CN108559552A - A kind of naturally military bio-fuel and preparation method thereof - Google Patents

A kind of naturally military bio-fuel and preparation method thereof Download PDF

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Publication number
CN108559552A
CN108559552A CN201810219377.4A CN201810219377A CN108559552A CN 108559552 A CN108559552 A CN 108559552A CN 201810219377 A CN201810219377 A CN 201810219377A CN 108559552 A CN108559552 A CN 108559552A
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fuel
bio
military
natural
preparation
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CN201810219377.4A
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车春玲
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Jiangxi Taid New Energy Co Ltd
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Jiangxi Taid New Energy Co Ltd
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Priority to CN201810219377.4A priority Critical patent/CN108559552A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/06Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0461Fractions defined by their origin
    • C10L2200/0469Renewables or materials of biological origin
    • C10L2200/0476Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention belongs to bio-fuel technical fields, and in particular to a kind of natural military bio-fuel further relates to the preparation method of above-mentioned military bio-fuel.The military bio-fuel of the present invention, the fuel are obtained by the following method:By the compound enzymatic treatment cyanobacteria formed with cellulase, pectase and microalgae, microbial fermentation zymolyte is then used again, is distilled the fermentate of gained, is obtained bio-fuel;The composite bacteria agent that used microorganism is made of photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus.The bio-fuel of the present invention, calorific value are high, and due in the fuel quite a few raw material be derived from the enzymolysis and biofermentation of cyanobacteria or microalgae, cost is relatively low, has larger application value.

