CN108559231A - A kind of flame-retarded resin - Google Patents
A kind of flame-retarded resin Download PDFInfo
- Publication number
- CN108559231A CN108559231A CN201810255854.2A CN201810255854A CN108559231A CN 108559231 A CN108559231 A CN 108559231A CN 201810255854 A CN201810255854 A CN 201810255854A CN 108559231 A CN108559231 A CN 108559231A
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- CN
- China
- Prior art keywords
- flame
- resin
- retarded
- carclazyte
- octoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/095—Carboxylic acids containing halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of flame-retarded resins, by following component according to mass percentage composition:Saturated polyester resin 30 50%, tetrachlorophthalic anhydride 10 20%, carclazyte fiber 5 10%, copper naphthenate 5 8%, cobalt iso-octoate 2 5%, calcium carbonate 10 20%, chloro styrene 5 10%, silica 5 10%.The present invention provides a kind of flame-retarded resin, and nontoxicity, product service life are long, and heat-resistant fireproof is had excellent performance, adhesive strength is high.
Description
Technical field
The present invention relates to technical field of polymer composite materials more particularly to a kind of flame-retarded resins.
Background technology
Currently, field is relatively simple using high-property resin composite material material both at home and abroad, mainly with unsaturated polyester (UP), second
Based on alkenyl esters resin, tough epoxy resin material, but in place of the different degrees of Shortcomings of these materials;As unsaturation is poly-
Ester, brittleness is big, and temperature in use is low, and adhesive strength is low;Although vinyl ester resin has good toughness, adhesive strength good, after solidification
The advantages that small toxicity, but there are the disadvantages such as temperature in use is low;Epoxy resin, although having many advantages, such as that good toughness, adhesive strength are high,
But it is poor that there are weatherabilities, and easy dusting, viscosity is big, and wettability is poor, at relatively high temperatures, bear compared with strong corrosive medium such as stronger acids,
The shortcomings of ability of alkali and solvent etc. is poor, and curing system toxicity is big, and cure cycle is long, and post-processing is costly.Therefore, traditional
Composite material is far from meeting market to its performance increasingly higher demands.
Invention content
The object of the present invention is to provide a kind of flame-retarded resins, and nontoxicity, product service life are long, heat-resistant fireproof
Energy is excellent, adhesive strength is high.
Technical scheme of the present invention:A kind of flame-retarded resin, which is characterized in that by following component according to mass percent group
At:Saturated polyester resin 30-50%, tetrachlorophthalic anhydride 10-20%, carclazyte fiber 5-10%, copper naphthenate 5-8%, cobalt iso-octoate 2-5%,
Calcium carbonate 10-20%, chloro styrene 5-10%, silica 5-10%.
A kind of flame-retarded resin above-mentioned, which is characterized in that by following component according to mass percentage composition:Saturated polyester tree
Fat 30%, tetrachlorophthalic anhydride 10%, carclazyte fiber 10%, copper naphthenate 5%, cobalt iso-octoate 5%, calcium carbonate 20%, chloro styrene 10%,
Silica 1 0%.
A kind of flame-retarded resin above-mentioned, which is characterized in that by following component according to mass percentage composition:Saturated polyester tree
Fat 50%, tetrachlorophthalic anhydride 18%, carclazyte fiber 5%, copper naphthenate 5%, cobalt iso-octoate 2%, calcium carbonate 10%, chloro styrene 5%, two
Silica 5%.
Beneficial effects of the present invention:Use tetrachlorophthalic anhydride for raw material, it can be with the anti-flammability of reinforced resin, while with Benzene Chloride
Ethylene is curing agent, further enhances the anti-flammability of resin;In addition obtained flame retardant resin have high temperature resistant, it is corrosion-resistant,
The features such as high intensity, product service life are long, and processing technology is simple and normal temperature solidified, and solidification is non-toxic, and adhesive strength is high.
Specific implementation mode
The present invention is further illustrated for following example, but is not intended as the foundation limited the present invention.
Embodiment 1:A kind of flame-retarded resin, by following component according to mass percentage composition:Saturated polyester resin 30-50%,
Tetrachlorophthalic anhydride 10-20%, carclazyte fiber 5-10%, copper naphthenate 5-8%, cobalt iso-octoate 2-5%, calcium carbonate 10-20%, Benzene Chloride second
Alkene 5-10%, silica 5-10%.
