CN108546880A - Steel BG22SiMnNi2CrMoA and preparation method thereof - Google Patents

Steel BG22SiMnNi2CrMoA and preparation method thereof Download PDF

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Publication number
CN108546880A
CN108546880A CN201810461564.3A CN201810461564A CN108546880A CN 108546880 A CN108546880 A CN 108546880A CN 201810461564 A CN201810461564 A CN 201810461564A CN 108546880 A CN108546880 A CN 108546880A
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steel
slag
preparation
annealing
electric furnace
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张群
赵千水
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Bengang Steel Plates Co Ltd
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Bengang Steel Plates Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses steel BG22SiMnNi2CrMoA and preparation method thereof, wherein the steel BG22SiMnNi2CrMoA, by weight percentage, including following component:C:0.19~0.22%, Si:1.35~1.65%, Mn:1.25~1.45%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.25~0.35%, Ni:1.70~1.90%, Mo:0.35~0.40%, Cu:≤ 0.15%, surplus is iron and inevitable impurity.Steel BG22SiMnNi2CrMoA homogeneity of ingredients is good, and degree of segregation is low, and preparation method solves existing production steel for rock drilling bits and mostly uses molding or electroslag remelting production greatly, and lumber recovery is low, of high cost, and yield is small, the slow problem of rhythm of production.

