CN108559400A - A kind of radiation protection water paint - Google Patents
A kind of radiation protection water paint Download PDFInfo
- Publication number
- CN108559400A CN108559400A CN201810019509.9A CN201810019509A CN108559400A CN 108559400 A CN108559400 A CN 108559400A CN 201810019509 A CN201810019509 A CN 201810019509A CN 108559400 A CN108559400 A CN 108559400A
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- radiation protection
- reaction kettle
- agent
- water paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention discloses a kind of radiation protection water paints, include the component of following parts by weight:0.3 0.5 parts of aqueous 45 60 parts of ordor removing radiation protection lotion, 0.1 0.3 parts of cellulose, 0.1 0.3 parts of wetting agent, 10 20 parts of deionized water, 0.1 0.3 parts of amine neutralizer, 0.2 0.6 parts of antifoaming agent, 0.2 0.4 parts of polyphosphate, 0.3 0.8 parts of levelling agent, 10 15 parts of antifreezing agent, 10 15 parts of coalescents, 15.3 25 parts of color stuffing, 5 10 parts of blanc fixe, 35 parts of diatomite and thickener.The radiation protection water paint of the present invention, pollution-free, environmentally protective have good radiation-proof effect.
Description
Technical field
Invention belongs to radiation protection water paint field, and in particular to interior wall radiation protection water paint and its preparation
Method.
Background technology
With the development of economy, electronic product is more and more universal, they while bringing huge convenient for the mankind,
There is troubling one side, wherein the most of people's attention is exactly electromagnetic radiation, live under electromagnetic radiation for a long time,
People are easy insomnia and dreamful sleep.The problems such as failure of memory, therefore develop a kind of coating of radiation protection.To solve the problems, such as this.
CN 201610551635.X, disclose a kind of graphene radiation shielding coating, which has used graphene and conduction
Filler, surfactant and a large amount of solvent.However, radiation shielding coating of graphene has used a large amount of conduction to fill out in this
Material (that is, copper powder, aluminium powder, silver powder, nickel powder etc., especially copper powder, silver powder, belonging to heavy metal, does lacquering and be easy to cause secondary dirt
Dye.Injury is also be easy to cause to human body.) a large amount of solvent use, huge pollution can be brought to environment.And graphene is in stone
It is process on the basis of ink, belongs to a kind of mineral resources, it is a large amount of to exploit, first, it is be easy to cause the pollution of environment, and two, it makes
At the loosening on stratum.
CN 201510002765.3 discloses a kind of environment-friendly type radiation shielding coating, which avoids having used graphene, also
It is still to have used heavy metal powder.This is disagreeableness to environment and human body.
CN 201310577898.4 discloses a kind of interior wall radiation shielding coating and its feedstock composition, preparation method and answers
With.Although largely having used metal-coated fabric, metallic fiber worsted fabric, stainless steel fibre sliver, not used graphene,
It is not just detached from the covert substance of heavy metal still.
Radiation shielding coating disclosed in the above prior art, although solving electron radiation to a certain extent,
Major part all employs the fabric of heavy metal powder or metal, still, these radiation shielding coatings or does not use graphite
The textile fabric of alkene, heavy metal powder or heavy metal is all that can not play the role of radiation protection to a certain extent.
Invention content
In order to solve the above-mentioned technical problem, the object of the present invention is to provide a kind of radiation protection water paints, with anti-spoke
The effect of penetrating.
In order to solve the above technical problems, the present invention adopts the following technical scheme that:
A kind of radiation protection water paint, includes the component of following parts by weight:
45-60 parts of aqueous ordor removing radiation protection lotion, 0.1-0.3 parts of cellulose, 0.1-0.3 parts of wetting agent, deionized water 10-
20 parts, it is 0.1-0.3 parts of amine neutralizer, 0.2-0.6 parts of antifoaming agent, 0.2-0.4 parts of polyphosphate, 0.3-0.8 parts of levelling agent, antifreeze
10-15 parts of agent, 10-15 parts of coalescents, 15.3-25 parts of color stuffing, 5-10 parts of blanc fixe, 3-5 parts of diatomite and thickener
0.3-0.5 parts.
Further, the radiation protection water paint includes the component of following parts by weight:
Aqueous 50 parts of ordor removing radiation protection lotion, 0.2 part of cellulose, 0.2 part of wetting agent, 15 parts of deionized water, amine neutralizer
0.2 part, 0.4 part of antifoaming agent, 0.3 part of polyphosphate, 0.5 part of levelling agent, 12 parts of antifreezing agent, 12 parts of coalescents, color stuffing 20
Part, 8 parts of blanc fixe, 4 parts of diatomite and 0.4 part of thickener.
