CN108554645A - A kind of foaming agent of energy conservation and environmental protection, clean and effective - Google Patents
A kind of foaming agent of energy conservation and environmental protection, clean and effective Download PDFInfo
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- CN108554645A CN108554645A CN201810169073.1A CN201810169073A CN108554645A CN 108554645 A CN108554645 A CN 108554645A CN 201810169073 A CN201810169073 A CN 201810169073A CN 108554645 A CN108554645 A CN 108554645A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/04—Frothers
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of energy conservation and environmental protection, the foaming agents of clean and effective.By the material composition of following parts by weight：30 60 parts of terpenic oil, 20 40 parts of ether alcohol oil, 10 30 parts of methyl anyl alcohol.The foaming agent foaming volume of energy conservation and environmental protection, clean and effective prepared by the present invention is big, drain long half time, and foam volume long half time shows good foaming characteristic and stability.The preparation method of the present invention is simple, and raw material sources are wide, is suitble to large-scale industrial production.
Description
Technical field
The present invention relates to a kind of foaming agent, more particularly to a kind of energy conservation and environmental protection, clean and effective foaming agent.
Background technology
Foaming agent is a kind of surface reactive material, and interfacial tension is mainly reduced on gas-water interface, and air is promoted to expect
Minute bubbles are formed in slurry, expand sorting interface, and ensure that bubble rises to form froth bed.The formation of bubble in flotation pulp, it is main
Various types of inflating and stirring devices in floatation equipment are depended on, and add suitable foaming agent into ore pulp.Foaming agent
General is surfactant, and molecular structure is made of nonpolar lipophilic group and polar hydrophilic radical, is formed existing
Hydrophily has so-called " amphiphilic structure " molecule of lipophilic again.Lipophilic group can be aliphatic alkyl, alicyclic alkyl and virtue
Fragrant race's alkyl or with the equiatomic aliphatic alkyl of O, N, alicyclic alkyl and aromatic hydrocarbyl；Hydrophilic group be generally carboxylic acid group,
Alkyl, sulfonic group, sulfate, phosphonic acid base, amino, itrile group, mercapto, halogen, ether etc..Foaming agent is added in water, hydrophilic group
It is inserted into water phase and lipophilic group to be inserted into oil phase or erect in air, aligning on boundary layer or surface is formed in, to make
Interfacial tension or surface tension reduce.In general, the aqueous solution of the foaming agent containing minute quantity has foaming characteristic.Currently, flotation
Foaming agent bubbling area used in ore pulp is small, the half-life short of foam, and stability is poor.
Main component terpenol (the C of terpenic oil10H17OH) it is cyclic structure and there are three types of isomers (α-terpenol, β-alkene
Alcohol, γ-terpenol).Terpenic oil is pale yellowish oil transparency liquid, and density (20 DEG C) 0.900-0.915g/mL is slightly soluble in water.
Ether alcohol oil is polymerized by propylene oxide and ethyl alcohol under caustic soda catalysis, structural formula C2H5-(OC3H6) n-OH, average molecular weight
It is 200.Methyl anyl alcohol is colourless transparent liquid, and density is 0.8g/cm at 20 DEG C3, still without being combined using above-mentioned substance, prepare
The report of efficient foaming agent.
Invention content
The purpose of the present invention is to provide a kind of energy conservation and environmental protection, the foaming agents of clean and effective.
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：30-60 parts of terpenic oil,
20-40 parts of ether alcohol oil, 10-30 parts of methyl anyl alcohol.
The foaming agent further includes 0.5-3 parts of metal oxide particle.
The grain size of the metal oxide particle is 6nm-15nm, and contact angle is 45 ° -55 °.
The metal oxide is copper oxide, zinc oxide, zirconium oxide, aluminium oxide, one kind or one in vanadium oxide iron oxide
Kind or more.
The foaming agent further includes 1-3 parts of nano imvite.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 30-60 parts of terpenic oil according to parts by weight,
20-40 parts of ether alcohol oil, 10-30 parts of methyl anyl alcohol stir 20-30min, are then allowed to stand 10-15min, are made.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 30-60 parts of terpenic oil according to parts by weight,
1-3 parts of 20-40 parts of ether alcohol oil, 10-30 parts of methyl anyl alcohol, 0.5-3 parts of metal oxide particle or nano imvite are mixed
20-30min is then allowed to stand 10-15min, is made.