Description

Steel BG22SiMnNi2CrMoA and preparation method thereof
Technical field
The present invention relates to field of steel preparation, specifically provide steel BG22SiMnNi2CrMoA and preparation method thereof.
Background technology
With the rapid industrial development in our country, domestic every profession and trade is continuous to the demand of mine resources product and electric power energy Increase, it is higher and higher to steel, drilling tool quality requirement.Compared with international advanced rock-drill steel, the steel grades of China's steel design It is essentially identical, but manufactured drilling tool product service life and mass difference are larger, cannot fully meet production needs, existing pricker There are the following problems for the preparation method of steel:
(1) electric furnace continuous casting smelting rhythm is fast, and hot metal ratio is small, and steel scrap alloy content is high;
(2) alloy content of BG22SiMnNi2CrMoA steel grades is high, and Si, Mn, Cr, Ni, Mo, V Composition Control are difficult;
(3) casting process easy tos produce the defects of alloying component is segregated, is loose;
(4) the high heating process of alloy content is not easy to grill thoroughly;
(5) the high operation of rolling of alloy content is larger to milling train drag;
(6) steel need to anneal, and burn steel temperature, time bad control.
Invention content
In consideration of it, the present invention provides steel BG22SiMnNi2CrMoA and preparation method thereof, to solve the above problems.
One aspect of the present invention provides a kind of steel BG22SiMnNi2CrMoA, which is characterized in that by weight percentage, packet Include following component:C:0.19~0.22%, Si:1.35~1.65%, Mn:1.25~1.45%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.25~0.35%, Ni:1.70~1.90%, Mo:0.35~0.40%, Cu:≤ 0.15%, surplus is iron With inevitable impurity.
It is preferred that the steel BG22SiMnNi2CrMoA, by weight percentage, including following component: C:0.20%, Si: 1.50%, Mn:1.35%, P:≤ 0.010%, S:≤ 0.008%, Cr:0.30%, Ni:1.80%, Mo:0.37%, Cu:≤ 0.10%, surplus is iron and inevitable impurity.
The present invention also provides a kind of preparation methods of steel BG22SiMnNi2CrMoA:It is blast-melted to pass through molten iron successively Pretreatment → electric furnace smelting → refining furnace LF → vacuum outgas VD → middle billet continuous casting 235mm × 265mm continuous casting billets → step-by-step movement Stove heat → high-pressure water descaling → roughing mill rolling → Continuous mill train → slow cooling → annealing → finishing → flaw detection → inspection is heated, is obtained To steel,
Wherein, electric furnace smelting uses 50t electric furnace smeltings, carbon to reach tapping deoxidization alloying after target content requires;
Refining furnace LF operates for white slag, under conditions of ensureing slag mobility, in control basicity of slag (CaO/SiO2) and slag Oxygen gesture FeO+MnO≤1%, constantly detect molten steel, be finely adjusted alloy, ensure molten steel composition reach standard requirement;
Vacuum outgas VD:Ensure degasifying effect and promotes inclusion floating, vacuum 25min or more, composition adjustment to satisfaction Calcium treatment is carried out after internally controlling requirement, so that the field trash in steel is further floated into slag, is improved Molten Steel Cleanliness;
Middle billet continuous casting:Ladle is sealed, using cinder inclusion in big covering agent, tundish covering flux, high alkalinity, in tundish Argon gas protective casting, M-EMS, adjustment end electromagnetic agitation current strength and secondary coolingwater, smashes column crystal, protects The maximization for demonstrate,proving equiax crystal, to improve equiaxed zone ratio;
Annealing:Steel are heated to 670 ± 10 DEG C with the constant heating rate of 65~75 DEG C/h, keep the temperature 3h or more, then go out Furnace cooling is but.
It is preferred that annealing:Steel are heated to 670 DEG C with the constant heating rate of 70 DEG C/h, keep the temperature 3h or more, then go out furnace cooling But.
Beneficial effects of the present invention are as follows:
1, steel for rock drilling bits is produced using square billet (235mm × 265mm) flow in 50t electric furnaces+LF+VD+ BG22SiMnNi2CrMoA, realizes the continuous casting of sequence casting, and ton steel cost is reduced than continuous casting or electroslag remelting production 1000 yuan or more, realize the breakthrough of electric furnace continuous casting flow batch production steel for rock drilling bits;
2, it solves electric furnace fast pace and smelts high-alloy steel, improve 80% or more hot metal ratio, effectively control what steel scrap was introduced Other harmful elements;
3, refining process realizes the equal control of Si, Mn, Cr, Ni, Mo, V ingredient, VD Fruit storages, Neng Gouchong Dividing reduces the gas contents such as [O], [H] in molten steel, and Calcium treatment ensures that field trash fully floats, ensure that Molten Steel Cleanliness;
4, continuous casting ensure that strand using means such as M-EMS, end electromagnetic agitation, control secondary cooling water flows Internal soundness uniformity improves equiaxed zone ratio;
5, heating process ensures that strand is grilled thoroughly, and the operation of rolling carries out temperature-controlled rolling, reduces shadow of the milling train to steel drag It rings, ensures the uniformity of steel tissue;
6, ensure homogeneity of steel structure after rational annealing process, ensure that steel product stress is small, hardness is low, meets standard and wants It asks.
Specific implementation mode
The present invention is further explained below in conjunction with specific embodiment, but the not limitation present invention.
Embodiment 1
Steel BG22SiMnNi2CrMoA, by weight percentage, including following component:C:0.19%, Si:1.65%, Mn: 1.25%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.25%, Ni:1.90%, Mo:0.35%, Cu:≤ 0.15%, it is remaining Amount is iron and inevitable impurity.
The preparation method of steel BG22SiMnNi2CrMoA is as follows:
