CN108546200A - A kind of special sustained and controlled release composite fertilizer of radix scutellariae and preparation method thereof - Google Patents

A kind of special sustained and controlled release composite fertilizer of radix scutellariae and preparation method thereof Download PDF

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CN108546200A
CN108546200A CN201810784606.7A CN201810784606A CN108546200A CN 108546200 A CN108546200 A CN 108546200A CN 201810784606 A CN201810784606 A CN 201810784606A CN 108546200 A CN108546200 A CN 108546200A
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coated urea
radix scutellariae
boric acid
controlled release
quinhydrones
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张晓虎
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Shangluo University
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Shangluo University
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/02Superphosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses special sustained and controlled release composite fertilizers of a kind of radix scutellariae and preparation method thereof, active ingredient is made of coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate, wherein the weight ratio of coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate ranging from 0.5 ~ 5:5~25:1~10:0.05~0.5:0.5~6.The invention discloses a kind of sustained and controlled release composite fertilizer material dedicated for radix scutellariae, including coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate, wherein coated urea is made of sulfur coated urea, quinhydrones and dicyandiamide, wherein quinhydrones is urease inhibitor, dicyandiamide is nitrification inhibitor, the present invention makes nitrogenous fertilizer delay controlled release, effectively extend fertilizer efficiency, reduce fertilizer application frequency, raise labour productivity, and to improve the yield and quality of radix scutellariae, increases the value and economic benefit of medicinal plant plantation.

Description

A kind of special sustained and controlled release composite fertilizer of radix scutellariae and preparation method thereof
Technical field
The present invention relates to a kind of compound fertilizers more particularly to a kind of special sustained and controlled release composite fertilizer of radix scutellariae and preparation method thereof.
Background technology
Radix scutellariae (Scutellaria baicalensis Georgi) is the drying of Labiatae (Labiatae) plant radix scutellariae Root is distributed in the ground such as northwest China, northeast, North China and Henan, Shandong, Sichuan, radix scutellariae is also for the large Chinese medicine of common certified products Ten thousand mu of radix scutellariae rule are had in the city Shangzhou District in Souther mountain of Shaanxi province Shangluo City famous one of " five big quotient's medicine of the Qinling Mountains ", Science and Technology Department of Shaanxi Province Generalized plants Demonstration Base.Flavone compound includes scutelloside, wogonoside, baicalein, the Chinese Huang that separated identification obtains A kind of reed mentioned in ancient books element, thousand paper layer elements etc. are the main chemical compositions of radix scutellariae, and wherein scutelloside is《Pharmacopeia》The index components of defined radix scutellariae, it is yellow Also contain a variety of chemical combination such as flavanone, Check ears ketone, terpene, alkaloid, glucose, sucrose, sterol, volatile ingredient in a kind of reed mentioned in ancient books Object.Radix scutellariae also has antibacterial, anti-inflammatory, antiviral, antioxygen in addition to having effects that the tradition such as heat-clearing, eliminating dampness, removing toxic substances, hemostasis, tocolysis The functions such as change, antitumor, with the expansion of radix scutellariae application value and range, wild resource has been unable to meet growing market Demand, artificial growth have become inexorable trend.
Implement the important symbol that rational application of fertilizers is modern precision agriculture, according to formula research and development are with strong points, fertilizer efficiency is good Special fertilizer receives praises from customers and is rapidly developed, and is widely used to various industrial crops, grain and oil crop, forest and flower garden Meadow etc..At present to improve medicinal plant yield and quality, promotes peasant to save Zhi Zengxiao, be engaged in Chinese medicine special fertilizer researcher and get over Come more, and shows out good development prospect especially.But ignore the supply of various nutrients in the planting process of radix scutellariae, organic fertilizer with Inorganic fertilizer is unbalance, and the unreasonable and improper fertilization that applies fertilizer causes utilization rate of fertilizer low, leads to radix scutellariae crop trophic disturbance, under quality Drop, medical value reduce;Arable soil character deteriorates simultaneously, serious environmental pollution, and the productive potentialities of radix scutellariae and soil etc. are certainly Right resource efficiency cannot play, and limit the yield and quality of radix scutellariae;Additionally, due to radix scutellariae be herbaceos perennial, 2 years More than life commodity Root yield and active constituent content significantly improve, and due to crop cycle longer reality, general fertilizer needs It repeatedly to apply fertilizer, reduce labor productivity, therefore a kind of sustained and controlled release composite fertilizer of suitable radix scutellariae growth of research and development is necessary, and And there are no any enterprises or personal disclosure for the special complex fertilizer of radix scutellariae.