Further, the indispensable method of the aqueous ordor removing radiation protection lotion is as follows:
A, deionized water is added in reaction kettle A, is warming up to 50 DEG C, stirred with the speed of 100-200rpm, is slowly added to bar
Moral richness ordor removing lotion 959W, reactor pressure 7.8MPa;
B, by extracting tea polyphenols (as long as ingredient is flavanols) flavanol compound, anthocyanin class, flavonoids, Huang from tealeaves
Reaction kettle A is slowly added dropwise in the one or several kinds of ketols and phenolic acid class;
C, continue reaction kettle A being warming up to 80 DEG C, initiator hydrogen peroxide is added dropwise into reaction kettle A, keep it poly- with 959W
It closes, is cooled to room temperature.
Further, the tea polyphenols are the tea polyphenols extracted from tealeaves using post separation the preparation method technique.
Further, the tea polyphenols are the one of flavanol compound, anthocyanin class, flavonoids, flavonols and phenolic acid class
Kind is several.
Further, the tea polyphenols are flavanols, by being obtained by extraction in tealeaves.
Further, the antifoaming agent is Nuo Pu sections SN-154 or BASF A10;The polyphosphate is DOW731A;Institute
It is Yi Shiman TEXANOL to state coalescents;The color stuffing is titanium dioxide, water-washed kaoline, blanc fixe, kaolin and coarse whiting
In one or several kinds.
Further, the polyphosphate can be DOW731A.
Further, the coalescents are Yi Shiman TEXANOL, and main component is 2,2,4- trimethyls -1,3- penta
Monoisobutyrate.
Further, the color stuffing is one kind in titanium dioxide, water-washed kaoline, blanc fixe, kaolin and coarse whiting
Or it is several.
Further, the thickener can be synthetic macromolecular compound, for example, Tao Shi thickener TT-935, are one
Kind high-content, low viscosity polyacrylate emulsion;Can also be modified natural polymer, such as sodium carboxymethylcellulose.
The present invention also provides a kind of preparation methods of radiation protection water paint, include the following steps:
(1), deionized water is added in reaction kettle A, is warming up to 50 DEG C, stirred with the speed of 100-200rpm, Ahmedabad is rich net
Taste lotion 959W, reaction kettle A pressure 7.8MPa, by extracting tea polyphenols flavanol compound from tealeaves, (main component is flavane
Alcohol), the one or several kinds of anthocyanin class, flavonoids, flavonols and phenolic acid class, be slowly added dropwise into reaction kettle A, continuing will be anti-
It answers kettle A to be warming up to 80 DEG C, initiator hydrogen peroxide is added dropwise into reaction kettle A, so that it is polymerize with 959W, is cooled to room temperature, obtain water
Property ordor removing radiation protection lotion;
(2), deionized water, amine neutralizer, polyphosphate and antifoaming agent are slowly added in reaction kettle B, with 500-
The speed of 800rpm is stirred until homogeneous;
(3), in reaction kettle B be added color stuffing, diatomite, blanc fixe, with the speed of 1200-1500rpm stir to
Mill base is uniform;
(4), slowly add the aqueous ordor removing radiation protection lotion in step (1), levelling agent, antifreezing agent, film forming in reaction kettle B
Auxiliary agent is stirred with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, thickener is added and is thickened, viscosity
Control stormer viscosity at 25 DEG C is 105-110KU.
Compared with prior art, advantageous effects of the invention:
It solves the problems, such as largely to use heavy metal and graphene and solvent, and this method is renewable resource,
It is very friendly to environment;Using water as diluent in radiation shielding coating, organic solvent is free of, such as benzene,toluene,xylene, formaldehyde
Equal VOC ingredients, favorable dispersibility, color development are had excellent performance, and filming performance is good, and scrub performance is excellent and can have good anti-
The effect of radiation, especially electron radiation.
Specific implementation mode
Heretofore described term is only to describe special embodiment, being not intended to limit disclosed by the invention
Content.Aqueous radiation protection lotion of the present invention is by extracting, concentrating and extracting CO_2 supercritical technology with tradition
Technology is combined, and prepares high-purity tea polypenols new process, and tea polyphenols (main component is flavanols) flavanols is extracted from tealeaves
The one or several kinds of class, anthocyanin class, flavonoids, flavonols and phenolic acid class.By the polycondensation reaction with ordor removing lotion from
And obtain a lotion with radiation proof function and ordor removing.
