CN108544138A - A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel and preparation method thereof - Google Patents
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel and preparation method thereof Download PDFInfo
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- CN108544138A CN108544138A CN201810703369.7A CN201810703369A CN108544138A CN 108544138 A CN108544138 A CN 108544138A CN 201810703369 A CN201810703369 A CN 201810703369A CN 108544138 A CN108544138 A CN 108544138A
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- Prior art keywords
- superelevation
- high fluorine
- vessel
- sintered flux
- type sintered
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3603—Halide salts
- B23K35/3605—Fluorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/362—Selection of compositions of fluxes
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Nonmetallic Welding Materials (AREA)
Abstract
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel and preparation method thereof, solder flux contains ingredient and is by mass percentage：CaF2：50~60%, TiO2：40~50%；The mass percent summation of each component is 100%；Preparation method：1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel after weighing each raw material, is uniformly mixed, and dry-mixed raw material is made, then waterglass and dry-mixed raw material are carried out wet mixing, wet mixed feed is made；2) wet mixed feed be granulated obtaining low temperature drying after semi-finished product；3) semi-finished product are sintered, the high fluorine-type sintered flux of superelevation titanium peculiar to vessel is made；The present invention high fluorine-type sintered flux of superelevation titanium peculiar to vessel, the property of welded joint index obtained by postwelding are as follows：Tensile strength intensity is 662~743MPa, and (40 DEG C) of low-temperature impact work is 65~89J.
Description
Technical field
The invention belongs to welding technology field, the high fluorine-type sintered flux of specifically a kind of superelevation titanium peculiar to vessel and its preparation side
Method.
Background technology
Submerged arc flux is one of main consumable material of submerged-arc welding, and Resistance of Weld Metal plays machinery and protects in the welding process
Shield, Metallurgical processing and the effect for improving welding technological properties, the welding technological properties and chemical metallurgy performance of solder flux are to determine weldering
An important factor for stitching metal quality.Compared to fysed flux, sintered flux is with sintered flux with low energy consumption, basicity adjustable range
Greatly, easy deoxidation, the advantages that being easy to alloying, being readily produced.Acidic oxide content is less in the high fluorine-type sintered flux of superelevation titanium,
Solder flux oxidisability is weak, and anti-stomata ability is strong, is conducive to the weld metal for obtaining high/low temperature toughness.To meet industrialized production to property
Can excellent solder flux pressing needs, it is necessary to prepare a kind of function admirable, can realize weld metal intensity and high low temperature
Toughness, while there is smooth welding bead, the high fluorine-type sintered flux of the good removability of slag.
Invention content
In view of the deficiencies of the prior art, the present invention provides a kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel and its preparation sides
Method；The present invention meets pressing needs of the deck of boat steel welding technology to the solder flux of function admirable, have developed a kind of welding process it is stable,
Weld metal high strength, low-temperature flexibility is high, composition of weld line and even tissue, welding bead surface are smooth, the removability of slag can good high fluorine
Type sintered flux.
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel is by mass percentage containing ingredient：：CaF2：50~60%,
TiO2：40~50%；The mass percent summation of each component is 100%.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel, the property of welded joint index obtained by postwelding are as follows：Tension is strong
Degree intensity is 662~743MPa, and (- 40 DEG C) of low-temperature impact work is 65~89J.
The preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel of the present invention, includes the following steps：
Step 1, batch mixing：
(1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel after weighing each raw material, is uniformly mixed, and is made dry
Mixed raw material；
(2) in mass ratio, waterglass：Waterglass and dry-mixed raw material are carried out wet mixing, are made by dry-mixed raw material=20~30%
Wet mixed feed；
Step 2, it is granulated：
(1) wet mixed feed is once granulated, it is semi-finished product to choose the particle that granularity is 16~50 mesh；
(2) granularity is more than to the particle of 50 mesh, is crushed, granularity is less than to the particle of 16 mesh, then is granulated, is returned
Step 2 (2), until whole particles become semi-finished product；
(3) by semi-finished product in 200~400 DEG C of low temperature dryings；
Step 3, it is sintered：
Semi-finished product are sintered, sintering temperature is 300~700 DEG C, 2~5h of sintering time, and it is high that superelevation titanium peculiar to vessel is made
Fluorine-type sintered flux.
The preparation method of the above-mentioned high fluorine-type sintered flux of superelevation titanium peculiar to vessel, wherein：
In the step 1 (1), each raw material is put into mixing equipment, is stirred evenly.
In the step 1 (2), waterglass is sodium silicate.
In the step 2 (3), drying uses tube furnace.
In the step 2 (3), 2~3h of drying time.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel, before welding need to be at 300~500 DEG C, drying >=2h.Drying is adopted
It is dried with drying box.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel and preparation method thereof of the present invention, compared with prior art, advantageous effect
For：
The present invention, which is prepared for a kind of high fluorine-type sintered flux of New Marine superelevation titanium, can be well matched with low-carbon and low-alloy
Ship steel obtains uniform composition of weld line, good weld strength and low-temperature flexibility.Weld metal welding bead is smooth, and the removability of slag is good
It is good, through ray detection zero defect, it disclosure satisfy that the technological requirement of welding.