Invention content
In order to solve artificial growth radix scutellariae low output, medical value is low, the problem of needing repeatedly to apply fertilizer, the invention discloses A kind of special sustained and controlled release composite fertilizer of radix scutellariae and preparation method thereof, goal of the invention is for supplementing radix scutellariae nutrient elements required for the growth And trace element, increase soil fertility, nitrogenous fertilizer is made to delay controlled release, effectively extend fertilizer efficiency, reduce fertilizer application frequency, improve labour production Rate increases the value and economic benefit of medicinal plant plantation to improve the yield and quality of radix scutellariae.
The above-mentioned purpose of the present invention is achieved by the following technical programs:
The present invention provides a kind of special sustained and controlled release composite fertilizers of radix scutellariae, and active ingredient is by coated urea, calcium superphosphate, sulfuric acid Potassium, boric acid and manganese sulfate composition, the wherein weight ratio of coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are ranging from 0.5~5:5~25:1~10:0.05~0.5:0.5~6.
Preferably, the weight ratio of active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate ranging from 0.8 ~2:10~15:2~6:0.08~0.2:1~1.5.
Preferably, the weight ratio of active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate is 1:12:4: 0.1:1.2.
Preferably, the coated urea is made of sulfur coated urea, quinhydrones and dicyandiamide, wherein the mixing of quinhydrones and dicyandiamide Object is coated on sulfur coated urea surface, and the content of the quinhydrones is the 1% of sulfur coated urea, and the content of the dicyandiamide is sulfur coated urea 10%.
Preferably, in the mixture of the quinhydrones and dicyandiamide include sodium carboxymethylcellulose, wherein carboxymethyl cellulose The content of plain sodium is 4%.
A kind of preparation method of the special sustained and controlled release composite fertilizer of radix scutellariae as described above, includes the following steps:
Step 1:Coated urea is prepared, quinhydrones, dicyandiamide and sodium carboxymethylcellulose are mixed, then apply mixture It is overlying on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
Step 2:By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio ranging from 0.5~5: 5~25:1~10:0.05~0.5:0.5~6 carries out dispensing, then by coated urea, calcium superphosphate, potassium sulfate, boric acid and sulphur Sour manganese is uniformly mixed and made into granule.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) the invention discloses a kind of sustained and controlled release composite fertilizer material dedicated for radix scutellariae, including coated urea, peroxophosphoric acid Calcium, potassium sulfate, boric acid and manganese sulfate, wherein coated urea are made of sulfur coated urea, quinhydrones and dicyandiamide, and wherein quinhydrones is urase Inhibitor, dicyandiamide are nitrification inhibitor, and the present invention makes nitrogenous fertilizer delay controlled release, effectively extend fertilizer efficiency, reduce fertilizer application frequency, improve labor Dynamic productivity increases the value and economic benefit of medicinal plant plantation to improve the yield and quality of radix scutellariae;
(2) composite fertilizer of the present invention is dedicated for radix scutellariae, and fertilising object height is accurate, compatibility science, according to the growth of radix scutellariae Demand, compatibility go out the fertilizer ratio of most suitable growth, and composite fertilizer's quality is good, fertilizer efficiency is long, plant recovery of nutrient is high, safety and environmental protection, Fertilization effect is excellent;
(3) composite fertilizer's nutrition of the present invention is comprehensive, and nutrient content is high, improves radix scutellariae yield, ensures quality, balance nutrient, Coordinate supply, reduce cost, improve benefit, reduce pollution, protect ecology, realize nutrients resource saving, it is environmental-friendly and Chinese medicine Quality advance.
