CN108559231A - A kind of flame-retarded resin - Google Patents

A kind of flame-retarded resin Download PDF

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Publication number
CN108559231A
CN108559231A CN201810255854.2A CN201810255854A CN108559231A CN 108559231 A CN108559231 A CN 108559231A CN 201810255854 A CN201810255854 A CN 201810255854A CN 108559231 A CN108559231 A CN 108559231A
Authority
CN
China
Prior art keywords
flame
resin
retarded
carclazyte
octoate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810255854.2A
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Chinese (zh)
Inventor
胡汉涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huzhou Five Stone Technology Co Ltd
Original Assignee
Huzhou Five Stone Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huzhou Five Stone Technology Co Ltd filed Critical Huzhou Five Stone Technology Co Ltd
Priority to CN201810255854.2A priority Critical patent/CN108559231A/en
Publication of CN108559231A publication Critical patent/CN108559231A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/095—Carboxylic acids containing halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/10—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of flame-retarded resins, by following component according to mass percentage composition：Saturated polyester resin 30 50%, tetrachlorophthalic anhydride 10 20%, carclazyte fiber 5 10%, copper naphthenate 5 8%, cobalt iso-octoate 2 5%, calcium carbonate 10 20%, chloro styrene 5 10%, silica 5 10%.The present invention provides a kind of flame-retarded resin, and nontoxicity, product service life are long, and heat-resistant fireproof is had excellent performance, adhesive strength is high.

Description

A kind of flame-retarded resin
Technical field
The present invention relates to technical field of polymer composite materials more particularly to a kind of flame-retarded resins.
Background technology
Currently, field is relatively simple using high-property resin composite material material both at home and abroad, mainly with unsaturated polyester (UP), second Based on alkenyl esters resin, tough epoxy resin material, but in place of the different degrees of Shortcomings of these materials；As unsaturation is poly- Ester, brittleness is big, and temperature in use is low, and adhesive strength is low；Although vinyl ester resin has good toughness, adhesive strength good, after solidification The advantages that small toxicity, but there are the disadvantages such as temperature in use is low；Epoxy resin, although having many advantages, such as that good toughness, adhesive strength are high, But it is poor that there are weatherabilities, and easy dusting, viscosity is big, and wettability is poor, at relatively high temperatures, bear compared with strong corrosive medium such as stronger acids, The shortcomings of ability of alkali and solvent etc. is poor, and curing system toxicity is big, and cure cycle is long, and post-processing is costly.Therefore, traditional Composite material is far from meeting market to its performance increasingly higher demands.
Invention content
The object of the present invention is to provide a kind of flame-retarded resins, and nontoxicity, product service life are long, heat-resistant fireproof Energy is excellent, adhesive strength is high.
Technical scheme of the present invention：A kind of flame-retarded resin, which is characterized in that by following component according to mass percent group At：Saturated polyester resin 30-50%, tetrachlorophthalic anhydride 10-20%, carclazyte fiber 5-10%, copper naphthenate 5-8%, cobalt iso-octoate 2-5%, Calcium carbonate 10-20%, chloro styrene 5-10%, silica 5-10%.
A kind of flame-retarded resin above-mentioned, which is characterized in that by following component according to mass percentage composition：Saturated polyester tree Fat 30%, tetrachlorophthalic anhydride 10%, carclazyte fiber 10%, copper naphthenate 5%, cobalt iso-octoate 5%, calcium carbonate 20%, chloro styrene 10%, Silica 1 0%.
A kind of flame-retarded resin above-mentioned, which is characterized in that by following component according to mass percentage composition：Saturated polyester tree Fat 50%, tetrachlorophthalic anhydride 18%, carclazyte fiber 5%, copper naphthenate 5%, cobalt iso-octoate 2%, calcium carbonate 10%, chloro styrene 5%, two Silica 5%.
Beneficial effects of the present invention：Use tetrachlorophthalic anhydride for raw material, it can be with the anti-flammability of reinforced resin, while with Benzene Chloride Ethylene is curing agent, further enhances the anti-flammability of resin；In addition obtained flame retardant resin have high temperature resistant, it is corrosion-resistant, The features such as high intensity, product service life are long, and processing technology is simple and normal temperature solidified, and solidification is non-toxic, and adhesive strength is high.
Specific implementation mode
The present invention is further illustrated for following example, but is not intended as the foundation limited the present invention.
Embodiment 1：A kind of flame-retarded resin, by following component according to mass percentage composition：Saturated polyester resin 30-50%, Tetrachlorophthalic anhydride 10-20%, carclazyte fiber 5-10%, copper naphthenate 5-8%, cobalt iso-octoate 2-5%, calcium carbonate 10-20%, Benzene Chloride second Alkene 5-10%, silica 5-10%.
Embodiment 2：A kind of flame-retarded resin, by following component according to mass percentage composition：Saturated polyester resin 30%, four Chloride anhydride 10%, carclazyte fiber 10%, copper naphthenate 5%, cobalt iso-octoate 5%, calcium carbonate 20%, chloro styrene 10%, silica 10%。
Embodiment 3：A kind of flame-retarded resin, by following component according to mass percentage composition：Saturated polyester resin 50%, four Chloride anhydride 18%, carclazyte fiber 5%, copper naphthenate 5%, cobalt iso-octoate 2%, calcium carbonate 10%, chloro styrene 5%, silica 5%.