Compared with prior art, the present invention has the advantages that：Energy conservation and environmental protection prepared by the present invention, clean and effective
Foaming agent foaming volume is big, drain long half time, and foam volume long half time shows good foaming characteristic and stability.This
The preparation method of invention is simple, and raw material sources are wide, is suitble to large-scale industrial production.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below, it is to be understood that protection scope of the present invention is not
It is restricted by specific implementation.
Embodiment 1
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：50 parts of terpenic oil, ether
30 parts of alcohol oil, 20 parts of methyl anyl alcohol.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 50 parts of terpenic oil, ether according to parts by weight
30 parts of alcohol oil, 20 parts of methyl anyl alcohol stir 25min, are then allowed to stand 12min, are made.
Embodiment 2
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：30 parts of terpenic oil, ether
20 parts of alcohol oil, 10 parts of methyl anyl alcohol, 1 part of Zinc oxide particles.The grain size of the Zinc oxide particles is 8nm, and contact angle is 50 °.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 30 parts of terpenic oil, ether according to parts by weight
20 parts of alcohol oil, 10 parts of methyl anyl alcohol, 1 part of Zinc oxide particles are mixed 20min, are then allowed to stand 10min, are made.
Embodiment 3
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：30 parts of terpenic oil, ether
20 parts of alcohol oil, 10 parts of methyl anyl alcohol, 2 parts of nano imvite.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 30 parts of terpenic oil, ether according to parts by weight
20 parts of alcohol oil, 10 parts of methyl anyl alcohol, 2 parts of nano imvite are mixed 30min, are then allowed to stand 15min, are made.
Embodiment 4
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：50 parts of terpenic oil, ether
30 parts of alcohol oil, 20 parts of methyl anyl alcohol, trimethyl (1,2,3,4,5- pentamethylcyclopentadiene base) 2 parts of silane.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 50 parts of terpenic oil, ether according to parts by weight
30 parts of alcohol oil, 20 parts of methyl anyl alcohol, trimethyl (1,2,3,4,5- pentamethylcyclopentadiene base) 2 parts of silane stir 25min, so
After stand 12min, be made.
Embodiment 5
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：50 parts of terpenic oil, ether
30 parts of alcohol oil, 20 parts of methyl anyl alcohol, 1 part of 4- vinyl benzocyclobutene.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 50 parts of terpenic oil, ether according to parts by weight
30 parts of alcohol oil, 20 parts of methyl anyl alcohol, 1 part of 4- vinyl benzocyclobutene stir 25min, are then allowed to stand 12min, are made.
Embodiment 6
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：50 parts of terpenic oil, ether
30 parts of alcohol oil, 20 parts of methyl anyl alcohol, single 5 parts of ball celery extract.
The extracting method of the list ball celery extract is：Single ball celery is taken, dries or dries, clay into power, is soaked in 5 times
It 1-3 days in 1% malic acid solution of quality, stirs evenly, stands 1-3 days, take supernatant, be evaporated and take shallow green powder, be made.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 50 parts of terpenic oil, ether according to parts by weight
30 parts of alcohol oil, 20 parts of methyl anyl alcohol, single 5 parts of ball celery extract stir 25min, are then allowed to stand 12min, are made.
Comparative example 1
A kind of foaming agent, by the material composition of following parts by weight：50 parts of terpenic oil, 30 parts of ether alcohol oil.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 50 parts of terpenic oil, ether according to parts by weight
30 parts of alcohol oil, stirs 25min, is then allowed to stand 12min, is made.
Comparative example 2
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：50 parts of terpenic oil, first
20 parts of base amylalcohol.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 50 parts of terpenic oil, first according to parts by weight
20 parts of base amylalcohol stirs 25min, is then allowed to stand 12min, is made.
Comparative example 3
The foaming agent of a kind of energy conservation and environmental protection, clean and effective, by the material composition of following parts by weight：30 parts of ether alcohol oil, first
20 parts of base amylalcohol.
A kind of energy conservation and environmental protection, the preparation method of foaming agent of clean and effective take 30 parts of ether alcohol oil, first according to parts by weight
20 parts of base amylalcohol stirs 25min, is then allowed to stand 12min, is made.