Description of the drawings
Fig. 1 is that each processing urea nitrogen attainment divides cumulative release amount schematic diagram.
Specific implementation mode
To keep the object of the invention, technical solution and advantage clearer, embodiments of the present invention will be made into one below Step is described in detail.
Trial zone of the present invention is located at Shaanxi Province Shangluo City Shangzhou District radix scutellariae planting base, and Shangzhou District is located in Shan southeast Qinling Mountains abdomen Ground, boundary belong to southern warm temperate zone to north subtropical border land between 109 ° 30 ' -111 ° 16 ' of east longitude, 33 ° 16 ' -34 ° 12 ' of north latitude The mountainous region monsoon climatic province of band, Shangzhou District are that native Mountainous Area agrotype is complicated, are experimental field selected in river valley Chuan Yuan Loamy texture moisture soil region on landforms terrace, prepartion of land, soil property are almost the same, and agricultural production conditions are good, experiment before Uniform stationing diagonal method in field acquires 0~40cm soil mixing samples, indoor processing, detection and according to soil fertility grading Reference index is evaluated.
Fertilising on medicinal plant have it is apparent influence to be confirmed by related test, be the rational Fertilization Level of determination to protect The stable yield, quality controllable of card plantation radix scutellariae uses three factor quadratic saturation D optimum design (i.e. 310 of N P and K in field Scheme), 10 processing, 3 repetitions, 30 area 4m × 6m=24m are set2Cell, random arrangement field trial, and in radix scutellariae It applies fertilizer three times in 2 years of growth, amount of application three times is identical.
Embodiment 1
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 0.5:5:1: 0.05:0.5, total weight 1kg, the wherein weight of coated urea are 70g, and the weight that conversion obtains quinhydrones is 0.7g, dicyandiamide Weight be 7g.
Coated urea is prepared, 0.7g quinhydrones, 7g dicyandiamides and sodium carboxymethylcellulose are mixed, then coat mixture It in sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 0.5:5:1:0.05:0.5 into Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by row dispensing.
Embodiment 2
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 5:25:10: 0.5:6, total weight 1kg, the wherein weight of coated urea are 100g, and the weight that conversion obtains quinhydrones is 1g, the weight of dicyandiamide Amount is 10g.
Coated urea is prepared, 1g quinhydrones, 10g dicyandiamides and sodium carboxymethylcellulose are mixed, then coat mixture It in sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 5:25:10:0.5:6 carry out Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by dispensing.
Embodiment 3
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 0.8:10: 2:0.08:1, total weight 1kg, the wherein weight of coated urea are 58g, and the weight that conversion obtains quinhydrones is 0.58g, dicyandiamide Weight be 5.8g.
Coated urea is prepared, 0.58g quinhydrones, 5.8g dicyandiamides and sodium carboxymethylcellulose are mixed, then by mixture It coated on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 0.8:10:2:0.08:1 into Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by row dispensing.
Embodiment 4
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 2:15:6: 0.2:1.5, total weight 1kg, the wherein weight of coated urea are 80g, and the weight that conversion obtains quinhydrones is 0.8g, dicyandiamide Weight is 8g.
Coated urea is prepared, 0.8g quinhydrones, 8g dicyandiamides and sodium carboxymethylcellulose are mixed, then coat mixture It in sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 2:15:6:0.2:1.5 carrying out Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by dispensing.
Embodiment 5
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 1:11:3: 0.15:0.8, total weight 1kg, the wherein weight of coated urea are 63g, and the weight that conversion obtains quinhydrones is 0.63g, dicyandiamide Weight be 6.3g.
Coated urea is prepared, 0.63g quinhydrones, 6.3g dicyandiamides and sodium carboxymethylcellulose are mixed, then by mixture It coated on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 1:11:3:0.15:0.8 into Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by row dispensing.
Embodiment 6
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 3:8:5: 0.3:1.2, total weight 1kg, the wherein weight of coated urea are 171g, and the weight that conversion obtains quinhydrones is 1.71g, dicyandiamide Weight be 17.1g.
Coated urea is prepared, 1.71g quinhydrones, 17.1g dicyandiamides and sodium carboxymethylcellulose are mixed, then by mixture It coated on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 3:8:5:0.3:1.2 carrying out Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by dispensing.
