是使用这种环保切削油进行油雾润滑加工。
进一步的，油雾润滑加工是指将环保切削油以油雾气体方式进行切削冷却。
油雾润滑加工方法是指微量润滑切削技术，这是一种典型的准干式切削方法，是指将压缩气体(空气、氮气、二氧化碳等)与极微量的润滑剂混合汽化，形成微米级的液滴，喷射到加工区进行有效润滑的一种切削加工方法。
以下通过具体的实施例对本发明的内容作进一步详细的说明。实施例中所用的原料如无特殊说明，均可从常规商业途径得到。
实施例1～5中，所用合成酯为季戊四醇四油酸酯、三羟甲基丙烷油酸酯、硬脂酸异辛酯、油酸异辛酯以质量比4:3:1:1组成的混合物；脂肪醇为异辛醇、正癸醇、月桂醇以质量比4:3:3组成的混合物；聚α烯烃为PAO4；抗氧剂为2,6-二叔丁基对甲酚；防锈剂为苯并三氮唑和2-巯基苯并噻唑以质量比1:1组成的混合物；金属减活剂为噻二唑衍生物与***衍生物以质量比1:1组成的混合物。
实施例1：
实施例1的环保切削油包括以下质量份数的原料：合成酯40份，脂肪醇22份，聚α烯烃35份，抗氧剂1份，防锈剂1份，金属减活剂1份。
实施例1环保切削油的制备方法，步骤如下：
1)按照质量份数称取原料，先将合成酯、脂肪醇和聚α烯烃放入调配釜中混合，搅拌，得到基础油；
2)将步骤1)得到的基础油升温搅拌，升温至60℃～100℃，加入抗氧剂，防锈剂，金属减活剂搅拌，然后降温至50℃以下，停止搅拌；
3)将步骤2)得到的油品进行过滤，得到切削油成品。
实施例2：
实施例2的环保切削油包括以下质量份数的原料：合成酯35份，脂肪醇32份，聚α烯烃30份，抗氧剂1份，防锈剂1份，金属减活剂1份。
实施例2环保切削油的制备方法与实施例1的相同。
实施例3：
实施例3的环保切削油包括以下质量份数的原料：合成酯30份，脂肪醇35份，聚α烯烃30份，抗氧剂1份，防锈剂1份，金属减活剂1份。
实施例3环保切削油的制备方法与实施例1的相同。
实施例4：
实施例4的环保切削油包括以下质量份数的原料：合成酯37份，脂肪醇30份，聚α烯烃30份，抗氧剂1份，防锈剂1份，金属减活剂1份。
实施例4环保切削油的制备方法与实施例1的相同。
实施例5：
实施例5的环保切削油包括以下质量份数的原料：合成酯35份，脂肪醇21份，聚α烯烃40份，抗氧剂1份，防锈剂1份，金属减活剂2份。
实施例5环保切削油的制备方法与实施例1的相同。
应用：
使用切削油对金属进行油雾润滑加工测试。加工的机床设备为FANUC robodrillα-D21MiA，材料的夹持方式为虎钳装夹。加工刀柄的型号为BT30-SKA183-90HF，加工的刀具为钨钢端铣刀，直径为6mm，刃数为4。切削所用的材料为钴铬钼合金，采用开粗的形式加工，铣削方式包括立铣、顺铣和逆铣，切削的要求是加工人体骨骼，各尺寸公差控制在0.01mm以内。具体测试步骤为：先加工29mm直径圆形面，然后在此基础上加工1mm深，20mm直径型腔，装刀长度为25mm。测试A使用的是实施例1的环保切削油进行外部喷雾。测试B使用的是外购的普通切削油进行外部喷雾，测试C使用的是普通乳化液进行液体冷却。表1为测试参数和测试结果。
表1测试参数和结果
测试A 测试B 测试C
冷却方式 外部喷雾 外部喷雾 液体冷却
主轴转速S 3000r/min 3000r/min 2150r/min
切削速度V 56.52m/min 56.52m/min 56.52m/min
进给量F 195mm/min 195mm/min 120mm/min
铣削宽度 3mm 3mm 3mm
背吃刀量 0.05mm 0.05mm 0.05mm
表面光洁度 Ra0.131μm Ra0.211μm Ra0.241μm
从表1的测试数据可以看出，使用实施例1的环保切削油进行外部喷雾，产品的表面光洁度要明显优于使用普通切削油和传统乳化液加工出来的产品。
使用实施例1的环保切削油通过油雾润滑加工的方式分别加工AL6063、SUS316L和陶瓷(高强度氧化锆结合氧化铝)，其刀具寿命测试数据如表2所示。
表2实施例1处理各种材料刀具寿命数据
材料 AL6063 SUS316L 陶瓷
切削深度(mm) 12 15 5
刀具直径(mm) 6 10 6
精修切削量(mm) 0.1 0.1 0.015
转速(r/min) 10000 7000 12000
精加工进给量(mm/min) 3000 5000 500
刀具寿命(米) 835 980 180
使用普通乳化液通过液体冷却的方式分别加工AL6063、SUS316L和陶瓷(高强度氧化锆结合氧化铝)，其刀具寿命测试数据如表3所示。
表3普通液处理各种材料刀具寿命数据
从以上测试结果可知，本发明制备的切削油性能与传统的水基型乳化液相比，具有良好的润滑性，可大大提高加工效率，并延长刀具使用寿命。
与现有技术相比，本发明的切削油具有以下的优点：(1)润滑性能优异；(2)抗氧化稳定性良好；(3)可生物降解，对人体和环境无毒无害。