Experimental example：
The foaming characteristic and stability experiment of foaming agent are measured using the Waring Blender methods of laboratory routine,
It is as follows：
The foaming agent of 100g is added in high speed agitator, 6800rpm stirs 1min, and record stops foaming agent when stirring
Volume, be denoted as V0(mL)；The semi-liquid time is precipitated in foam, is denoted as foams drain half-life period t1/2(s)；Foam volume becomes
For the time of original half, it is denoted as foam volume half-life period tv(1/2).V0 indicates the foamability of foam, t1/2、tv(1/2)Indicate bubble
The stability of foam.
The index of each embodiment and comparative example foaming characteristic and stability is as shown in table 1：
Table 1
| Embodiment | Foaming volume (mL) | Drain half-life period S | Foam volume half-life period S |
| Embodiment 1 | 540 | 821 | 6357 |
| Embodiment 2 | 550 | 921 | 6566 |
| Embodiment 3 | 549 | 967 | 6577 |
| Embodiment 4 | 599 | 1312 | 7388 |
| Embodiment 5 | 601 | 1238 | 7691 |
| Embodiment 6 | 588 | 1329 | 7821 |
| Comparative example 1 | 321 | 621 | 4217 |
| Comparative example 2 | 312 | 666 | 4214 |
| Comparative example 3 | 322 | 589 | 4322 |
As can be seen from Table 1, the numerical value of the foaming volume of comparative example 1-3, drain half-life period, foam volume half-life period is apparent
Less than embodiment 1, compared with Example 1, comparative example 1-3 adds methyl anyl alcohol, ether alcohol oil and terpenic oil less respectively, it was demonstrated that on
The combination of two for stating substance is ineffective, and only 3 kinds of substances are combined, competence exertion maximum effect；Embodiment 2-3 and reality
It applies example 1 to compare, the numerical value of foaming volume, drain half-life period, foam volume half-life period is increased slightly, and in embodiment 2-3 is distinguished more
Add Zinc oxide particles and nano imvite, it was demonstrated that Zinc oxide particles and nano imvite are for increasing the foaming characteristic of foaming agent
It is powerful with stability；The numerical value of the foaming volume of embodiment 4-6, drain half-life period, foam volume half-life period is apparently higher than reality
Apply example 1, compared with Example 1, other conditions are identical, only embodiment 4-6 respectively add trimethyl (1,2,3,
4,5- pentamethylcyclopentadiene bases) silane, 4- vinyl benzocyclobutenes, single ball celery extract, it was demonstrated that trimethyl (1,2,3,4,
5- pentamethylcyclopentadienes base) silane, 4- vinyl benzocyclobutenes, single ball celery extract, for increasing the blistering of foaming agent
Property and stability have good effect, be composition key component.
Disclosed above is only specific embodiments of the present invention, and still, the present invention is not limited to this, any this field
What technical staff can think variation should all fall into protection scope of the present invention.
Claims (7)
1. the foaming agent of a kind of energy conservation and environmental protection, clean and effective, which is characterized in that by the material composition of following parts by weight：Pine camphor
It is 30-60 parts oily, 20-40 parts of ether alcohol oil, 10-30 parts of methyl anyl alcohol.
2. the foaming agent of energy conservation and environmental protection according to claim 1, clean and effective, which is characterized in that the foaming agent also wraps
Include 0.5-3 parts of metal oxide particle.
3. the foaming agent of energy conservation and environmental protection according to claim 2, clean and effective, which is characterized in that the metal oxide
The grain size of particle is 6nm-15nm, and contact angle is 45 ° -55 °.
4. the foaming agent of energy conservation and environmental protection according to claim 2, clean and effective, which is characterized in that the metal oxide
For copper oxide, zinc oxide, zirconium oxide, aluminium oxide, the one or more in vanadium oxide iron oxide.
5. the foaming agent of energy conservation and environmental protection according to claim 1, clean and effective, which is characterized in that the foaming agent also wraps
Include 1-3 parts of nano imvite.
6. a kind of preparation method of the foaming agent of energy conservation and environmental protection, clean and effective, which is characterized in that according to parts by weight, take pine camphor
30-60 parts oily, 20-40 parts of ether alcohol oil, 10-30 parts of methyl anyl alcohol stirs 20-30min, is then allowed to stand 10-15min, is made.