Embodiment 7
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 1:12:4: 0.1:1.2, total weight 1kg, the wherein weight of coated urea are 55g, and the weight that conversion obtains quinhydrones is 0.55g, dicyandiamide Weight be 5.5g.
Coated urea is prepared, 0.55g quinhydrones, 5.5g dicyandiamides and sodium carboxymethylcellulose are mixed, then by mixture It coated on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 1:12:4:0.1:1.2 carrying out Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by dispensing.
Embodiment 8
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 2:13:5: 0.15:1.1, total weight 1kg, the wherein weight of coated urea are 94g, and the weight that conversion obtains quinhydrones is 0.94g, dicyandiamide Weight be 9.4g.
Coated urea is prepared, 0.94g quinhydrones, 9.4g dicyandiamides and sodium carboxymethylcellulose are mixed, then by mixture It coated on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 2:13:5:0.15:1.1 into Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by row dispensing.
Embodiment 9
The application active ingredient coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 1.2:11: 4:0.11:1, total weight 1kg, the wherein weight of coated urea are 69g, and the weight that conversion obtains quinhydrones is 0.69g, dicyandiamide Weight be 6.9g.
Coated urea is prepared, 0.69g quinhydrones, 6.9g dicyandiamides and sodium carboxymethylcellulose are mixed, then by mixture It coated on sulfur coated urea surface, is rolled and is granulated using machinery, dry screening is spare;
By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio be 1.2:11:4:0.11:1 into Coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate are then uniformly mixed and made into granule by row dispensing.
Embodiment 10
Check experiment is set simultaneously, selects the common nitrogen, phosphorus and potassium fertilizer that can be bought currently on the market.
It is experiment Production rate object with biennial scutellariae,radix, 4m is harvested per cell2, root is completely dug out, cleans, go it Skin and fibrous root, 80 DEG C of drying of baking oven measure dry mass and are scaled to a hectare yield.Radix scutellariae complex chemical composition, in view of《Pharmacopeia》Rule Determine scutelloside as radix scutellariae index components and must not be less than 9% requirement, test to the dry scutellariae,radix of harvest through crushing, at sieving Reason, using the content of ultrasonic and circulated extraction determined by ultraviolet spectrophotometry its scutelloside as evaluate radix scutellariae quality it is whether up to standard according to According to.
Under the premise of test process radix scutellariae requisite quality, to test radix scutellariae yield and calculate yield effect with reference to market price Benefit deducts the economic benefit of fertilizers input measuring and calculating fertilizer treatment, calculates the amount of increasing income and increases income rate, is shown in Table 1.
The amount of increasing income (member/hm2)=(tests the yield of yield-check experiment) × unit price
1 Examples 1 to 10 different ratio of table tests yield and Economic Efficiency
Composite fertilizer of the present invention can dramatically increase the yield of radix scutellariae as can be seen from Table 1, and production benefit is produced according to field trial Amount and local market medicinal material procurement price calculate (20.00 yuan/kg of Shanglou radix scutellariae market price dry weights), and the yield of check experiment is 4001.778kg/hm2, the application fertilising after yield be all higher than 5000kg/hm2, reach as high as 6255.556kg/hm2, total to receive Benefit is all higher than 100000 yuan/hm2, reach as high as 125111.1 yuan/hm2, while increasing income rate and being all higher than 20%, 36% is reached as high as, Therefore radix scutellariae special complex fertilizer of the present invention can be effectively used for radix scutellariae, promote radix scutellariae increasing both production and income, improve the valence of medicinal plant plantation Value and economic benefit.