Description

A kind of naturally military bio-fuel and preparation method thereof
Technical field
The invention belongs to bio-fuel technical fields, and in particular to a kind of natural military bio-fuel further relates to above-mentioned The preparation method of military bio-fuel.
Background technology
Bio-fuel refers to the solid, liquid or gaseous fuel for being made of or converting organism.It is regenerative resource exploitation profit Important directions have good storing properties and rodability, it is possible to provide the liquid fuel of alternative oil.The life of narrow sense Object fuel only refers to liquid biofuel, includes mainly alcohol fuel, biodiesel and aviation bio-fuel etc..
It since the 1970s, has been influenced by traditional energy price, environmental protection and Global climate change, countries in the world are increasingly Pay attention to the development of bio-fuel.Especially Brazil, the U.S., European Union etc. actively develop bio-fuel technology, currently, the U.S. and Brazil It is the first in the world, the second bio-fuel producing country respectively.China is the corn searching for digesting grain in storage for years and being high yield at the end of the 20th century New outlet starts to promote alcohol fuel.It is at present the sound development of promotion bio-fuel industry, the emphasis of China's research and development mainly collects In using the starchiness such as cassava, sugar grass or saccharic non-grain crop and lignocellulosic as the biological liquid fuel skill of raw material Art.
Bio-fuel all has diversity on raw material and product.It is remaining that bio-fuel can utilize crop material, forestry to process Organic wastewater waste residue, the municipal refuse of object, feces of livestock and poultry, food processing industry are also planted using low-quality soil various Energy-source plant.Bio-fuel has the bio-ethanol and diesel oil of liquid, solid prototype and shaped fuel, gaseous biogas etc. a variety of Energy products.Both oil, coal and natural gas can be substituted, it can also be for heat and generating power.
Bio-fuel has recyclability and the feature of environmental protection.Bio-fuel is in the innoxious of agricultural and town and country organic waste With the product produced during recycling;The biology that whole living matters of bio-fuel can enter the earth recycles, The carbon dioxide of release also can be absorbed by plants and participate in the cycle of the earth again, accomplish zero-emission.Indissolubility on substance, Recyclability in resource is a kind of Advanced Production Paradigms Towards in modern times.
Bio-fuel has drive property.Bio-fuel can expand agricultural production, drive rural economic development, increase Farmers' income;It can also promote manufacturing industry, construction industry, automobile and other industries development.Develop bio-fuel in China etc., can also promote agriculture Industry industrializes and Small Urban development, reduces the difference between industry and agriculture, has important our economy, our society and our politics' meaning.
Invention content
In order to solve the above technical problems, it the present invention provides a kind of natural military bio-fuel, further relates to above-mentioned The preparation method of military bio-fuel.
Natural military bio-fuel provided by the present invention, the fuel are obtained by the following method:
A kind of natural military bio-fuel, the fuel are obtained by the following method:
By the compound enzymatic treatment cyanobacteria formed with cellulase, pectase and microalgae, microbial fermentation enzyme is then used again Object is solved, the fermentate of gained is distilled, obtains microbial fermentation enzymolysis liquid;
Used microorganism is answered by what photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus formed Combined bacteria agent.
Preferably, cellulase, pectase dosage be 1-4:2-5.
Cellulase, pectase dosage be 3:2.
Photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus weight ratio be 1-4:2-3:1-3: 1-4:1-3:2-4.
The preparation method of natural military bio-fuel, including following steps:
Methanol or ethyl alcohol and lye is added into mixing channel, mixes, stirs evenly, then by vegetable oil be uniformly mixed Material, which is placed in reactor, to react, stratified liquid, obtains glycerine and ester phase, steams methyl alcohol process, and petroleum ether and washing oil, liquid phase is added Layering, oil phase is dried, and is steamed petroleum ether, is obtained product biodiesel;
Then the fuel given birth to microbial fermentation enzymolysis liquid mixes.
The volume ratio of methanol or ethyl alcohol and lye is 1-4:2-3;Lye is sodium hydroxide or potassium hydroxide;
The mass concentration of lye is 4-6%.
Vegetable oil is biodiesel of the gutter oil as obtained by refining.
Petroleum ether is 3-6 with the volume ratio of methanol or ethyl alcohol:1-2.
The beneficial effects of the present invention are method using the present invention prepares the natural military bio-fuel of gained, heat Value is high, and due in the fuel quite a few raw material be derived from the enzymolysis and biofermentation of cyanobacteria or microalgae, cost is relatively low, It, can be by absorbing sunlight, carbon dioxide and since cyanobacteria or microalgae possess relatively high photon conversion efficiency The rapid synthesising biological matter of abundant natural resources with inorganic nutrient substance etc..
Cyanobacteria or microalgae are simple in structure, growth is rapid, it produces bio-fuel economically feasible, have larger popularization and application Value.
Specific implementation mode
The present invention is further described with reference to specific embodiment, so that those skilled in the art knows more about The present invention, but be not intended to limit the present invention.
Embodiment 1
A kind of natural military bio-fuel, the fuel are obtained by the following method:
By the compound enzymatic treatment cyanobacteria formed with cellulase, pectase and microalgae, microbial fermentation enzyme is then used again Object is solved, the fermentate of gained is distilled, obtains microbial fermentation enzymolysis liquid;
Used microorganism is answered by what photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus formed Combined bacteria agent.
Cellulase, pectase dosage be 3:2.
Photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus weight ratio be 3:2:2:2:2:3.
The preparation method of natural military bio-fuel, including following steps:
Methanol or ethyl alcohol and lye is added into mixing channel, mixes, stirs evenly, then by vegetable oil be uniformly mixed Material, which is placed in reactor, to react, stratified liquid, obtains glycerine and ester phase, steams methyl alcohol process, and petroleum ether and washing oil, liquid phase is added Layering, oil phase is dried, and is steamed petroleum ether, is obtained product biodiesel;
Then the fuel given birth to microbial fermentation enzymolysis liquid mixes.
The volume ratio of methanol or ethyl alcohol and lye is 3:2;Lye is potassium hydroxide;
The mass concentration of lye is 5%.
Vegetable oil is biodiesel of the gutter oil as obtained by refining.
Petroleum ether is 4 with the volume ratio of methanol or ethyl alcohol:1.5.
Embodiment 2
Natural military bio-fuel, the fuel are obtained by the following method:
By the compound enzymatic treatment cyanobacteria formed with cellulase, pectase and microalgae, microbial fermentation enzyme is then used again Object is solved, the fermentate of gained is distilled, obtains microbial fermentation enzymolysis liquid;
Used microorganism is answered by what photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus formed Combined bacteria agent.Cellulase, pectase dosage be 2:3.
Photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus weight ratio be 4:2:2:3:2:3.
The preparation method of natural military bio-fuel, including following steps:
Methanol or ethyl alcohol and lye is added into mixing channel, mixes, stirs evenly, then by vegetable oil be uniformly mixed Material, which is placed in reactor, to react, stratified liquid, obtains glycerine and ester phase, steams methyl alcohol process, and petroleum ether and washing oil, liquid phase is added Layering, oil phase is dried, and is steamed petroleum ether, is obtained product biodiesel;
Then the fuel given birth to microbial fermentation enzymolysis liquid mixes.
The volume ratio of methanol or ethyl alcohol and lye is 3:2;Lye is potassium hydroxide;
The mass concentration of lye is 5%.
Vegetable oil is biodiesel of the gutter oil as obtained by refining.
Petroleum ether is 4 with the volume ratio of methanol or ethyl alcohol:1.5.
Embodiment 3
Natural military bio-fuel, the fuel are obtained by the following method:
By the compound enzymatic treatment cyanobacteria formed with cellulase, pectase and microalgae, microbial fermentation enzyme is then used again Object is solved, the fermentate of gained is distilled, obtains microbial fermentation enzymolysis liquid;
Used microorganism is answered by what photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus formed Combined bacteria agent.Cellulase, pectase dosage be 2:3.
Photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus weight ratio be 4:2:2:3:2:3.
The preparation method of natural military bio-fuel, including following steps:
Methanol or ethyl alcohol and lye is added into mixing channel, mixes, stirs evenly, then by vegetable oil be uniformly mixed Material, which is placed in reactor, to react, stratified liquid, obtains glycerine and ester phase, steams methyl alcohol process, and petroleum ether and washing oil, liquid phase is added Layering, oil phase is dried, and is steamed petroleum ether, is obtained product biodiesel;
Then the fuel given birth to microbial fermentation enzymolysis liquid mixes.
The volume ratio of methanol or ethyl alcohol and lye is 1:2;Lye is sodium hydroxide;
The mass concentration of lye is 5%.
Vegetable oil is biodiesel of the gutter oil as obtained by refining.
Petroleum ether is 5 with the volume ratio of methanol or ethyl alcohol:1.5.