Claims (10)

1.一种环保切削油，其特征在于：由以下质量份的原料组成：
2.根据权利要求1所述的一种环保切削油，其特征在于：合成酯为季戊四醇四油酸酯、三羟甲基丙烷油酸酯、新戊二醇油酸酯、硬脂酸异辛酯、油酸异辛酯中的至少一种。
3.根据权利要求1所述的一种环保切削油，其特征在于：脂肪醇为碳原子数6～24的脂肪醇。
4.根据权利要求1所述的一种环保切削油，其特征在于：聚α烯烃为PAO4。
5.根据权利要求1所述的一种环保切削油，其特征在于：抗氧剂为酚类抗氧剂、烷基苯胺类抗氧剂中的至少一种。
6.根据权利要求1所述的一种环保切削油，其特征在于：防锈剂为苯并三氮唑、2-巯基苯并噻唑中的至少一种。
7.根据权利要求1所述的一种环保切削油，其特征在于：金属减活剂为噻二唑衍生物、***衍生物中的至少一种。
8.一种环保切削油的制备方法，其特征在于：包括以下步骤：
1)按权利要求1～7任一项所述的组成称取原料，将合成酯、脂肪醇和聚α烯烃，混合搅拌，得到基础油；
2)将基础油加热搅拌，加入抗氧剂、防锈剂和金属减活剂，混合搅拌，得到粗油品；
3)将粗油品过滤，得到环保切削油。
9.根据权利要求8所述的一种环保切削油的制备方法，其特征在于：步骤2)具体为：将基础油加热至60℃～100℃搅拌，加入抗氧剂、防锈剂和金属减活剂，混合搅拌均匀，然后降温至50℃以下，停止搅拌，得到粗油品。
10.一种金属的切削加工方法，其特征在于：使用权利要求1～7任一项所述的环保切削油进行油雾润滑加工。
CN201810490976.XA 2018-05-21 2018-05-21 一种环保切削油及其制备方法和应用 Withdrawn CN108559592A (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201810490976.XA CN108559592A (zh) 2018-05-21 2018-05-21 一种环保切削油及其制备方法和应用
CN201910136672.8A CN109852457B (zh) 2018-05-21 2019-02-25 一种环保切削油及其制备方法和应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810490976.XA CN108559592A (zh) 2018-05-21 2018-05-21 一种环保切削油及其制备方法和应用

Publications (1)

Publication Number Publication Date
CN108559592A true CN108559592A (zh) 2018-09-21

Family

ID=63539417

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201810490976.XA Withdrawn CN108559592A (zh) 2018-05-21 2018-05-21 一种环保切削油及其制备方法和应用
CN201910136672.8A Active CN109852457B (zh) 2018-05-21 2019-02-25 一种环保切削油及其制备方法和应用

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201910136672.8A Active CN109852457B (zh) 2018-05-21 2019-02-25 一种环保切削油及其制备方法和应用