The application delays controlled release coat urea nitrogen nutrient cumulative release amount experiment:
Accurately weighing each processing 2.5000g fertilizer and 100g, experimental field wind desiceted soil is fitted into small plastic bag, after mixing A certain amount of distilled water is added, makes its water content up to 30% (be equivalent to field capacity 100%), then seals, close to soil 1 horizontally-arranged ventilation hole (totally 6) is pricked above earth at 1cm to create aerobic environment, is placed in 25 DEG C of biochemical constant incubator.For Examination nitrogen source is urea (containing N46%), during culture, daily using weight method moisturizing 1 time, so that soil moisture content is maintained at field and holds The 60%~65% of water is separately added into same amount of urea (U), urea (U)+quinhydrones (HQ), urea (U)+bis- in the soil Cyanamide (DCD), sulfur coated urea (SCU), sulfur coated urea (SCU)+quinhydrones (HQ)+dicyandiamide (DCD), while being not added with pair of urea According to experiment, the measurement that 4 repeating samples carry out soil nitrogen is adopted in the 7th, 14,21,28,35,42d respectively, respectively handles nitrogen nutrient Cumulative release amount is shown in Fig. 1.
As seen from Figure 1, each to handle nitrogen nutrient cumulative release curve in increase trend during constant temperature incubation, wherein It is the processing of urea that Nitrogen Accumulation burst size amplification is maximum, increases to 42d's from the 250.87mg/kg of 1d 1046.98mg/kg;Nitrogen Accumulation burst size amplification minimum is sulfur coated urea (SCU)+quinhydrones (HQ)+dicyandiamide (DCD), always In incubation time nitrogen is handled compared with urea (U), urea (U)+quinhydrones (HQ), urea (U)+dicyandiamide (DCD), sulfur coated urea (SCU) Plain cumulative release amount reduces by 58.4%, 33.3%, 12.96%, 11.05% respectively, show sulfur coated urea (SCU)+quinhydrones (HQ)+ The lower nitrogen of dicyandiamide (DCD) processing delays controlled release ability and is handled well compared with other.
Urease inhibitor hydroquinone (HQ) can delay the hydrolysis of urea, so that urea is spread and be moved to deeper soil layer In, to reduce ammonium state and ammoniacal nitrogen total concentration in topsoil, to reduce ammonia loss by volatilization.Nitrification inhibitor dicyandiamide (DCD) it is nitrification inhibitor for improving utilization rate of nitrogen fertilizer, is capable of the oxidation of urease inhibiting effective hydrolysate, makes it to hand over Change state NH4 +Form withhold for a long time in the soil.Sulfur coated urea (SCU) be with sulphur be main lapping to granular urea It is wrapped up, realizes to the sustained-controll-release fertiliser of the slow release of nitrogen, belong to inorganic coating class slow release fertilizer.
It is aided with urease inhibitor or nitrification inhibitor in urea, urea NH in soil can be slowed down2The hydrolysis of-N and NH4 +- N to NO3 -The oxidation of-N, reduces HN3Loss caused by volatilization.The mechanism of action of urease inhibitor and nitrification inhibitor is Difference, urease inhibitor can delay the hydrolysis of urea in soil to reduce HN3Volatilization loss to delaying NH indirectly4 +Oxidation For NO3 -, and nitrification inhibitor is then direct inhibition HN4 +It is oxidized to NO3 -And reduce NO3 -Leaching and N2And N2O isothermal chamber gas Body discharges, therefore effect is not notable always during exclusive use.Urease inhibitor is added in urea when simultaneously Quinhydrones (HQ) and when nitrification inhibitor dicyandiamide (DCD), can effectively inhibit soil urease liveness to delay hydrolysis of urea, show It writes and inhibits NH in soil4 +The oxidation of-N will keep higher NH the long periods4 +The content of-N simultaneously can reduce NO3 -- N leachings and The possibility of denitrification loss.Sulfur coated urea (SCU) is due to there is the protection of coated fertilizer sulphur, to show to nitrogen controlled release Long-term effect.Based on above-mentioned, the slow controlled release nitrogen of sulfur coated urea (SCU)+quinhydrones (HQ)+dicyandiamide (DCD) processing in this research Effect it is more notable compared with sulfur coated urea (SCU), urea (U)+quinhydrones (HQ), urea (U)+dicyandiamide (DCD).
Quinhydrones, dicyandiamide 4% sodium carboxymethylcellulose (binder) are coated on sulfur coated urea surface, machinery in the application It rolls and is granulated, dry screening is spare, and wherein quinhydrones additive amount is the 1% of sulfur coated urea dosage, and dicyandiamide additive amount is urinated for sulphur clothing The 10% of plain dosage.