Embodiment 2:A kind of flame-retarded resin, by following component according to mass percentage composition:Saturated polyester resin 30%, four
Chloride anhydride 10%, carclazyte fiber 10%, copper naphthenate 5%, cobalt iso-octoate 5%, calcium carbonate 20%, chloro styrene 10%, silica
10%。
Embodiment 3:A kind of flame-retarded resin, by following component according to mass percentage composition:Saturated polyester resin 50%, four
Chloride anhydride 18%, carclazyte fiber 5%, copper naphthenate 5%, cobalt iso-octoate 2%, calcium carbonate 10%, chloro styrene 5%, silica 5%.
Claims (3)
1. a kind of flame-retarded resin, which is characterized in that by following component according to mass percentage composition:Saturated polyester resin 30-
50%, tetrachlorophthalic anhydride 10-20%, carclazyte fiber 5-10%, copper naphthenate 5-8%, cobalt iso-octoate 2-5%, calcium carbonate 10-20%, chlorination
Styrene 5-10%, silica 5-10%.
2. a kind of flame-retarded resin according to claim 1, which is characterized in that by following component according to mass percent group
At:Saturated polyester resin 30%, tetrachlorophthalic anhydride 10%, carclazyte fiber 10%, copper naphthenate 5%, cobalt iso-octoate 5%, calcium carbonate 20%, chlorine
Change styrene 10%, silica 1 0%.
3. a kind of flame-retarded resin according to claim 1, which is characterized in that by following component according to mass percent group
At:Saturated polyester resin 50%, tetrachlorophthalic anhydride 18%, carclazyte fiber 5%, copper naphthenate 5%, cobalt iso-octoate 2%, calcium carbonate 10%, chlorine
Change styrene 5%, silica 5%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810255854.2A CN108559231A (en) | 2018-03-27 | 2018-03-27 | A kind of flame-retarded resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810255854.2A CN108559231A (en) | 2018-03-27 | 2018-03-27 | A kind of flame-retarded resin |
Publications (1)
Publication Number | Publication Date |
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CN108559231A true CN108559231A (en) | 2018-09-21 |
Family
ID=63533400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201810255854.2A Withdrawn CN108559231A (en) | 2018-03-27 | 2018-03-27 | A kind of flame-retarded resin |
Country Status (1)
Country | Link |
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CN (1) | CN108559231A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109535663A (en) * | 2018-11-14 | 2019-03-29 | 芜湖市元奎新材料科技有限公司 | A kind of novel resin material having anti-flammability |
WO2024104374A1 (en) * | 2022-11-18 | 2024-05-23 | 北京微构工场生物技术有限公司 | Degradable filament, preparation method therefor, and use thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102174247A (en) * | 2011-03-02 | 2011-09-07 | 中国科学技术大学苏州研究院 | Halogen-free flame retardant glass fiber reinforced polyester composite and preparation method thereof |
CN102558800A (en) * | 2010-12-25 | 2012-07-11 | 李霞 | Flame-retarded resin |
CN102675837A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of enhanced flame retardant PBT (polybutylece terephthalate) |
CN103540112A (en) * | 2013-10-19 | 2014-01-29 | 山东吉青化工有限公司 | High-temperature-resistant flame-retardant resin |
CN105176010A (en) * | 2014-06-09 | 2015-12-23 | 南通慧源塑胶有限公司 | Improved polyethylene terephthalate formula |
CN105647097A (en) * | 2016-04-12 | 2016-06-08 | 无锡南理工科技发展有限公司 | Flame-retardant resin |
-
2018
- 2018-03-27 CN CN201810255854.2A patent/CN108559231A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102558800A (en) * | 2010-12-25 | 2012-07-11 | 李霞 | Flame-retarded resin |
CN102174247A (en) * | 2011-03-02 | 2011-09-07 | 中国科学技术大学苏州研究院 | Halogen-free flame retardant glass fiber reinforced polyester composite and preparation method thereof |
CN102675837A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of enhanced flame retardant PBT (polybutylece terephthalate) |
CN103540112A (en) * | 2013-10-19 | 2014-01-29 | 山东吉青化工有限公司 | High-temperature-resistant flame-retardant resin |
CN105176010A (en) * | 2014-06-09 | 2015-12-23 | 南通慧源塑胶有限公司 | Improved polyethylene terephthalate formula |
CN105647097A (en) * | 2016-04-12 | 2016-06-08 | 无锡南理工科技发展有限公司 | Flame-retardant resin |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109535663A (en) * | 2018-11-14 | 2019-03-29 | 芜湖市元奎新材料科技有限公司 | A kind of novel resin material having anti-flammability |
WO2024104374A1 (en) * | 2022-11-18 | 2024-05-23 | 北京微构工场生物技术有限公司 | Degradable filament, preparation method therefor, and use thereof |
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Application publication date: 20180921 |