Specific implementation mode
Embodiment 1
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel is by mass percentage containing ingredient：：CaF2：55%, TiO2：
45%.
The preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel of the present invention, includes the following steps：
Step 1, batch mixing：
(1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel is put into mixing equipment after weighing each raw material, stirs
It mixes uniformly, dry-mixed raw material is made；
(2) in mass ratio, waterglass：Waterglass and dry-mixed raw material are carried out wet mixing, wet mixing are made by dry-mixed raw material=22%
Material；Wherein, waterglass is sodium silicate；
Step 2, it is granulated：
(1) wet mixed feed is once granulated, it is semi-finished product to choose the particle that granularity is 16~50 mesh；
(2) granularity is more than to the particle of 50 mesh, is crushed, granularity is less than to the particle of 16 mesh, then is granulated, is returned
Step 2 (2), until whole particles become semi-finished product；
(3) by semi-finished product in 300 DEG C of low temperature drying 2h；
Step 3, it is sintered：
Semi-finished product are sintered, sintering temperature is 400 DEG C, sintering time 2.5h, and the high fluorine-type of superelevation titanium peculiar to vessel is made and burns
Tie solder flux.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel manufactured in the present embodiment uses drying box at 300 DEG C before welding, drying
2h；Then, the fysed flux cooperation low-carbon type welding wire after drying welds EH36 grades of ship steels, the welding obtained by postwelding
Joint performance index is as follows：Tensile strength intensity is 663MPa, and (- 40 DEG C) of low-temperature impact work is 67J, and composition of weld line is uniform, weldering
Road is smooth, and the removability of slag can be good.
Embodiment 2
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel is by mass percentage containing ingredient：：CaF2：54%, TiO2：
46%.
The preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel of the present invention, includes the following steps：
Step 1, batch mixing：
(1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel is put into mixing equipment after weighing each raw material, stirs
It mixes uniformly, dry-mixed raw material is made；
(2) in mass ratio, waterglass：Waterglass and dry-mixed raw material are carried out wet mixing, wet mixing are made by dry-mixed raw material=23%
Material；Wherein, waterglass is sodium silicate；
Step 2, it is granulated：
(1) wet mixed feed is once granulated, it is semi-finished product to choose the particle that granularity is 16~50 mesh；
(2) granularity is more than to the particle of 50 mesh, is crushed, granularity is less than to the particle of 16 mesh, then is granulated, is returned
Step 2 (2), until whole particles become semi-finished product；
(3) by semi-finished product in 400 DEG C of low temperature drying 3h；
Step 3, it is sintered：
Semi-finished product are sintered, sintering temperature is 600 DEG C, sintering time 2h, and the high fluorine-type sintering of superelevation titanium peculiar to vessel is made
Solder flux.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel manufactured in the present embodiment uses drying box 300~500 before welding
DEG C, drying >=2h；Then, the fysed flux cooperation low-carbon type welding wire after drying welds EH36 grades of ship steels, postwelding
The property of welded joint index of gained is as follows：Tensile strength intensity is 683MPa, and (- 40 DEG C) of low-temperature impact work is 81J, weld seam at
Divide uniformly, welding bead is smooth, and the removability of slag can be good.
Embodiment 3
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel is by mass percentage containing ingredient：：CaF2：58%, TiO2：
42%.
The preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel of the present invention, includes the following steps：
Step 1, batch mixing：
(1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel is put into mixing equipment after weighing each raw material, stirs
It mixes uniformly, dry-mixed raw material is made；
(2) in mass ratio, waterglass：Waterglass and dry-mixed raw material are carried out wet mixing, wet mixing are made by dry-mixed raw material=26%
Material；Wherein, waterglass is sodium silicate；
Step 2, it is granulated：
(1) wet mixed feed is once granulated, it is semi-finished product to choose the particle that granularity is 16~50 mesh；
(2) granularity is more than to the particle of 50 mesh, is crushed, granularity is less than to the particle of 16 mesh, then is granulated, is returned
Step 2 (2), until whole particles become semi-finished product；
(3) by semi-finished product in 200 DEG C of low temperature drying 3h；
Step 3, it is sintered：
Semi-finished product are sintered, sintering temperature is 700 DEG C, sintering time 3h, and the high fluorine-type sintering of superelevation titanium peculiar to vessel is made
Solder flux.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel manufactured in the present embodiment uses drying box at 300 DEG C before welding, drying
4h；Then, the fysed flux cooperation low-carbon type welding wire after drying welds EH36 grades of ship steels, the welding obtained by postwelding
Joint performance index is as follows：Tensile strength intensity is 723MPa, and (- 40 DEG C) of low-temperature impact work is 81J, and composition of weld line is uniform, weldering
Road is smooth, and the removability of slag can be good.
Embodiment 4
A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel is by mass percentage containing ingredient：：CaF2：53%, TiO2：
47%.
The preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel of the present invention, includes the following steps：
Step 1, batch mixing：
(1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel is put into mixing equipment after weighing each raw material, stirs
It mixes uniformly, dry-mixed raw material is made；
(2) in mass ratio, waterglass：Waterglass and dry-mixed raw material are carried out wet mixing, wet mixing are made by dry-mixed raw material=24%
Material；Wherein, waterglass is sodium silicate；
Step 2, it is granulated：
(1) wet mixed feed is once granulated, it is semi-finished product to choose the particle that granularity is 16~50 mesh；
(2) granularity is more than to the particle of 50 mesh, is crushed, granularity is less than to the particle of 16 mesh, then is granulated, is returned
Step 2 (2), until whole particles become semi-finished product；
(3) by semi-finished product in 400 DEG C of low temperature drying 2h；
Step 3, it is sintered：
Semi-finished product are sintered, sintering temperature is 700 DEG C, sintering time 5h, and the high fluorine-type sintering of superelevation titanium peculiar to vessel is made
Solder flux.
The high fluorine-type sintered flux of superelevation titanium peculiar to vessel manufactured in the present embodiment uses drying box at 500 DEG C before welding, drying
2h；Then, the fysed flux cooperation low-carbon type welding wire after drying welds EH36 grades of ship steels, the welding obtained by postwelding
Joint performance index is as follows：Tensile strength intensity is 741MPa, and (- 40 DEG C) of low-temperature impact work is 88J, and composition of weld line is uniform, weldering
Road is smooth, and the removability of slag can be good.
Claims (6)
1. a kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel, which is characterized in that it contains ingredient and is by mass percentage：CaF2：50
~60%, TiO2：40~50%；The mass percent summation of each component is 100%.
2. a kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel according to claim 1, which is characterized in that the superelevation peculiar to vessel
The high fluorine-type sintered flux of titanium, the property of welded joint index obtained by postwelding are as follows：Tensile strength intensity is 662~743MPa, low
(- 40 DEG C) of warm ballistic work is 65~89J.
3. the preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel described in claim 1, which is characterized in that including walking as follows
Suddenly：
Step 1, batch mixing：
(1) composition proportion for pressing the high fluorine-type sintered flux of superelevation titanium peculiar to vessel after weighing each raw material, is uniformly mixed, dry-mixed original is made
Material；
(2) in mass ratio, waterglass: waterglass and dry-mixed raw material are carried out wet mixing, wet mixing is made by dry-mixed raw material=20~30%
Material；
Step 2, it is granulated：
(1) wet mixed feed is once granulated, it is semi-finished product to choose the particle that granularity is 16~50 mesh；
(2) granularity is more than to the particle of 50 mesh, is crushed, granularity is less than to the particle of 16 mesh, then is granulated, return to step
2 (2), until whole particles become semi-finished product；
(3) by semi-finished product in 200~400 DEG C of low temperature dryings；
Step 3, it is sintered：
Semi-finished product are sintered, sintering temperature is 300~700 DEG C, 2~5h of sintering time, and the high fluorine-type of superelevation titanium peculiar to vessel is made
Sintered flux.
4. the preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel according to claim 3, which is characterized in that the step
In rapid 1 (2), waterglass is sodium silicate.
5. the preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel according to claim 3, which is characterized in that the step
In rapid 2 (3), 2~3h of drying time.
6. the preparation method of the high fluorine-type sintered flux of superelevation titanium peculiar to vessel according to claim 3, which is characterized in that described
The high fluorine-type sintered flux of superelevation titanium, before welding need to be at 300~500 DEG C, drying >=2h.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810703369.7A CN108544138A (en) | 2018-06-30 | 2018-06-30 | A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel and preparation method thereof |
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| CN201810703369.7A CN108544138A (en) | 2018-06-30 | 2018-06-30 | A kind of high fluorine-type sintered flux of superelevation titanium peculiar to vessel and preparation method thereof |
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| CN108544138A true CN108544138A (en) | 2018-09-18 |
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|---|---|---|---|---|
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| CN104668816A (en) * | 2015-01-09 | 2015-06-03 | 天津重型装备工程研究有限公司 | Submerged-arc welding flux for low-alloy-steel narrow-gap welding and preparation method thereof |
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| CN105149817A (en) * | 2015-07-04 | 2015-12-16 | 威县亚泰密封件有限公司 | Sintering flux for submerged-arc welding of X100 pipeline steel and preparation method for sintering flux |
| CN105215576A (en) * | 2015-09-22 | 2016-01-06 | 机械科学研究院哈尔滨焊接研究所 | A kind of nickel-base strip pole submerged arc overlay welding sintered flux and manufacture method |
| CN106271218A (en) * | 2016-08-10 | 2017-01-04 | 中国船舶重工集团公司第七二五研究所 | A kind of sintered flux for the welding of ocean engineering high-strength steel and preparation method thereof |
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2018
- 2018-06-30 CN CN201810703369.7A patent/CN108544138A/en active Pending
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| CN104668816A (en) * | 2015-01-09 | 2015-06-03 | 天津重型装备工程研究有限公司 | Submerged-arc welding flux for low-alloy-steel narrow-gap welding and preparation method thereof |
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Application publication date: 20180918 |