The application composite fertilizer only needs fertilising three times in two years what radix scutellariae was grown, and amount of application three times is identical, and general Fertilizer needs to apply fertilizer at least 6 times or more, therefore the application composite fertilizer reduces fertilizer application frequency, improves labor productivity.
The invention discloses a kind of sustained and controlled release composite fertilizer material dedicated for radix scutellariae, including coated urea, calcium superphosphate, sulphur Sour potassium, boric acid and manganese sulfate, wherein coated urea are made of sulfur coated urea, quinhydrones and dicyandiamide, and wherein quinhydrones inhibits for urase Agent, dicyandiamide are nitrification inhibitor, and the present invention makes nitrogenous fertilizer delay controlled release, effectively extend fertilizer efficiency, reduce fertilizer application frequency, improve labour life Yield increases the value and economic benefit of medicinal plant plantation to improve the yield and quality of radix scutellariae.
Composite fertilizer of the present invention is dedicated for radix scutellariae, and fertilising object height is accurate, compatibility science, according to the growth need of radix scutellariae It asks, compatibility goes out the fertilizer ratio of most suitable growth, and composite fertilizer's quality is good, fertilizer efficiency is long, plant recovery of nutrient is high, safety and environmental protection, applies Fertile excellent effect.
Composite fertilizer's nutrition of the present invention is comprehensive, and nutrient content is high, improves radix scutellariae yield, ensures quality, balance nutrient, coordination Supply, reduces cost, improves benefit, and reduces pollution, protects ecology, realizes nutrients resource saving, environmental-friendly and Chinese medicine The unification of Quality advance three.
The preferred embodiment for the present invention is explained in detail above in conjunction with attached drawing, but the present invention is not limited to above-mentioned implementations Mode within the knowledge of a person skilled in the art can also be without departing from the purpose of the present invention It makes a variety of changes.
Many other changes and remodeling can be made by not departing from the spirit and scope of the present invention.It should be appreciated that the present invention is not It is limited to specific embodiment, the scope of the present invention is defined by the following claims.

Claims (6)

1. a kind of special sustained and controlled release composite fertilizer of radix scutellariae, it is characterised in that:Active ingredient by coated urea, calcium superphosphate, potassium sulfate, Boric acid and manganese sulfate composition, the wherein weight ratio of coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate ranging from 0.5 ~ 5:5~25:1~10:0.05~0.5:0.5~6.
2. the special sustained and controlled release composite fertilizer of a kind of radix scutellariae according to claim 1, it is characterised in that:Active ingredient coating urine The weight ratio ranging from 0.8 ~ 2 of element, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate:10~15:2~6:0.08~0.2:1~1.5.
3. the special sustained and controlled release composite fertilizer of a kind of radix scutellariae according to claim 2, it is characterised in that:Active ingredient coating urine Element, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate weight ratio be 1:12:4:0.1:1.2.
4. according to a kind of special sustained and controlled release composite fertilizer of radix scutellariae of claim 1 ~ 3 any one of them, it is characterised in that:The coating Urea is made of sulfur coated urea, quinhydrones and dicyandiamide, and wherein the mixture of quinhydrones and dicyandiamide is coated on sulfur coated urea surface, institute The content for stating quinhydrones is the 1% of sulfur coated urea, and the content of the dicyandiamide is the 10% of sulfur coated urea.
5. the special sustained and controlled release composite fertilizer of a kind of radix scutellariae according to claim 4, it is characterised in that:The quinhydrones and dicyandiamide Mixture in include sodium carboxymethylcellulose, wherein the content of sodium carboxymethylcellulose be 4%.