Claims (8)

1. a kind of natural military bio-fuel, the fuel are obtained by the following method:
By the compound enzymatic treatment cyanobacteria formed with cellulase, pectase and microalgae, microbial fermentation enzyme is then used again Object is solved, the fermentate of gained is distilled, obtains microbial fermentation enzymolysis liquid;
Used microorganism is answered by what photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus formed Combined bacteria agent.
2. a kind of natural military bio-fuel as described in claim 1, it is characterised in that:
Cellulase, pectase dosage be 1-4:2-5.
3. a kind of natural military bio-fuel as described in claim 1, it is characterised in that:
Cellulase, pectase dosage be 3:2.
4. a kind of natural military bio-fuel as described in claim 1, it is characterised in that:
Photosynthetic bacteria, saccharomycete, lactic acid bacteria, whiterot fungi, nitrobacteria, bacillus weight ratio be 1-4:2-3:1-3:1-4: 1-3:2-4.
5. a kind of preparation method of natural military bio-fuel as described in claim 1, including following steps:
Methanol or ethyl alcohol and lye is added into mixing channel, mixes, stirs evenly, then by vegetable oil be uniformly mixed Material, which is placed in reactor, to react, stratified liquid, obtains glycerine and ester phase, steams methyl alcohol process, and petroleum ether and washing oil, liquid phase is added Layering, oil phase is dried, and is steamed petroleum ether, is obtained product biodiesel;
Then the fuel given birth to microbial fermentation enzymolysis liquid mixes.
6. a kind of preparation method of natural military bio-fuel as claimed in claim 5, which is characterized in that
The volume ratio of methanol or ethyl alcohol and lye is 1-4:2-3;Lye is sodium hydroxide or potassium hydroxide;
The mass concentration of lye is 4-6%.
7. a kind of preparation method of natural military bio-fuel as claimed in claim 5, which is characterized in that vegetable oil is trench Biodiesel of the oil as obtained by refining.
8. a kind of preparation method of natural military bio-fuel as claimed in claim 5, which is characterized in that petroleum ether and methanol Or the volume ratio of ethyl alcohol is 3-6:1-2.
CN201810219377.4A 2018-03-16 2018-03-16 A kind of naturally military bio-fuel and preparation method thereof Withdrawn CN108559552A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115449409A (en) * 2022-10-19 2022-12-09 中润油新能源股份有限公司 Microbial fermentation methanol gasoline and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115449409A (en) * 2022-10-19 2022-12-09 中润油新能源股份有限公司 Microbial fermentation methanol gasoline and preparation method thereof

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Application publication date: 20180921