Unless otherwise stated, all technical and scientific terms used herein has routine of the art
The normally understood identical meanings of technical staff.Indicate that the unit of material content is based on weight in terms of part.As in the present invention
Other raw material refer both to usually used raw material in the art.
Embodiment 1
A kind of radiation protection water paint, in parts by weight, including component be:60 parts of aqueous radiation protection lotion, go from
15 parts of sub- water, 0.3 part of France west compose gloomy chemistry S150, wetting agent 0.3,0.2 part of Nuo Pu sections SN-154 silica-types antifoaming agent,
0.3 part of the high TEGO450 levelling agents of 0.4 part of DOW731A polyphosphate, enlightening, 10 parts of antifreezing agent, Yi Shiman TEXANOL coalescents
5 parts of 20 parts, 25 parts of color stuffing (wherein 15 parts of titanium dioxide, 10 parts of blanc fixe), 5 parts of diatomite and TT-935 thickeners.
Preparation method is as follows:
(1), deionized water is added in reaction kettle A, is warming up to 80 DEG C, stirred with the speed of 100-200rpm, is added aqueous
Ordor removing lotion, reactor pressure 7.8MPa are slowly added to flavanols, by polycondensation reaction, obtain aqueous in the case where nickel is catalyst
Ordor removing radiation protection lotion, is cooled to room temperature.
(2), deionized water, amine neutralizer, polyphosphate DOW731A and Nuo Pu section SN- are slowly added in reaction kettle B
154, it is stirred until homogeneous with the speed of 500-800rpm;
(3), in reaction kettle B be added color stuffing, diatomite, blanc fixe, with the speed of 1200-1500rpm stir to
Mill base is uniform;
(4), slowly add aqueous ordor removing radiation protection lotion, levelling agent, antifreezing agent, the film forming in step (1) in reaction kettle B
Auxiliary agent is stirred with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, thickener is added and is thickened, 25 DEG C
When stormer viscosity be 108KU.
Embodiment 2
A kind of radiation protection water paint of the present embodiment 2:In parts by weight, including component be:Aqueous radiation protection breast
Gloomy chemistry S150, the defoaming of BASF A10 aqueous mineral oil are composed in 55 parts of liquid, wetting agent 0.3,20 parts of deionized water, 0.3 part of France west
0.4 part of agent, 0.3 part of DOW731A polyphosphate, 0.5 part of the high TEGO450 levelling agents of enlightening, 12 parts of antifreezing agent, Yi Shiman TEXANOL
17 parts of coalescents, 30 parts of color stuffing (wherein 15 parts of dragon boa R-996 titanium dioxides, 15 parts of blanc fixe), 5 parts of diatomite and hydroxyl second
Base cellulose is the HS 30000YP2 of Japanese SHIN-ETSU HANTOTAI.
Preparation method is as follows:
(1), deionized water 1.1, is added in retort A, is warming up to 50 DEG C, is stirred with the speed of 100-200rpm, slowly
Ahmedabad richness ordor removing lotion 959W, reactor pressure 7.8MPa is added;
1.2, by extracted from tealeaves tea polyphenols (as long as ingredient be flavanols) flavanol compound, anthocyanin class, flavonoids,
Reaction kettle A is slowly added dropwise in the one or several kinds of flavonols and phenolic acid class;
1.3, continue reaction kettle A being warming up to 80 DEG C, initiator hydrogen peroxide is added dropwise into reaction kettle A, makes itself and 959W
Polymerization, is cooled to room temperature;
(2), deionized water, cellulose, amine neutralizer, polyphosphate and antifoaming agent are slowly added in retort B, with
The speed of 500-800rpm is stirred until homogeneous;
(3), color stuffing, diatomite are added in retort B, is stirred with the speed of 1200-1500rpm uniform to mill base;
(4), in retort B slowly plus the aqueous ordor removing radiation protection lotion in step (1), levelling agent, antifreezing agent, her scholar
Graceful TEXANOL coalescents are stirred with the speed of 800-1200rpm, survey initial viscosity, and according to initial viscosity, thickener is added
It is thickened, stormer viscosity is 110KU at 25 DEG C.
Embodiment 3
A kind of radiation protection water paint of the present embodiment 3:In parts by weight, including component be:The aqueous anti-spoke of ordor removing
Penetrate 50 parts of lotion, 0.15 part of wetting agent, 10 parts of deionized water, the gloomy chemistry S150 of 0.1 part of France's west spectrum, the aqueous mines of BASF A10
0.2 part of object oil antifoaming agent, 0.2 part of DOW731A polyphosphate, 0.3 part of the high TEGO450 levelling agents of enlightening, 10 parts of antifreezing agent, Yi Shiman
15 parts of TEXANOL coalescents, 35 parts of color stuffing (wherein 15 parts of dragon boa R-996 titanium dioxides, 20 parts of blanc fixe), diatomite 3
Part, 5 parts of Tao Shi TT935 thickeners.