Claims (3)

1. a kind of flame-retarded resin, which is characterized in that by following component according to mass percentage composition：Saturated polyester resin 30- 50%, tetrachlorophthalic anhydride 10-20%, carclazyte fiber 5-10%, copper naphthenate 5-8%, cobalt iso-octoate 2-5%, calcium carbonate 10-20%, chlorination Styrene 5-10%, silica 5-10%.
2. a kind of flame-retarded resin according to claim 1, which is characterized in that by following component according to mass percent group At：Saturated polyester resin 30%, tetrachlorophthalic anhydride 10%, carclazyte fiber 10%, copper naphthenate 5%, cobalt iso-octoate 5%, calcium carbonate 20%, chlorine Change styrene 10%, silica 1 0%.
3. a kind of flame-retarded resin according to claim 1, which is characterized in that by following component according to mass percent group At：Saturated polyester resin 50%, tetrachlorophthalic anhydride 18%, carclazyte fiber 5%, copper naphthenate 5%, cobalt iso-octoate 2%, calcium carbonate 10%, chlorine Change styrene 5%, silica 5%.
CN201810255854.2A 2018-03-27 2018-03-27 A kind of flame-retarded resin Withdrawn CN108559231A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810255854.2A CN108559231A (en) 2018-03-27 2018-03-27 A kind of flame-retarded resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810255854.2A CN108559231A (en) 2018-03-27 2018-03-27 A kind of flame-retarded resin

Publications (1)

Publication Number Publication Date
CN108559231A true CN108559231A (en) 2018-09-21

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Family Applications (1)

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CN201810255854.2A Withdrawn CN108559231A (en) 2018-03-27 2018-03-27 A kind of flame-retarded resin

Country Status (1)

Country Link
CN (1) CN108559231A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535663A (en) * 2018-11-14 2019-03-29 芜湖市元奎新材料科技有限公司 A kind of novel resin material having anti-flammability
WO2024104374A1 (en) * 2022-11-18 2024-05-23 北京微构工场生物技术有限公司 Degradable filament, preparation method therefor, and use thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102174247A (en) * 2011-03-02 2011-09-07 中国科学技术大学苏州研究院 Halogen-free flame retardant glass fiber reinforced polyester composite and preparation method thereof
CN102558800A (en) * 2010-12-25 2012-07-11 李霞 Flame-retarded resin
CN102675837A (en) * 2012-05-22 2012-09-19 苏州新区华士达工程塑胶有限公司 Formula of enhanced flame retardant PBT (polybutylece terephthalate)
CN103540112A (en) * 2013-10-19 2014-01-29 山东吉青化工有限公司 High-temperature-resistant flame-retardant resin
CN105176010A (en) * 2014-06-09 2015-12-23 南通慧源塑胶有限公司 Improved polyethylene terephthalate formula
CN105647097A (en) * 2016-04-12 2016-06-08 无锡南理工科技发展有限公司 Flame-retardant resin

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558800A (en) * 2010-12-25 2012-07-11 李霞 Flame-retarded resin
CN102174247A (en) * 2011-03-02 2011-09-07 中国科学技术大学苏州研究院 Halogen-free flame retardant glass fiber reinforced polyester composite and preparation method thereof
CN102675837A (en) * 2012-05-22 2012-09-19 苏州新区华士达工程塑胶有限公司 Formula of enhanced flame retardant PBT (polybutylece terephthalate)
CN103540112A (en) * 2013-10-19 2014-01-29 山东吉青化工有限公司 High-temperature-resistant flame-retardant resin
CN105176010A (en) * 2014-06-09 2015-12-23 南通慧源塑胶有限公司 Improved polyethylene terephthalate formula
CN105647097A (en) * 2016-04-12 2016-06-08 无锡南理工科技发展有限公司 Flame-retardant resin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535663A (en) * 2018-11-14 2019-03-29 芜湖市元奎新材料科技有限公司 A kind of novel resin material having anti-flammability
WO2024104374A1 (en) * 2022-11-18 2024-05-23 北京微构工场生物技术有限公司 Degradable filament, preparation method therefor, and use thereof

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Application publication date: 20180921