The blast-melted molten iron pretreatment → electric furnace smelting → refining furnace LF → vacuum outgas VD → middle square billet that passes through successively connects Casting 235mm × 265mm continuous casting billets → stepped heating stove heat → high-pressure water descaling → roughing mill rolling → Continuous mill train → slow Cold → annealing → finishing → flaw detection → inspection, obtains steel,
Wherein, electric furnace smelting uses 50t electric furnace smeltings, carbon to reach tapping deoxidization alloy after target content requires 0.19% Change;
Refining furnace LF operates for white slag, under conditions of ensureing slag mobility, in control basicity of slag (CaO/SiO2) and slag Oxygen gesture FeO+MnO≤1%, constantly detect molten steel, be finely adjusted alloy, ensure molten steel composition reach standard requirement:C: 0.19%, Si:1.65%, Mn:1.25%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.25%, Ni:1.90%, Mo: 0.35%, Cu:≤ 0.15%;
Vacuum outgas VD:Ensure degasifying effect and promotes inclusion floating, vacuum 25min or more, composition adjustment to satisfaction Internally controlling requirement (C:0.19%, Si:1.65%, Mn:1.25%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.25%, Ni: 1.90%, Mo:0.35%, Cu:≤ 0.15%) Calcium treatment is carried out afterwards, so that the field trash in steel is further floated into slag, is carried High Molten Steel Cleanliness;
Middle billet continuous casting:Ladle is sealed, using cinder inclusion in big covering agent, tundish covering flux, high alkalinity, in tundish Argon gas protective casting, M-EMS, adjustment end electromagnetic agitation current strength and secondary coolingwater, smashes column crystal, protects The maximization for demonstrate,proving equiax crystal, to improve equiaxed zone ratio;
Annealing:Steel are heated to 680 DEG C with the constant heating rate of 65 DEG C/h, keep the temperature 4h, cooling of then coming out of the stove.
Embodiment 2
Steel BG22SiMnNi2CrMoA, by weight percentage, including following component:C:0.22%, Si:1.35%, Mn:1.45%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.35%, Ni:1.70%, Mo:0.40%, Cu:≤ 0.15%, Surplus is iron and inevitable impurity.
The preparation method of steel BG22SiMnNi2CrMoA is as follows:
The blast-melted molten iron pretreatment → electric furnace smelting → refining furnace LF → vacuum outgas VD → middle square billet that passes through successively connects Casting 235mm × 265mm continuous casting billets → stepped heating stove heat → high-pressure water descaling → roughing mill rolling → Continuous mill train → slow Cold → annealing → finishing → flaw detection → inspection, obtains steel,
Wherein, electric furnace smelting uses 50t electric furnace smeltings, carbon to reach tapping deoxidization alloy after target content requires 0.22% Change;
Refining furnace LF operates for white slag, under conditions of ensureing slag mobility, in control basicity of slag (CaO/SiO2) and slag Oxygen gesture FeO+MnO≤1%, constantly detect molten steel, be finely adjusted alloy, ensure molten steel composition reach standard requirement:C: 0.22%, Si:1.35%, Mn:1.45%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.35%, Ni:1.70%, Mo: 0.40%, Cu:≤ 0.15%;
Vacuum outgas VD:Ensure degasifying effect and promotes inclusion floating, vacuum 25min or more, composition adjustment to satisfaction Internally controlling requirement (C:0.22%, Si:1.35%, Mn:1.45%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.35%, Ni: 1.70%, Mo:0.40%, Cu:≤ 0.15%) Calcium treatment is carried out afterwards, so that the field trash in steel is further floated into slag, is carried High Molten Steel Cleanliness;
Middle billet continuous casting:Ladle is sealed, using cinder inclusion in big covering agent, tundish covering flux, high alkalinity, in tundish Argon gas protective casting, M-EMS, adjustment end electromagnetic agitation current strength and secondary coolingwater, smashes column crystal, protects The maximization for demonstrate,proving equiax crystal, to improve equiaxed zone ratio;
Annealing:Steel are heated to 660 DEG C with the constant heating rate of 75 DEG C/h, keep the temperature 5h, cooling of then coming out of the stove.
Embodiment 3
Steel BG22SiMnNi2CrMoA, by weight percentage, including following component:C:0.20%, Si:1.50%, Mn:1.35%, P:≤ 0.010%, S:≤ 0.008%, Cr:0.30%, Ni:1.80%, Mo:0.37%, Cu:≤ 0.10%, Surplus is iron and inevitable impurity.
The preparation method of steel BG22SiMnNi2CrMoA is as follows:
The blast-melted molten iron pretreatment → electric furnace smelting → refining furnace LF → vacuum outgas VD → middle square billet that passes through successively connects Casting 235mm × 265mm continuous casting billets → stepped heating stove heat → high-pressure water descaling → roughing mill rolling → Continuous mill train → slow Cold → annealing → finishing → flaw detection → inspection, obtains steel,
Wherein, electric furnace smelting uses 50t electric furnace smeltings, carbon to reach tapping deoxidization alloy after target content requires 0.20% Change;
Refining furnace LF operates for white slag, under conditions of ensureing slag mobility, in control basicity of slag (CaO/SiO2) and slag Oxygen gesture FeO+MnO≤1%, constantly detect molten steel, be finely adjusted alloy, ensure molten steel composition reach standard requirement:C: 0.20%, Si:1.50%, Mn:1.35%, P:≤ 0.010%, S:≤ 0.008%, Cr:0.30%, Ni:1.80%, Mo: 0.37%, Cu:≤ 0.10%;
Vacuum outgas VD:Ensure degasifying effect and promotes inclusion floating, vacuum 25min or more, composition adjustment to satisfaction Internally controlling requirement (C:0.20%, Si:1.50%, Mn:1.35%, P:≤ 0.010%, S:≤ 0.008%, Cr:0.30%, Ni: 1.80%, Mo:0.37%, Cu:≤ 0.10%) Calcium treatment is carried out afterwards, so that the field trash in steel is further floated into slag, is carried High Molten Steel Cleanliness;
Middle billet continuous casting:Ladle is sealed, using cinder inclusion in big covering agent, tundish covering flux, high alkalinity, in tundish Argon gas protective casting, M-EMS, adjustment end electromagnetic agitation current strength and secondary coolingwater, smashes column crystal, protects The maximization for demonstrate,proving equiax crystal, to improve equiaxed zone ratio;
Annealing:Steel are heated to 670 DEG C with the constant heating rate of 70 DEG C/h, keep the temperature 5h, cooling of then coming out of the stove.
Steel obtained in 100 stove embodiments 1 to embodiment 3 are respectively taken to test, the stable quality of steel meets user Requirement.