The Novel radiation-protection coating of the present embodiment 3, preparation method are as follows:
(1), deionized water 1.1, is added in retort A, is warming up to 50 DEG C, is stirred with the speed of 100-200rpm, slowly
Ahmedabad richness ordor removing lotion 959W, reactor pressure 7.8MPa is added.
1.2, by extracted from tealeaves tea polyphenols (as long as ingredient be flavanols) flavanol compound, anthocyanin class, flavonoids,
Reaction kettle A is slowly added dropwise in the one or several kinds of flavonols and phenolic acid class.
1.3, continue reaction kettle A being warming up to 80 DEG C, initiator hydrogen peroxide is added dropwise into reaction kettle A.Make itself and 959W
Polymerization.It is cooled to room temperature.
(2), it is slowly added to deionized water in retort B, cellulose, amine neutralizer, polyphosphate and antifoaming agent, with
The speed of 500-800rpm is stirred until homogeneous;
(3), be added in retort B color stuffing, diatomite, stirred with the speed of 1200-1500rpm it is uniform to mill base;
(4), in retort B slowly plus step (1) in aqueous ordor removing radiation protection lotion, levelling agent 2025, antifreezing agent,
Coalescents are stirred with the speed of 800-1200rpm, survey initial viscosity, according to initial viscosity, thickener are added and is thickened,
Stormer viscosity is 106KU at 25 DEG C.
1 embodiment 1-3 base paint the performance test results of table
A kind of Novel radiation-protection coating disclosed in embodiment 1-3, performance meets base paint technical requirement, especially good
Good shielding property.
Embodiment described above is only that the preferred embodiment of the present invention is described, and is not carried out to the scope of the present invention
It limits, under the premise of not departing from design spirit of the present invention, those of ordinary skill in the art make technical scheme of the present invention
Various modifications and improvement, should all fall into claims of the present invention determination protection domain in.
Claims (8)
1. a kind of radiation protection water paint, it is characterised in that:Include the component of following parts by weight:Aqueous ordor removing radiation protection lotion
45-60 parts, 0.1-0.3 parts of cellulose, 0.1-0.3 parts of wetting agent, 10-20 parts of deionized water, 0.1-0.3 parts of amine neutralizer, disappear
0.2-0.6 parts of infusion, 0.2-0.4 parts of polyphosphate, 0.3-0.8 parts of levelling agent, 10-15 parts of antifreezing agent, coalescents 10-15
Part, 15.3-25 parts of color stuffing, 5-10 parts of blanc fixe, 3-5 parts of diatomite and 0.3-0.5 parts of thickener.
2. radiation protection water paint according to claim 1, it is characterised in that:Include the component of following parts by weight:It is aqueous
50 parts of ordor removing radiation protection lotion, 0.2 part of cellulose, 0.2 part of wetting agent, 15 parts of deionized water, 0.2 part of amine neutralizer, antifoaming agent
0.4 part, 0.3 part of polyphosphate, 0.5 part of levelling agent, 12 parts of antifreezing agent, 12 parts of coalescents, 20 parts of color stuffing, blanc fixe 8
0.4 part of part, 4 parts of diatomite and thickener.
3. radiation protection water paint according to claim 1, it is characterised in that:The aqueous ordor removing radiation protection lotion
Indispensable method is as follows:
A, deionized water is added in reaction kettle A, is warming up to 50 DEG C, stirred with the speed of 100-200rpm, be slowly added to Ahmedabad richness
Ordor removing lotion 959W, reactor pressure 7.8MPa;
B, by extracting tea polyphenols (as long as ingredient is flavanols) flavanol compound, anthocyanin class, flavonoids, flavonols from tealeaves
Reaction kettle A is slowly added dropwise in the one or several kinds of class and phenolic acid class;
C, continue reaction kettle A being warming up to 80 DEG C, initiator hydrogen peroxide is added dropwise into reaction kettle A, it is made to polymerize with 959W, it is cold
But room temperature is arrived.
4. radiation protection water paint according to claim 3, it is characterised in that:The tea polyphenols are to utilize post separation system
The tea polyphenols that standby method technique is extracted from tealeaves.
5. radiation protection water paint according to claim 4, it is characterised in that:The tea polyphenols are flavanol compound, flower
The one or several kinds of color glycoside, flavonoids, flavonols and phenolic acid class.