6. a kind of preparation method of the special sustained and controlled release composite fertilizer of radix scutellariae as claimed in claim 5, which is characterized in that including following step Suddenly:
Step 1:Coated urea is prepared, quinhydrones, dicyandiamide and sodium carboxymethylcellulose are mixed, are then coated on mixture Sulfur coated urea surface is rolled using machinery and is granulated, and dry screening is spare;
Step 2:By coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate according to weight ratio ranging from 0.5 ~ 5:5~25: 1~10:0.05~0.5:0.5 ~ 6 carries out dispensing, then uniformly mixes coated urea, calcium superphosphate, potassium sulfate, boric acid and manganese sulfate Granule is made in conjunction.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110218123A (en) * 2019-07-05 2019-09-10 商洛学院 A kind of dedicated slow release compound fertilizer of campanulaceae and preparation method thereof
CN113521089A (en) * 2021-07-21 2021-10-22 河南中医药大学 Baicalin hydrogel and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100998287A (en) * 2007-01-26 2007-07-18 贺强 Method for planting with machinery of licorice, astragalus mongholicus, kub-seng, scutellaria baicalensis, saposhnikovia divaricata, radix stellariae dichotomae
CN101367683A (en) * 2008-08-19 2009-02-18 吕庆淮 Mixed type sustained and controlled release chemical fertilizer
CN101423431A (en) * 2007-11-03 2009-05-06 寇庆德 Long acting synergistic formula fertilizer special for crops
CN102675002A (en) * 2012-06-04 2012-09-19 史丹利化肥股份有限公司 Efficient multifunctional selenium-rich fertilizer and production process thereof
CN103254023A (en) * 2013-05-06 2013-08-21 嘉施利(应城)化肥有限公司 Slow release BB (bulk blending) fertilizer and preparation method thereof
CN104250182A (en) * 2014-07-02 2014-12-31 安徽拜尔福生物科技有限公司 Controlled release BB fertilizer
CN104262063A (en) * 2014-07-02 2015-01-07 安徽拜尔福生物科技有限公司 A controlled-release BB fertilizer
CN105461410A (en) * 2014-08-19 2016-04-06 青岛炜烨锻压机械有限公司 Mixed sustained and controlled release chemical fertilizer and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100998287A (en) * 2007-01-26 2007-07-18 贺强 Method for planting with machinery of licorice, astragalus mongholicus, kub-seng, scutellaria baicalensis, saposhnikovia divaricata, radix stellariae dichotomae
CN101423431A (en) * 2007-11-03 2009-05-06 寇庆德 Long acting synergistic formula fertilizer special for crops
CN101367683A (en) * 2008-08-19 2009-02-18 吕庆淮 Mixed type sustained and controlled release chemical fertilizer
CN102675002A (en) * 2012-06-04 2012-09-19 史丹利化肥股份有限公司 Efficient multifunctional selenium-rich fertilizer and production process thereof
CN103254023A (en) * 2013-05-06 2013-08-21 嘉施利(应城)化肥有限公司 Slow release BB (bulk blending) fertilizer and preparation method thereof
CN104250182A (en) * 2014-07-02 2014-12-31 安徽拜尔福生物科技有限公司 Controlled release BB fertilizer
CN104262063A (en) * 2014-07-02 2015-01-07 安徽拜尔福生物科技有限公司 A controlled-release BB fertilizer
CN105461410A (en) * 2014-08-19 2016-04-06 青岛炜烨锻压机械有限公司 Mixed sustained and controlled release chemical fertilizer and preparation method thereof

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
《中国中医药年鉴•学术卷》编辑委员: "《中国中医药年鉴 2015学术卷》", 31 January 2016, 上海:上海辞书出版社 *
巴闯等: "包膜/抑制剂联合调控对农田土壤N2O排放和氨挥发的影响", 《农业环境科学学报》 *
滕训辉 等: "《黄芩生产加工适宜技术》", 30 November 2017, 北京:中国医药科技出版社 *
石家庄工商行政管理局: "《石家庄风物•特产篇》", 31 March 2018, 石家庄:河北人民出版社 *
罗光明等: "《药用植物栽培学》", 31 January 2013, 上海:上海科学技术出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110218123A (en) * 2019-07-05 2019-09-10 商洛学院 A kind of dedicated slow release compound fertilizer of campanulaceae and preparation method thereof
CN113521089A (en) * 2021-07-21 2021-10-22 河南中医药大学 Baicalin hydrogel and preparation method thereof

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Application publication date: 20180918