Claims (4)

1. steel BG22SiMnNi2CrMoA, which is characterized in that by weight percentage, including following component:C:0.19~ 0.22%, Si:1.35~1.65%, Mn:1.25~1.45%, P:≤ 0.012%, S:≤ 0.010%, Cr:0.25~ 0.35%, Ni:1.70~1.90%, Mo:0.35~0.40%, Cu:≤ 0.15%, surplus is iron and inevitable impurity.
2. steel BG22SiMnNi2CrMoA described in accordance with the claim 1, which is characterized in that by weight percentage, including such as Lower component:C:0.20%, Si:1.50%, Mn:1.35%, P:≤ 0.010%, S:≤ 0.008%, Cr:0.30%, Ni: 1.80%, Mo:0.37%, Cu:≤ 0.10%, surplus is iron and inevitable impurity.
3. the preparation method of steel BG22SiMnNi2CrMoA as claimed in claim 1 or 2, it is characterised in that:It is blast-melted according to It is secondary to pass through molten iron pretreatment → electric furnace smelting → refining furnace LF → vacuum outgas VD → middle billet continuous casting 235mm × 265mm continuous castings Base → stepped heating stove heat → high-pressure water descaling → roughing mill rolling → Continuous mill train → slow cooling → annealing → finishing → spy Wound → inspection, obtains steel,
Wherein, electric furnace smelting uses 50t electric furnace smeltings, carbon to reach tapping deoxidization alloying after target content requires;
Refining furnace LF operates for white slag, under conditions of ensureing slag mobility, the oxygen in control basicity of slag (CaO/SiO2) and slag Gesture FeO+MnO≤1%, constantly detects molten steel, is finely adjusted alloy, ensures that molten steel composition reaches standard requirement;
Vacuum outgas VD:Ensure degasifying effect and promote inclusion floating, vacuum 25min or more, composition adjustment is to meeting internal control Calcium treatment is carried out after it is required that, so that the field trash in steel is further floated into slag, is improved Molten Steel Cleanliness;
Middle billet continuous casting:Ladle is sealed, using cinder inclusion in big covering agent, tundish covering flux, high alkalinity, argon gas in tundish Protective casting, M-EMS, adjustment end electromagnetic agitation current strength and secondary coolingwater, smashes column crystal, ensure etc. The maximization of axialite, to improve equiaxed zone ratio;
Annealing:Steel are heated to 670 ± 10 DEG C with the constant heating rate of 65~75 DEG C/h, keep the temperature 3h or more, then go out furnace cooling But.
4. the preparation method of steel BG22SiMnNi2CrMoA described in accordance with the claim 3, it is characterised in that:Annealing:Steel 670 DEG C are heated to the constant heating rate of 70 DEG C/h, keeps the temperature 3h or more, cooling of then coming out of the stove.
CN201810461564.3A 2018-05-15 2018-05-15 Steel BG22SiMnNi2CrMoA and preparation method thereof Pending CN108546880A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852881A (en) * 2019-02-21 2019-06-07 本钢板材股份有限公司 A kind of 45CrNiMoVA drilling tool steel and its production method
CN110551880A (en) * 2019-10-24 2019-12-10 成都先进金属材料产业技术研究院有限公司 softening heat treatment process for small-size 22Si2MnCrNi2MoA steel rolled material
CN110904388A (en) * 2019-12-30 2020-03-24 本钢板材股份有限公司 Excavator crawler belt steel BG45MnCrB and preparation method thereof
CN110964984A (en) * 2019-12-30 2020-04-07 本钢板材股份有限公司 Steel SAE4160M for middle and large automobile shaft sleeve and production process thereof
CN111004962A (en) * 2019-12-30 2020-04-14 本钢板材股份有限公司 Steel BG80MnCr for steel balls of ball mill and preparation method thereof
CN111961974A (en) * 2020-08-20 2020-11-20 本钢板材股份有限公司 Preparation method of drill rod tail shaft of tapping machine

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852881A (en) * 2019-02-21 2019-06-07 本钢板材股份有限公司 A kind of 45CrNiMoVA drilling tool steel and its production method
CN109852881B (en) * 2019-02-21 2020-12-01 本钢板材股份有限公司 Steel for 45CrNiMoVA drill tool and production method thereof
CN110551880A (en) * 2019-10-24 2019-12-10 成都先进金属材料产业技术研究院有限公司 softening heat treatment process for small-size 22Si2MnCrNi2MoA steel rolled material
CN110904388A (en) * 2019-12-30 2020-03-24 本钢板材股份有限公司 Excavator crawler belt steel BG45MnCrB and preparation method thereof
CN110964984A (en) * 2019-12-30 2020-04-07 本钢板材股份有限公司 Steel SAE4160M for middle and large automobile shaft sleeve and production process thereof
CN111004962A (en) * 2019-12-30 2020-04-14 本钢板材股份有限公司 Steel BG80MnCr for steel balls of ball mill and preparation method thereof
CN110964984B (en) * 2019-12-30 2021-09-24 本钢板材股份有限公司 Steel SAE4160M for middle and large automobile shaft sleeve and production process thereof
CN111961974A (en) * 2020-08-20 2020-11-20 本钢板材股份有限公司 Preparation method of drill rod tail shaft of tapping machine
CN111961974B (en) * 2020-08-20 2021-07-09 本钢板材股份有限公司 Preparation method of drill rod tail shaft of tapping machine

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