6. radiation protection water paint according to claim 4 or 5, it is characterised in that:The tea polyphenols are flavanols, by
It is obtained by extraction in tealeaves.
7. radiation protection water paint according to claim 1, it is characterised in that:The antifoaming agent be Nuo Pu sections SN-154 or
BASF A10;The polyphosphate is DOW731A;The coalescents are Yi Shiman TEXANOL;The color stuffing is titanium white
One or several kinds in powder, water-washed kaoline, blanc fixe, kaolin and coarse whiting.
8. a kind of preparation method of radiation protection water paint, it is characterised in that:Include the following steps:
(1), deionized water is added in reaction kettle A, is warming up to 50 DEG C, stirred with the speed of 100-200rpm, Ahmedabad richness ordor removing breast
Liquid 959W, reaction kettle A pressure 7.8MPa, by extracting tea polyphenols flavanol compound, anthocyanin class, flavonoids, flavones from tealeaves
The one or several kinds of alcohols and phenolic acid class are slowly added dropwise into reaction kettle A, continue reaction kettle A being warming up to 80 DEG C, to reaction kettle
Initiator hydrogen peroxide is added dropwise in A, so that it is polymerize with 959W, is cooled to room temperature, obtain aqueous ordor removing radiation protection lotion;
(2), deionized water, amine neutralizer, polyphosphate and antifoaming agent are slowly added in reaction kettle B, with 500-800rpm's
Speed is stirred until homogeneous;
(3), color stuffing, diatomite are added in reaction kettle B, blanc fixe is stirred with the speed of 1200-1500rpm to mill base
Uniformly;
(4), slowly add the aqueous ordor removing radiation protection lotion in step (1) in reaction kettle B, levelling agent, antifreezing agent, film forming help
Agent is stirred with the speed of 800-1200rpm, surveys initial viscosity, according to initial viscosity, thickener is added and is thickened, viscosity control
System stormer viscosity at 25 DEG C is 105-110KU.
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CN201810019509.9A CN108559400A (en) | 2018-01-09 | 2018-01-09 | A kind of radiation protection water paint |
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CN201810019509.9A CN108559400A (en) | 2018-01-09 | 2018-01-09 | A kind of radiation protection water paint |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109666342A (en) * | 2018-11-19 | 2019-04-23 | 河北晨阳工贸集团有限公司 | It can avoid accumulation of salt in the surface soil type exterior coating and preparation method thereof |
CN109810583A (en) * | 2019-02-01 | 2019-05-28 | 宝骏新兴建材(天津)有限公司 | A kind of super scrubbing resistance bottom surface unification easily japanning and preparation method thereof |
CN109971264A (en) * | 2019-04-23 | 2019-07-05 | 德江嘉艺装饰建材有限公司 | A kind of new coating |
CN110229578A (en) * | 2019-06-19 | 2019-09-13 | 河北晨阳工贸集团有限公司 | A kind of radiation protection water paint and preparation method thereof |
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CN106189573A (en) * | 2016-07-19 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | Radiation shielding coating and preparation method thereof |
CN106905781A (en) * | 2017-02-20 | 2017-06-30 | 河北晨阳工贸集团有限公司 | Excellent color-adjustable base paint of color development and preparation method thereof |
CN107118627A (en) * | 2017-05-11 | 2017-09-01 | 东莞市金基环保科技有限公司 | Ultralow radiation removes formaldehyde low-carbon health coating |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN106189573A (en) * | 2016-07-19 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | Radiation shielding coating and preparation method thereof |
CN106905781A (en) * | 2017-02-20 | 2017-06-30 | 河北晨阳工贸集团有限公司 | Excellent color-adjustable base paint of color development and preparation method thereof |
CN107118627A (en) * | 2017-05-11 | 2017-09-01 | 东莞市金基环保科技有限公司 | Ultralow radiation removes formaldehyde low-carbon health coating |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109666342A (en) * | 2018-11-19 | 2019-04-23 | 河北晨阳工贸集团有限公司 | It can avoid accumulation of salt in the surface soil type exterior coating and preparation method thereof |
CN109810583A (en) * | 2019-02-01 | 2019-05-28 | 宝骏新兴建材(天津)有限公司 | A kind of super scrubbing resistance bottom surface unification easily japanning and preparation method thereof |
CN109971264A (en) * | 2019-04-23 | 2019-07-05 | 德江嘉艺装饰建材有限公司 | A kind of new coating |
CN110229578A (en) * | 2019-06-19 | 2019-09-13 | 河北晨阳工贸集团有限公司 | A kind of radiation protection water paint and preparation method thereof |
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