7. a kind of preparation method of the foaming agent of energy conservation and environmental protection, clean and effective, which is characterized in that according to parts by weight, take pine camphor
It is 30-60 parts oily, 20-40 parts of ether alcohol oil, 10-30 parts of methyl anyl alcohol, 0.5-3 parts of metal oxide particle or nano imvite 1-3
Part, 20-30min is mixed, is then allowed to stand 10-15min, is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810169073.1A CN108554645A (en) | 2018-02-28 | 2018-02-28 | A kind of foaming agent of energy conservation and environmental protection, clean and effective |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810169073.1A CN108554645A (en) | 2018-02-28 | 2018-02-28 | A kind of foaming agent of energy conservation and environmental protection, clean and effective |
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| CN108554645A true CN108554645A (en) | 2018-09-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810169073.1A Pending CN108554645A (en) | 2018-02-28 | 2018-02-28 | A kind of foaming agent of energy conservation and environmental protection, clean and effective |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110699057A (en) * | 2019-09-27 | 2020-01-17 | 中国石油化工股份有限公司 | Temperature-resistant high-strength foam system with synergistic lamellar nano-particles and preparation method thereof |
| CN112169694A (en) * | 2020-09-22 | 2021-01-05 | 新沂市锡沂高新材料产业技术研究院有限公司 | Preparation method of foaming agent for impurity removal of quartz sand |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6022953A (en) * | 1983-07-18 | 1985-02-05 | Neos Co Ltd | Flotation collector |
| CN1403206A (en) * | 2002-10-09 | 2003-03-19 | 武汉理工大学 | Mineral-floating foaming agent and its prepn |
| CN101507949A (en) * | 2009-03-19 | 2009-08-19 | 株洲市湘麒科技开发有限公司 | Stone-like coal navajoite physical mineral dressing method |
| CN101823025A (en) * | 2010-04-01 | 2010-09-08 | 西安科技大学 | Coal flotation agent and preparation method thereof |
| CN102172565A (en) * | 2010-12-10 | 2011-09-07 | 太原理工大学 | Method for floating coal by using modified waste oil as flotation agent |
| CN103721860A (en) * | 2013-12-20 | 2014-04-16 | 安徽冠华稀贵金属集团有限公司 | Lead-copper oxidized ore flotation agent and preparation method thereof |
| CN105038753A (en) * | 2015-08-03 | 2015-11-11 | 中国石油天然气股份有限公司 | Foaming agent and preparation method and application thereof |
| CN107670844A (en) * | 2017-09-30 | 2018-02-09 | 江苏闽江矿业有限公司 | A kind of preparation method of foaming agent for quartz sand flotation process |
-
2018
- 2018-02-28 CN CN201810169073.1A patent/CN108554645A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6022953A (en) * | 1983-07-18 | 1985-02-05 | Neos Co Ltd | Flotation collector |
| CN1403206A (en) * | 2002-10-09 | 2003-03-19 | 武汉理工大学 | Mineral-floating foaming agent and its prepn |
| CN101507949A (en) * | 2009-03-19 | 2009-08-19 | 株洲市湘麒科技开发有限公司 | Stone-like coal navajoite physical mineral dressing method |
| CN101823025A (en) * | 2010-04-01 | 2010-09-08 | 西安科技大学 | Coal flotation agent and preparation method thereof |
| CN102172565A (en) * | 2010-12-10 | 2011-09-07 | 太原理工大学 | Method for floating coal by using modified waste oil as flotation agent |
| CN103721860A (en) * | 2013-12-20 | 2014-04-16 | 安徽冠华稀贵金属集团有限公司 | Lead-copper oxidized ore flotation agent and preparation method thereof |
| CN105038753A (en) * | 2015-08-03 | 2015-11-11 | 中国石油天然气股份有限公司 | Foaming agent and preparation method and application thereof |
| CN107670844A (en) * | 2017-09-30 | 2018-02-09 | 江苏闽江矿业有限公司 | A kind of preparation method of foaming agent for quartz sand flotation process |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110699057A (en) * | 2019-09-27 | 2020-01-17 | 中国石油化工股份有限公司 | Temperature-resistant high-strength foam system with synergistic lamellar nano-particles and preparation method thereof |
| CN112169694A (en) * | 2020-09-22 | 2021-01-05 | 新沂市锡沂高新材料产业技术研究院有限公司 | Preparation method of foaming agent for impurity removal of quartz sand |
| CN112169694B (en) * | 2020-09-22 | 2022-07-26 | 新沂市锡沂高新材料产业技术研究院有限公司 | Preparation method of foaming agent for impurity removal of quartz sand |
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