Country Status (1)

Country Link
CN (2) CN108559592A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111088103A (zh) * 2019-12-24 2020-05-01 南京科润工业介质股份有限公司 一种环保型刀具磨削油

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628493B (zh) * 2019-10-01 2021-09-21 中科孚迪科技发展有限公司 一种高抗氧化性微量润滑切削油及其制备方法和应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2172412B1 (es) * 2000-07-21 2003-10-01 Nueva Fl Iberica S A Procedimiento para la preparacion de fluidos lubrificantes de corte.
CN1197942C (zh) * 2002-03-29 2005-04-20 中国石油化工股份有限公司 极压抗磨复合剂浓缩物及其使用方法
SG10201404267UA (en) * 2006-04-24 2014-10-30 Lubrizol Corp Star Polymer Lubricating Composition
CN101654636A (zh) * 2009-09-14 2010-02-24 上海金兆节能科技有限公司 一种生物型微量润滑油及其制备方法和应用
CN102031190A (zh) * 2010-12-28 2011-04-27 东莞太平洋博高润滑油有限公司 一种切削油及其制备方法
CN102250673B (zh) * 2011-06-15 2013-04-10 启东尤希路化学工业有限公司 高润滑、高渗透性环境友好型金属加工用乳化切削油
CN104911004A (zh) * 2015-06-19 2015-09-16 司徒建辉 一种高性能极压抗磨乳化切削油
CN106544077B (zh) * 2016-11-04 2017-12-12 青岛冠军石油化学有限公司 一种酯类组合物及其在润滑油中的应用
CN107629831A (zh) * 2017-09-22 2018-01-26 东莞安默琳机械制造技术有限公司 一种用于低温微量润滑的切削油

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111088103A (zh) * 2019-12-24 2020-05-01 南京科润工业介质股份有限公司 一种环保型刀具磨削油
CN111088103B (zh) * 2019-12-24 2021-12-03 南京科润工业介质股份有限公司 一种环保型刀具磨削油

Also Published As

Publication number Publication date
CN109852457A (zh) 2019-06-07
CN109852457B (zh) 2022-05-17

Similar Documents

Publication Publication Date Title
Lawal et al. Application of vegetable oil-based metalworking fluids in machining ferrous metals—a review
CN108929764B (zh) 一种半合成不锈钢切削液及其制备方法
Virdi et al. Performance Evaluation of Inconel 718 under vegetable oils based nanofluids using Minimum Quantity Lubrication Grinding
CN103865617B (zh) 一种润滑切削剂及其制备方法
CN105154187A (zh) 一种可替代油品的乳化液及其制备方法
CN109852457A (zh) 一种环保切削油及其制备方法和应用
Suarez et al. MoS2 solid lubricant application in turning of AISI D6 hardened steel with PCBN tools
EP2003190A9 (en) Oil composition for metal working, method for metal working, and metal work
US10633611B2 (en) Water-soluble metal working oil agent
CN101965393A (zh) 精密冲裁加工用润滑油组合物
CN104711106B (zh) 一种有效降低钛合金高速切削刀具磨损的切削液
RU2597599C1 (ru) Концентрат смазочно-охлаждающей жидкости
CN106929137A (zh) 全合成切削液
KR20090015142A (ko) 금속 가공 오일제 조성물, 금속 가공 방법 및 금속 가공품
Nurul Adlina et al. A Study of Surface Roughness & Surface Integrity in Drilling Process Using Various Vegetable–Oil Based Lubricants In Minimum Quantity Lubrication
JP5280713B2 (ja) 金属加工油組成物
Boswell et al. Feasibility study of adopting minimal quantities of lubrication for end milling aluminium
CN104830492A (zh) 切削液
Deshpande et al. A review on sustainable eco-friendly cutting fluids
CN104046419A (zh) 一种镁铝合金拉丝用润滑油
JPH08501119A (ja) 無アミン冷却潤滑剤
CN107674744A (zh) 一种环保型冷锻压油及其制备方法
CN107523388A (zh) 一种环保切削油及其制备方法
WO2021128618A1 (zh) 一种环保型刀具磨削油
CN107573994A (zh) 一种具有防锈效果的金属切削油

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180921

WW01 Invention patent application withdrawn after publication